UHScienceResource.squarespace.com Simulated Exam II (SSF16Gc2E2F) UHScienceResource.squarespace.com 1 UHScienceResource.squarespace.com Disclaimer: UHScienceResource provides resources and services but is not responsible for, and expressly disclaims all liability for, damages of any kind arising out of use, reference to, or reliance on any information provided. While the information contained within the site is periodically updated, no guarantee is given that the information provided is correct, complete, and up-to-date. Moreover, UHScienceResource is not responsible for the accuracy or content of information contained in external sites provided by links. Notice to User: Great effort has been used to make this document accurate and comprehensive but may still contain typos or other errors. If any errors are found, please email them to: [email protected] UHScienceResource.squarespace.com 2 UHScienceResource.squarespace.com 1. The reaction below is endothermic. if pressure is increased N2O4(g) 2NO2(g) A. B. C. D. E. Goes toward the left toward reacants Goes to the left toward products Goes to the right toward reacants Goes to the right toward products None of the above 2. Which is the strongest acid? A. B. C. D. E. Species NH3 CH3NH2 H2NNH2 C6H5NH2 C5H5N2 Kb 1.8 x 10-5 4.4 x 10-4 3.0 x 10—6 3.8 x 10-10 1.7 x 10-9 3. If a 100 mL, 0.5 M solution of CH3NH2 (Kb = 4.4 x 10-4) is mixed with a 50 ml 0.5 M HCl solution, what is the pH? A. B. C. D. E. 1.46 10.64 4.38 6.14 None of the above 4. Ammonium chloride solid decomposes after heating in the reaction below. What is K p at the temperature for the given reaction if the total pressure is 6.6 atm? NH4Cl(s) NH3(g) + HCl(g) A. B. C. D. E. 11.6 4.38 10.9 8.39 10.2 5. Kw = 2.92 x 10-14 at 40⁰ C. Find the H3O+ and OH- and pH of water. UHScienceResource.squarespace.com 3 UHScienceResource.squarespace.com 6. For the reaction given below at 600⁰ C, Kp = 1.16. A 100 g of CaCO3 (100 g/mol) in a 10 L container is heated to 600⁰ C. What is the mass in grams of CaCO3 reacted to get to equilibrium? CaCO3(s) CaO(s) + CO2(g) A. B. C. D. E. 21.4 g 16.2 g 8.21 g 7.26 g None of the above 7. A 100 mL, 0.5 M solution of phenol (Ka = 1.05 x 10-10) is mixed with 100 mL, 0.5 M NaOH solution. What is the pH? A. B. C. D. E. 1 Greater than 7 Less than 7 Equal to 7 None of the above 8. You have a weak acid solution (0.063 M, pH = 3.95). Find its Ka 9. The equilibrium constants below are at 427⁰ C. What is the equilibrium constant for the reaction given below. 2NaO(g) Na2O2(s) Na2O(s) 2Na(l) + ½ O2(g) NaO(g) Na(l) + ½ O2(g) Na2O2(s) 2Na(l) + O2(g) Na2O2(s) Na(l) + O2(g) K = 2 x 10-25 K = 2 x 10-5 K = 5 x 10-29 K = 3 x 10-14 10. Rank 0.1 M solutions given below in order of most to least acidic KOH, HCl, KNO3, KCN, NH4Cl UHScienceResource.squarespace.com 4 UHScienceResource.squarespace.com 11. For a 1 M HF and 0.4 M KF solution mixture (Ka = 7.24 x 10-4), what is the pH? 12. N2(g) + O2 (g) 2NO(g) (Kp = 1 x 10-27 at 25⁰ C). Find the concentration of NO in molecules/cm3 in the air when equilibrium is reached at 25⁰ C (PN2 = 0.8 atm, PO2 = 0.2 atm, at 1 atm there’s ~ 2.46 x 1019 molecules) 13. A basic sodium acetate aqueous solution gives what net ionic equation? 14. For N2(g) + 3H2(g) 2NH3(g) Kp is given for the various temperatures shown below. Select the true statement. Kp = 4.34 x 10-3 at 300⁰ C Kp = 1.56 x 10-5 at 500⁰ C Kp = 2.25 x 10-6 at 600⁰ C A. Reaction shifts toward the reactants as T increases and reaction is exothermic in the forward direction B. Reaction shift toward products as T increases and reaction is endothermic in the forward direction C. Reaction shifts toward the reactants as T increases and reaction is endothermic in the forward direction D. None of the above 15. The figures below show the titration of HOCl (Ka = 1.1 x 10-9) with varying amounts of KOH. Rank the following in order of increasing pH. UHScienceResource.squarespace.com 5 UHScienceResource.squarespace.com 16. What is the pH for a 0.02M solution of HIO3 (Ka = 0.17) 1.74 17. 1.2 mol of Cl2, 7.5 x 10-3 mol of NO, 1.0 mol of NOCl are in a container that is 3.0 L. What is the K c for the reaction given below 2NOCl(g) 2NO(g) + Cl2(g) 18. What is the Ba(OH)2 (aq) concentration if pH = 11.5? 19. A solution contains 100 mL of 0.06 M HCl and 100 mL of 0.1 M NaF (HF Ka = 7.24 x 10 -4). Find the pH. 20. A container that is 1 L in volume has 0.01 atm NO, 2.0 atm O2 and 0.11 atm N2. True or False, this reaction is at equilibrium. 2NO(g) N2(g) + O2(g) (Keq = 2.2 x 103) UHScienceResource.squarespace.com 6
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