CHEMISTRY WKST KEY: Ch. 6 Review p.1 23 1) 6.022 x 10 2) a) 24.31 g Mg 3) a) ratio of the atoms 4) a) BaCl2 137.33 g + 2(35.45 g) = 208.23 g b) P4O10 4(30.97g) + 10(16.00 g) = 283.88 g c) Pb(C2H3O2)4 207.2 g + 8(12.01 g) + 12(1.01 g) + 8(16.00 g) = 443.40 g d) Ba(OH)2•8H2O 137.33 g + 2(16.00 g) + 2(1.01 g) + 8(18.02 g) = 315.51 g 5) b) 6.022 x 10 ) ( a) )( ( ( a) NaCl )( )( b) H2O )( 8 8 ) 8 ) ) )( 9) ( ) H ( c) 7) H )( ) 8 b) 8) H 8 ) H ( c) 6) H ( H b) Mg atoms b) mole ratio of the elements ( a) 23 ) CHEMISTRY WKST KEY: Ch. 6 Review 10) g solute = (2.25 M)(40.00 g/mol)(1.750 L) = 158 g NaOH 11) H ( 8 )( ( 12) a) CuSO4 ) 63.55 g + 32.07 g + 4(16.00 g) = 159.62 g ( b) Ba(NO3)2 ) 137.33 g + 2(14.01 g) + 6(16.00 g) = 261.35 g ( 13) 8 ) H ( ( ) ) ) 14) H 100x = 22.25x + 11125 g 77.75x = 11125 g x = 143.1 g Mg(NO3)2 p.2 CHEMISTRY WKST KEY: Ch. 6 Review p.3 15) ZnSO4 65.38 g + 32.07 g + 4(16.00 g) = 161.45 g 8 161.45x = 3269 g x = 20.25 g Zn 16) 8 0.342 x = 22340 g x = 65321.64 g = 65300 g 17) a) C3H4O3 18) b) CH 8 8 8 8 S1.00Cl2.01 SCl2 - assume 100 g sample 60.8 % Na 60.8 g Na 28.5 % B 28.5 g B 10.5 % H 20) 8 2.62 g S 8.44 g – 2.62 g = 5.82 g Cl 19) c) C14H18N2O5 C2HCl 8 8 10.5 g H 8 H 8 8 Na1.00B1.00H3.94 H H H 60.48 C2x3H1x3Cl1x3 C6H3Cl3 NaBH4 CHEMISTRY WKST KEY: Ch. 6 Review 21) p.4 - assume 100 g sample 42.87 % C 42.87 g C 3.598 % H 3.598 g H 28.55 % O 28.55 g O 25.00 % N 25.00 g N 8 8 H H H H 8 8 8 8 8 8 C2.001H2.00O1.000N1.000 8 8 C2H2ON empirical formula 8 C2H2ON ≈ 56 8 22) C2x3H2x3O1x3N1x3 ( a) ) ( b) )( )( ( c) d) 8 C6H6O3N3 molecular formula )( 8 ) ) 8 K = °C + 273 = 12.9°C + 273.15 = 286.05 K = 286.0 K e) °F = 1.8(°C) + 32 = 1.8(−44°C) + 32 = −79 + 32 = −47°F “ z ” 23) A Kelvin 24) The atomic mass for hydrogen (as well as for all elements) is the average of ALL the hydrogen atoms in the universe. 25) The purpose of distilling a solution is to separate the liquid from the solutes dissolved in the liquid. 26) This was a physical change because the liquid, which was H2O, never changed—it was still H2O as steam and H2O when converted back into a liquid. The color seen in the solution was from something that was dissolved in the liquid. 27) When steam is converted back into liquid water, the water loses energy. This is an exothermic process. CHEMISTRY WKST KEY: Ch. 6 Review p.5 28) When distilling the colored substance in the solution is left behind in the boiler—only the pure liquid (H2O in our case) was distilled. When filtering, the filter paper does NOT stop any substance still dissolved in the liquid. Therefore, the colored substance passes through the filter paper since it was still dissolved in the H 2O. 29) Solubility of the solids in the liquid determines whether or not they can be separated by filtering. One of the solids in the mixture is soluble in H2O while the other substance was insoluble in H2O. The insoluble solid will be stopped by the filter paper while the soluble solid will pass through. 30) a) 1 mol Fe(s) : 1 mol Cu(s) b) Since the ratio between Fe(s) and FeSO4(aq) is 1:1, there will be 0.75 mol FeSO4 produced. c) CuSO4 when dissolved in H2O gives a blue color to the solution. The filtrate was still blue after filtering, indicating that not all the CuSO4 reacted. Thus, there was enough CuSO4 to make sure all the Fe reacted. 31) You will find the mass of the object by weighing it on a balance. There are two ways to find the volume: If the object is small enough, place an known amount of water in a graduated cylinder. Place the object into the water and see how much the volume of the water in the graduated cylinder increases—this will be the volume of the object. If the object is too large for a graduated cylinder, put water into a container with an overflow spout—fill it with enough water to have some come out of the spout. After the water quits coming out of the spout, place a graduated cylinder under the spout, place the object into the water, and catch the water that comes out of the spout. The volume of water that comes out will be the volume of the object. 32) 1.00 33)
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