Atomic Models Democritus to Rutherford 10/8/2005 Atomic Models: Democritus~~Rutherford 2 1 10/8/2005 Atomic Models: Democritus~~Rutherford 3 Democritus Atomic Theory 1) 2) 3) 4) 5) 10/8/2005 All matter is composed of atoms, which are bits of matter too small to be seen These atoms CANNOT be further split into smaller portions There is a void, which is empty space between atoms Atoms are completely solid Atoms are homogeneous, with no internal structure Atoms are different in their sizes, shapes, weight, arrangement, position… Atomic Models: Democritus~~Rutherford 4 2 John Dalton (1766~~1844) ¾ A New System of Chemical Philosophy ¾ Developed the first useful atomic theory of matter ¾ Gifted in for recognizing and interpreting patterns in experimental data ¾ First to associate the idea of atoms with stoichiometry 10/8/2005 Atomic Models: Democritus~~Rutherford 5 10/8/2005 Atomic Models: Democritus~~Rutherford 6 3 Dalton’s Atomic Model 1. 2. 3. 4. 10/8/2005 All matter consists of tiny particles Atoms are indestructible and unchangeable Elements are characterized by the mass of their atoms When elements react, their atoms combine in simple, whole-number ratios Atomic Models: Democritus~~Rutherford 7 J. J. Thomson ( 1856~~1940) Discovered electrons in 1891. Cathode ray tubes 10/8/2005 Atomic Models: Democritus~~Rutherford 8 4 A Cathode Ray Tube 10/8/2005 Atomic Models: Democritus~~Rutherford 9 10/8/2005 Atomic Models: Democritus~~Rutherford 10 5 10/8/2005 Atomic Models: Democritus~~Rutherford Rutherford 11 (1871~~1937) Discovered the nucleus in 1911 The gold foil experiment 10/8/2005 Atomic Models: Democritus~~Rutherford 12 6 10/8/2005 Atomic Models: Democritus~~Rutherford 13 10/8/2005 Atomic Models: Democritus~~Rutherford 14 7 Rutherford’s solution to the enigma of explaining both large- and small-angle scattering, was the nucleus 10/8/2005 Atomic Models: Democritus~~Rutherford 15 All Rutherford had to do was explain how it all fit together Well established that atomic radius is 10-8 cm Thomson model spread the entire mass of the atom throughout that space Rutherford put most of the mass of the atom at the center of the atom, in a space much, much smaller that the atom itself this is the nucleus 10/8/2005 Atomic Models: Democritus~~Rutherford 16 8 10/8/2005 Atomic Models: Democritus~~Rutherford 17 10/8/2005 Atomic Models: Democritus~~Rutherford 18 9 Empty space!! If an atom were the size of a baseball stadium, The nucleus would be the size of a PEA 10/8/2005 Atomic Models: Democritus~~Rutherford 19 Structure of the Nucleus 10/8/2005 Atomic Models: Democritus~~Rutherford 20 10 A Model of Helium 2 protons 2 neutrons 2 electrons 10/8/2005 Atomic Models: Democritus~~Rutherford 21 Elements Chart Element Symbol Atomic # Atomic Mass Mass # # Protons # Electrons # Neutrons H 1 1.008 1 1 1 0 He 2 4.003 4 2 2 2 O 8 N 7 C 6 F 9 P 15 Sn 50 C-14 6 10/8/2005 Atomic Models: Democritus~~Rutherford 22 11 10/8/2005 Atomic Models: Democritus~~Rutherford 23 Isotopes Same Atomic Number, Different Atomic Mass Same # of Protons, Different # of Neutrons Hydrogen: Heavy Hydrogen 1 proton, 0 neutrons 1 proton, 1 neutron (Deuterium): Heavier Hydrogen (Tritium): Carbon~12: Carbon~14: 10/8/2005 1 proton, 2 neutrons 6 protons, 6 neutrons 6 protons, 8 neutrons Atomic Models: Democritus~~Rutherford 24 12 Alkali Metals Boron Family Nitrogen Family Halogens Alkaline Earth Metals Carbon Family Oxygen Family Atomic Models: 10/8/2005 Transition Metals Noble Gases25 Democritus~~Rutherford gas liquid 10/8/2005 Atomic Models: Democritus~~Rutherford 26 13 Source of Images and Text http://antoine.frostburg.edu/chem/senese /101/atoms/dalton.shtml http://dbhs.wvusd.k12.ca.us/RutherfordModel.html 10/8/2005 Atomic Models: Democritus~~Rutherford 27 14
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