General Papers
ARKIVOC 2014 (iv) S1-S11
Supplementary Material
Asymmetric Michael Addition of Acetone to β-Nitrostyrenes
Catalyzed by Novel Organocatalysts Derived from
D-Isomannide or L-Isoidide
Ling-Yan Chen,a,b Stéphane Guillarme,a Andrew Whitingc and Christine
Saluzzoa,*
a
IMMM, UMR CNRS 6283, Faculté des Sciences,
Université du Maine, Av. O. Messiaen, 72085 Le Mans Cedex 09, France
b
College of Chemistry and Chemical Engineering,
Shanghai University of Engineering Science, 201620, China
c
Department of Chemistry,
Durham University, Science Laboratories, South Road, Durham, DH1 3LE, UK
E-mail: [email protected]
Table of contents
NMR data
1
H NMR and 13C NMR spectra of monothiourea 2
1
H NMR and 13C NMR spectra of monothiourea 3
1
H NMR and 13C NMR spectra of monothiourea 6
1
H NMR and 13C NMR spectra of diimine 7
1
H NMR and 13C NMR spectra of diimine 8
1
H NMR and 13C NMR spectra of compound 10a
1
H NMR and 13C NMR spectra of compound 10b
1
H NMR and 13C NMR spectra of compound 10c
1
H NMR and 13C NMR spectra of compound 10d
1
H NMR and 13C NMR spectra of compound 10e
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S2
S3
S4
S5
S6
S7
S8
S9
S10
S11
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General Papers
ARKIVOC 2014 (iv) S1-S11
1
H NMR spectrum of monothiourea 2
O
H2N
S
O
N
H
N
H
13
C NMR spectrum of monothiourea 2
O
H2N
S
O
Page S2
N
H
N
H
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General Papers
ARKIVOC 2014 (iv) S1-S11
1
H NMR spectrum of monothiourea 3
O
S
H2N
N
H
O
N
H
13
C NMR spectrum of monothiourea 3
O
S
H2 N
O
N
H
N
H
Page S3
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General Papers
ARKIVOC 2014 (iv) S1-S11
1
H NMR spectrum of monothiourea 6
CF3
O
H 2N
S
N
H
O
N
H
CF3
13
C NMR spectrum of monothiourea 6
CF3
O
H 2N
S
O
N
H
N
H
Page S4
CF3
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General Papers
ARKIVOC 2014 (iv) S1-S11
1
H NMR spectrum of diimine 7
O
N
N
N
N
O
13
C NMR spectrum of diimine 7
O
N
N
N
O
Page S5
N
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ARKAT-USA, Inc
General Papers
ARKIVOC 2014 (iv) S1-S11
1
H NMR spectrum of diimine 8
O
N
N
N
O
N
13
C NMR spectrum of diimine 8
O
N
N
N
O
Page S6
N
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General Papers
ARKIVOC 2014 (iv) S1-S11
1
H NMR spectrum of compound 10a
O
Ph
NO2
13
C NMR spectrum of compound 10a
O
Ph
Page S7
NO2
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General Papers
ARKIVOC 2014 (iv) S1-S11
1
H NMR spectrum of compound 10b
O
NO 2
Cl
13
C NMR spectrum of compound 10b
O
NO 2
Cl
Page S8
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General Papers
ARKIVOC 2014 (iv) S1-S11
1
H NMR spectrum of compound 10c
O
NO 2
Me
13
C NMR spectrum of compound 10c
O
NO 2
Me
Page S9
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General Papers
ARKIVOC 2014 (iv) S1-S11
1
H NMR spectrum of compound 10d
O
NO 2
MeO
13
C NMR spectrum of compound 10d
O
NO 2
MeO
Page S10
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General Papers
ARKIVOC 2014 (iv) S1-S11
1
H NMR spectrum of compound 10e
O
NO 2
13
C NMR spectrum of compound 10e
O
NO 2
Page S11
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