AP Chemistry Summer Assignment

AP Chemistry Summer Assignment
2017
Future AP Chemistry Student,
Welcome to AP Chemistry! In order to ensure the best start for everyone next fall, I have prepared a summer
assignment that reviews basic chemistry concepts that you learned while studying Chemistry. Each of the 6 Big Ideas in
AP Chemistry is represented according to their weight in the course, with specific emphasis on topics which need
mastery before beginning an AP Chemistry course.
The information in this packet will be reviewed, and you will be tested on the material during the first weeks of school.
You are responsible for answering all the questions in this packet, as well as coming in prepared to be tested on this
information. The score you receive on the test will give an indicator as to how much Chemistry you recall from previous
years, as well as how well you are likely to perform in AP Chemistry this school year. A second part to your assignment is
to come in with a prepared lab notebook containing the information given in the rubric included in this packet.
The due date for the Summer Packet (including the prepared lab notebook) is: AUGUST 7, 2017
The Introduction to Chemistry Test will be: AUGUST 11, 2017
It is also important that you realize up front how your performance in this course will be measured. You will be treated
and assessed as if this is a college Chemistry course and will be expected to meet those expectations. Even when absent,
you are expected to keep up with material. This will require you to work on assignments after school, on weekends, and
at times over holidays. If you do not feel you are mature or prepared enough to take on a college Chemistry course, you
may want to think about your course selection for next year. You will be considered a college Chemistry student from
the first day of classes, and expected to have the work ethic of a college Chemistry student.
I am available as a resource throughout the summer for both you and your parents, if you or they have questions or
concerns. You may contact me by email: ([email protected]) this summer, and I will do my best to answer your
questions in a timely manner. There is a page on my website (lhfleming.weebly.com) you can use to contact me as well.
My website will be used as a place for us to communicate throughout the school year. Over the summer, I encourage
you to use all resources out there to help prepare for the upcoming year, but I have included some resources
throughout your summer packet as well.
Finally, I recommend that you spread out the summer assignment. Please do not try to complete it all in the final weeks
of the summer. Chemistry takes time to process and understand, especially at the college level. Trying to cram all this
information into one week will not serve you well during the school year. I would highly recommend that you try to form
a study group you could keep up with through the summer, and the school year to get some help when I am not
available. Getting help from peers is useful, especially with a difficult course like AP Chemistry.
Please sign up for the class Remind to get updates about the course. Text @jchsapchem to 81010.
Have a great summer and make good choices!
Ms. Fleming
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You will need the following supplies for AP Chemistry next year, it would be a good idea to go ahead and get these
things now. Keeping yourself organized will help you be successful throughout the year!
 3 ring binder: preferably 1.5”-2”(for AP Chemistry ONLY)
 Composition notebook (for labs-see attached rubric)
 LOTS and LOTS of paper
 Calculator (it needs to do basic math, scientific notation, and logarithms)
Utilize the resources included, as well as outside resources to complete this packet. The packet is weighted to give you a
sample of what you will be expected to understand when coming into class in August. Do not wait until the last minute
to work on this packet; you will be graded on your work. If you lose a part of the packet, you can find one on my
website. If you have any questions about the packet, please let me know and I will try and respond in a timely manner.
Completed work must be submitted by hand on or before AUGUST 7th. Late work will not be accepted without penalty
of only receiving 70% of the credit. You will be required to take the Foundations Exam regardless of if your packet is
turned in, and one week after the exam no more packets will be accepted for credit.
Show work for all the problems. Questions cover topics from general chemistry, which were covered in your Chemistry
course. Use necessary resources, but make sure the work you present is your own. Remember to always use significant
figures in your answers.
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2.
3.
4.
5.
6.
Fundamentals (40 points)
Read through Chapters 22, 23, and 24 in your textbook and take notes on these chapters. This information is
considered previous knowledge, and will not be covered in AP Chemistry next year.
Create a flow chart for classification of matter, including examples.
Complete the following nomenclature practice.
a. Calcium sulfate
f. LiOH
b. Ammonium nitride
g. P4S10
c. Lithium nitrite
h. NI3
d. Tricarbon octahydride
i. BaCl2
e. Dinitrogen monoxide
j. Fe3(PO4)2
Fill in the blanks of the common ion sheet included in the packet.
Complete the following mole practice.
a. Calculate the mass of oxygen produced if 3.450 grams of potassium chlorate is completely decomposed by
heating in the presence of a catalyst (Manganese dioxide).
b. What is the empirical formula of a compound that contains 53.73% Fe and 46.27% of S?
c. Determine the number of molecules present in 4.56 mol of nitrogen (N2).
d. How many grams of methane (CH4) are present in 5.6 moles of methane gas?
e. Calculate the mass in grams of 12.4x1015 atoms of neon.
f. What mass of copper is required to replace silver from 4.00 grams of silver nitrate dissolved in water?
Cu(s) + AgNO3 → Cu(NO3)2 + Ag(s)
g. Calculate the molar mass of ammonia.
h. Calculate the molar mass of sodium hydrogen carbonate (baking soda).
i. When benzene reacts with bromine, bromobenzene is produced. What is the theoretical yield of
bromobenzene in this reaction when 30.0 g of benzene reacts with 65.0 g of bromine? If the actual yield
was 56.7 g what was the percentage yield?
C6H6 + Br2 → C6H5Br + HBr
j. Chlorine and fluorine react to form chlorine trifuoride gas. If you start with 1.75 mol of chlorine and 4.3
mol of fluorine, what is the limiting reactant? How much of the excess remains?
Create a flowchart for physical and chemical properties and changes, including examples.
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7.
8.
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10.
11.
12.
13.
14.
Write and balance the following chemical equations. When needed, consult the activity series sheet included in
the packet. If no reaction occurs, simply write no reaction.
a. Boron trifluoride gas reacts with water to give liquid hydrogen fluoride and solid boric acid (H3BO3).
b. The reaction of magnesium oxide with iron form iron (III) oxide and magnesium.
c. Ethane burns in air.
d. Calcium carbonate decomposes into calcium oxide and carbon dioxide.
e. Zinc is dissolved in sulfuric acid produces the salt zinc sulfate and hydrogen gas.
f. Sulfurous acid and potassium hydroxide react in a double displacement reaction.
g. Sulfurous acid is synthesized from sulfur dioxide and water.
h. Tin reacts with water in a single displacement reaction.
i. Calcium reacts with water.
j. Aluminum reacts with hydrochloric acid.
DENSITY PRACTICE
a. A 47.3 mL sample of ethanol (C2H5OH) has a mass of 37.32 g. What is its density?
b. If 116 g of ethanol is needed for a chemical reaction, what volume is needed? The density of ethanol is
0.785 g/mL.
c. What is the mass of a rectangular piece of copper 24.4 cm x 11.4 cm x 8.9 cm? The density of copper is
8.92 g/cm3).
d. The mass of an empty container is 77.664 g, but when filled with water the container weighs 99.65 g.
Calculate the volume of the container using 1.00 g/mL as the density of water.
e. Vinegar has a density of 1.0056 g/cm3. What is the mass of 3 liters of vinegar?
Write a short summary of accuracy and precision. Include real world and scientific examples.
List and define the four states of matter, including examples.
Matter (25 points)
Give the complete electron configuration for the following atoms and ions.
a. Al
f. N-3
-1
b. Br
g. Fe
+2
c. Mg
h. Fe+2
d. O
i. Fe+3
e. Mg
j. S
Draw the Lewis Dot Diagrams for the following elements.
a. Sodium
f. Lead (III)
b. Nitrogen
g. Barium
c. Boron
h. Sulfur
d. Xenon
i. Helium
e. Lead (II)
j. Selenium
Use the following URLs to take notes on Periodic Arrangement.
http://dl.clackamas.edu/ch104/lesson6arrangement.html
http://dl.clackamas.edu/ch104/lesson6periodictrends.html
http://dl.clackamas.edu/ch104/lesson6periodictrends2.html
LIGHT/WAVES PRACTICE
a. A green line of wavelength 4.86x10-7m is observed in the emission spectrum of hydrogen. Calculate the
energy of the photon.
b. Calculate the wavelength in meters of an electron traveling at 1.24x107 m/s. The mass of an electron is
9.11x10-28 g.
c. What color light is seen at 6573 Å?
d. Copper (I) chloride emits a blue light wavelength of 450 nm. What is the quantum of energy that is
emitted at 450x102 nm?
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15.
16.
17.
18.
19.
20.
21.
e. The laser in an audio CD player uses light with a wavelength of 7.80x102 nm. Calculate the frequency of
this light?
Use the following URL to take notes on Atomic Spectra.
https://www.youtube.com/watch?v=1uPyq63aRvg
Use the following URL to take notes on Orbitals.
https://www.youtube.com/watch?v=KrXE_SzRoqw
Behavior of Matter (15 points)
GAS LAWS PRACTICE
a. A sample of nitrogen collected in a laboratory occupies a volume of 725 mL at a pressure of 0.971 atm.
What volume will the gas occupy at a pressure of 1.40 atm, assuming the temperature will remain
constant?
b. A container of oxygen has a volume of 349 mL at a temperature of 22°C. What volume will the gas occupy
at 50°C?
c. A cylinder of gas has a pressure of 4.40 atm at 25°C. At what temperature in K will it reach a pressure of
6.50 atm?
d. A sample of hydrogen gas has a volume of 65.0 mL at a pressure of 0.992 atm and a temperature of 16°C.
What volume will the hydrogen occupy at 0.984 atm and 25°C?
e. An engineer pumps 5.00 mol of carbon monoxide gas into a cylinder that has a capacity of 20.0 L. What is
the pressure in kPa of CO inside the cylinder at 25°C?
f. A student collects oxygen gas by water displacement at a temperature of 16°C. The total volume is 188 mL
at a pressure of 92.3 kPa. What is the pressure of the oxygen collected?
g. An unknown gas has a density of 0.0262 g/mL at a pressure of 0.918 atm and a temperature of 10°C. What
is the molar mass of the gas?
h. What is the pressure in kPa of 3.95 mol of chlorine gas if it is compressed in a cylinder with a volume of
850. mL at a temperature of 15°C?
MOLAR VOLUME PRACTICE
a. Calculate the molar volume of 2500 mL of carbon dioxide gas at STP.
b. Calculate the molar volume of 1.20x1024 molecules of nitrogen dioxide at STP.
c. Calculate the molar volume of 22.41 grams of hydrogen sulfide gas at STP.
Use the following URLs to take notes on the Kinetic Molecular Theory.
https://www.youtube.com/watch?v=fIMdIMACyN4
https://www.youtube.com/watch?v=apOSDqZd6Fg
Equilibrium (16 points)
Use the following URL to take notes on Le Chatelier’s Principle.
https://www.khanacademy.org/science/chemistry/chemical-equilibrium/factors-that-affect-chemicalequilibrium/v/le-chatelier-s-principle
pH PRACTICE
a. The hydroxide ion concentration of an aqueous solution is 6.4x10-5 M. What is the hydronium ion
concentration?
b. Calculate the hydroxide and hydronium concentration in a 7.50x10-4 M solution of HNO3.
c. Determine the pH of a 0.00118 M solution of HBr.
d. What is the pH of a solution with a hydroxide concentration of 1.0x10-5 M?
e. Calculate the pH of a solution with a hydroxide concentration of 2.90x10-11 M.
f. Calculate the hydroxide ion concentration of a 0.05 M sodium hydroxide solution.
g. What is the hydronium ion concentration of a solution of a 0.150 M nitric acid solution?
h. The pH of an aqueous solution of NaOH is 12.9. What is the molarity?
i. What is the pH of a 0.0001 M solution of NaOH?
j. What is the molarity of a solution of the strong base Ca(OH)2 in a solution that has a pH of 10.80?
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22.
23.
24.
25.
26.
Use the following URLs to take notes on Buffers.
https://www.youtube.com/watch?v=gjKmQ501sAg
https://www.youtube.com/watch?v=LJmFbcaxDPE
Thermochemistry (18 points)
Write a short summary of the Law of Conservations (Matter, Energy, Work).
CALORIMETRY PRACTICE
a. How much heat is required to heat 75.0 g of aluminum from 25.0°C to 175.0°C? The specific heat of
aluminum is 0.900 J/g°C.
b. A 75.0 g piece of aluminum initially at a temperature of 175.0°C is dropped into a calorimeter containing
150.0 g of water at an initial temperature of 15.0°C. What will the final temperature be once the system
has reached equilibrium (assume no heat is lost by the container). The specific heat of aluminum is 0.900
J/g°C.
c. When 3.425 kJ of heat is added to a calorimeter containing 50.0 g of water, the temperature rises from
24.00°C to 36.54°C. Calculate the heat capacity of the calorimeter in J/°C. The specific heat of water is
4.184 J/g°C.
d. A piece of silver has a mass of 362 g and a heat capacity of 85.7 J/°C. What is the specific heat of silver?
e. Calculate the amount of heat absorbed (in kJ) by a 6.33 kg sample of copper heated from 20.5°C to
324.3°C.
Use the following URL to take notes on: Entropy, Enthalpy, and Free Energy.
https://www.khanacademy.org/science/chemistry/thermodynamics-chemistry
Electrochemistry (5 points)
Use the following URL to take notes on Oxidation-Reduction.
https://www.youtube.com/watch?v=5rtJdjas-mY
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Complete this sheet as a part of your summer packet.
It will be returned to you to use on tests throughout the year.
Ion Name
Formula
Charge
Acetate
Ammonium
Carbonate
Chlorate
Chlorite
Chromate
Cyanide
Dichromate
Hydroxide
Nitrate
Nitrite
Perchlorate
Permanganate
Peroxide
Phosphate
Sulfate
Sulfite
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Activity Series of Metals in a Single Displacement Reaction.
Keep this page and put it in your three ring binder you will use for this class.
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Lab Notebook Setup Rubric
You will need a lab notebook for AP Chemistry and it needs to be a composition notebook (not a spiral notebook). You
will do all of your lab work in this notebook.
Make sure you set up your lab notebook according to the following guidelines before the first day of school. These are
due with your AP Chemistry Summer Packet. You will receive a quiz grade (25 points) for having your lab notebook
prepared on the first day.
Please write only on the front side of your pages (reserve the back side for scratch work). You will need to write all
formal lab information (that will be assessed) in blue or black ink ONLY. Each lab will be assessed based on the following
requirements:
 Title
 Purpose
 Prelab Questions
 Materials
 Procedure
 Data/Observations
 Post Lab Discussion
You need a cover page on the first page of your notebook. The cover page should include:
Your name
Lab partner’s name (will be filled out first week of school)
Lab station (will be filled out first week of school)
Ms. Fleming
AP Chemistry
2017-2018
You need a 1-2 page table of contents which will include the names of the labs with corresponding pages.
Example:
Density Lab
Measurements Lab
Page 1
Page 3
After your table of contents, you need an equipment list with hand drawn pictures to refer to during labs. The list of
equipment you will need to have on these pages is below:
o
o
o
o
o
o
Beaker
Beaker clamp
Buret
Buret clamp
Bunsen burner
Clay triangle
o
o
o
o
o
o
Crucible and lid
Crucible clamp
Erlenmeyer flask
Evaporating dish
Funnel
Glass rod
o
o
o
o
o
o
Graduated cylinder
Iron ring
Pipette
Ring stand
Scoopula
Test tube
o
o
o
o
o
o
Test tube clamp
Test tube rack
Thermometer
Utility clamp
Watch glass
Wire gauze
You will also need in your lab notebook the rubric (included in the next page) for the formal lab reports you will be
writing this year. Please tape the rubric to the INSIDE BACK COVER of your composition notebook so you can reference
it throughout the year. You can find this rubric on the next page of this packet.
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Print this page and tape it to the INSIDE BACK COVER of your lab notebook before the first day of school.
Results
Methods
Materials
Introduction
Title
Section
Requirements
AP Chemistry Lab Rubric
Superior
Excellent Average



4 of 4
requirements
present
3 of 4






Author Name
Lab Partner’s Name
Lab/Lab Report Title – Cannot be the title of
the lab in the lab manual – has to be related to
the lab but unique
Date
Stated question/problem being studied
Clearly stated purpose of lab
Personal hypothesis stated
Cited any definitions/research used
Used research other than the Lab Manual
10 of 10
requirements
present
8 of 10



Formatted correctly as bulleted list
Proper detail included (how much, many, etc)
List was complete-no items left out
3 of 3
requirements
present
2 of 3
1 or less of 3




Steps written as commands in a list format
NO pronoun usage (I, We, etc)
Detailed but not redundant
NOT copied directly from the lab manual – put
into own words
Comprehensive; nothing missing
Data presented in table/graph
Correct units were used
Each figure has a number, title, and explanation
Results were clearly analyzed - explain ONLY
results, no explanations of why
3 of 3
requirements
present
2 of 3
1 or less of 3
10 of 10
requirements
present
8 of 10
6 of 10
4 of 10
2 or less of
10
10 of 10
requirements
present
8 of 10
6 of 10
4 of 10
2 or less of
10
4 of 4
requirements
present
3 of 4
2 of 4
1 of 4
0 of 4



Results and Analysis was tied back to purpose
of lab
Explanation of why you got the results you got
Address if personal hypothesis is valid or
invalid
Possible influence of errors on conclusion
Implications of findings – how can you expand
on this research
Resources correctly cited in body of lab report
Resources correctly cited in bibliography
Correct format for citations used
You must have at least 2 sources of
information, other than the lab manual
Overall format is clear
Overall format is concise & neat
Each section has a heading
3 of 3
requirements
present
2 of 3
1 of 3



No Spelling Errors
No Grammatical errors
Do Not Use I, We, Our, My, etc
3 of 3
requirements
present
2 of 3
1 of 3





Syntax
Format
Citations
Conclusion

Totals








2 of 4
Needs
Improvement
1 of 4
Not even
close
0 of 4
6 of 10
4 of 10
2 or less of
10
Comments
Total Grade
/50
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