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DOW CORNING CORPORATION
Material Safety Data Sheet
E
Page: 1 of 10
Version:3.1
24 Hour Emergency Telephone: (989) 496-5900
Customer Service: (989) 496-6000
Product Disposal lnformation: (989) 496-6315
Dow Corning Corporat¡on
South Saginaw Road
Midland, Michigan 48686
No.:
CHEMTREÇ: (800)424-9300
04093284
Kevrsr(
Generic Description: Mixture of inorganic and organìc compounds
Phys¡cal
Form: Liquid
Color: Colorless to Pale Yellow
Odor: Solvent odoÍ.
NFPA Profile:
Health
2
Flammabil¡ty
3
lnstability/React¡vity 0
POTENTIAL HEALTH EFFECTS
Acute Effects
Eye:
Direct contact may cause severe irritation.
Skin:
l\¡ay cause moderate irr¡tat¡on.
lnhalation:
Vapor and/or mist may ¡rritate respiratory tract. Overexposure by inhalat¡on may cause
drowsiness, dizzìness, confus¡on or loss of coordination.
Oral:
Asp¡ration of liquid while vomiting may injure lungs seriously
Prolonqed/Repeated Exposure Effects
Skin:
Repeated or prolonged contact may cause defatting and dry¡ng of skin which may result in
skin irritation and dermatitis. Repeated or prolonged exposure may ¡rritate serìously.
lnhalation:
No known appl¡cable information.
Oral:
Repeated ¡ngestion or swallowing large amounts may ¡njure ¡nternally
No known applìcable information.
Medical Cond¡tions Aqqravated bv Exposure
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DOW CORNTNG gORPORATTON
Material Safety Data Sheet
I
Page: 2 of 10
Version: 3.1
Revis¡on Datè: 2O12106119
No known applicable ìnformation,
The above listed potential effects of overexposure are based on actual data, results of studles performed upon similar compositions,
ínformation.
Number
647 42-89-8
%
70,0 - 90.0
'18765-38-3 3.0 - 7.0
682-01-9 3.0 - 7.0
5593-70-4 3.0 - 7.0
CAS
Wt
Component Name
Solvent naphiha (petroleum), light aliph
Butoxy ethyl orthosilicate
Tetrapropyl orthosìlicate
Titanium tetrabutanolate
The above components are hazardous as defined in 29 CFR 1910.1200.
AID
Eye:
lmmediately flush the contaminated eye(s) with lukewarm, gently flowing water for 15 - 20
minutes while holding the eyelid(s) open, lf contact lens is present, DO NOT delay irr¡gation
or attempt to remove the lens. Take care not to rinse contaminated wâter ¡nto the unaffected
eye or onto the face. lmmediately obtain medical attention.
Skin:
As quickly as possible remove contaminated clothing, shoes and leather goods (e.9.
watchbands, belts). Quickly and gently blot or brush away excess chemical. lmmedìately
flush with lukewarm gently flow¡ng water for 15 minutes. Completely decontaminate clothing,
shoes and leather goods before reuse or discard. Obta¡n medical attention.
lnhalat¡on:
Remove from the source of contaminatìon or move to fresh air. lf breathing ¡s difficult, trained
personnel should administer emergency oxygen. Obtaìn medical attention.
Oral:
Never give anfhing by mouth if victìm is rapìdly losing consciousness or convulsing. Have
vìctim rinse mouth thoroughly with water DO NOT INDUCE VOI\4|T|NG. Have victim drink 2
to B oz. (60 to 240 mL) of water. lf vomiting occurs naturally, have victim lean forward to
reduce the risk of asp¡rat¡on. Have victim rinse mouth with water again. lmmed¡ately obtain
medical attention.
Notes to
Physician:
Treat according to person's condition and specifics of exposure,
55.4'F I 13 'C (Tag Closed Cup)
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DOW CORNING CORPORATION
Material Safety Data Sheet
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Page: 3 of 10
Version: 3.1
Auto¡gnition Temperature:
Not determ¡ned.
Flammabilìty L¡mits in Air:
Not determined.
Extinguishing Media:
On large fires use dry chemical, foam or water spray. On small fires use carbon dioxìde
(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.
F¡re Fighting l\,4easures:
Self-contained breath¡ng apparatus and protective clothing should be worn in flghting large
fires involving chemicals. Determine the need to evacuate or isolate the area according to
your local emergency plan. Use water spray to keep flre exposed conta¡ners cool.
Unusual Fire Hazards:
Vapors are heavier than air and may travel to a source of ignition and flash back. Static
electrÌcìty will accumulate and may ignite vapors. Prevent a possible fÌre hazard by bond¡ng
and grounding or inert gas purge.
Remove possible ignit¡on sources. Determine whether to evacuate or ¡solate the area
according to your local emergency plan. Observe all personal protection equipmeni
recommendations described ìn Sect¡ons 5 and 8. For large spills, provide dikìng or other
appropr¡ate conta¡nment to keep mater¡aì from spreading. lf diked mater¡al can be pumped,
store recovered mater¡al in appropriate container. Clean up remaining materials from spill
with su¡tabte absorbant. Clean area as appropr¡ate sìnce spilled materials, even ìn small
quantities, may present a slip hazard. Final cleaning may requ¡re use of steam, solvents or
detergenls. Dispose of saturated absorbant or cleaning materials appropr¡ately, s¡nce
spontaneous heating may occur. Local, state and federal laws and regulations may apply to
releases and disposal of this material, as well as those materials and items employed in the
cleânup of releases, You w¡ll need to determine whìch federal, state and local laws and
regulations are appl¡cable. Sectìons 13 and 15 of this MSDS provìde informatìon regarding
certain federal and state requ¡rements.
Note: See Section
I
for Personal Protectìve Equipment for Spills. Call (989) 496-5900,
¡f
additional ìnformatìon
¡s
required.
Use w¡th adequate vent¡lation. Product evolves 2-butoxyethanol when exposed to water or humìd air. Provìde ventìlation
during use to control 2-butoxyethanol exposures within exposure guidelines or use resp¡ratory protection. Product
evolves n-propyl alcohot when exposed lo water or humid air. Provide ventilation durìng use to control n-propyl alcohol
withìn exposure guìdelines or use resp¡ratory protection. Product evolves n-butyl alcohol when exposed to water or humid
air. Provide ventilation dur¡ng use to control n-butyl alcohol within exposure gu¡delìnes or use respiratory protection.
Avoid eye contact. Avoid skin contact. Avoid breathing vapor, mist, dust, or fumes. Keep container closed Do not take
internally.
Stat¡c electricity w¡ll accumulate and may Ìgnite vapors. Prevent a possible fire hazard by bond¡ng and ground¡ng or ¡nert
gas purge. Keep conta¡ner closed and away from heat, sparks, and flame. Keep container closed and store away from
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DOW CORNING CORPORATION
Material Safety Data Sheet
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Page: 4 of 10
Version: 3.1
Rêvision Dâte
Component ExÞosure Limits
CAS
Number
64742-89-8
Component Name
Solvent naphtha (petroleum), l¡ght aliph.
Exposure Limits
Observe petroleum dist¡llates l¡m¡ts. OSHA PEL (final rule)
TWA 400 ppm.
18765-38-3 Butoxyethylorthosilicate
See 2-butoxyethanol comments.
682-0'l-9
Tetrapropylorthosilicate
See n-propyl alcohol comments.
5593-70-4
Titaniumtetrabutanolate
See n-butyl alcohol comments.
2-Butoxyethanol forms on contact with water or humid air, Provide adequate ventilat¡on to control exposures within
guidelinesof OSHA PEL-sk¡n (final rule): TWA 50 ppm, 240 mg/m3 and ACGIH TLV: TWA20ppm. n-Propyl alcohol
¡s formed upon contact with water or hum¡d a¡r. Prov¡de adequate vent¡lation to control exposures within guidelines of
OSHA PEL (final rule): TWA 200 ppm, STEL 250 ppm. ACGIH TLV: TWA 100 ppm. n-Butyl alcohol is foÍmed on
contact with water or humid air. Provide adequate vent¡lat¡on to control exposures within guidelines of OSHA PEL
(final rule): TWA'100 ppm and ACGIH TLV: 20 ppm.
Enqineerinq Controls
Ventilation:
Ventilat¡oni
Local
General
Recommended.
Recommended.
Personal Protective Equ¡pment for Routine Handlino
Eyes:
Use chemical worker's goggles.
Skin:
Wash at mealtime and end of shift, lf skin contact occurs, change contaminated clothing as
soon as possible and thoroughly flush affected areas with cool water. Chemical protective
gloves are recommended.
Suitable Gloves:
Avoid sk¡n contact by implementing good industrial hygiene practices and procedures. Select
and use gloves and/or protective clothing to further minimize the potent¡al for skin contact,
Consult with your glove and/or personnel protective equipment manufacturer for selection of
appropriate compatìble materials.
lnhalation:
Use respiratory protection unless adequate local exhaust ventìlation is provided or exposure
assessment demonstrates that exposures are within recommended exposure guidelines. lH
personnel can assist in judging the adequacy of existing engineering controls.
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DOW GORNING CORPORATION
Material Safety Data Sheet
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Su¡table Respirator
General and local exhaust ventilat¡on ìs recommended to ma¡ntain vapor exposures below
recommended l¡mits. Where concentrations are above recommended limits or are unknown,
appropriate resp¡ratory protection should be worn. Follow OSHA respirator regulatìons (29
CFR 1910.134) and use NIOSH/MSHA approved respirators.
Personal Protêctive Equiþment for Soills
Eyes:
Use full face respirator.
Skin:
Wash at mealt¡me and end of shift. lf skin contact occurs, change contaminated cloth¡ng as
soon as possible and thoroughly flush affected areas with cool water. Chemical protective
gloves are recommended.
lnhalat¡on/Su¡table
Resp¡rator:
Respiratory protect¡on recommended. Follow OSHA Resp¡rator Reguìat¡ons (29 CFR
1910.134) and use NIOSH/MHSA approved respirators. Protection provided byairpurifying
respirators aga¡nst exposure to any hazardous chem¡cal is lim¡ted. Use a positìve pressure a¡r
supplied respirator if there is any potential for uncontrolled release, exposure levels are
unknown, or any other circumstance where a¡r pur¡fy¡ng respirators may not provide adequate
protection.
fumes
Precautìonary Measures
Avoid eye contact. Avoid sk¡n contact. Avoìd breâthing vapor, mist, dust, or
container closed. Do not take internally. Use reasonable care
Comments:
Product evotves 2-butoxyethanol when exposed to water or hum¡d air. Provide vent¡lation
during use to control 2-butoxyethanol exposures within exposure guidelines or use respiratory
protection. Product evolves n-propyl alcohol when exposed to water or humid air. Prov¡de
ventìlatìon during use to control n-propyl alcoholwithin exposure guidelines or use respiratory
protection. Product evolves n-butyl alcohol when exposed to water or humid a¡r, Provide
ventilation during use to control n-butyl alcohol w¡thÌn exposure guidelines or use respiratory
Keep
Protection.
Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require
added precautions, For further ìnformatton regarding aerosol ¡nhalation toxicity, please refer to the guidance document regarding the
use of silicone-based materials in aerosol appìications that has been developed by the sìlicone industry (www.SÊHSC.com) or contact
cLrstomer service
Physical Form:
Liq uid
Color: Colorless to pale yellow
Odor: Solvent odor.
Specific Grav¡ty @ 25'C: 0.76
Viscosity: 1mm2/s
Freezing/Melt¡ng Point: Not deteÍmined.
Boiling Point: >80'c
Vapor Pressure @ 25"C: Not determined.
Vapor Density: Not determ¡ned.
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DOW CORNING CORPORATION
Material Safety Data Sheet
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Page: 6 of 10
Version:3.1
Revis¡on Date: 2012106119
Soìubility ¡n Water: Not determined.
pH: Not determined.
Volatile Content: Not determìned.
Flash Point: 55.4'F I 13 'C (Tag Closed Cup)
Autoignition Temperature: Not determined.
Flammabil¡ty Limits in Air: Not determ¡ned.
Note: The above information is not intended for use in preparìng product specifications. Contact Dow Corn¡ng before writing
Stability:
Hazardous
Polymer¡zation:
Conditìons to Avoid:
l\4ater¡als to Avoìd:
Chemical
Stable.
Hazardous polymer¡zâtion will not occur.
None.
Ox¡dìzing material can cause a react¡on. Water, moisture, or humid air can cause hazardous
vapors to form as described ¡n Section 8.
Hazardous Decomoosition Products
Thermal breakdown of this product during fìre or very hìgh heat conditions may evolve the following decomposition
products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Metal oxides.
Formaldehyde.
Complete information is not yet availabìe.
Env¡ronmental Effects
Complete information ¡s not yet available,
Fate and Effects ¡n Waste Water Treatment Plants
Complete information ¡s not yet ava¡lable.
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DOW CORNING CORPORATION
Material Safety Data Sheet
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Pâge: 7 of 10
Vers¡on: 3.1
Revision Date: 2012106119
Parameters (LC50 or EC50)
Acute Aquatic Toxiciiy (mg/L)
>1 and <=100
>100 and <= 2000
table is adapted from "Environmental Toxicolooy and R¡sk Assessment", ASTM STP 1179, p.34,
This table can be used
10
classify the ecotoxicity ofthìs product when ecotoxicity data is l¡sted above. Please read the other information presented ìñ the
DOT Road Sh¡pment lnformation (49 CFR 172.1011
Proper Shipping
Name:
Hazard Technical
Name:
Flammable liquids, n.o-s.
Petroleum distillates / Tetrabutyl titanate
Hazard Class:
3
UN/NA Number
uN 1993
Group:
Hazard Label(s):
Packing
Proper Shipping
Name:
Hazard Technical
Hazard
Glass:
Name:
ll
Flammable Liquid
FLAMI\,'IABLE LIOUID, N.O.S.
Petroleum distillates / Tetrabutyl tìtanate
3
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DOW CORNING CORPORATION
Material Safety Data Sheet
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Page: I of 10
Version: 3.1
Rev¡sion Date: 2O12106119
UN/NA Number:
uN 1993
Packing Group:
lt
Hazard Label(s):
flammable liquid
Air Shipment (IATA)
Proper Shipp¡ng
Name:
Hazard Technical
Name:
Flammable l¡quid, n.o.s.
Petroleum distillates / Tetrabutyl titanate
Hazard Class:
UN/NA Number:
uN 1993
Packing Group:
Hazard Label(s)
Flammable Liqu¡d
Call Dow Corning Transportat¡on, (989) 496-8577, if additional ¡nformat¡on is requ¡red,
Contents of this [/SDS complywith the OSHA Hazard Communicatìon Standard 29 CFR 1910.1200.
TSCA Status:
All chemical substances in this materìal are ¡ncluded on or exempted from listìng on the TSCA
lnventory of Chemical Substances.
EPA SARA Title lll Chemical Listinqs
Section 302 Extremely Hazardous Substances (40 CFR 355):
None.
Section 304 CERGLA Hazardous Substances (40 GFR 302):
None.
Sect¡on 311/312 Hazard Class (40 CFR 370):
Acute: Yes
Chronic: No
Fire: Yes
Pressure: No
Reactive: No
Sect¡on 313 Tox¡c Chemicals (40 CFR 372):
None present or none present in regulated quantities.
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DOW CORNING CORPORATION
Material Safety Data Sheet
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.
Page: 9 of 10
Version: 3.1
RevisionDate: 2012106119
Note: Chemicals are listed under the 313 Toxic Chemlcals section only
¡f
they meet or exceed a report¡ng threshold.
California
Warning: This product conta¡ns the following chem¡cal(s) listed by the State of California under the Safe Þrinking Water
and Toxic Enforcement Act of 1986 (Propos¡tion 65) as being known to cause cancer, b¡rth defects or other
reproductive harm.
Number
Wt%
108-88-3
<0.'1000
Toluene
Deveìopmental toxin
100-41-4
<0.1000
Ethylbenzene
Carc¡nogenic.
CAS
Component Name
Massachusetts
No ¡ngredient regulated by N/A Right-to-Know Law present.
New Jersey
%
64742-89-8 70.0 - 90.0
18765-38-3 3.0 - 7.0
682-01-9 3.0 - 7.0
5593-70-4 3.0 - 7.0
CAS
Number
Wt
Comþonent Name
Solvent naphtha (petroleum), light alìph
Butoxy ethyl orthos¡licate
Tetrapropyl orthosilicate
Titanium tetrabutanolate
Pennsylvan¡a
cAS Number
64742-89-8
18765-38-3
682-01-9
5593-70-4
%
70.0 - 90.0
3.0 - 7.0
3.0 - 7.0
3.0 - 7.0
Wt
Component Name
Solvent naphtha (petroleum), light al¡ph.
Butoxy ethyl orthosilicate
Tetrapropyl orthosilicate
Titan¡um tetrabutanolate
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DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 10 of 10
Version: 3.1
Revision Date: 2012106119
Prepared by: Dow Corning Corporation
These data are offered in good fa¡th as typicalvalues and not as product specificatìons. No warranty, eìther expressed or
implied, ìs hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally
applicable. However, each user should review these recommendations in the spec¡fic context of the intended use and
determine whether they are appropr¡ate.
(R) indicates Registered Trademark