Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1
1.2
1.3
1.4
Product identifier
Product Name
Nitric Acid <65%
Alternative Name(s)
Aqua fortis, Azotic acid.
Chemical Formula
HNO3.
CAS No.
7697-37-2.
EINECS No.
231-714-2.
REACH Registration No.
01-2119487297-23-0020.
Relevant identified uses of the substance or mixture and uses advised against
Identified use(s)
See Section: 7.3.
Uses advised against
Any consumer use with concentration >5%.
Details of the supplier of the Safety Data
Sheet
Company Identification
CF Fertilisers UK Limited (formerly GrowHow UK Ltd)
Ince, Chester CH2 4LB.
Telephone
+44 (0) 151 357 2777
Fax
+44 (0) 151 357 1755
E-mail
[email protected]
Emergency telephone number
Emergency Phone No.
+44 (0)1642 542824
E-mail
[email protected]
SECTION 2: HAZARDS IDENTIFICATION
2.1
2.1.1
Classification of the substance or mixture
Regulation (EC) No. 1272/2008 (CLP)
Skin Corr. 1A; Causes severe skin burns and eye damage.
Met. Corr. 1; May be corrosive to metals.
Corrosive to the respiratory tract.
2.1.2
Directive 67/548/EEC & Directive
1999/45/EC
2.2
Label elements
According to Regulation (EC) No. 1272/2008 (CLP).
Trade name
Nitric Acid
C Corrosive; Causes severe burns.
Hazard Pictogram
Signal word(s)
GHS05
Danger.
Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
Hazard statement(s)
H314: Causes severe skin burns and eye damage.
H290: May be corrosive to metals.
EUH071: Corrosive to the respiratory tract.
Precautionary statement(s)
P234, P260, P264, P280, P301 + P330 + P331, P305 + P351 + P338, P303 + P361 + P353,
P363, P304 + P340, P310, P390, P404, P406, P501.
According to Directive 67/548/EEC & Directive 1999/45/EC.
Hazard Symbol
Risk Phrases
R35: Causes severe burns.
Safety Phrases
S1/2, S23, S26, S36, S45.
2.3
Other hazards
None.
2.4
Additional Information
For full text of H/P phrases see section 16.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Mixture
EC Classification No. 1272/2008
Hazardous
%W/W
CAS No.
ingredient(s)
Nitric acid
<65%
7697-37-2
EC Classification No. 67/548/EEC
Hazardous
%W/W
ingredient(s)
Nitric acid
20%≤Conc<70%
EC No.
REACH Registration No.
231-714-2
01-2119487297-23-0020
CAS No.
EC No.
7697-372
231714-2
Hazard pictogram(s) and
Hazard statement(s)
GHS03, Ox. Liq. 3; H272,
GHS05, Skin Corr. 1A; H314,
Met. Corr. 1; H290, EUH071.
EC Classification and
Risk Phrases
O; R8, C; R35.
3.2 Additional Information
For full text of H/P phrases see section 16.
SECTION 4: FIRST AID MEASURES
Speed is essential. Get medical attention immediately. Self-protection of the first aider. (See Section: 7). Remove patient from exposure.
Guarantee that the eye flushing systems and safety showers are located close to the working place.
4.1
Description of first aid measures
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Apply artificial respiration if breathing has ceased or shows signs of failing. Administer oxygen if
available.
Skin Contact
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Wash contaminated clothing before reuse.
Eye Contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
Ingestion
IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTRE or
doctor/physician.
4.2
Most important symptoms and effects,
both acute and delayed
Causes severe burns. Fluid build-up in lungs may cause shortness of breath after severe
exposure causing acute pulmonary oedema.
4.3
Indication of immediate medical
attention and special treatment needed
Due to possible delayed effect of poisoning, persons who have inhaled the vapour or the fumes
produced in a fire must be kept under medical observation for at least 48 hours.
SECTION 5: FIRE-FIGHTING MEASURES
5.1
Extinguishing Media
Suitable Extinguishing Media
Water and Carbon dioxide.
Unsuitable Extinguishing Media
Do not use dry chemical or foam. Do not attempt to smother the fire with sand or steam.
5.2
Special hazards arising from the
substance or mixture
Decomposes in a fire giving off toxic fumes: Nitrogen oxides.
Explosive when mixed with strong reducing agents. Reacts with most common metals to liberate
hydrogen which can form explosive mixtures with air.
5.3
Advice for fire-fighters
Fire fighters should wear complete protective clothing including self-contained breathing
apparatus. Keep fire exposed containers cool by spraying with water.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1
Personal precautions, protective
equipment and emergency procedures
For non-emergency personnel
Evacuate surrounding areas. Do not touch or walk through spilt material. Shut off all ignition
sources in hazard area. Wear appropriate personal protective equipment, avoid direct contact with
vapour, mist or spilt material. Provide adequate ventilation, and wear appropriate respirator when
ventilation is inadequate.
For emergency responders
If specialized clothing is required to deal with a release, take note of information in section 8 on
suitable materials. See ‘non-emergency personnel’ above.
6.2
Environmental precautions
Avoid contact of spilt material and runoff with soil, waterways, drains and sewers. Spillages or
uncontrolled discharges into watercourses must be alerted to the appropriate regulatory body.
6.3
Methods and material for containment
and cleaning up
Small spillages
Large spillages
6.4
Reference to other sections
Stop leak if without significant risk. Dilute with water. Neutralise carefully with anhydrous sodium
carbonate, a solution of sodium carbonate or lime. Transfer to a suitable container for disposal.
Stop leak if without significant risk. Approach the release form upwind. Prevent entry into sewers,
water courses, basements or confined areas. Adsorb spillages onto sand, earth or any suitable
adsorbent non-combustible material. Place into container for disposal via a licensed waste
disposal contractor. Contaminated adsorbent material may pose the same hazard as the spilt
product.
See Section 1 for emergency contact information.
See Section 8 for appropriate PPE.
See Section 13 for additional waste treatment information.
Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
SECTION 7: HANDLING AND STORAGE
7.1
Precautions for safe handling
Provide adequate ventilation. Do not breathe fumes. Avoid contact with skin and eyes. Wear
suitable protective clothing, gloves and eye/face protection. When diluting, add acid to water and
not water to acid. Wash hands thoroughly after handling.
7.2
Conditions for safe storage, including
any incompatibilities
Store in a closed corrosion resistant container. Keep only in original container. Keep away from
heat, sources of ignition and direct sunlight. Keep away from combustible material.
Storage Temperature
Store in a well-ventilated place. Keep cool.
Storage Life
Stable under normal conditions.
Incompatible materials
Organic matter, Reducing agent, Alkaline, Metallic Powder, Hydrogen sulphide, Alcohols,
Chlorates, Carbides, Carbon steel, Monel, Copper, Several other metals and alloys, Flammable
liquid and Chromic acid.
Appropriate packaging
Low carbon stainless steel and PVC.
7.3
•
•
•
•
•
•
•
•
Specific end use(s)
Surface active agent
Fertiliser
Laboratory chemicals
Oxidizing agents
Intermediates
Processing aid (used to generate ion exchange resins), not otherwise listed
Plating agents and metal surface treating agents
pH Regulating agent
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1
8.1.1
Control parameters
Occupational Exposure Limits
SUBSTANCE.
Nitric acid
CAS No.
7697-37-2
8.1.2
Biological limit value
8.1.3
PNECs and DNELs
LTEL
(8 hr TWA
ppm)
-
DNEL
Industry - Long Term – Local effects
Industry - Long Term - Systemic effects
Industry - Short term - Local effects
Industry - Short term - Systemic effects
Professional - Long Term – Local effects
Professional - Long Term - Systemic effects
Professional - Short term - Local effects
Professional - Short term - Systemic effects
Consumer - Long Term - Local effects
Consumer - Long Term - Systemic effects
Consumer - Short term - Local effects
Consumer - Short term - Systemic effects
LTEL
(8 hr TWA
mg/m³)
-
STEL
(15 min
ppm)
1
STEL
(15 min
mg/m3)
2.6
Note:
EH40 WEL
10/2007
Not established.
Oral
-
Inhalation
1.3 mg/m³
2.6 mg/m³
0.65 mg/m³
1.6 mg/m³
--
Dermal
-
Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
Aquatic Compartment
Terrestrial Compartment
Atmospheric Compartment
PNEC
-
Not established. Nitric acid, an inorganic substance which is highly soluble in water forming ions. It will be found predominantly in aquatic environment and
will not adsorb on particulate matter or surfaces.
8.2
8.2.1
Exposure controls
Appropriate engineering controls
8.2.2
Personal protection equipment
Eye/face protection
8.2.3
Local exhaust ventilation is required. Guarantee that the eye flushing systems and safety showers
are located close to the working place.
Goggles giving complete protection to eyes: EN 166. When combined with full face respiratory
protection – EN 316 (for full face devices) or EN 402 (for self-contained breathing apparatus)
Skin protection (Hand protection/ Other)
Chemical protection suit, boots and plastic or rubber gloves.
Gloves: Impervious gloves (EN 374). Butyl rubber, PVC, PTFE fluoro-elastomer.
Respiratory protection
Where engineering controls are not fitted or inadequate wear suitable respiratory protective
equipment. Or the above exposure limits are likely to be exceeded, masks equipped with filter E
(EN 14387) and B.
Thermal hazards
Not applicable.
Environmental Exposure Controls
Avoid release to the environment.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1
9.2
Information on basic physical and chemical properties
Appearance
Liquid.
Colour
Colourless.
Odour (Vapours or fumes)
Pungent and choking.
Odour Threshold (ppm)
0.29.
pH (Value)
Acidic.
Melting Point (°C)
-23°C (60%)
118°C (60%)
Boiling point/boiling range (°C):
Flash Point (°C)
Not applicable.
Not available.
Evaporation rate
Flammability (solid, gas)
Non-flammable.
Explosive limit ranges.
Not applicable.
Vapour Pressure (mm Hg)
5.498 (70%).
Vapour Density (Air=1)
2.
Density (g/ml)
1.36 g/ml (69%)
Bulk Density (g/ml)
Not applicable.
Completely miscible with water.
Solubility (Water)
Solubility (Other)
Not applicable.
Partition Coefficient (n-Octanol/water)
Not established.
Auto Ignition Temperature (°C)
Not applicable.
Decomposition Temperature (°C)
Not available.
Viscosity (mPa.s)
0.75 @ 25°C
Explosive properties
Not explosive.
Oxidising properties
Not oxidising.
Other information
Met. Corr. 1; May be corrosive to metals.
Not pyrophoric.
Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
SECTION 10: STABILITY AND REACTIVITY
10.1
Reactivity
Stable under normal conditions.
10.2
Chemical stability
Stable under normal conditions.
10.3
Possibility of hazardous reactions
Stable under normal conditions.
10.4
Conditions to avoid
Keep away from heat, sources of ignition and direct sunlight.
10.5
Incompatible materials
Organic matter, Reducing agent, Alkaline, Metallic Powder, Hydrogen sulphide, Alcohols,
Chlorates, Carbides, Carbon steel, Monel, Copper, Several other metals and alloys, Flammable
liquid and Chromic acid.
10.6
Hazardous Decomposition Product(s)
Nitrogen oxides.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1
Information on toxicological effects
11.1.1 Mixture
Acute toxicity
Ingestion
11.2
An acute toxicity test does not generally need to be conducted if the substance is classified as
corrosive to the skin.
Inhalation
LC50 (rat) = 1562.5 mg/m³ [4 hour(s)]. Inconclusive data. Not classified.
Skin Contact
An acute toxicity test does not generally need to be conducted if the substance is classified as
corrosive to the skin.
Eye Contact
An acute toxicity test does not generally need to be conducted if the substance is classified as
corrosive to the skin.
Repeated dose toxicity
Ingestion
Low oral toxicity. Potassium nitrate: NOAEL (rat) = 1500 mg/kg/day.
Inhalation
Not classified. NO2: NOAEC (rat) = ≥ 2.15 ppm.
Skin Contact
No data.
Eye Contact
No data.
Skin corrosion/irritation
Skin Corr. 1A; Causes severe skin burns and eye damage.
Serious eye damage/irritation
Corrosive.
Respiratory or skin sensitization
No data. Testing for skin sensitization does not need to be conducted if the substance is a strong
acid (pH < 2.0).
Mutagenicity
There is no evidence of mutagenic potential.
Carcinogenicity
Inadequate information available to assess carcinogenic hazard.
Reproductive toxicity
Aspiration hazard
Not classified. Potassium nitrate: NOAEL (rat) = 1500 mg/kg/day
.
Not classified.
Other information
Corrosive to: Respiratory system and digestive tract.
Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
SECTION 12: ECOLOGICAL INFORMATION
12.1
Toxicity
Low toxicity to aquatic organisms.
Fish - Median lethal pH (96 hour): 3.0 – 3.5.
By analogy with similar materials: Sodium nitrate:
LC50 (Rainbow trout)(96 hour): 8226 mg/l.
EC50 (Daphnia magna)[24hour(s)]: 8609 mg/l.
12.2
Persistence and degradability
The methods for determining the biological degradability are not applicable to inorganic
substances.
12.3
Bioaccumulative potential
The product has no potential for bioaccumulation.
12.4
Mobility in soil
The product is soluble in water.
12.5
Results of PBT and vPvB assessment
Not classified as PBT or vPvB.
12.6
Other adverse effects
Large discharges may contribute to the acidification of water and soil and will injure aquatic life
and soil micro-organisms.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1
Waste treatment methods
Neutralise carefully with lime or carbonates. The generation of waste should be avoided or
minimized wherever possible. Waste packaging should be recycled. Dispose of contents/container
to: licensed recycles, reclaimer or incinerator.
13.2
Additional Information
Empty containers may retain some product residues. Avoid dispersal of spilt material and runoff
and avoid contact with soil, waterways, drains and sewers. Disposal should be in accordance with
local, state or national legislation.
SECTION 14: TRANSPORT INFORMATION
14.1
UN number
UN2031.
14.2
Proper Shipping Name
NITRIC ACID.
14.3
Transport hazard class(es)
8 (5.1).
14.4
Packing Group
II.
14.5
Environmental hazards
Not classified as a Marine Pollutant.
14.6
Special precautions for user
Not available.
14.7
Transport in bulk according to Annex II
of MARPOL73/78 and the IBC Code
Proper Shipping Name: Nitric acid (less than 70%)
Ship type: 2
Pollution category: Y
14.8
Additional Information
Classification code: CO1 (Inorganic, Liquid).
EmS: F-A; S-B.
SECTION 15: REGULATORY INFORMATION
15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1
EU regulations
Authorisations and/or restrictions on use
None known.
15.1.2
National regulations
None known.
Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
15.2
Chemical Safety Assessment
Available
SECTION 16: OTHER INFORMATION
The following sections contain revisions or new statements, marked in italics: 1, 2, 6, 9, 13, 14
LEGEND
LTEL
STEL
DNEL
PNEC
PBT
vPVB
WEL
NOAEL
NOAEC
Ox. Liq. 3
Skin Corr. 1A
Met. Corr. 1
O
C
EUH071
Long Term Exposure Limit
Short Term Exposure Limit
Derived No Effect Level
Predicted No Effect Concentration
PBT: Persistent, Bioaccumulative and Toxic
very Persistent and very Bioaccumulative
Workplace Exposure Limit (UK HSE EH40)
No Observable Adverse Effect Level
No Observable Adverse Effect Concentration
Oxidising liquid Category 3
skin corrosion/irritation Category 2
Substance or mixture corrosive to metals Category 1
Oxidizing
Corrosive
Corrosive to the respiratory tract.
Risk Phrases and Safety Phrases
R8
R35
S1/2
S23
S26
S36
S45
Contact with combustible material may cause fire.
Causes severe burns.
Keep locked up and out of the reach of children.
Do not breathe fumes.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Wear suitable protective clothing.
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Hazard statement(s) and Precautionary statement(s)
H272
May intensify fire; oxidizer.
H314
Causes severe skin burns and eye damage.
P210
Keep away from heat, sparks, open flame, hot surfaces - No smoking
P220
Keep away from clothing and other combustible materials.
P221
Take any precaution to avoid mixing with combustibles….
H290
May be corrosive to metals.
P234
Keep only in original container.
P260
Do not breathe fume.
P264
Wash hands thoroughly after handling.
P280
Wear protective gloves/eye protection.
P301 + P330 + P331
IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P303 + P361 + P353
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P363
Wash contaminated clothing before reuse.
P304+P340
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P310
Immediately call a POISON CENTRE or doctor/physician.
P390
Absorb spillage to prevent material damage.
P404
Store in a closed container.
P406
Store in corrosive resistant container with a resistant inner liner.
P501
Dispose of contents/container to: Send to a licensed recycler, reclaimer or incinerator.
Hazard pictogram(s) and Hazard Symbol
Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
GHS05
C
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith, but it is for
the Users to satisfy themselves of the suitability of the product for their own particular purpose. CF Fertilisers UK Limited gives no
warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is
excluded except to the extent that exclusion is prevented by law. CF Fertilisers Limited accepts no liability for loss or damage (other than
that arising from death or personal injury caused by defective product, if proved), resulting from reliance on this information. Freedom
under Patents, Copyright and Designs cannot be assumed.
Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
ANNEX TO THE EXTENDED SAFETY DATA SHEET : EXPOSURE SCENARIO
Identification of the substance or mixture
Product definition
Product name
Section 1 - Title
Short title of the exposure
scenario
List of use descriptors
: Mono-constituent substance
: Nitric acid <65%
: CF Fertilisers UK Ltd - Nitric acid... % <65% /Manufacture /Industrial /Distribution
Identified use name: Industrial USE as reactive agent/processing aid and for general chemical
applications (e.g. organic/inorganic synthesis, corrosion protection, latex production, extraction,
plastics, water treatment/septicity control, pH/neutralising agent, ion exchange)
Industrial USE to manufacture specialist chemical/other products (e.g. adhesives, biocides, catalysts,
cleaning products, cosmetics, coatings/paints, construction chemicals, corrosion protection, insulation,
inks, pharmaceuticals, polymer preparations)
Process Category: PROC02, PROC03, PROC08b, PROC04, PROC07, PROC13
Substance supplied to that use in form of: As such, In a mixture
Sector of end use: SU09, SU04
Subsequent service life relevant for that use: No.
Environmental Release Category: ERC04, ERC06a, ERC06b, ERC06d
Market sector by type of chemical product: PC35
Article category related to subsequent service life: Not applicable.
Environmental contributing
scenarios
Health Contributing
scenarios
: Used EUSES model
Number of the ES
CFESWNAC002
Processes and activities
covered by the exposure
scenario
Covers the use as a component of cleaning products including transfer from storage,
pouring/unloading from drums or containers.
Exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying,
brushing, dipping, wiping, automated and by hand), related equipment cleaning and maintenance.
Covers the use as a component of cleaning products within closed or contained systems including
incidental exposures during transfer from storage, mixing/diluting in the preparatory phase and
cleaning activities, related equipment cleaning and maintenance.
Formulation of the substance and its mixtures in batch or continuous operations within closed or
contained systems, including incidental exposures during storage, materials transfers, mixing,
maintenance, sampling and associated laboratory activities.
Manufacture of the substance or use as an intermediate or a process chemical or extraction agent.
Includes recycling/recovery, material transfers, storage, maintenance and loading (including marine
vessel/barge, road/rail car and bulk container), sampling and associated laboratory activities.
Use of the substance within laboratory settings within enclosed or contained systems, including
incidental exposures during material transfers and equipment cleaning.
Loading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums
and small packs) of substance, including its sampling, storage, unloading distribution and associated
laboratory activities.
Spraying - PROC07
Section 2 - Exposure controls
Contributing exposure scenario controlling environmental exposure for 0:
Product Characteristics
Readily biodegradable liquid.
Concentration of substance
in mixture or article
Covers percentage substance in the product up to 75% aqueous preparations25%>75%
Frequency and Duration of use
8 h (full shift). Covers frequency up to: daily, weekly, monthly, yearly use.
Environmental factors not influenced by
risk management
Not applicable
Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
Other operational conditions of use
affecting environmental exposure
pH 6-9 (Practically non-toxic to aquatic organisms.)
Technical on-site conditions and measures
to reduce or limit discharges, air emissions
and releases to soil
Air emission controls are not applicable as there is no direct release to air.
Soil emission controls are not applicable as there is no direct release to soil.
Risk management measures - Air
Not applicable.
Risk management measures - Water
Dispose of waste in accordance with environmental legislation.
Risk management measures - Soil
Not applicable.
Organisational measures to prevent/limit
release from site
Prevent leaks and prevent soil/water pollution caused by leaks. Prevent entry into sewers, basements
or confined areas. Dyke if necessary.
Conditions and measures related to
municipal sewage treatment plant
Neutralisation is normally necessary before waste water is discharged into water treatment plants.
Suitable waste treatment
Not applicable.
Waste management measures - Water
pH adjustment. Do not release undiluted and un-neutralised into the sewer.
Waste management measures - Gas.
Not applicable.
Conditions and measures related to
external recovery of waste
Not applicable.
Suitable recovery operations
Not applicable.
Contributing exposure scenario controlling worker exposure for 0: Spraying
Product Characteristics
Acidic Corrosive material.
Concentration of substance in mixture or
article
Covers percentage substance in the product up to 75% aqueous preparations 25% >75%.
Physical state
Liquid.
Dust
Not applicable.
Frequency and duration of :
use
If during normal use the material presents a respiratory hazard, use only with adequate ventilation or
wear appropriate respirator.
Exposure duration per day: 8 h (full shift). Exposure to product aerosol can irritate the eyes, mouth and
throat.
Do not carry out operation for more than 15 minutes
Human factors not influenced by risk
management
Not applicable.
Other operational conditions affecting
worker exposure
Not applicable.
Area of use:
Indoor and outdoor use.
Technical conditions and measures at
process level (source) to prevent release
Observe the usage/storage instructions.
Technical conditions and measures to
control dispersion from source towards the
worker
Automate activity where possible. Ensure control measures are regularly inspected and maintained.
Engineering controls
Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at
openings. Only allow access to authorised persons.
Ventilation control
measures
Only use product in a well-ventilated area. Provide a good standard of general ventilation (not less than
3 to 5 air changes per hour). Ensure the ventilation system is regularly maintained and tested.
Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
Product substance-related measures
Observe technical data sheet/instructions for use.
Product safety-related measures
Do not breathe gas/vapour/aerosol.
Wear eye or face protection. Avoid contact with eyes.
Avoid contact with skin and mucous membranes.
Organisational measures to prevent/limit
releases, dispersion and exposure
Only allow access to authorised staff.
Extraction: Use appropriate containment to avoid environmental contamination.
If necessary: Use complete process isolation technology. Automate activity where possible.
Ensure operatives are trained to minimise exposure. No action shall be taken involving any personal
risk or without suitable training.
Ensure control measures are regularly inspected and maintained.
Conditions and measures related to personal protection, hygiene and health evaluation
Personal protection
Wear eye or face protection. - Face shield, splash goggles.
Use safety eyewear designed to protect against splash of liquids.
CEN: EN166
Wear suitable gloves (tested to EN374), coverall and eye protection.
See Section 8 of the safety data sheet (personal protective equipment).
Respiratory protection
Short term exposure: Do not carry out operation for more than 15 minutes. If technical extraction or
ventilation is not possible or inadequate, respiratory protection must be worn.
Long term exposure: Wear appropriate respiratory protection. - Filter P2SL (EN 143, 140), inorganic
gases/vapours filter (Type B).
Do not carry out operation for more than 4 hours
If necessary (4 - 8 hours): Wear self-contained breathing apparatus during spray application.
Section 3 - Exposure estimation and reference to its source
Exposure estimation and reference to its source - Environment: 0: Spraying
Exposure assessment (environment):
Qualitative approach used to conclude safe use.
Exposure estimation
Practically non-toxic to aquatic organisms.: pH 6-9
Exposure estimation and reference to its source - Workers: 0: The ECETOC TRA tool has been used to estimate workplace exposures unless
otherwise indicated.
Exposure assessment (human):
The MEASE tool has been used to estimate workplace exposures unless otherwise indicated.
Exposure estimation
Predicted exposures are not expected to exceed the applicable exposure limits (given in section 8 of
the SDS) when the operational conditions/risk management measures given in section 2 are
implemented.
DNEL Human, inhalation, long term (repeated): 1.3 mg/m3
DNEL Human, inhalation short term (acute):2.6 mg/m3
Section 4 - Guidance to Downstream User to evaluate if he works inside the boundaries set by the ES
Environment
The product is not expected to harm the environment when used properly according to directions. No
additional risk management measures required.
Health
Refer to special instructions/safety data sheet. Comply with the safety instructions.
Risk management measures (RMM) : In accordance with Classification and labelling according to
Regulation (EC) 1272/2008 (CLP)
Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
ANNEX TO THE EXTENDED SAFETY DATA SHEET : EXPOSURE SCENARIO
Identification of the substance or mixture
Product definition
Product name
Mono-constituent substance
Nitric acid <65%
Section 1 - Title
Short title of the exposure scenario
CF Fertilisers UK Ltd - Nitric acid... % <65% /Professional
List of use descriptors
Identified use name: Professional formulation of mixtures using substance.
Professional USE of substance, as such or in a mixture, as reactive agent/processing aid and for
general chemical applications (e.g. corrosion protection products, pH/neutralising agent, processing of
manure as fertiliser, water treatment) Professional USE of substance as a laboratory/research
chemical.
Professional USE of substance, as such or in a mixture, for surface/article treatment (e.g. metal,
textiles/leather, plastics, wood, etching concrete)
Professional USE as part of specialist chemicals/other products (e.g. adhesives, biocides, cleaning
products, corrosion protection, cosmetics, coatings/paints, de-icing/antifreeze, inks/dyes, insulation,
photochemical, polymer preparations).
Professional USE of substance as fertiliser in Greenhouse (e.g. Fertigation, includes pH control of
fertiliser solution with acid)
Professional USE of substance for dilution or suspension of liquid or solid fertilizers.
Professional distribution of substance.
Process Category: PROC05, PROC08a, PROC08b, PROC09, PROC10, PROC11, PROC13,
PROC15, PROC19
Substance supplied to that use in form of: As such, In a mixture
Sector of end use: SU01, SU04, SU10, SU15, SU16, SU17, SU19, SU23, SU24
Subsequent service life relevant for that use: No
Environmental Release Category: ERC08a, ERC08b, ERC08e
Market sector by type of chemical product: PC12, PC14, PC20, PC21, PC35
Article category related to subsequent service life: Not applicable
Environmental contributing scenarios
: Used EUSES model
Health Contributing scenarios
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise
indicated.
Number of the ES
: CFESWNAC003
Processes and activities covered by the
exposure scenario
Agricultural industry
Professional applications
Use as functional fluids e.g. cable oils, transfer oils, coolants, insulators, refrigerants, hydraulic fluids in
professional equipment including maintenance and related material transfers.
Covers the use as a component of cleaning products including transfer from storage,
pouring/unloading from drums or containers.
Exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying,
brushing, dipping, wiping, automated and by hand), related equipment cleaning and maintenance.
Application of surface coatings and binders in road and construction activities, including paving uses,
manual mastic and in the application of roofing and waterproofing membranes.
Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including
materials receipt, storage, preparation and transfer from bulk and semi-bulk, application by spray,
roller, spreader, dip, flow, fluidised bed on production lines and film formation) and equipment cleaning,
maintenance and associated laboratory activities.
Covers the use of the substance for the treatment of water in open and closed systems.
Covers the use as a component of cleaning products within closed or contained systems including
incidental exposures during transfer from storage, mixing/diluting in the preparatory phase and
cleaning activities, related equipment cleaning and maintenance.
Formulation of the substance and its mixtures in batch or continuous operations within closed or
contained systems, including incidental exposures during storage, materials transfers, mixing,
maintenance, sampling and associated laboratory activities.
Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
Manufacture of the substance or use as an intermediate or a process chemical or extraction agent.
Includes recycling/recovery, material transfers, storage, maintenance and loading (including marine
vessel/barge, road/rail car and bulk container), sampling and associated laboratory activities.
Use of the substance within laboratory settings within enclosed or contained systems, including
incidental exposures during material transfers and equipment cleaning.
Loading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums
and small packs) of substance, including its sampling, storage, unloading distribution and associated
laboratory activities.
Section 2 - Exposure controls
Contributing exposure scenario controlling environmental exposure for 0.
Product Characteristics
Readily biodegradable liquid
Concentration of substance in mixture or
article
Covers percentage substance in the product up to 75% aqueous preparations 25%>75%
Frequency and Duration of Use
8 h (full shift). Covers frequency up to: daily, weekly, monthly, yearly use
Environmental factors not influenced by
risk management
Not applicable.
Other operational conditions of use
affecting environmental exposure
pH 6-9 (Practically non-toxic to aquatic organisms.)
Technical on-site conditions and measures
to reduce or limit discharges, air emissions
and releases to soil
Air emission controls are not applicable as there is no direct release to air.
Soil emission controls are not applicable as there is no direct release to soil.
Risk management measures - Air
Not applicable.
Risk management measures - Water
Dispose of waste in accordance with environmental legislation.
Risk management measures - Soil
Not applicable.
Organisational measures to prevent/limit
release from site
Prevent leaks and prevent soil/water pollution caused by leaks. Prevent entry into sewers, basements
or confined areas. Dyke if necessary.
Conditions and measures related to
municipal sewage treatment plant
Risk from exposure via the aquatic environment is driven by effluent releases to freshwater.
Conditions and measures related to
external treatment of waste for disposal
Neutralisation is normally necessary before waste water is discharged into water treatment plants.
Suitable waste treatment
Not applicable.
Waste management measures - Water
pH adjustment. Do not release undiluted and un-neutralised into the sewer.
Waste management measures - Gas.
Not applicable.
Conditions and measures related to
external recovery of waste
Not applicable.
Suitable recovery operations
Not applicable.
Contributing exposure scenario controlling worker exposure for 0:
Product Characteristics
Acidic corrosive material.
Concentration of substance in mixture or
article
Covers percentage substance in the product up to 75% aqueous preparations 25%>75%.
Physical state
Liquid.
Dust
Not applicable.
Frequency and duration of : use
Covers daily exposures up to 8 hours (unless stated differently). Covers frequency up to: daily,
weekly, monthly, yearly use.
Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
Human factors not influenced by risk
Management
Not applicable.
Other operational conditions affecting
worker exposure
Not applicable.
Area of use:
Indoor and outdoor use.
Technical conditions and measures at
process level (source) to prevent release
Observe the usage/storage instructions.
Technical conditions and measures to
control dispersion from source towards the
worker
Ensure control measures are regularly inspected and maintained. Consider technical advances and
process upgrades (including automation) for the elimination of releases.
Minimise exposure using measures such as closed systems, dedicated facilities and suitable
general/local exhaust ventilation.
Drain down systems and clear transfer lines prior to breaking containment.
Clean/flush equipment, where possible, prior to maintenance.
Where there is potential for exposure: restrict access to authorised persons; provide specific activity
training to operators to minimise exposures; wear suitable gloves and coveralls to prevent skin
contamination; wear respiratory protection when its use is identified for certain contributing scenarios;
clear up spills immediately and dispose of wastes safely.
Ensure safe systems of work or equivalent arrangements are in place to manage risks.
Regularly inspect, test and maintain all control measures.
Consider the need for risk-based health surveillance.
Engineering controls
Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation
at openings. Only allow access to authorised persons.
Ventilation control measures
Only use product in a well-ventilated area. Provide a good standard of general ventilation (not less
than 3 to 5 air changes per hour). Ensure the ventilation system is regularly maintained and tested.
Product substance-related measures
Observe technical data sheet/instructions for use.
Product safety-related measures
Do not breathe gas/vapour/aerosol.
Wear eye or face protection. Avoid contact with eyes.
Avoid contact with skin and mucous membranes.
Organisational measures to prevent/limit
releases, dispersion and exposure
Only allow access to authorised staff.
Extraction: Use appropriate containment to avoid environmental contamination.
If necessary: Use complete process isolation technology. Automate activity where possible.
Ensure operatives are trained to minimise exposure. No action shall be taken involving any personal
risk or without suitable training.
Ensure control measures are regularly inspected and maintained.
Conditions and measures related to personal
protection, hygiene and health evaluation
Personal protection
Respiratory protection
Wear eye or face protection. - Face shield, splash goggles.
Use safety eyewear designed to protect against splash of liquids.CEN: EN166.
Wear suitable gloves (tested to EN374), coverall and eye protection.
See Section 8 of the safety data sheet (personal protective equipment).
No personal respiratory protective equipment normally required.
If ventilation is inadequate, use respirator that will protect against dust/mist.
Filter P2SL (EN 143, 140), acid gas filter (Type E).
Self-contained respirator (DIN EN 133)
Section 3 - Exposure estimation and reference to its source
Exposure estimation and reference to its source - Environment: 1
Exposure assessment (environment):
Qualitative approach used to conclude safe use.
Exposure estimation
Practically non-toxic to aquatic organisms.: pH 6-9
Exposure estimation and reference to its source - Workers: 0:
Exposure assessment
(human):
The MEASE tool has been used to estimate workplace exposures unless otherwise indicated.
Nitric Acid < 65%
SAFETY DATA SHEET
ACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)
Revision 2, May 2012
Exposure estimation
Predicted exposures are not expected to exceed the applicable exposure limits (given in section 8 of
the SDS) when the operational conditions/risk management measures given in section 2 are
implemented.
DNEL Human, inhalation, long term (repeated): 1.3 mg/m3
DNEL Human, inhalation short term (acute):2.6 mg/m3
Section 4 - Guidance to Downstream User to evaluate if he works inside the boundaries set by the ES
Environment
The product is not expected to harm the environment when used properly according to directions. No
additional risk management measures required.
Health
Refer to special instructions/safety data sheet. Comply with the safety instructions.
Risk management measures (RMM) : In accordance with Classification and labelling according to
Regulation (EC) 1272/2008 (CLP)