Name: ________________________ Class: ___________________ Date: __________ ID: A Extra Practice for Midterm Multiple Choice Identify the choice that best completes the statement or answers the question. Important constants For Water ΔHfus = 6.01 kJ/mol or 334 J/g ΔHvap = 40.7 kJ/mol or 2260 J/g c = 4.18 J/goC or 1.00 cal/g oC ____ ____ ____ ____ ____ ____ 1. What type of bond do all of the molecules in the table above have in common? a. polar c. ionic b. metallic d. covalent 2. What is the volume of 63.8 g of Carbon Dioxide at a pressure of 75.0 kPa and a temperature of 345 K? a. 22.4 L c. 8.23 L b. 55.4 L d. 78.4 L 3. How much energy would be required to raise the temperature of 75.0 g of water from 25.0 oC to 75.0oC? a. 15.7 kJ c. 1.25 x 106 J b. 334 kJ d. 4.85 kJ 4. What is the correct noble gas electron configuration for a Chloride ion? c. [Ne]3s23p5 a. [Ar]3s23p5 b. [Ar]3s23p6 d. [Ne]3s23p6 5. What is the correct order of the following bonds in terms of decreasing polarity? a. As-Cl, P-Cl, N-Cl c. P-Cl, N-Cl, As-Cl b. As-Cl, N-Cl, P-Cl d. P-Cl, As-Cl, N-Cl 6. How many lone pairs of electrons are on the central atom of nitrogen trihydride? a. 1 c. 3 b. 2 d. 4 1 Name: ________________________ ____ ____ ____ ____ ____ 7. Which of the following covalent bonds is the most polar? a. C---C c. C---Cl b. C---Br d. C---H 32+ 8. Arrange the following elements: P , S , K , Ca2+, Sc3+, in order of increasing ionic size. a. Sc3+, Ca2+, K+, S2-, P3c. P3-, S2-, K+, Ca2+, Sc3+ + 2+ 3+ 23b. K , Ca , Sc , S , P d. Sc3+, Ca2+, K+, P3-, S29. Which of the following elements has the smallest atomic size? a. Cesium c. Calcium b. Oxygen d. Chlorine 10. A syringe contains 10 ml of a gas at 120. kPa. What is the pressure if the volume is compressed to 4.2 mL. a. 50. kPa c. 290 kPa b. 350 kPa d. 101.3 kPa 11. Why is boiling a cooling process? a. The particles with less kinetic energy c. The particles with more potential energy b. ____ ID: A leave the liquid first, leaving the remaining particles with more kinetic energy. The particles with more kinetic energy leave the liquid first, leaving the remaining particles with less kinetic energy. d. leave the liquid first, leaving the remaining particles with less potential energy. The particles with less potential energy leave the liquid first, leaving the remaining particles with more potential energy. 12. In the above phase diagram for carbon dioxide, carbon dioxide is a liquid at 250 C and a very high pressure. Carbon dioxide solidifies when the temperature decreases and the pressure remains constant. Which letter represents the point at which all three states coexist? a. A b. B c. C d. D 2 Name: ________________________ ____ ____ ID: A 13. What is the specific heat of a substance if 1560 cal are required to raise the temperature of a 312-g sample by 15°C? cal g°C cal 0.33 g°C cal g°C cal 1.33 g°C a. 0.033 c. 0.99 b. d. 14. The following equation shows the reaction that occurs when nitroglycerine explodes. 4 C3H5O9N3 --> 12CO2 + 6N2 + O2 + 10H2O + 1725 kJ This reaction is ____________. a. endothermic c. a combination reaction b. exothermic d. a combustion reaction ____ ____ ____ ____ 15. How much heat must you add to boil 101 g of water at 100oC? a. 4.18 x104 J c. 2.26 x107 J 5 b. 2.28 x 10 J d. 3.34 x 104 16. What is the molarity of 200 mL of solution in which 2.0 moles of sodium bromide is dissolved? a. 2.0M c. 0.40M b. 4.0M d. 10M 17. How many mL of a 2.0M NaBr solution are needed to make 200.0 mL of 0.50M NaBr? a. 25 mL c. 50 mL b. 150 mL d. 100 mL 18. What is the molality of a solution containing 8.0 grams of solute in 0.50 kg of solvent? (molar mass of solute = 24 g) a. 0.17m b. 0.67m c. 4m d. 1.67m 3 Name: ________________________ ID: A Multiple Response Identify one or more choices that best complete the statement or answer the question. ____ 19. a. hydrochloric acid b. sodium nitrate ____ ____ c. sucrose d. ammonium sulfate 20. Carbon disulfide is nonpolar. The molecular shape and bond angle consistent with this observation is _____. a. A c. C b. B d. D 21. How many valence electrons does an atom of any halogen group have? a. 4 c. 7 b. 5 d. 8 4 Name: ________________________ ID: A ____ 22. Using the electron dot structure, a phosphide ion would most look like _____. ____ a. A c. C b. B d. D 23. Which of the following pairs of elements is most likely to form an ionic compound? a. magnesium and fluorine c. nitrogen and sulfur b. sodium and aluminum d. oxygen and chlorine ____ ____ ____ ____ 24. Choose the correct molecular shapter for ammonia, NH3. a. bent c. trigonal planar b. linear d. trigonal pyramidal 25. What causes water molecules to have a bent shape, according to VSPER theory? a. the attractive forces between the two c. ionic attractions and repulsion hydrogen’s b. the unusual location of the free d. repelling from the unshared pairs of electrons electrons 26. This force will influence the temperature at which molecules change state. a. electrostatic c. electromagnetic b. intermolecular d. intramolecular 27. Which of the following elements has the same Lewis dot structure as Silicon? ____ a. Germanium c. Gallium b. Aluminum d. Arsenic 28. Which sample is composed of particles arranged in a regular geometric pattern? a. Cl2 (g) c. LiCl (s) b. CCl4 (l) d. LiCl (aq) 5 Name: ________________________ ____ ID: A 29. Which structural formula represents a nonpolar molecule? a. ____ c. b. d. 30. Which structural formula represents a polar molecule? a. ____ ____ ____ ____ ____ ____ ____ c. b. d. 31. Determine the shape of SCl2: a. bent c. tetrahedral b. linear d. trigonal pyramidal 32. The reason salt crystals, such as KCl, hold together so well is because the cations are strongly attracted to a. neighboring cations. c. free electrons in the crystals. b. the protons in the neighboring d. neighboring anions. nucleus. 33. Determine the shape of HNO: a. linear c. tetrahedral b. bent d. trigonal planar 34. What intermolecular forces are present in CH3OH? a. Dispersion c. Hydrogen Bonding b. Dipole-Dipole d. Ionic Bonding 35. Which of the following molecules will have hydrogen bonding? a. H2O2 c. H2O b. CH4 d. HF 36. What intermolecular forces are present between molecules of HCN? a. Dipole-Dipole c. Hydrogen Bonding b. Dispersion d. Ionic Bonding 37. Is the following process exothermic or endothermic? CO2(l) --> CO2(s) a. Endothermic b. Exothermic 6 ID: A Extra Practice for Midterm Answer Section MULTIPLE CHOICE 1. ANS: D 2. ANS: B Stt. 4h PTS: PTS: 1 3. ANS: A St. 7d STA: 4h 4. 5. 6. 7. 8. 9. PTS: ANS: ANS: ANS: ANS: ANS: ANS: 1 D A A C A B 1 STA: PTS: PTS: PTS: PTS: PTS: 7d 1 1 1 1 1 PTS: 1 STA: PTS: PTS: STA: PTS: PTS: PTS: STA: PTS: STA: PTS: STA: 7a 1 1 Ch.7.d 1 1 1 Ch.6.d 1 Ch.6.d 1 Ch.6.d STA: 2b St. 1c PTS: 1 10. ANS: C 11. ANS: B St. 7a 12. 13. 14. 15. 16. 17. 18. PTS: ANS: ANS: OBJ: ANS: ANS: ANS: OBJ: ANS: OBJ: ANS: OBJ: 1 D B 17.1.3 B B D 16.2.1 C 16.2.2 B 16.4.1 1 DIF: L1 REF: p. 509 | p. 510 DIF: L2 REF: p. 481 DIF: L2 REF: p. 483 | p. 484 DIF: L2 REF: p. 491 ID: A MULTIPLE RESPONSE 19. ANS: C 2c PTS: 1 20. ANS: B 2f PTS: 1 21. ANS: C 2a PTS: 1 22. ANS: C 2e PTS: 1 23. ANS: A 2c PTS: 1 24. ANS: D 2f PTS: 1 25. ANS: D 2f PTS: 1 26. ANS: B 2c PTS: 1 27. ANS: A 2e PTS: 1 28. ANS: C 2c PTS: 1 2 ID: A 29. ANS: C 2f PTS: 1 30. ANS: D 2f PTS: 1 31. ANS: A 2f PTS: 1 32. ANS: D 2c PTS: 1 33. ANS: B 2f 34. 35. 36. 37. PTS: ANS: ANS: ANS: ANS: 1 A, B, C A, C, D A, B B PTS: PTS: PTS: PTS: 1 1 1 1 3
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