Espertise ™ Scientific Facts 3M ESPE Lava Plus High Translucency Zirconia: Translucent and Strong ™ ™ ™ Lava™ Plus High Translucency Zirconia is the next generation of Lava™ Frame Zirconia that has proven its reliability in more than 10 years of clinical history. The Lava™ Plus System is designed to enable unprece dented Lava™ Zirconia esthetics with uncompromised strength. a) Lava™ Plus High Translucency Zirconia Esthetics is determined by the viewing light, the observer and finally the optical properties of the restoration: Restorations reflect, scatter or absorb part of the viewing light while the remainder is transmitted. Theses optical properties depend on the surface texture, the chemical composition and the microstructure of the materials used. Simplified one can say that the potential of a restoration material to mimic tooth structure is determined by its color and translucency. Lava™ Plus is a complete zirconia restoration system offering a high translucency combined with a unique shading solution for full color control. This sheet focuses on the science behind the improved translucency of the Lava™ Plus material. b) No name zirconia – highlighted impurity and pore What is behind the excellent translucency of Lava™ Plus restorations? Translucency is the physical property of allowing light to pass through a material. The translucency of zirconia materials is mainly determined by • Presence of impurities and structural defects • Alumina content and distribution Impurities lead to light absorption and structural defects like pores to scattering. Both factors reduce the translucency. The high quality processing of Lava™ Zirconia minimizes these effects (Fig. 1 a). This is very much in contrast to what was found for some low quality materials (Fig. 1 b). Alumina is a dopand with many useful effects including increased aging stability of zirconia. However, Alumina has a different refractive index and can segregate in the zirconia material (Fig. 1 c) which decreases translucency by scattering. Some zirconias do not contain Alumina to enhance translucency. To fully maintain the aging stability a different approach was chosen for Lava™ Plus Zirconia: The Alumina content is reduced to 0.1 wt%. At the same time the Alumina distribution was improved to fully maintain the aging stability on Lava™ Zirconia level. 1, 2 c) Branded competitive zirconia – highlighted segregated Alumina grains Fig. 1: SEM images (3M ESPE internal data) 35 30 1-CR (%) 25 glass ceramics were found more translucent, however at a fraction of the flexural strength of zirconia (Fig. 4). 1800 1600 Biaxial Flexural Strength (MPa) A common method to compare material translucency is to determine the Contrast Ratio CR: The white light remission from a specimen placed over a standardized black (Yb) and white (Yw) background is determined. CR is calculated as CR = Yb /Yw. CR is ≤ 1, a CR value of 1 represents a completely opaque specimen. The lower CR the higher is the trans lucency of a specimen; translucency can be expressed by 1-CR. 20 a a a a 1400 1200 1000 800 600 b 400 c 200 15 0 e idg t Br cen EC nslu T O ra EN T 10 Z 5 me ™ va La me 3 FS Fra ™ a v La s Fra ™ va La Plu ax IPS e.m ss Pre MO1 IPS x ma T D L A2 CA e. Fig. 4: Biaxial flexural strength of zirconia and glass ceramic materials. Bars with same letter indicate no significant difference (P< 0.05) 4. 0 ) ) ) ) ) e ) Zr ll) nt nt) d” nd PE PE MS hn MS idg ) ce n) we de on S) TAR and) za ES ES ela Br land (DL (DL de gu slu zah on S el Wi iam LM ZR (Wie Gli HS (3M (3M irk HT (De ran rkon e( “D ia (D ENO (Wi ® ( C Z a s T e g ( a i T E t i i Z ure lu T n a on rid on Zir on nia (Z nia ram nH ™ P P NO ce irc ux yst rc irc co RB co ™ F rco Br nt ZE anslu Cr Zi va ™ Z ™ Z Zir Zir CZ va Ce ce a La Tr La TE sta ICE tau slu yst y t r O n r e C N C Pr Tra ZE ™ Fig. 2: Translucency (1-CR) of unshaded zirconia samples (1 mm thickness, Color i7, 3M ESPE internal data, partially published 3 ). 3M™ ESPE™ Lava™ Plus High Translucency Zirconia offers excellent trans lucency while keeping Alumina inside to ensure aging stability (Fig. 2). The high strength of zirconia allows thinner walled, tooth structure preserving restorations. The minimum occlusal wall thickness is 0.5 mm for Lava™ Zirconia posterior crowns as compared to 1.5 mm for lithium disilicate. The wall thickness also has a big influence on the translu cency – thin structures are more translucent. Comparing minimum allowed occlusal thicknesses reveals that A3 shaded Lava™ Plus Zirconia can reach a translucency level in the range of IPS e.max CAD LT A3 (Fig. 5). 25 45 40 A3 20 A3 35 A3 30 A3 15 1-CR (%) 1-CR (%) A3 A3 10 A3 25 20 15 10 5 5 0 0 ™ ta ys Cr HT * nia S) co LM Zir (D T n H t)* rco en Ce egud (D ™ a yst Cr ia on )* irc S ” Z LM nd (D o iam “D CZ TE Z O EN e idg r RB t en ) luc nd ns iela Tra (W TA OS N ZE r RZ ure ) t P nd en ela luc (Wi s n Tra ICE n co Zir nt ce n) slu zah ran rkon T ia (Zi s Plu E) va SP La 3M E ( ™ Fig. 3: Translucency (1-CR) of zirconia samples samples shaded A3 with the manufacturers shading liquid except “*” shaded with Zirkonzahn Prettau Color Liquid A3 (1 mm thickness, Color i7, 3M ESPE internal data, partially published 3). Zirconia is mostly used in the shaded state. Color is generated by absorbing part of the white light spectrum. Therefore shading is always accompanied with a loss in translucency. Lava™ Plus is a complete system including dyeing liquids tailored to the microstructure of Lava™ Plus Zirconia. The patented 3M ESPE ion dyeing technology allows higher translucency in the shaded state (Fig. 3). Lava™ Plus Zirconia translucency improvement was achieved keeping strength at the high level of Lava™ Zirconia. Strength of Lava™ Plus restorations was investigated at Tokyo Medical & Dental University: “… Lava™ Plus High Translucency Zirconia showed improved translucency without compromising its mechanical properties.” In the same study 3M Deutschland GmbH Location Seefeld 3M ESPE · ESPE Platz 82229 Seefeld · Germany [email protected] www.3MESPE.com IPS x ma 3 ™ va La e. 1 mm thickness 3 sA TA DL CA Plu IPS x ma e. 3 TA D L mm CA 1.5 ™ va La 3 sA m Plu 5 m 0. Minimum occlusal thickness posterior crowns Fig. 5: Translucency (1-CR) of IPS e.max CAD LT A3 and Lava™ Plus shaded A3 for a thickness of 1 mm and for the respective minimum occlusal wall thickness for posterior crowns (Color i7, 3M ESPE internal data). Lava™ Plus High Translucency Zirconia – A plus in translucency you can rely on Lava™ Plus Zirconia is smartly engineered for excellent translucency. The esthetical improvement comes with the quality you can expect from a Lava™ Zirconia restoration: Precision of fit, high strength and aging stability. This is backed up by a 15 years limited warranty on Lava™ Plus Highly Translucent Zirconia frameworks and monolithic restorations. Wear behavior of Zirconia after hydrothermal accelerated aging, Dittmann R, Urban M, Braun P, Schmalzl A, Theelke B, J Dent Res 90 (Spec Iss B):307, 2011 Wear behavior of a new Zirconia after hydrothermal accelerated aging, Dittmann R, Urban M, Schechner G, Hauptmann H, Mecher E, J Dent Res 91 (Spec Iss A):1317, 2012 3) C ontrast Ratios of Uncolored and Colored Zirconia Materials, Schechner G, Dittmann R, A. Fischer, Hauptmann H, J Dent Res 91 (Spec Iss A):1323, 2012 4) Translucency and Biaxial Flexural Strength of Dental Ceramics, Wang F, Takahashi H, J Dent Res 91 (Spec Iss A): 422, 2012 1) 2) 3M, ESPE, Espertise and Lava are trademarks of 3M Company or 3M Deutschland GmbH. Used under license in Canada. All other trademarks are owned by other companies. © 2012, 3M. All rights reserved.
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