Indian Journal of Fibre & Textile Research Vol. 34, December 2009, pp. 338-344 Tensile characteristics of yarns in wet condition A Dasa, S M Ishtiaque, S Singh & H C Meena Department of Textile Technology, Indian Institute of Technology, New Delhi 110 016, India Received 22 December 2008; accepted 25 February 2009 This paper reports the tensile characteristics of cotton, polyester, viscose and polyester/viscose (P/V) ring and rotor yarns of different linear densities and blend proportions in dry and wet conditions. An experimental set-up has been fabricated, which can be attached with the tensile tester to study the tensile characteristics of yarns under water. The tenacity of yarns is found to be higher in wet condition as compared to that in dry condition for all the yarns, except the viscose yarns where tenacity drops in wet condition. The increase in tenacity in case of cotton is much higher than that in case of polyester and P/V blended yarns. In case of polyester and cotton, the breaking elongation of yarns increases while in viscose and viscose-rich P/V blended yarns, the breaking elongation decreases in wet condition. In viscose and viscose-rich P/V blended ring-spun yarns, the increase in initial modulus is found to be very high, whereas in the case of polyester and cotton, there is moderate increase in initial modulus of yarns in wet condition. In case of cotton ring-spun yarns, there is very high level of increase in work of rupture in wet condition. Yarn fineness significantly affects the tensile characteristics. Keywords: Breaking elongation, Cotton, Initial modulus, Polyester, Ring yarn, Rotor yarn, Tenacity, Viscose, Work of rupture 1 Introduction There are many application areas where textile materials are used under water, e.g. swimming or any other under water activities. It will therefore be beneficial to know the tensile characteristics of yarns under water. Yarn properties, such as dimensions, tensile strength, elasticity recovery, elongation, modulus, rigidity, electrical resistance, and energy at break point, are affected by the amount of water absorbed. In the case of polyester, although the fibre is less hygroscopic, polyester yarns or fabrics absorb water by wicking action. Similarly, in case of yarns or fabrics made of hydrophilic fibres or blends, the absorption behaviour is entirely different. There are large numbers of publications available on the effect of various parameters on tensile characteristics of yarn. But, almost all the studies were carried out with normal dry yarn. Midgely and Pierce1 first suggested the effect of rate of loading on the tensile properties of spun yarn. Balasubramanian and Salhotra2 and Kaushik et al.3 investigated the influence of rate of loading on the tensile behavior of rotor-spun yarns in dry conditions. Serwatka et al.4 gave a new approach for modeling the stress-strain curve of linear textile products in dry conditions. They explained the stress-strain curve of yarn in three _____________ a To whom all the correspondence should be addressed. E-mail: [email protected] zones. Robert et al.5 studied resiliency and modulus of viscose rayon as a function of swelling and temperature in wet condition. Bryant and Walter6 measured the tensile properties of yarn, immersed in water, as a function of temperature. Paul et al.7 presented preliminary result of the deep star polymer taut leg mooring project. Preston and Nimkar8 studied the adhesion force between fibres in the yarn. They observed that the capillary water, present in the spaces between fibres, attracted to one another by the hydrostatic tension in water. The present work is undertaken to study the tensile characteristics of different types of yarns in wet condition. The tensile characteristics of yarns under water is expected to be affected by fibre type and blend proportion and also by the yarn structure. Hence, a detailed study has been reported on the effect of blend proportion and yarn count on tensile characteristics of ring and rotor yarns in dry and wet (under water) conditions. 2 Materials and Methods 2.1 Materials Polyester, viscose rayon, cotton and polyester/viscose (P/V) blend were used for the study. The specifications of cotton fibres were: ring-spun yarns–2.5% span length 30mm, fineness 4.2 micronaire; and rotor-spun yarns–2.5% span length 25 mm, fineness 4.5 micronaire. The lengths and deniers of polyester and viscose staple fibres were DAS et al.: TENSILE CHARACTERISTICS OF YARNS IN WET CONDITION 44 mm×1.4 den and 44 mm × 1.5 den respectively. The tensile tests of these staple fibres were carried out in dry and wet (under water) conditions and the results are given in Table 1. Two types of yarn structures were used, i.e. ring-spun and rotor-spun yarns. Ring-spun yarns were produced from different blend proportions of polyester and viscose (100% polyester, 65/35 P/V, 50/50 P/V and 100% viscose) and cotton of different yarn counts (10s Ne, 20s Ne, 30s Ne and 40s Ne). Rotor-spun yarns of different counts (7s Ne, 8s Ne, 10s Ne and 12s Ne) were produced from only cotton. 2.2 Methods 2.2.1 Preparation of Yarn Samples The cotton fibre was processed through blow room and card. The carded sliver was then fed to the two passage of draw frame to produce a sliver of linear density 4.54 ktex. The same drawn sliver was then processed in roving frame to produce the rovings of required linear densities. Total twenty different types of ring-spun yarns and four rotor-spun yarns were studied. 2.2.2 Evaluation of Under Water Tensile Characteristics of Yarns An experimental set-up was fabricated to study the tensile characteristics of yarns under water. The setup was attached with the Instron tensile tester (Fig. 1). The tensile tests of yarns, both in conditioned yarn (referred as dry test) and under water (wet condition), were carried out using similar test conditions to eliminate the possibilities of any errors introduced during the test. The transparent water tray was filled up with water until the yarn specimen was fully dipped in water. The yarn specimen was placed in between a fixed jaw and a movable jaw. The movable jaw moves with the help of movable jaw of Instron tensile tester through a very strong non-extensible (extension at lower level of load was almost zero) Kevlar string. The Instron tensile tester was then started and the load-elongation behaviour of the yarns under water was recorded. In this experiment, 10 kg load cell was used for test reading of yarn in dry and 339 wet conditions. Gauge length was taken as 200mm and Instron cross-head speed was kept at 100mm/min. Average of twenty readings were taken. The test results are given in Tables 2 – 6. 3 Results and Discussion 3.1 Tensile Properties of Fibres and Yarns Table 1 shows that the tenacity of cotton fibre increases to a great extent in wet conditions, whereas in case of viscose fibre the tenacity drops to a great extent in wet condition. In case of polyester staple fibre, there is hardly any change in tenacity in wet condition. As far as breaking elongation is concerned, there is hardly any change in case of polyester and viscose staple fibres, but in case of cotton, a significant increase in breaking elongation is observed in wet condition. It is a well-known fact that the polyester and viscose fibres in wet condition loose strength as compared to dry condition, while cotton shows exactly opposite trend. The increase in tenacity of cotton fibre in wet condition is due to the relief of shear stress that can occur by untwisting and unbending of the fibre. When the fibrils are bonded together, the complex stress leads to early breakdown but when they are free to move and release stress, the fibre is strong9. In case of viscose staple fibre, the drop in tenacity in wet condition is due to more amorphous region and therefore the bonds are more susceptible to be damaged by water molecule. Fig. 1 Schematic diagram of experimental set-up Table 1 Tenacity and breaking elongation of fibres in dry and wet conditions Parameter Tenacity, g/tex Elongation-at-break, % Dry Polyester Wet % Change Dry Viscose Wet % Change Dry Cotton Wet % Change 6.02 14.9 6.03 15.0 2.89 11.80 1.92 12.0 3.47 6.8 4.42 9.5 +0.25 +0.67 Dry – Tested in dry condition; Wet – Tested in wet condition. -33.6 +2.0 +27.6 +27.0 INDIAN J. FIBRE TEXT. RES., DECEMBER 2009 340 Polyester staple fibre does not show any significant change in tenacity in wet condition due to very low moisture absorption. But, when the tensile characteristics of staple yarns in dry and in under water conditions are considered, the mechanics are not straight forward. The phenomenon of fibre swelling, change in fibre-fibre surface friction due to wetting, effect of hydrostatic forces, etc. play significant role in addition to the change in fibre characteristics on tensile characteristics. 3.2 3.2.1 Ring-spun Yarns Effects of Fibre Type Table 2 shows that in general the tenacity of yarns is higher in wet condition, except in case of viscose yarns. The significant drop in tenacity in case of viscose staple fibre in wet condition is the basic reason for drop in tenacity of viscose yarns. In case of polyester yarn, tenacity in wet condition is more than that in dry condition, which is due to the formation of water film between the fibres in the yarns. Water film enhances the fibre-fibre friction and generates stickslip phenomenon between the fibres in the yarn9. In case of P/V blended yarns the combined effect of above two phenomena play important role. In case of cotton yarn, the tenacity increases significantly in wet condition. It is also clear from Table 2 that in general the increase in tenacity under water in polyester and cotton yarns is more in case of finer yarn. This may be due to the fact that more compact water film friction is created between the fibre and the water molecule of finer yarn. But, in case of other polyester- viscose blended yarns, tenacity does not increase significantly due to higher viscose fibre proportion in the blended yarn. Table 3 shows that in case of polyester and cotton the breaking elongation of yarns increases while in case of viscose and viscose-rich P/V blended yarns the breaking elongation decreases in wet condition. The increase in breaking elongation in case of polyester is found to be marginal, whereas it is very high in case of cotton yarns. This is mainly due to higher breaking elongation of cotton fibre in wet condition (Table 1). There are no definite trends in the case of polyester/viscose blended yarns, which is due to totally different nature of changes when the polyester and viscose fibres are wet. In case of cotton yarns, the increase in breaking elongation in wet condition is higher for finer yarn. Very interesting results are observed in case of initial modulus of yarns in wet condition. Table 4 shows that in case of viscose and viscose-rich P/V blended yarns, the increase in initial modulus is found to be very high, whereas in the case of polyester and cotton, there is moderate increase in initial modulus of yarns in wet condition. It is also observed that with the increase in fineness of yarns the % increase in their initial modulus becomes more in all the yarns, except in cotton yarn. The twisting and bending effects will be easier when the fibre is internally lubricated by absorbed water so that fibrils can slide past one another. This is probably the main reason why cotton fibre has lower modulus when wet. Even in the simple Table 2 Tenacity (cN/tex) of ring-spun yarns in dry and wet conditions Linear density of yarns Ne Polyester Dry Wet Polyester/Viscose (65/35) % Change Polyester/Viscose (50/50) Dry Wet % Change Dry Wet % Change 20.31 (8.30) 23.91 (6.40) +17.7 19.51 (7.31) Viscose Dry Wet Cotton % Dry Change Wet % Change 10s 31.7 (9.38) 32.9 +4.06 (6.13) 20.29 (4.96) +3.99 14.64 8.37 (8.75) (11.49) -42.8 15.34 19.82 +29.20 (4.36) (5.12) 20s 23.34 (9.19) 29.78 +27.5 20.80 23.51 +13.02 21.23 18.19 (8.50) (13.07) (6.50) (10.40) (5.92) -14.3 14.97 9.84 (9.60) (14.80) -34.2 13.75 20.36 +48.07 (5.28) (6.68) 30s 22.84 27.53 +20.5 18.67 20.77 +11.2 (13.35) (11.20) (13.40) (12.10) 19.91 18.32 (9.88) (10.16) -7.9 13.83 10.98 (10.06) (15.60) -20.6 13.34 22.88 +71.5 (8.90) (9.31) 40s 21.91 27.32 +24.69 16.43 16.31 (14.26) (13.97) (13.77) (6.40) 18.36 17.59 (10.80) (18.45) -4.19 14.77 10.43 (12.30) (16.10) -29.3 13.66 24.04 +75.9 (8.70) (8.89) Values in parentheses indicate CV% of tenacity. -0.73 DAS et al.: TENSILE CHARACTERISTICS OF YARNS IN WET CONDITION 341 Table 3 Breaking elongation (%) of ring-spun yarns in dry and wet conditions Linear density of yarns Ne Polyester Polyester/Viscose (65/35) % Change 10s 12.13 (9.00) 12.63 (7.75) +3.95 13.13 14.63 +11.4 13.56 14.17 +4.49 (7.36) (4.20) (8.50) (5.80) 18.52 16.78 -9.93 (5.50) (14.12) 7.24 9.13 +26.1 (15.32) (13.85) 20s 11.89 11.96 +0.58 12.95 13.77 +6.33 13.05 13.93 +6.31 (9.46) (4.60) (13.60) (11.18) (12.40) (11.2) 17.08 17.33 +1.46 (8.02) (15..09) 6.82 8.92 +30.79 (15.21) (13.19) 30s 8.87 9.17 +3.38 12.50 12.67 +1.36 12.75 12.20 -4.3 (15.26) (13.62) (10.32) (9.30) (11.4) (10.32) 16.12 16.02 -0.62 (12.0) (16.10) 6.03 8.44 +39.96 (13.10) (11.80) 40s 11.81 (8.10) 14.34 13.18 -8.08 (12.1) (13.90) 5.59 8.21 +46.8 (13.10) (11.85) 10.60 10.28 (13.99) (9.94) % Change -3.01 Dry Wet % Change 11.29 10.27 -9.03 (7.25) (7.22) Dry Wet Cotton Wet +2.70 Wet Viscose Dry 12.13 (9.37) Dry Polyester/Viscose (50/50) % Change Dry Wet % Change Values in parentheses indicate CV% of breaking elongation. Linear density of yarns Ne Polyester Dry Wet Table 4 Initial modulus (cN/tex) of ring-spun yarns in dry and wet conditions Polyester/Viscose Polyester/Viscose Viscose (65/35) (50/50) % Change Dry Wet % Change Dry Wet % Change Dry Wet % Change Cotton Dry Wet % Change 10s 254.85 271.62 +6.58 191.79 226.43 +18.06 176.43 287.93 +63.19 165.79 199.24 +20.17 164.45 242.17 +47.26 (8.90) (4.19) (12.70) (12.70) (10.52) (8.20) (5.52) (13.45) (6.69) (9.20) 20s 234.57 257.95 +9.96 216.17 275.98 +27.66 184.98 356.56 +92.75 206.11 270.78 +31.37 238.86 285.56 +19.55 (18.0) (13.20) (15.83) (13.60) (12.19) (12.20) (4.15) (15.52) (7.10) (10.97) 30s 333.42 388.86 +16.62 320.25 449.35 +40.31 287.69 601.18 +108.9 244.28 400.82 +64.08 250.57 297.53 +18.74 (30.38) (26.60) (12.30) (8.75) (12.03) (10.30) (7.79) (20.46) (11.32) (11.44) 40s 434.35 556.44 +28.10 539.53 962.46 +78.38 365.52 797.59 +118.2 285.75 707.31 +147.5 315.73 322.33 +2.09 (37.24) (33.80) (13.54) (11.60) (12.26) (7.60) (8.65) (19.20) (11.73) (11.90) Values in parentheses indicate CV% of initial modulus. extension of helical assembly, there is also a shear deformation, which will be easier if the fibrils are free of one another9. Table 5 shows that the work of rupture increases in wet condition for polyester yarn, whereas for viscose yarn, there is a drop in work of rupture from marginal to moderate level in wet condition. But, in case of cotton, there is very high level of increase in work of rupture in wet condition. This can be explained on the basis of per cent change in tenacity and breaking elongation of yarns in wet condition as compared to that in dry condition. Very high level of increase in the work of rupture of cotton in wet condition is mainly due to the increase in both breaking elongation and tenacity in wet condition. The trends for polyester, viscose and P/V blended yarns can be explained on the basis of changes in tenacity and elongation of these yarns in wet condition. 3.2.2 Effects of Linear Density of Yarn Effects of linear density of ring-spun yarns on tenacity in dry as well as wet conditions are shown in Table 2. It is observed that in case of polyester and cotton, with the increase in yarn fineness the % increase in tenacity is more in wet condition as compared to that in dry condition. However, in case of viscose and viscose-rich P/V blended yarns, the tenacity decreases in wet condition and there are no specific trends with the change in yarn fineness. This may be due to the fact that more compact INDIAN J. FIBRE TEXT. RES., DECEMBER 2009 342 Table 5 Work of rupture (cN/tex) of ring-spun yarns in dry and wet conditions Linear density of yarns Ne Polyester Dry Wet Polyester/Viscose (65/35) % Change Dry Wet % Change Polyester Viscose (50/50) Dry Wet % Change Viscose Dry Wet Cotton % Change Dry Wet % Change 10s 268.01 270.75 +1.02 177.07 227.59 +28.53 115.31 124.34 +7.83 (14.70) (16.97) (10.89) (15.72) (9.52) (6.59) 74.68 73.18 (7.8) (6.73) -2.10 37.32 87.43 +134.2 (8.65) (9.31) 20s 89.35 113.01 +26.48 74.55 92.95 +24.68 67.06 70.87 (13.60) (17.50) (20.35) (13.08) (10.90) (9.20) +5.68 67.04 56.21 (5.50) (5.32) -16.1 25.51 57.78 +126.5 (9.76) (16.19) 30s 43.75 67.99 +55.4 47.62 55.75 +17.07 53.95 44.05 -18.3 (13.30) (16.31) (15.20) (13.62) (17.20) (13.30) 33.70 29.20 (4.36) (3.10) -13.3 16.47 39.00 +136.8 (12.26) (12.60) 40s 43.16 44.63 +3.40 29.98 35.50 +18.41 32.46 30.88 -4.86 (6.13) (13.07) (16.90) (17.08) (13.32) (10.35) 28.83 24.03 -16.64 13.17 29.44 +123.53 (5.40) (2.40) (14.80) (15.37) Values in parentheses indicate CV% of work of rupture. water film friction is created between the fibre and the water molecule of finer yarn. It is observed from Table 3 that in all the yarns, except for cotton yarns, there is not much change in yarn breaking elongation in wet condition as compared to that in dry condition. In case of cotton yarns the breaking elongation increases significantly in wet condition. This is mainly due to the higher breaking elongation of cotton fibre in wet condition. Table 3 also shows that in case of cotton, the per cent increase in breaking elongation increases with the increase in yarn fineness. As already explained, this may also be due to the formation of water film which enhances fibre-fibre friction and thus reduces fibre-tofibre sliding. It is clear from Table 4 that initial modulus of all the yarns increases in wet condition as compared to dry yarn, irrespective of the type of material and blend proportion. This may be due to the fact that in wet condition, water film forms inside the yarn structure, which enhances the fibre-fibre friction and thus resists initial deformation. It is also interesting to observe that in case of cotton yarns, with the increase in yarn fineness, the % increase in initial modulus of yarn reduces in wet condition as compared to that in dry condition, but for all other yarns the trends are just opposite. It is observed from Table 5 that the work of rupture of cotton and polyester yarns increases in wet condition, whereas in case of viscose yarns the trend is just opposite due to the reason as explained above. No specific trends are observed in case of viscose-rich P/V blended yarns. It is also observed from Table 5 that the yarn fineness has no specific effect on the per cent increase in work of rupture of yarns. 3.3 Rotor-spun Yarns 3.3.1 Effect on Yarn Tenacity It can be observed from Table 6 that irrespective of fineness of yarn, the yarn tenacity under water is always higher than that of dry yarn. No specific trend on per cent change in yarn tenacity in wet condition is observed when the linear density of rotor yarns is changed. The trend is exactly the same as that for ring-spun yarns and the reason has been explained earlier. 3.3.2 Effect on Yarn Breaking Elongation It is evident from Table 6 that for all the yarn linear densities, the breaking elongation of yarn under water is always higher than that of dry yarn. The trend is exactly the same as that for ring-spun yarns due to the reason as explained earlier. No specific trend on the per cent change in breaking elongation of yarn in wet condition is observed when the linear density of rotor yarns is changed. 3.3.3 Effect on Yarn Initial Modulus It is clear from Table 6 that the initial modulus of yarns in wet condition is always higher than that of dry yarn. The trend is exactly the same as that for ring-spun yarns due to the reason as explained earlier. DAS et al.: TENSILE CHARACTERISTICS OF YARNS IN WET CONDITION 343 Table 6 Tensile property of open-end yarns of different fineness in dry and wet conditions Yarn parameter 7s Ne yarn 8s Ne yarn 10s Ne yarn 12s Ne yarn Dry Wet % Change Dry Wet % Change Dry Wet % Change Dry Wet % Change Tenacity 11.63 16.03 37.83 12.08 16.68 38.08 12.52 16.77 33.94 12.84 16.89 31.54 cN/tex (6.6) (6.3) (8.5) (7.87) (8.75) (8.06) Elongation at break, % 8.27 12.59 8.93 12.66 8.89 13.12 (5.06) (13.8) (6.20) (7.01) 127.9 242.4 144.1 333.6 (4.85) (16.00) (5.30) (13.96) 59.43 103.5 48.16 89.63 (9.11) (14.70) (5.96) (5.60) Initial modulus cN/tex Work of rupture, N.mm (4.9) (15.4) 131.9 143.7 (8.75) (8.00) 67.63 133.8 (9.06) (6.80) (6.8) (5.3) 52.23 9.70 12.46 (5.6) (8.6) 8.95 122.9 158.5 (5.20) (6.70) 80.01 125.8 (6.48) (13.06) 97.84 28.45 28.96 57.23 41.76 89.52 74.15 47.58 131.51 86.10 Values in parentheses indicate CV%. Also, it is very clear that the per cent increase in initial modulus increases rapidly as the yarns become finer. 3.3.4 Effect on Work of Rupture It is evident from Table 6 that for all the yarn linear densities, the work of rupture of yarn under water is always higher than that of dry yarn. The trend is exactly the same as that for ring-spun yarns due to the reason as explained above. No specific trend on the per cent change in breaking elongation of yarn in wet condition is observed when the linear density of rotor yarns is changed. 4 Conclusions 4.1 The tenacity of ring-spun yarns is higher in wet condition as compared to that of dry yarn for all the yarns, except for viscose yarns where tenacity drops in wet condition. The increase in tenacity in case of cotton is much higher than that of polyester and P/V blended yarns. In general, the increase in tenacity under water for polyester and cotton yarns is more in the case of finer yarn. For polyester and cotton, with the increase in yarn fineness the per cent increase in tenacity in wet condition enhances as compared to yarn tenacity in dry condition. 4.2 In case of polyester and cotton, the breaking elongation of ring-spun yarns increases, while in viscose and viscose-rich P/V blended yarns the breaking elongation decreases in wet condition. For cotton yarns, the increase in breaking elongation in wet condition is higher in case of finer yarn. 4.3 In viscose and viscose-rich P/V blended ringspun yarns the increase in initial modulus is found to be very high, whereas in case of polyester and cotton, there is moderate increase in initial modulus of yarns in wet condition. In case of cotton yarns, with the increase in yarn fineness the % increase in initial modulus of yarn reduces in wet condition as compared to dry yarns, but for all other yarns the trends are just opposite. 4.4 In case of polyester ring-spun yarn, work of rupture is increased and in case of viscose ringspun yarn, there is drop in work of rupture from marginal to moderate level in wet condition. But in case of 100% cotton ring-spun yarns, there is very high level of increase in the work of rupture in wet condition. 4.5 In case of cotton rotor yarn, the tenacity, breaking elongation, initial modulus and work of rupture under water are higher than that of dry yarn. Industrial Importance: There are many applications in which the textile materials are used in wet condition such as swim wear, rain wear, etc. This paper describes the characteristics of different types of yarns with various blend proportions used in such applications. 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