Stainless Steel and Hygienic Design Claus Qvist Jessen & Erik-Ole Jensen; Damstahl a/s Everybody wants to stay healthy, and food hygiene is an integral part of this. Outside Europe, the lack of fridges and the use of wooden cutting tables frequently causes stomach illness among tourists. In Europe, such matters are easily taken care of in our kitchens, however, when the food/pharma moves into large-scale plants, all cleaning has to be carried out automatically. As we are suddenly not able to see what we are doing, the risk of contamination is far higher, increasing the risk of severe illness and, at worst, death. That this is not all fiction was proved in Denmark in the summer of 2014. Here, an inadequate cleaning procedure at a factory producing pork rolls caused a major outbreak of Listeria which in turn caused the tragic death of 18 people. In 2015, Listeria caused another three deaths in Denmark. Fig 1: Further south, keeping the meat in the sun, directly exposed to the heat of the sun as well as the plethora of flies, frequently causes a few upset stomachs. This happy butcher is from Mauritania, West Africa; note the swarm of flies on the piece of meat to the lower left. Stainless Steel is not Always Stainless On the micro level, the cleanability of the stainless steels surface is closely related to the corrosion resistance of the steel. Stainless steel owes it’s fantastic corrosion resistance to an invisible layer of mainly chromium oxide. This “passive” layer effectively protects the metal and ensures that the corrosion process never really gets any further than the natural maintenance of the oxide layer. Treated correctly, and not exposed to extreme conditions, stainless steel becomes “an eternity metal”. If stressed beyond its capability, corrosion may occur very fast, and penetration may be a question of weeks rather than years. Either the steel remains passive and lasts forever, or failure happens within a few weeks of operation. In that respect stainless steel reminds a lot of a fishing line (Fig. 2)! If a fishing line is subject to a load below its breaking strain, it lasts forever, however, if the load is too heavy, the line snaps at once. Most anglers know the sad feeling of losing river giant due to a weak line. Stainless steel behaves very much the same way. When subject to a load below the breaking strain, the system lasts forever – even though we get very close to the limit, such as a 17.9 kg load in an 18 kg fishing line. Once the load exceeds the breaking strain of the line, the punishment is swift and consequent (Fig. 2). The fishing line metaphor even explains the importance of correct manufacturing. Heat tintings, surface defects, incorrect welding, crevices and other weaknesses may reduce the breaking strain of the line, and corrosion may occur at conditions which should be harmless when exposed to the perfect fishing line. Actually, we can learn a lot about the corrosion properties of stainless steel by going fishing……. ☺ consideration – not the distance in between the peaks. This is very important as the corrosion resistance as well as the cleanability of the surface are highly dependent on the surface topography. Thus, rather than trying to describe the surface condition through just one single number (Ra), we recommend that the surface profile is used. However, evaluating from the profile whether the surface is good enough or not is much more difficult. Fig 2: Corrosion of stainless steel frequently resembles a fishing line. If the line is stressed below its breaking strain, it lasts forever. Alternatively, if the line is stressed beyond the limit, failure occurs quickly. Here, increasing the load from 10 to 17.9 kgs does not affect the life-time of fishing line (with 18.0 kg breaking strain). Increasing the load from 17.9 to 18.1 kg causes the line to snap. There is nothing in between. In practice, pitting corrosion, crevice corrosion and stress corrosion cracking (Fig. 3) are all major dangers to the stainless steel equipment, and the risk of corrosion has not reduced throughout the years. This is due to the fact that the production time of the equipment has increased from, say, eight hours daily to more than 16 hours. As such, the cleaning time is vastly reduced, and stronger and stringer disinfectants are used. Consequently, the “standard stainless steel grade” in food/pharma has moved from the 4301 class (~ AISI 304) to the molybdenumcontaining 4401 class (~ AISI 316). Different Surface, Different Ra Both dealing with corrosion and hygiene, the surface of the steel plays a major role. As a rule, a fine surface has a tendency of increasing the corrosion resistance as well as the cleanability, and this has made various authorities to implement a “standard” saying that Ra ≤ 0.8 µm. In practice, Ra is an average throughout a certain length, however, it only takes the heights of the roughness peaks and the depth of the valleys into Fig 3: A fine example of stress corrosion cracking in austenitic stainless steel type EN 1.4307 (AISI 304L). The steel originates from the bottom of an oven used for baking bread, and the corrosion was caused by salty water dripping onto the bottom of the oven. As such, using a single factor like the Ra has a certain purpose, however, it is only useful for comparing two surfaces which have been subject to similar treatments – i.e. a ground surface with another ground one, or two rolled ones. In contrast, the Ra is less useful when comparing two specimens which have been treated differently. By experience, a ground surface of Ra = 0.8 µm is somewhat less corrosion resistant and equally less cleanable than a cold-rolled surface sporting the same Ra. Then why doesn’t this always show in a corrosion testing? Because corrosion testing is usually done with respect to pitting corrosion alone, and such a testing only lasts a couple of hours. In such a short time span, crevice corrosion may not reveal itself as a threat, and a surface containing crevices may show a too positive result. Such a surface is shown below in Fig. 4. Doing so, a higher Ra is accepted for the cold-rolled 2B, simply because such a surface is, by experience, easier to clean (and is more corrosion resistant) than a ground surface with the same Ra. Ground / glass bead-blasted: Ra ≤ 0.8 µm Fig 4: “Real” micro section through a ground (P80) surface, 4404, 2 mm. The yellow line shows the real surface. The blue line is the roughness profile when using indefinitely fine laser equipment; the red one show the profile when using a physical roughness meter. The two green arrows show “hiding places” for bacteria = initiation sites of crevice corrosion. Such sites can never be measured properly. Photo by Rasmus Lage; Technical University of Denmark. All this is particularly important above water (or periodically above water), as the various types of surface vary a lot when it comes to holding on to the corrosive/bacterial water. After all, there is a reason why we grind our garage door before painting it: We want the new paint to stick – and so does the saltwater, the dirt and other corrosive stuff, along with bacteria and other contaminations. Thereby, it is obvious that the almost universal Ra ≤ 0.8 µm is far from ideal and doesn’t really relate to “real life”. A fine example of the importance of the surface treatment when dealing with contact time is shown in Fig. 5. Ideally, the Ra should reflect the practical experience, and we therefore recommend that different Ra’s are used for different surface classes, all dependent on the mechanical surface treatment. 2B, cold-rolled: Ra ≤ 1.2 µm 2B, post-pickled: Ra ≤ 1.2 µm Weld, pickled: Ra ≤ 3.0 µm Such a list is never perfect, however, it correlates with practice. As such, there is no reason to grind the tank welds at all. In practice, a “perfect” weld is quite corrosion resistant and equally cleanable. After all, all assembly welds in tube systems are left as they are (pickled at the most), strongly indicating that there is no need for a subsequent grinding. If needed, the tank welds may be ground in a narrow belt, 40 mms on each side of the seam. Fig 5: Superficial pitting corrosion above water observed on a stainless steel tube grade 4432 (2.5 % Mo) mounted of a salt vessel at a Danish dairy. The back wall suffers from no corrosion at all, despite the fact that the conditions are exactly the same as the tube – and the wall is made of the lower-alloyed 4404. So, why the difference? The tube has been ground, while the back wall hasremained as the dull and grey 2B. The latter is much less prone to collecting salts and humidity than any ground or blasted surface. Where to Find a 30 cm Tall Welder? During the latest decades, outsourcing has become increasingly popular. Unfortunately, this is bad news for the communication in between the designer and the welder. The larger the distance in between the two (physically and mentally!), the bigger is the risk of a communication breakdown. Through blueprints, the orders may flow from the designer in Europe to the welder in China, however, the designer never gets to know if his design is impossible to make properly. Often his design includes very little space for the welder to do his job properly, however, there is no one to tell him that the 30 cm welder has yet to be born. Fig 7: The example from Fig. 6 carried out in practice. Flow Design Ideally, flow systems should provide the free and unhindered flow from A to B, including a high degree of drainability, and a minimised risk of creating air pockets. Some general “advice” is listed below: Ensure that the equipment can be properly cleaned. The simpler, the better. Drainability! Stagnant water may end up as a puddle of bacteria, and may cause corrosion as well. Corrosion may lead to hygienic problems. In order to deliver the best performance, the designer and constructor need to know the production methods. Unfortunately, this is often classified as “a company secret”. Pick the best surface for the job – not necessarily the one with the lowest Ra (see above). Optimize the welding procedure; no weld defects are permitted – crevice corrosion and bacterial growth may take place. Good manufacturing practice, please. Fig 6: Not all designs are equally easy to make. On the paper, the grey top version (30 x 15 mm steel bars, 4307) looked brilliant, however, welding the 30° angle proved close to impossible due to the lack of physical space. Instead, inserting a bend in the lower bar (green drawing, below) made the whole construction possible. Fig. 6 and Fig. 7 show such an example. The 30° angle on the top drawing may look good on the blueprint, however, making the weld requires a very small welder with an equally small piece of equipment. Such a message never gets back to the designer. Instead, by inserting a bend on the lower bar (the green drawing below) the construction is easier to make and more easy to keep clean. However, even obeying all these “rules”, funny things may happen as shown in Fig. 8. Here, the designer obviously loves elbows, as his design includes no less than four extra pieces of fittings. From a supplier point of view, this may be close to perfect, but from a company point of view, this is unattractive for at least four reasons: Extra cost for buying the four elbows Extra cost for the assembly (five or six extra welds) Increased pressure loss during operation = extra costs Increased risk of air pockets in the top of the loop Instead of the present design, it would have been much better to skip the four elbows and instead move the T at the blue arrow to the position of the green arrow. Case closed! Fig 8: Fittings are necessary, however, they should like anything else be used with thought and care. Here, no less than four extra elbows have been inserted into the construction (the red arrows), however, that solution is bound to increase the costs of building and operating the system. By moving the T-piece from the position of the blue arrow to the green one, all four elbows can be omitted. Claus Qvist Jessen is chemical engineer (MSc) and PhD and works with Damstahl a/s, Denmark, as a consultant engineer specialised in stainless steel, corrosion and corrosion As a writer Claus has produced a number of articles on the topic, and left his footprint in several articles as well as five books on the topic, notably “Stainless Steel and Corrosion” (Damstahl, 2011) and “Stainless Steel for Hygienic Design in Food / Pharma” (Damstahl, 2015). Erik-Ole Jensen is mechanical engineer (BSc) and has spent more than 25 years in the Danish food industry, mostly with Arla. Currently, he is employed with Damstahl a/s as consultant engineer, specialised in hygienic design, control and inspection. As a writer, Erik-Ole has produced a number of articles as well as half of the book “Stainless Steel for Hygienic Design in Food / Pharma” (Damstahl, 2015).
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