MATERIAL SAFETY DATA SHEET
D44 Chlorine Sanitizer
HMIS
Health
Fire Hazard
Reactivity
3
0
0
NFPA
3
0
0
Personal protective equipm ent
Version Number: 1
Preparation date: 2009-04-24
1.
PRODUCT AND COMPANY IDENTIFICATION
Product nam e:
D44 Chlorine Sanitizer
MSDS #:
Product Code:
Recom m ended use:
MS0100782
3037765
Chlorine Sanitizer. This product is intended to be diluted prior to use.
Manufacturer, im porter, supplier:
US Headquarters
JohnsonDiversey, Inc.
8310 16th St.
Sturtevant, Wisconsin 53177-1964
Phone: 1-888-352-2249
MSDS Internet Address:
w w w .johnsondiversey.com
Em ergency telephone num ber:
Canadian Headquarters
JohnsonDiversey - Canada, Inc.
2401 Bristol Circle
Oakville, Ontario L6H 6P1
Phone: 1-800-668-3131
1-800-851-7145 (U.S.); 1-651-917-6133 (Int'l)
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER. CORROSIVE. CAUSES SKIN AND EYE BURNS. HARMFUL OR FATAL IF SWALLOWED.
Principle routes of exposure:
Eye contact:
Skin contact:
Inhalation:
Ingestion:
Eye contact. Skin contact. Inhalation. Ingestion.
Corrosive. Causes permanent eye damage, including blindness.
Corrosive. Causes permanent damage.
May cause irritation and corrosive effects to nose, throat and respiratory tract.
Corrosive. Causes burns to mouth, throat and stomach.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ingredients
Ingredient(s)
Sodium hypochlorite
CAS #
Weight %
7681-52-9
10 - 20%
LD50 Oral - Rat
(m g/kg)
8200
LD50 Derm al Rabbit
>10000 mg/kg
LC50 Inhalation Rat
Not available
4. FIRST AID MEASURES
Eye contact:
Skin contact:
Inhalation:
Ingestion:
Aggravated Medical Conditions:
Immediately flush eyes w ith running w ater for 15-20 minutes, keeping eyelids open. Get medical
attention immediately.
Immediately flush w ith plenty of w ater for 15-20 minutes . Get medical attention immediately.
If breathing is affected, remove to fresh air. Get medical attention immediately.
If sw allow ed, rinse mouth. Give a cupful of w ater or milk . THEN IMMEDIATELY CONTACT A PHYSICIAN
OR POISON CENTER. DO NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person.
Individuals w ith chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc., may
be more susceptible to irritating effects.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing m edia:
Specific hazards:
Unusual hazards:
Specific m ethods:
The product is not flammable. Extinguish fire using agent suitable for surrounding fire.
Thermal decomposition can lead to release of irritating gases and vapors.
Corrosive material (See sections 8 and 10).
No special methods required
Special protective equipm ent for firefighters: As in any fire, w ear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear.
Extinguishing m edia w hich m ust not be used for safety reasons: None.
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6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Environm ental precautions
and clean-up m ethods:
Put on appropriate personal protective equipment (see Section 8.). Ensure adequate ventiliation.
Use appropriate containment to avoid environmental contamination. Absorb spill w ith inert material (e.g.
dry sand or earth), then place in a chemical w aste container. Use a w ater rinse for final clean-up.
7. HANDLING AND STORAGE
Handling:
Avoid contact w ith skin, eyes and clothing. Do not taste or sw allow . Avoid breathing vapors or mists. Use only w ith adequate ventilation. Remove
and w ash contaminated clothing and footw ear before re-use. Wash thoroughly after handling. Mix only w ith w ater . DO NOT MIX WITH ACIDS,
TOILET BOWL CLEANERS, AMMONIA, OR ANY OTHER CHEMICAL . Can react to release chlorine gas . Product residue may remain on/in empty
containers. All precautions for handling the product must be used in handling the empty container and residue. FOR COMMERCIAL AND INDUSTRIAL
USE ONLY.
Storage:
Protect from freezing. Keep tightly closed in a dry, cool and w ell-ventilated place. KEEP OUT OF REACH OF CHILDREN.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering m easures to reduce exposure:
Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not required if good ventilation is maintained.
Personal Protective Equipm ent
Eye protection:
Hand protection:
Skin and body protection:
Respiratory protection:
Hygiene m easures:
Chemical-splash goggles.
Chemical-resistant gloves
Protective footw ear. If major exposure is possible, w ear suitable protective clothing and footw ear.
In case of insufficient ventilation w ear suitable respiratory equipment. A respiratory protection program
that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be follow ed w henever
w orkplace conditions w arrant a respirator's use.
Handle in accordance w ith good industrial hygiene and safety practice
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State:
pH:
Appearance:
Color:
Odor:
Specific gravity:
Density:
VOC:
Flash point:
Solubility:
Viscosity:
Liquid
12
Aqueous solution
Clear Yellow Green
Chlorine
1.175
9.8 lbs/gal Kg/L
0% *
>200°F >93.4°C
Completely Soluble
No information available
Bulk density:
No information available
Dilution pH:
11 @ 1:100
Vapor density:
No information available
Evaporation Rate
No information available
Boiling point/range:
Not determined
Melting point/range:
Not determined
Decom position tem perature:
Not determined
Autoignition tem perature:
No information available
Partition coefficient (n-octanol/w ater): No information available
Solubility in other solvents:
No information available
Elem ental Phosphorus: 0% by w t.
* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508
10. STABILITY AND REACTIVITY
Stability:
Polym erization:
Hazardous decom position products:
Materials to avoid:
Conditions to avoid:
The product is stable
Hazardous polymerization does not occur
Chlorine.
Do not mix w ith any other product or chemical. Ammonia. Strong acids. Reducing agents.
Strong sunlight for prolonged periods..
11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Com ponent Inform ation:
Corrosive
Oral LD50 estimated to be betw een 500 - 2000 mg/kg
Dermal LD50 estimated to be > 2000 mg/kg
See Section 3
Chronic toxicity:
None know n
Specific effects
Carcinogenic effects:
Mutagenic effects:
Reproductive toxicity:
Target organ effects:
None know n
None know n
None know n
None know n
Hazardous ingredients
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11. TOXICOLOGICAL INFORMATION
Ingredient(s)
Sodium hypochlorite
CAS #
7681-52-9
NTP
IARC
3
OSHA
12. ECOLOGICAL INFORMATION
Environm ental Inform ation:
No data available
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products:
Undiluted product is regulated under environmental and transportation law s as a corrosive w aste. Dispose of in compliance w ith all Federal, state,
provincial, and local law s and regulations..
RCRA Hazard Class: D002
14. TRANSPORT INFORMATION
DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information
15. REGULATORY INFORMATION
International Inventories
All components of this product are listed on the follow ing inventories: U.S.A. (TSCA), Canada (DSL), Europe (EINECS/ELINCS/NLP), Australia (AICS),
Korea (ECL), Japan (ENCS), Philippines (PICCS), New Zealand (NZIoC), China (IECSC).
U.S. Regulations
California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65
STATE RIGHT TO KNOW
Ingredient(s)
Sodium chloride
Sodium hypochlorite
Water
CAS #
7647-14-5
7681-52-9
7732-18-5
CERCLA/ SARA
Ingredient(s)
Sodium hypochlorite
CAS #
7681-52-9
MARTK:
X
-
Weight %
10 - 20%
NJRTK:
X
-
CERCLA/SARA RQ (lbs)
100
PARTK:
X
-
Section 302 TPQ (lbs)
RIRTK:
-
Section 313
CAA HAP/CAA ODS/CWA Priority Pollutants: None
SARA 311/312 Hazard Categories
Im m ediate:
Delayed:
Fire:
Reactivity:
Sudden Release of Pressure:
x
-
Canada
WHMIS hazard class: E Corrosive material .
16. OTHER INFORMATION
Reason for revision:
Prepared by:
Additional advice:
Not applicable
NAPRAC
None
Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty,
express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User
is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and
Local laws and regulations.
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