AP Chemistry Summer Assignment 2017 Future AP Chemistry Student, Welcome to AP Chemistry! In order to ensure the best start for everyone next fall, I have prepared a summer assignment that reviews basic chemistry concepts that you learned while studying Chemistry. Each of the 6 Big Ideas in AP Chemistry is represented according to their weight in the course, with specific emphasis on topics which need mastery before beginning an AP Chemistry course. The information in this packet will be reviewed, and you will be tested on the material during the first weeks of school. You are responsible for answering all the questions in this packet, as well as coming in prepared to be tested on this information. The score you receive on the test will give an indicator as to how much Chemistry you recall from previous years, as well as how well you are likely to perform in AP Chemistry this school year. A second part to your assignment is to come in with a prepared lab notebook containing the information given in the rubric included in this packet. The due date for the Summer Packet (including the prepared lab notebook) is: AUGUST 7, 2017 The Introduction to Chemistry Test will be: AUGUST 11, 2017 It is also important that you realize up front how your performance in this course will be measured. You will be treated and assessed as if this is a college Chemistry course and will be expected to meet those expectations. Even when absent, you are expected to keep up with material. This will require you to work on assignments after school, on weekends, and at times over holidays. If you do not feel you are mature or prepared enough to take on a college Chemistry course, you may want to think about your course selection for next year. You will be considered a college Chemistry student from the first day of classes, and expected to have the work ethic of a college Chemistry student. I am available as a resource throughout the summer for both you and your parents, if you or they have questions or concerns. You may contact me by email: ([email protected]) this summer, and I will do my best to answer your questions in a timely manner. There is a page on my website (lhfleming.weebly.com) you can use to contact me as well. My website will be used as a place for us to communicate throughout the school year. Over the summer, I encourage you to use all resources out there to help prepare for the upcoming year, but I have included some resources throughout your summer packet as well. Finally, I recommend that you spread out the summer assignment. Please do not try to complete it all in the final weeks of the summer. Chemistry takes time to process and understand, especially at the college level. Trying to cram all this information into one week will not serve you well during the school year. I would highly recommend that you try to form a study group you could keep up with through the summer, and the school year to get some help when I am not available. Getting help from peers is useful, especially with a difficult course like AP Chemistry. Please sign up for the class Remind to get updates about the course. Text @jchsapchem to 81010. Have a great summer and make good choices! Ms. Fleming 1 You will need the following supplies for AP Chemistry next year, it would be a good idea to go ahead and get these things now. Keeping yourself organized will help you be successful throughout the year! 3 ring binder: preferably 1.5”-2”(for AP Chemistry ONLY) Composition notebook (for labs-see attached rubric) LOTS and LOTS of paper Calculator (it needs to do basic math, scientific notation, and logarithms) Utilize the resources included, as well as outside resources to complete this packet. The packet is weighted to give you a sample of what you will be expected to understand when coming into class in August. Do not wait until the last minute to work on this packet; you will be graded on your work. If you lose a part of the packet, you can find one on my website. If you have any questions about the packet, please let me know and I will try and respond in a timely manner. Completed work must be submitted by hand on or before AUGUST 7th. Late work will not be accepted without penalty of only receiving 70% of the credit. You will be required to take the Foundations Exam regardless of if your packet is turned in, and one week after the exam no more packets will be accepted for credit. Show work for all the problems. Questions cover topics from general chemistry, which were covered in your Chemistry course. Use necessary resources, but make sure the work you present is your own. Remember to always use significant figures in your answers. 1. 2. 3. 4. 5. 6. Fundamentals (40 points) Read through Chapters 22, 23, and 24 in your textbook and take notes on these chapters. This information is considered previous knowledge, and will not be covered in AP Chemistry next year. Create a flow chart for classification of matter, including examples. Complete the following nomenclature practice. a. Calcium sulfate f. LiOH b. Ammonium nitride g. P4S10 c. Lithium nitrite h. NI3 d. Tricarbon octahydride i. BaCl2 e. Dinitrogen monoxide j. Fe3(PO4)2 Fill in the blanks of the common ion sheet included in the packet. Complete the following mole practice. a. Calculate the mass of oxygen produced if 3.450 grams of potassium chlorate is completely decomposed by heating in the presence of a catalyst (Manganese dioxide). b. What is the empirical formula of a compound that contains 53.73% Fe and 46.27% of S? c. Determine the number of molecules present in 4.56 mol of nitrogen (N2). d. How many grams of methane (CH4) are present in 5.6 moles of methane gas? e. Calculate the mass in grams of 12.4x1015 atoms of neon. f. What mass of copper is required to replace silver from 4.00 grams of silver nitrate dissolved in water? Cu(s) + AgNO3 → Cu(NO3)2 + Ag(s) g. Calculate the molar mass of ammonia. h. Calculate the molar mass of sodium hydrogen carbonate (baking soda). i. When benzene reacts with bromine, bromobenzene is produced. What is the theoretical yield of bromobenzene in this reaction when 30.0 g of benzene reacts with 65.0 g of bromine? If the actual yield was 56.7 g what was the percentage yield? C6H6 + Br2 → C6H5Br + HBr j. Chlorine and fluorine react to form chlorine trifuoride gas. If you start with 1.75 mol of chlorine and 4.3 mol of fluorine, what is the limiting reactant? How much of the excess remains? Create a flowchart for physical and chemical properties and changes, including examples. 2 7. 8. 9. 10. 11. 12. 13. 14. Write and balance the following chemical equations. When needed, consult the activity series sheet included in the packet. If no reaction occurs, simply write no reaction. a. Boron trifluoride gas reacts with water to give liquid hydrogen fluoride and solid boric acid (H3BO3). b. The reaction of magnesium oxide with iron form iron (III) oxide and magnesium. c. Ethane burns in air. d. Calcium carbonate decomposes into calcium oxide and carbon dioxide. e. Zinc is dissolved in sulfuric acid produces the salt zinc sulfate and hydrogen gas. f. Sulfurous acid and potassium hydroxide react in a double displacement reaction. g. Sulfurous acid is synthesized from sulfur dioxide and water. h. Tin reacts with water in a single displacement reaction. i. Calcium reacts with water. j. Aluminum reacts with hydrochloric acid. DENSITY PRACTICE a. A 47.3 mL sample of ethanol (C2H5OH) has a mass of 37.32 g. What is its density? b. If 116 g of ethanol is needed for a chemical reaction, what volume is needed? The density of ethanol is 0.785 g/mL. c. What is the mass of a rectangular piece of copper 24.4 cm x 11.4 cm x 8.9 cm? The density of copper is 8.92 g/cm3). d. The mass of an empty container is 77.664 g, but when filled with water the container weighs 99.65 g. Calculate the volume of the container using 1.00 g/mL as the density of water. e. Vinegar has a density of 1.0056 g/cm3. What is the mass of 3 liters of vinegar? Write a short summary of accuracy and precision. Include real world and scientific examples. List and define the four states of matter, including examples. Matter (25 points) Give the complete electron configuration for the following atoms and ions. a. Al f. N-3 -1 b. Br g. Fe +2 c. Mg h. Fe+2 d. O i. Fe+3 e. Mg j. S Draw the Lewis Dot Diagrams for the following elements. a. Sodium f. Lead (III) b. Nitrogen g. Barium c. Boron h. Sulfur d. Xenon i. Helium e. Lead (II) j. Selenium Use the following URLs to take notes on Periodic Arrangement. http://dl.clackamas.edu/ch104/lesson6arrangement.html http://dl.clackamas.edu/ch104/lesson6periodictrends.html http://dl.clackamas.edu/ch104/lesson6periodictrends2.html LIGHT/WAVES PRACTICE a. A green line of wavelength 4.86x10-7m is observed in the emission spectrum of hydrogen. Calculate the energy of the photon. b. Calculate the wavelength in meters of an electron traveling at 1.24x107 m/s. The mass of an electron is 9.11x10-28 g. c. What color light is seen at 6573 Å? d. Copper (I) chloride emits a blue light wavelength of 450 nm. What is the quantum of energy that is emitted at 450x102 nm? 3 15. 16. 17. 18. 19. 20. 21. e. The laser in an audio CD player uses light with a wavelength of 7.80x102 nm. Calculate the frequency of this light? Use the following URL to take notes on Atomic Spectra. https://www.youtube.com/watch?v=1uPyq63aRvg Use the following URL to take notes on Orbitals. https://www.youtube.com/watch?v=KrXE_SzRoqw Behavior of Matter (15 points) GAS LAWS PRACTICE a. A sample of nitrogen collected in a laboratory occupies a volume of 725 mL at a pressure of 0.971 atm. What volume will the gas occupy at a pressure of 1.40 atm, assuming the temperature will remain constant? b. A container of oxygen has a volume of 349 mL at a temperature of 22°C. What volume will the gas occupy at 50°C? c. A cylinder of gas has a pressure of 4.40 atm at 25°C. At what temperature in K will it reach a pressure of 6.50 atm? d. A sample of hydrogen gas has a volume of 65.0 mL at a pressure of 0.992 atm and a temperature of 16°C. What volume will the hydrogen occupy at 0.984 atm and 25°C? e. An engineer pumps 5.00 mol of carbon monoxide gas into a cylinder that has a capacity of 20.0 L. What is the pressure in kPa of CO inside the cylinder at 25°C? f. A student collects oxygen gas by water displacement at a temperature of 16°C. The total volume is 188 mL at a pressure of 92.3 kPa. What is the pressure of the oxygen collected? g. An unknown gas has a density of 0.0262 g/mL at a pressure of 0.918 atm and a temperature of 10°C. What is the molar mass of the gas? h. What is the pressure in kPa of 3.95 mol of chlorine gas if it is compressed in a cylinder with a volume of 850. mL at a temperature of 15°C? MOLAR VOLUME PRACTICE a. Calculate the molar volume of 2500 mL of carbon dioxide gas at STP. b. Calculate the molar volume of 1.20x1024 molecules of nitrogen dioxide at STP. c. Calculate the molar volume of 22.41 grams of hydrogen sulfide gas at STP. Use the following URLs to take notes on the Kinetic Molecular Theory. https://www.youtube.com/watch?v=fIMdIMACyN4 https://www.youtube.com/watch?v=apOSDqZd6Fg Equilibrium (16 points) Use the following URL to take notes on Le Chatelier’s Principle. https://www.khanacademy.org/science/chemistry/chemical-equilibrium/factors-that-affect-chemicalequilibrium/v/le-chatelier-s-principle pH PRACTICE a. The hydroxide ion concentration of an aqueous solution is 6.4x10-5 M. What is the hydronium ion concentration? b. Calculate the hydroxide and hydronium concentration in a 7.50x10-4 M solution of HNO3. c. Determine the pH of a 0.00118 M solution of HBr. d. What is the pH of a solution with a hydroxide concentration of 1.0x10-5 M? e. Calculate the pH of a solution with a hydroxide concentration of 2.90x10-11 M. f. Calculate the hydroxide ion concentration of a 0.05 M sodium hydroxide solution. g. What is the hydronium ion concentration of a solution of a 0.150 M nitric acid solution? h. The pH of an aqueous solution of NaOH is 12.9. What is the molarity? i. What is the pH of a 0.0001 M solution of NaOH? j. What is the molarity of a solution of the strong base Ca(OH)2 in a solution that has a pH of 10.80? 4 22. 23. 24. 25. 26. Use the following URLs to take notes on Buffers. https://www.youtube.com/watch?v=gjKmQ501sAg https://www.youtube.com/watch?v=LJmFbcaxDPE Thermochemistry (18 points) Write a short summary of the Law of Conservations (Matter, Energy, Work). CALORIMETRY PRACTICE a. How much heat is required to heat 75.0 g of aluminum from 25.0°C to 175.0°C? The specific heat of aluminum is 0.900 J/g°C. b. A 75.0 g piece of aluminum initially at a temperature of 175.0°C is dropped into a calorimeter containing 150.0 g of water at an initial temperature of 15.0°C. What will the final temperature be once the system has reached equilibrium (assume no heat is lost by the container). The specific heat of aluminum is 0.900 J/g°C. c. When 3.425 kJ of heat is added to a calorimeter containing 50.0 g of water, the temperature rises from 24.00°C to 36.54°C. Calculate the heat capacity of the calorimeter in J/°C. The specific heat of water is 4.184 J/g°C. d. A piece of silver has a mass of 362 g and a heat capacity of 85.7 J/°C. What is the specific heat of silver? e. Calculate the amount of heat absorbed (in kJ) by a 6.33 kg sample of copper heated from 20.5°C to 324.3°C. Use the following URL to take notes on: Entropy, Enthalpy, and Free Energy. https://www.khanacademy.org/science/chemistry/thermodynamics-chemistry Electrochemistry (5 points) Use the following URL to take notes on Oxidation-Reduction. https://www.youtube.com/watch?v=5rtJdjas-mY 5 Complete this sheet as a part of your summer packet. It will be returned to you to use on tests throughout the year. Ion Name Formula Charge Acetate Ammonium Carbonate Chlorate Chlorite Chromate Cyanide Dichromate Hydroxide Nitrate Nitrite Perchlorate Permanganate Peroxide Phosphate Sulfate Sulfite 6 Activity Series of Metals in a Single Displacement Reaction. Keep this page and put it in your three ring binder you will use for this class. 7 Lab Notebook Setup Rubric You will need a lab notebook for AP Chemistry and it needs to be a composition notebook (not a spiral notebook). You will do all of your lab work in this notebook. Make sure you set up your lab notebook according to the following guidelines before the first day of school. These are due with your AP Chemistry Summer Packet. You will receive a quiz grade (25 points) for having your lab notebook prepared on the first day. Please write only on the front side of your pages (reserve the back side for scratch work). You will need to write all formal lab information (that will be assessed) in blue or black ink ONLY. Each lab will be assessed based on the following requirements: Title Purpose Prelab Questions Materials Procedure Data/Observations Post Lab Discussion You need a cover page on the first page of your notebook. The cover page should include: Your name Lab partner’s name (will be filled out first week of school) Lab station (will be filled out first week of school) Ms. Fleming AP Chemistry 2017-2018 You need a 1-2 page table of contents which will include the names of the labs with corresponding pages. Example: Density Lab Measurements Lab Page 1 Page 3 After your table of contents, you need an equipment list with hand drawn pictures to refer to during labs. The list of equipment you will need to have on these pages is below: o o o o o o Beaker Beaker clamp Buret Buret clamp Bunsen burner Clay triangle o o o o o o Crucible and lid Crucible clamp Erlenmeyer flask Evaporating dish Funnel Glass rod o o o o o o Graduated cylinder Iron ring Pipette Ring stand Scoopula Test tube o o o o o o Test tube clamp Test tube rack Thermometer Utility clamp Watch glass Wire gauze You will also need in your lab notebook the rubric (included in the next page) for the formal lab reports you will be writing this year. Please tape the rubric to the INSIDE BACK COVER of your composition notebook so you can reference it throughout the year. You can find this rubric on the next page of this packet. 8 Print this page and tape it to the INSIDE BACK COVER of your lab notebook before the first day of school. Results Methods Materials Introduction Title Section Requirements AP Chemistry Lab Rubric Superior Excellent Average 4 of 4 requirements present 3 of 4 Author Name Lab Partner’s Name Lab/Lab Report Title – Cannot be the title of the lab in the lab manual – has to be related to the lab but unique Date Stated question/problem being studied Clearly stated purpose of lab Personal hypothesis stated Cited any definitions/research used Used research other than the Lab Manual 10 of 10 requirements present 8 of 10 Formatted correctly as bulleted list Proper detail included (how much, many, etc) List was complete-no items left out 3 of 3 requirements present 2 of 3 1 or less of 3 Steps written as commands in a list format NO pronoun usage (I, We, etc) Detailed but not redundant NOT copied directly from the lab manual – put into own words Comprehensive; nothing missing Data presented in table/graph Correct units were used Each figure has a number, title, and explanation Results were clearly analyzed - explain ONLY results, no explanations of why 3 of 3 requirements present 2 of 3 1 or less of 3 10 of 10 requirements present 8 of 10 6 of 10 4 of 10 2 or less of 10 10 of 10 requirements present 8 of 10 6 of 10 4 of 10 2 or less of 10 4 of 4 requirements present 3 of 4 2 of 4 1 of 4 0 of 4 Results and Analysis was tied back to purpose of lab Explanation of why you got the results you got Address if personal hypothesis is valid or invalid Possible influence of errors on conclusion Implications of findings – how can you expand on this research Resources correctly cited in body of lab report Resources correctly cited in bibliography Correct format for citations used You must have at least 2 sources of information, other than the lab manual Overall format is clear Overall format is concise & neat Each section has a heading 3 of 3 requirements present 2 of 3 1 of 3 No Spelling Errors No Grammatical errors Do Not Use I, We, Our, My, etc 3 of 3 requirements present 2 of 3 1 of 3 Syntax Format Citations Conclusion Totals 2 of 4 Needs Improvement 1 of 4 Not even close 0 of 4 6 of 10 4 of 10 2 or less of 10 Comments Total Grade /50 9
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