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Authors requiring further information regarding Elsevier’s archiving and manuscript policies are encouraged to visit: http://www.elsevier.com/copyright Author's personal copy Tectonophysics 500 (2011) 34–49 Contents lists available at ScienceDirect Tectonophysics j o u r n a l h o m e p a g e : w w w. e l s ev i e r. c o m / l o c a t e / t e c t o Two models for the formation of magma reservoirs by small increments Chloé Michaut a,⁎, Claude Jaupart b a b Institut de Physique du Globe de Paris, 4, av. de Neptune, 94107 Saint-Maur des Fossés, France Institut de Physique du Globe de Paris, 4, Place Jussieu, 75257 Paris Cédex 05, France a r t i c l e i n f o Article history: Received 7 November 2008 Received in revised form 22 June 2009 Accepted 19 August 2009 Available online 6 September 2009 Keywords: Magma reservoirs Crystallization kinetics Thermal evolution Plutons Bimodal volcanism Intrusion Magma injection rate Latent heat of crystallization a b s t r a c t It is now clear that magma reservoirs develop over long time intervals out of a large number of individual intrusions. Evidence from some large volcanic deposits, including those of the Bishop Tuff, California, and Fish Canyon Tuff, Colorado, indicates that such reservoirs may experience pervasive and rapid heating before catastrophic eruptions. Injection of hot primitive melt in the reservoir is often invoked to explain these observations, but this requires the rapid emplacement of a large magma volume (at least 25 km3 in less than 100 years for the Bishop Tuff) and efficient heat transfer through a thick cumulate pile. Within a magma body that grows incrementally, temperatures rise progressively and may eventually lead to a permanent volume of melt. Temperature and crystallization follow two completely different paths depending on the thickness of individual intrusive sheets. In one limit, corresponding to thick sheets, crystallization proceeds at equilibrium. Initial magma batches crystallize completely and a permanent body of melt develops progressively once ambient temperatures in the complex rise above the solidus. In the other limit, corresponding to thin sheets, crystallization is kinetically-controlled, such that initial intrusions do not crystallize completely and preserve a glassy residue. Once temperatures within the growing magma pile reach a certain threshold value, nucleation and growth of crystals get reactivated in the residual glass. Crystallization then proceeds catastrophically in a positive feedback loop involving latent heat release and temperature rise. Thus, an initial phase with no evolved melt present ends with the sudden formation of a large volume of evolved melt in a crystal mush. After this initial phase, new intrusions get emplaced in heated surroundings and follow a thermal path similar to that of the equilibrium case, with melts that become increasingly more primitive with time. Evidence for kinetic controls on crystallization in the natural environment is provided by the significant amounts of glass (up to 40%) that are found in thin isolated basaltic sills and dykes. Owing to sluggish crystallization kinetics, more glass should be generated in andesitic and dacitic magmas emplaced in similar conditions. Devitrification of such quantities of glass accounts for the rapid heating of a thick sill complex. The two models of magma reservoir formation involve different requirements: the intrusion thickness must be smaller than a critical value in the kinetic model and the average magma input rate must exceed a threshold value in the equilibrium model. For a given injection rate, a permanent magma reservoir forms in a shorter time interval and over a smaller cumulative magma thickness in the kinetic model than in the equilibrium one. The kinetic model is such that the amount of evolved melt generated increases with decreasing injection rate, in contrast to the equilibrium model for which the opposite relationship holds. © 2009 Elsevier B.V. All rights reserved. 1. Introduction Crustal magma reservoirs may feed eruptions over long time intervals that exceed one million years (Halliday et al., 1989; Davies et al., 1994; Simon and Reid, 2005). This has challenged our understanding of how such reservoirs form and evolve thermally. If a large volume of magma is emplaced rapidly with little further melt input, the bulk compositional and thermal evolution is monotonic. Convective motions in the melt are unavoidable, implying that cooling is ⁎ Corresponding author. E-mail address: [email protected] (C. Michaut). 0040-1951/$ – see front matter © 2009 Elsevier B.V. All rights reserved. doi:10.1016/j.tecto.2009.08.019 effected rapidly, typically in less than a thousand years (Worster et al., 1990; Sparks et al., 1990). One must therefore consider that magma reservoirs grow in small increments, with initial magma batches providing a heated crustal environment that allows later intrusions to remain partially molten (Petford and Gallagher, 2001; Annen and Sparks, 2002; Glazner et al., 2004; Annen et al., 2006). Detailed geological and petrological observations show indeed that large batholiths and plutons have developed out of sill and dyke complexes (Sisson et al., 1996; McNulty et al., 1996; Coleman et al., 2004). On a smaller scale, mixing and mingling figures, primitive magma enclaves as well as cycles of cooling and heating recorded by crystal zoning provide evidence for the repeated injection of primitive magma in the same storage zone. Mahood (1990) has envisioned phases of cooling Author's personal copy C. Michaut, C. Jaupart / Tectonophysics 500 (2011) 34–49 and differentiation followed by the remelting of older cumulate assemblages depending on the balance between cooling during repose periods and heating due to recharge events. In a magma body that grows by small increments, temperatures rise progressively, so that the residual melt becomes increasingly more primitive with time. In contradiction with this prediction, several eruption deposits provide evidence for the rapid formation of large volumes of evolved magma (Murphy et al., 2000; Bachmann and Bergantz, 2003). Zoning in quartz phenocrysts from the Bishop Tuff indicates that temperatures rose by about 100 °C in less than 100 yr just before eruption (Wark et al., 2007). Similar heating events prior to major eruptions have been documented in other volcanic systems (Table 1). Taken together, the different pieces of evidence available seem contradictory. In a reservoir that has grown in small increments, rapid rejuvenation of a thick cumulate pile requires a major change in the intrusion sequence and the sudden emplacement of a large primitive magma volume elsewhere. For example, emplacement of at least 25 km3 of primitive magma is required for the Bishop Tuff (Wark et al., 2007). In that particular case, the injection process must have lasted less than the duration of the heating phase, indicating that the input rate was at least 0.25 km3 yr− 1, which is much larger than known rates in active and fossil systems (Crisp, 1984; Fialko and Simons, 2000). Furthermore, heating of an essentially solid cumulate pile can only be achieved by conduction, which cannot be efficient over more than a few tens of meters in such a short time. To overcome these difficulties, Lipman et al. (1997) and Bachmann and Bergantz (2006) have proposed that rejuvenation is achieved through gas sparging, which involves pervasive gas flow due to the degassing of an underlying magma body. Bachmann and Bergantz (2003) find that about 3000 km3 of volatile rich basaltic magma is required to reheat the Fish Canyon cumulate pile in this manner, implying the accumulation of at least 2 km of magma beneath it. Another requirement is that the cumulate pile must be highly permeable. Physical models of a reservoir that grows incrementally have been developed by several authors (Petford and Gallagher, 2001; Annen and Sparks, 2002; Glazner et al., 2004; Annen et al., 2006). Successive injections progressively warm up the crust until temperatures become large enough to sustain a melt body. Tens to hundreds of thousand years must elapse before the formation of a permanent melt body and the magma input rate must be larger than a threshold value of a few centimeters per year per unit area (Annen et al., 2008), which is larger than values that have been determined for a large number of magmatic/plutonic systems (Crisp, 1984; Fialko and Simons, 2000). One observation that is not accounted for by these models is a late and rapid heating event. A recent model accounts for this peculiar feature. According to this model, magma emplacement proceeds through thin intrusive sheets which cool so rapidly that crystallization is kinetically-controlled. In such conditions, early magma batches do not crystallize completely and leave a substantial amount of residual glass. With time, as the amount of magma emplaced increases, temperatures 35 rise in the reservoir, which eventually acts to reactivate the nucleation and growth of crystals in the glassy interstitial parts of the cumulate pile (Michaut and Jaupart, 2006). Such crystallization releases latent heat at near solidus temperatures, which thermally rejuvenates the magma pile and leads to a rather homogeneous crystal mush containing chemically evolved melt. In this model, thermal rejuvenation is an intrinsic feature of the thermal sequence and proceeds fast because it operates quasi simultaneously over a large magma thickness. This can reconcile the two features of reservoir evolution invoked above, with slow growth due to small magma increments leading to a late and rapid heating/rejuvenation event. Like the other models, the kinetic model has specific requirements because it only works if individual magma additions are sufficiently thin. In this paper, we reevaluate the kinetic model and compare it to the equilibrium crystallization model of (Annen and Sparks, 2002; Annen et al., 2006). We assess its validity using recently published laboratory experiments (Pupier et al., 2008). We review field observations of glassy residues in sills and dykes as well as data on magma emplacement rates and intrusion thicknesses. One criticism of the kinetic model is that field evidence for thin intrusive sheets is difficult to find because chilled margins and contacts between intrusive units get obliterated in the interior of magma bodies (although they can be found, e.g. (Wiebe et al., 2007)). In a similar fashion, the other models for the formation of magma reservoirs have specific requirements that are difficult to test in the field. For example, direct physical evidence for pervasive gas sparging is lacking. Also, it is currently impossible to verify that the average input rate in a fossil magmatic system was indeed above the threshold value needed for a permanent melt body. Thus, we resort to indirect evidence, i.e. predictable consequences, to assess the merits, likelihood and limitations of the different models. 2. Crystallization kinetics There is plenty of evidence for some kinetic control on crystallization in geological conditions. These include crystal size variations away from chilled margins, as well as quench textures and crystal morphologies that may be found even in the deep interior of plutons (Moore and Lockwood, 1973; Tegner et al., 1993; Sisson et al., 1996). In some cases, the order of appearance of certain mineral phases is kinetically-controlled (Gibb, 1974). Such evidence has already been reviewed by Brandeis et al. (1984) and Michaut and Jaupart (2006) and need not be repeated here. A few kinetic data are available from different types of measurements, either in the laboratory or in the natural environment, but they do not allow construction of full kinetic functions over a whole crystallization interval. Calculations demonstrate that the nucleation rate is the critical input (Brandeis and Jaupart, 1987a). For our present purposes, what is important is how crystallization kinetics can be included in a large-scale thermal model and specifically how the nucleation and growth rates of crystals depend on temperature and composition. Table 1 Heating of magma reservoir before an eruption. Eruption Volume Heating Santorini, Greece, Minoan rhyodacite Soufriere Hills, Montserrat, 1995–1999 andesitic eruption Ceboruco, Mexico, Jala pumice eruption, 1000 yr Mount Unzen, Japan, 1991–1995 rhyodacitic eruption La Garita Caldera, Colorado Fish Canyon Tuff, 28 Ma Bishop tuff magma system Campanian Ignimbrite, Italy 30 km3 35 to 85 °C ~ 0.3 km3 mixed dacite (+ ~ 3 km3 rhyodacite) 5000 km 500 km3 200 km3 3 Timescales Authors Cottrell et al. (1999) 20 to 200 °C 3 yr Murphy et al. (2000) ~ 70 °C 34 to 47 days Chertkoff and Gardner (2004) 60 to 110 °C Few weeks Few months Venezky and Rutherford (1999) Nakamura (1999) Bachmann et al. (2002) <100 yr ~ 100 yr Wark et al. (2007) Pappalardo et al. (2008) ~ 40 °C ~100 °C Author's personal copy 36 C. Michaut, C. Jaupart / Tectonophysics 500 (2011) 34–49 Table 2 Values for the physical properties. Parameters and physical properties Symbol Value Thermal conductivity Heat capacity Latent heat of crystallization Magma density Magma liquidus temperature Initial silica content of magma Country rock solidus temperature Country rock liquidus temperature Intrusion depth k Cp L ρ TL C0 Tsr Tlr Zs 2.5 W K− 1 m− 1 1.3 × 103 J kg− 1 K− 1 4.18 × 105 J kg− 1 2500 kg m− 3 1187 °C 47% 800 °C 1100 °C 5 km Recent experiments shed important light on crystallization kinetics and provide benchmark data for the theoretical model (Pupier et al., 2008). For these experiments, the starting liquid composition was that of a Fe-rich basalt thought to be the parental liquid for the famous Skaergaard intrusion of Greenland. For the redox conditions of the QFM buffer and at atmospheric pressure, the natural order of crystallization is as follows: plagioclase (1175 °C), olivine (1165 °C), clinopyroxene (1130 °C) and Fe–Ti oxides (1100 °C). Experiments were conducted with two control parameters: the time spent by the melt above the liquidus and the cooling rate. Cooling rates ranged from 3 K h− 1 to 0.02 K h− 1, which are relevant to natural conditions. Pupier et al. (2008) find that nucleation of the liquidus phase critically depends on the time spent above the liquidus. The longer this time is the less efficient nucleation is. Crystallization can in fact be completely suppressed for lack of suitable nucleation sites. Pupier et al. (2008) were not able to identify nucleation sites in their experiments and proposed that they were microbubbles presumably due to the sample preparation technique (a powder that is heated to the liquidus). One expects that natural conditions favour heterogeneous nucleation due to the entrainment of xenoliths and perhaps antecrysts from the deep magma source, but the fact remains that crystallization efficiency is sensitive to the number of pre-existing nucleation sites. Even when the liquidus phase crystallizes easily, nucleation can be difficult for the other phases. In the experiments of Pupier et al. (2008), the nucleation delay for the second phase on the liquidus, olivine, is between 10 °C and 20 °C, and that for the third phase, clinopyroxene, is even larger as it exceeds 30 °C. In fact, Pupier et al. (2008) found that clinopyroxene is absent from almost all their kinetic experiments. Nucleation delays probably depend on the cooling conditions and specifically on the cooling rate, which is not kept constant in the natural environment. Thus, the only way to assess the true crystallization behaviour in geological conditions is to use data on natural samples. Numerical calculations of kineticallycontrolled crystallization reproduce the observed variations of crystal size away from dyke margins and can be used to infer nucleation and growth rates from crystal size data (Brandeis and Jaupart, 1987a; Spohn et al., 1988). The basic principle behind kinetically-controlled crystallization is encapsulated by the following equation for melt fraction U: ∂U f ðT ⁎Þ = −U τk ∂t ð1Þ where τk is a characteristic time for crystallization. U, the noncrystallized fraction, depends on time and position within the intrusion. T ⁎ = T/TL is the dimensionless temperature, with T and TL, the liquidus temperature, in K. f(T ⁎) is an effective function for the total crystallization rate which lumps together the nucleation and growth rates (Fig. 1). For scaling purposes, this dimensionless function is such that its maximum value is 1. In principle, one should introduce a separate kinetic function for each phase but there are not enough experimental data to allow this. Accordingly, we use a simple function and test it against the data of Pupier et al. (2008). We discuss Fig. 1. Effective kinetic function f for both nucleation and growth rates as a function of K2 dimensionless temperature T ⁎ = T/TL with T and TL in K. f ðT ⁎Þ = CT ⁎exp − 2 T ⁎ðT ⁎−1Þ h i K exp − 3⁎ , with K2 = 10− 3, K3 = 30, and C such that max( f ) = 1. The small horizontal T arrow shows the nucleation delay of the initial liquidus phase. Also shown is the temperature at which devitrification becomes significant. independently the key ingredients that are required for kinetics to play a significant role in natural emplacement conditions. From the available kinetic data (summarized in Tables 3 and 4), we have estimated that, to within a factor about 2, characteristic time τk is about 106 s for common basaltic magmas (Michaut and Jaupart, 2006) and this is the value we have chosen for our calculations. If dimensionless function f(T ⁎) is of the box-car type, such that it is 1 for a large range of undercoolings, the melt fraction decreases to 37% in time t = τk, or about 280 h for τk = 106 s. This is within the time-scale of the laboratory studies of Pupier et al. (2008). We use below a more appropriate kinetic function, which peaks at a dimensionless temperature of 0.96, corresponding to an undercooling (TL − T) of about 60 K for TL = 1460 K (Fig. 1). For a fixed cooling rate Γ, Eq. (1) is easily integrated and compared to the experimental data (Fig. 2). As expected from the preceding discussion, calculated values of the melt fraction are smaller than the experimental ones when nucleation sites are absent (i.e. for melts that have been kept above the liquidus for more than 10 h). They are close to the experimental values for heterogeneous nucleation and in fact underestimate the residual melt fraction for the smallest cooling rate investigated (0.2 K h− 1). Overall, calculated values are reasonably close to the experimental data. For experiments at a constant cooling rate Γ, it is easy to evaluate the influence of the two unknowns in the kinetic function, characteristic time τk and function f(T ⁎). Eq. (1) can be rewritten as follows: Ln½UðT ⁎Þ = 1 T⁎ ∫ f ðuÞdu Γτk 1 ð2Þ where Γ is positive and melt fraction U is expressed as a function of temperature (or, equivalently, undercooling). From this, the amount of glass that is formed in an experiment, noted Ug, may be obtained by setting dimensionless temperature T ⁎ at a very small value, for example 0: the result is not sensitive to the exact value chosen because the kinetic function drops to zero rapidly. Thus: LnðUg Þ = 1 0 ∫ f ðuÞdu Γτk 1 ð3Þ Author's personal copy C. Michaut, C. Jaupart / Tectonophysics 500 (2011) 34–49 37 Table 3 Rates of nucleation (I) and growth (Y) in silicate melts. Y (cm s− 1) I (cm− 3 s-1) Refs Ym = 1 × 10− 5 Ym = 5 × 10− 5 Ym = 2 × 10− 6 / / / Muncill and Lasaga (1987) Muncill and Lasaga (1987) Kirkpatrick et al. (1979) 10− 10–10-9 6 × 10− 11–10− 10 3 × 10− 11–2 × 10− 10 3 × 10− 9–8 × 10− 7 10− 9–2 × 10− 8 2 × 10− 11–5 × 10− 8 2 × 10− 11–4 × 10− 8 10− 2–1 3 × 10− 2 9 × 10− 7–6 × 10− 6 3 × 10− 4–3 × 10− 2 2 × 10− 4–3 × 10− 3 10− 3–4 × 10− 1 10− 3–8 × 10− 2 Kirkpatrick (1977) Cashman and Marsh (1988) Mangan (1990) Burckard (2002) Burckard (2002) Oze and Winter (2005) Oze and Winter (2005) Laboratory experiments on natural systems Plagioclase Basalt Pyroxene Basalt Plagioclase Basalt Plagioclase Basalt 10− 11–10− 10 10− 9–10− 8 6 × 10− 11–3 × 10− 10 Ym = 10− 9–3 × 10− 10 10− 6–10− 4 10− 6–10− 4 107–1010 Burckard (2002) Burckard (2002) Pupier et al. (2008) Pupier et al. (2008) Theoretical calculations of crystal size variations Opx and Plag. Diabase Dykes Ym ≈ 10− 7 Im ≈ 1 Brandeis and Jaupart (1987b) Mineral System Laboratory experiments on synthetic systems Ab–An Plagioclase An30 Ab–An Plagioclase An40 Ab–An Plagioclase An50 Natural systems–natural conditions Plagioclase Basaltic Plagioclase Basaltic Olivine Basaltic Plagioclase Basaltic Pyroxene Basaltic Plagioclase Basaltic Pyroxene Basaltic lava lava lava lava lava lava lava lake in-situ lake lake lake lake flow flow I and Y are average values measured in small samples at small undercoolings, Im and Ym are maximum rates over the whole crystallization interval. This introduces the width of the kinetic function, noted ΔTc⁎, which is related to the undercooling interval over which crystallization occurs: ΔTc⁎ = ∫0 f ðuÞdu 1 ð4Þ Note that this parameter is dimensionless, such that ΔTc⁎ = ΔTc/TL. Thus: " ΔT ⁎ Ug = exp − c Γτk # ð5Þ explained in Brandeis and Jaupart (1987b) and Michaut and Jaupart (2006), available measurements of kinetic rates as well as simulations of crystal size variations indicate that τk ≈ 106 s for many basalts. More evolved melt compositions are associated with sluggish kinetics and larger values of τk (Michaut and Jaupart, 2006) (Table 4). The other parameter of importance is the temperature range over which nucleation may occur. For the function f(T ⁎) chosen here, the crystallization rate becomes entirely negligible at a dimensionless temperature of about 0.65, or about 950 K for TL = 1460 K (Fig. 1). For this function and this liquidus temperature, ΔTc ≈ 100 K. ΔTc corresponds to the width of the kinetic function at mid-height and is smaller than the whole crystallization interval, which may be spread over a large temperature interval of ~500 K. This shows that the amount of glass increases with increasing cooling rate and increasing τk, as well as with decreasing ΔTc⁎. These equations show that the melt fraction is very sensitive to characteristic time τk: changing the value of τk by a factor of 2 would lead to unacceptable departures from the experimental data. We conclude that our kinetic formulation is adequate for the ferro-basalt of Pupier et al. (2008). For other magma compositions, the data are fewer. As Table 4 Laboratory determinations of peak rates of nucleation (Im) and growth (Ym) in evolved melts. Mineral System Ym (cm s− 1) Im (cm-3 s-1) Refs Plagioclase Andesite + 6.4% H20† 1.7 × 10− 9 3.2 × 10− 2 Plagioclase Granite (synthetic) + 3.5% H20 Granodiorite (synthetic) + 6.5% H20 Granodiorite (synthetic) + 12% H20 Granite (synthetic) + 3.5% H20 Granodiorite (synthetic) + 6.5% H20 Granodiorite (synthetic) + 12% H20 10− 6 ‡ Couch et al. (2003) Swanson (1977) Swanson (1977) Swanson (1977) Swanson (1977) Swanson (1977) Swanson (1977) Plagioclase Plagioclase Alkali Fs Alkali Fs Alkali Fs 5 × 10 −7 ‡ ≈10− 8 ‡ 2 × 10− 7 ‡ −7 ‡ 10 ≈10 −8 ‡ † Crystallization is induced by decompression. ‡ Not measured. Fig. 2. Mass fraction of residual melt as a function of temperature calculated for cooling rates equal to 0.2 °C/h and 3 °C/h, using (2) and kinetic function f (Fig. 1). For comparison, results from different experiments from Pupier et al. (2008) are indicated with different symbols. Experiments XP01 and XP04 were both conducted at a cooling rate of 0.2 °C/h. Experiments XP06 and XP07 were conducted at a cooling rate of 3 °C/h. Author's personal copy 38 C. Michaut, C. Jaupart / Tectonophysics 500 (2011) 34–49 3. Controls on the thickness of individual intrusive sheets physical properties that are not known accurately, however, and it is useful to evaluate natural observations. The time-scale for conductive cooling of an intrusion of thickness d is given by: 2 τd = d 4κ ð6Þ where thermal diffusivity κ is typically ≈10− 6 m2 s− 1. This characteristic time must be compared to the kinetic time-scale τk. For τd/ τk ≪ 1, kinetic limitations do not allow large rates of nucleation and growth and the melt does not crystallize completely, leaving a glassy residue. The amount of residual glass decreases with increasing values of τd/τk. In the other limit, such that τd/τk ≫ 1, kinetics are not important and crystallization proceeds at equilibrium. For τk = 106 s, the ratio τd/τk is equal to 1 for d = 2 m. We now evaluate the controls on the thickness of individual intrusions using both simple mechanical models and observations on both active and fossil volcanic systems. 3.1. Mechanics of emplacement For the geometry of a sill, solutions are available for the inflation of a circular fracture fed from the center (Fialko et al., 2001a). For the purposes of this discussion, we treat roof deformation in an approximate manner using the analytical solution for an elastic plate whose edges are clamped, which is valid for small roof aspect ratios, i.e. for small values of the depth to radius ratio of the magma sheet (Fialko et al., 2001a). This simple solution is within a factor of 3 of that for the circular crack for aspect ratios that are smaller than 0.5. We assume a constant magma overpressure ΔP within the intrusive sheet. The vertical displacement of the roof is largest at the axis, where it is equal to: 2 w= 4 3 ð1−ν Þ ΔPR 16 E h3 ð7Þ where E is Young's modulus, ν Poisson's ratio, h the roof thickness (or reservoir depth) and R the intrusion radius. The displacement amplitude is proportional to the magmatic overpressure and very sensitive to the intrusion size (here radius R). For illustration purposes, we use R = 10 km, h = 5 km and a typical value of 4 × 1010 Pa for E/(1−ν2). The magma overpressure is unknown in practice, but may be estimated using two different arguments. One argument is that this overpressure is due to magma buoyancy and hence cannot exceed the pressure difference at the top of a static magma column extending from source to emplacement level. In reality, most of the magma buoyancy is taken up by viscous head losses due to flow and hence a static calculation provides an overestimate of magma overpressure. Taking into account the compressibility of silicate melt, the average buoyancy of basalt in crustal rocks is about Δρ = 102 kg m− 3. For a magma column extending over 20 km, as appropriate in an extensional environment, the maximum static magma overpressure is about 2 × 107 Pa. Another argument is that the magma overpressure cannot exceed the tensile strength of upper crustal rocks, which is less than 107 Pa (Rubin, 1995). We therefore consider that ΔP < 107 Pa, which leads to w < 4 m for R = 10 km and h = 5 km. Note that the displacement is smaller for smaller magma bodies with R < 10 km. In this calculation, we have assumed a uniform magma overpressure over the whole roof area, and hence have neglected viscous losses due to the horizontal flow of magma filling the cavity. In reality, the magma overpressure must decrease away from the injection point, so that the average overpressure applied to the roof region is smaller than the above estimates. We conclude that it is difficult to envision individual intrusive sheets that are more than a few meters in thickness. The calculation depends on several parameters and 3.2. Deformation in active volcanic zones Monitoring of ground deformation in active volcanic zones has considerably improved recently due to the development of new instruments and techniques such as satellite InSAR. Most cases investigated so far do not allow clear-cut conclusions on the geometrical shapes of intrusions and data interpretation relies on either the Mogi point-source or an inflating spherical body. The geometry of a sill has been used to fit the data in very few instances. Fialko et al. (2001b) have studied broad surface uplift in Socorro, New Mexico and determined that a deep crustal source has been inflating there at a rate of about 6 × 10− 3 km3 yr− 1 over a 30 yr interval between 1951 and 1981. Such a long period of inflation is obviously not consistent with a sudden intrusion event and Fialko et al. (2001b) have proposed that the observed deformation is due to crustal anatexis induced by the intrusion of mafic magmas. More recently, InSAR images of an intrusive episode at Eyjafjallajškull volcano, Iceland, indicate the injection of a sill at a depth of 6.3 km (Pedersen and Sigmundsson, 2006). The sill thickness is about 1 m and the total intruded volume is small (≈0.03 km3). 3.3. Sills, laccoliths and sill complexes Several studies document the presence of individual intrusive units which usually are a few meters thick (Table 5). We briefly review some of the available evidence. In Iceland, Gudmundsson (1995) has described sheet swarms with an average thickness of about 1 m near extinct central volcanoes. Many of these swarms are associated with large plutons which can be interpreted as fossil magma reservoirs. The small Njardvik sill is wellexposed and consists of at least seven injections over a total thickness of 20 m (Burchardt, 2008), which corresponds to an average sheet thickness of less than 3 m. In the Isle of Mull, Scotland, where there was a large central volcano, one finds a large number of sills whose thicknesses typically vary between 0.5 and 6 m (Preston et al., 1998). These sills involve a range of magma compositions and were fed from a reservoir or storage zone. They can be separated in two different groups depending on their thickness and characteristics. Sills that are thicker than ≈3 m fed fissure eruptions, are associated with large thermal aureoles and lack chilled margins, indicating that they were kept active for extended lengths of time (Holness and Humphreys, 2003). Thus, they may not be representative of intrusions involved in the build-up of a magma reservoir at depth. In areas where there is no evidence for large volcanoes, magma sheet thicknesses are also in the same range. Laccoliths are typically in a range of 50 m–1 km thickness and are often found near individual sills with thicknesses of a few meters (Corry, 1988). For example, one finds 0.5–10 m thick diorite sills near 10–200 m thick laccoliths at Henry Mountains, Utah (Johnson and Pollard, 1973). Detailed field mapping shows that the latter are in fact made of several intrusive sheets whose thickness is typically a few meters (Jackson and Pollard, 1988; Morgan et al., 2008). Dolerite sills that intrude Silurian sedimentary rocks in SW Connacht, Ireland, have thicknesses in the 2–7 m range (Mohr, 1990). Amongst these, the thickest ones are clearly made of several sheets. At deeper structural levels in the crust, identification of individual sheets is more difficult but has been made in several instances. 0.1 to 4 m thick units have been identified in the Onion Valley complex, (Sisson et al., 1996). In the Lightning Creek complex, Queensland, Australia, the thickness of intrusions ranges from 1 mm to a few meters (Perring et al., 2000). The border phases of the McDoogle pluton, Sierra Nevada, California, terminate via lit-par-lit injections of Author's personal copy C. Michaut, C. Jaupart / Tectonophysics 500 (2011) 34–49 39 Table 5 Sheeted sill complexes. Location Composition Sill thickness Refs Sierra Nevada Batholith, Onion Valley, California Upper sill complex Lower sill complex Hornblende gabbro Hornblende gabbro 0.1–1.5 m 2–4 m Sisson et al. (1996) Everest region, eastern Nepal Leucogranite cm to several m Viskupic and Bowring (2005) Southeast Coast Plutonic Complex, British Columbia Scuzzy pluton margins Tonalite cm to 100 m Brown (2000) Queensland, Australia Lightning Creek sill complex Quartzofeldspathic 1 mm to a few m Perring et al. (2000) McDoogle Pluton and adjacent plutons, Sierra Nevada, California Sheeted intrusions Mafic granodiorite 1 to 10 m Mahan et al. (2003) Njardvik, Northeast Iceland Sill Basalt 3 m on average Burchardt (2008) Loch Scridain, Isle of Mull, Scotland Sill Complex Tholeiite to rhyolite 1 to 14 m (Preston et al., 1998; Holness and Humphreys, 2003) Icelandic cone-sheet swarms Extinct central volcanoes Regional dyke swarms Geitafell volcano, SE Thverartindur volcano Gabbro Gabbro Gabbro Gabbro 1 m on average 2 m on average 0.5 to 1 m 0.9 m on average Gudmundsson (1995) Gudmundsson (1995) Gudmundsson and Brenner (2005) Klausen (2004) numerous sheets with a typical thickness of a few meters (Mahan et al., 2003). The fact that individual intrusive sheets are typically a few meters thick is in good agreement with estimates of injection rates and repose time intervals that have been obtained at a large number of volcanic and magmatic systems (Crisp, 1984; White et al., 2006). Repose time intervals between two eruptions are typically between 10 and 102 yr when primitive lavas are involved (White et al., 2006). They are much larger for intermediate to silicic compositions, between 104 to 106 yr, presumably because the formation of chemically evolved melts requires time for magma accumulation, differentiation and assimilation at depth. Repose time intervals between two eruptions of primitive lavas provide estimates for the time separating individual intrusive events. For time intervals between 10 and 100 yr and eruption rates per unit area in the ~10− 3–10− 2 m yr− 1 range (Crisp, 1984), we find that the characteristic thickness of an individual intrusive sheet is indeed about 1 m. 4. Two crystallization models The thermal model has already been described in Michaut and Jaupart (2006) and its main features are summarized in the Appendices, where the governing equations are also given. The thermal problem is solved in the vertical direction only because of the small aspect ratios of sill complexes. Intrusive sheets of thickness d are emplaced at a constant time interval τi, such that the average magma input rate is Q = d/τi. The peculiar thermal evolution of such a sill complex is recapitulated in detail in Appendix B, where we show results that did not appear in Michaut and Jaupart (2006). Parameters of the model are given in Table 2. Calculations were made for a simple binary eutectic diagram and a simple kinetic function involving specific choices for parameters that remain poorly constrained. Thus, the results may not be very accurate and are only meant to illustrate the important features of the kinetic model. We assess the applicability of this model using observations on the amounts of glass in natural intrusions and simple thermal balance arguments. The importance of kinetic effects may be measured by dimensionless ratio τd/τk, which is very sensitive to the intrusion thickness. In this section, we compare two cases with the same input rate Q = 0.025 m yr− 1, one with 4 m thick intrusions (4 m every 160 yr), for which kinetic effects are negligible, and another one where units are only 1 m thick (1 m every 40 yr) and crystallize in a kineticallycontrolled regime. For the former case, we chose a thickness of 4 m because thicker sills may develop convective instabilities upon cooling and hence evolve in a different regime than the conductive one studied here. For the latter case, the small thickness was chosen at the lower end of the natural range in order to illustrate the kinetic model in its most blatant form, with large amounts of residual glass. 4.1. Thick intrusions: equilibrium crystallization 4.1.1. Thermal evolution In this case, magma injections are thick enough for crystallization at thermal equilibrium (τd ≫ τk). Crystallization proceeds to completion even in the first sill emplaced in cold country rock and all latent heat is released soon after emplacement. Temperatures increase progressively with each new injection (Fig. 3). At t = τce = 110 kyr, the solidus temperature is reached in a complex that extends over 2.75 km in height. At that time, there is still no residual melt and yet another intrusion must occur for temperatures to rise above the solidus. Subsequent evolution is slow and a permanent body of melt builds up gradually, so that a large number of intrusions are required to sustain a large magma reservoir. During the initial phase at temperatures below the solidus, the amount of latent heat released is maximum. Once temperatures exceed the solidus, crystallization does not proceed to completion (Annen and Sparks, 2002) and latent heat gets released in ever-diminishing amounts. In this second phase, residual melts become progressively more primitive. 4.1.2. Conditions for the formation of a permanent magma reservoir Here, “permanent” means that the storage zone sustains a volume of melt for times longer than the interval between two intrusions. For thick injections, a minimum input rate is required (Annen et al., 2008). Each new intrusion acts to enhance the thermal anomaly that builds up in the roof region. If injections are allowed to proceed indefinitely, thermal steady-state conditions are achieved, such that Author's personal copy 40 C. Michaut, C. Jaupart / Tectonophysics 500 (2011) 34–49 For larger rates of injection, the temperature at the top of the storage zone eventually increases above the solidus. The approximate thermal balance is: Qρ½CP ðTl −Tmax Þ + LχðTmax Þ = k Tmax −T0 ZS ð11Þ where χ(Tmax) is the fraction crystallized at temperature Tmax. This equation shows that the amount of melt sustained in the storage zones increases with input rate Q. 4.1.3. Time to reach the solidus At temperatures below the solidus, the amount of heat lost to the surroundings by each intrusion is equal to ρ(CPΔT + L) per unit area, when T < Ts, with ΔT = Tl − T. The heat lost is evacuated by conduction between two intrusions, i.e. in time τi. We assume that the maximum temperature is at the top of the system, corresponding to sheets that get emplaced at the top of the pile. Heat is transported through a thermal boundary layer of thickness δ ≈ (κt)1/2. An approximate heat balance at the roof for the cooling of one intrusion is: Fig. 3. Maximum temperature evolution in two different sill complexes growing at a rate of 0.025 m/yr. Dashed line, sills are 4 m thick and are injected every 160 yr. Solid line, sills are 1 m thick and are injected every 40 yr. The solidus temperature is reached after 67 kyr, i.e. for a sill complex of 1.67 km thickness in the kinetically-controlled scenario (thin intrusive sheets), and after 110 kyr, i.e. for a sill complex of 2.75 km thickness, in the equilibrium scenario (thick sheets). the amount of heat brought by each injection is balanced by heat lost by conduction through the roof rocks. The minimum magma input rate Qc for a permanent melt body corresponds to such a steady-state with the temperature at the top of the sill complex at the solidus and can be estimated with a very simple thermal balance. As will be seen later, the time required to reach the solidus exceeds 100,000 years. For such a long time, the thermal halo extends over a few kilometers and hence over a large fraction of the roof. We may therefore assume that the conductive heat flux out of the reservoir is: φT = k TS −T0 ZS ρd½CP ΔT + L≈k T−T0 τi ðκtÞ1 = 2 ð12Þ where τi is the time until the next intrusion and T the roof temperature. Thus, T = Ts is achieved at time t = τce such that: 2 Ts −T0 −2 Q τce ≈κ ΔTs + L= CP ð13Þ where we have used Q = d/τi. This simple analysis fits very well the results of the full numerical simulation (Fig. 4). 4.2. Thin intrusions For the specific parameterization used in the present calculations, crystallization is kinetically-limited for d < 4 m. In this case, it does not go to completion and leaves a glassy residue in the solidified sheet. ð8Þ where TS is the solidus temperature, T0 ≈ 0 the surface temperature and ZS the roof thickness, i.e. the reservoir depth. The total heat released by one intrusion is the sum of sensible heat due to cooling from the injection temperature Tl to the solidus temperature and latent heat due to crystallization. Crystallization proceeds to completion and the thermal balance is: Qc ρ½CP ðTl −Ts Þ + L = k Ts −T0 ZS ð9Þ and hence: Qc = kðTs −T0 Þ ZS ρ½CP ðTl −Ts Þ + L ð10Þ Using k = 2.5 W m− 1 K− 1, Tl = 1187 °C, Ts = 1000 °C, T0 = 0 °C, ρ = 2500 kg m− 3, CP = 1300 J kg− 1 K− 1 and ZS = 5000 m, L = 4.18 × 105 J/k, the critical rate of injection is equal to 0.01 m yr− 1 per unit area, i.e. 4 m every 400 yr, at the top of the range of geological input rates determined by Crisp (1984). This value is consistent with the numerical results of Annen et al. (2008). One should note that this estimate corresponds to thermal steady-state in the roof region and that more heat is lost by the magma pile in early phases of intrusion, when the thermal aureole in the roof region is thin. As a consequence, early formation of a permanent magma reservoir requires magma input rates that are larger than Qc. Fig. 4. Time to reach the solidus or time for catastrophic devitrification as a function of magma input rate Q. Circles: time for catastrophic devitrification τck for 1 m thick injections; diamonds: time to reach the solidus τce for4m thick intrusions. Thin line: time to reach the solidus calculated from Eq. (13) using TS = 1000 °C, TL = 1187 °C. Bold line, time for catastrophic devitrification, i.e. time to reach temperature Tc at which kinetics start to kick in, calculated from a similar thermal balance as Eq. (13), but with no latent heat release. In both cases, the simple thermal balance allows a very good fit to the full numerical results. Author's personal copy C. Michaut, C. Jaupart / Tectonophysics 500 (2011) 34–49 We present results for d = 1 m, which should be considered as a limit case emphasizing the amount of glass that can accumulate in a frozen magma pile. 4.2.1. Thermal and structural evolution The basic evolution is the same as before, with temperatures gradually rising in the sill complex (Fig. 3). Crystallization does not proceed to completion for a large number of injections and a large amount of uncrystallized magma accumulates in the storage zone. With time, as temperatures increase, the thermal contrast between a new injection and the older sheets decreases, which enhances crystallization and hence latent heat release. Eventually, temperatures become large enough to reactivate nucleation and growth. Because of latent heat release, the magma pile has a peculiar thermal evolution with the residual glass crystallizing whilst temperatures are rising. Starting from low crystallization rates at large undercoolings (Fig. 1), heating promotes faster nucleation and growth and hence large rates of latent heat release. This process is such that temperatures rise very rapidly and may be called runaway devitrification (see Appendix B). The solidus is reached at t = τck = 67 kyr for Q = 0.025 m yr− 1, 43,000 years earlier than for 4-m thick intrusions (Fig. 3). At that time, a transient reservoir of residual liquid in a crystal mush (with 10–25 wt.% liquid) is formed and the sill complex is much thinner than in the equilibrium model. Extensive crystallization of magma within the sill complex leads to the formation of a large volume of very evolved and homogeneous melt. In addition, rapid heating enhances melting of the encasing rocks. A large volume of evolved melt from two different sources is therefore made available for eruption. Fractional crystallization is rapid and typically occurs over a few tens to a few hundred years, so that almost no intermediate lavas can be sampled by eruption. On Fig. 5, melt compositions are sampled every 40 yr at the maximum temperature in the sill complex, just before a new intrusion event. Before the runaway devitrification event, only primitive lavas associated with the latest injection can be sampled at the surface. Due to devitrification, the silica content of the non-crystallized part jumps from 57 to 75 wt.% in 40 years only. In this example, devitrification generates melt at the eutectic. The time to the devitrification event increases as the magma input rate decreases (Fig. 4). As in the equilibrium model, this time is approximately proportional to Q− 2 because the basic thermal balance is essentially the same. For the kinetic function used here, devitrifi- 41 cation begins at temperatures below the solidus, and hence the time to the runaway event is less than the time to reach the solidus in the magma pile. Dividing the volumes of the Fish Canyon and Bishop Tuff deposits by the areas of the associated calderas, and accounting for the presence of crystals in the Fish Canyon tuff, we estimate that pure melt had accumulated over a cumulative thickness of at least 1 km in both cases. By extrapolation of the curves in Fig. 11, these volumes are achieved at magma input rates of ≥10− 3 m/yr. These curves can also be deduced from a simple thermal argument which reproduces the full numerical simulations, and hence are valid over a larger parameter range than that of the calculations. For our calculations, we have used relatively high values for the solidus and liquidus temperatures of country rock (800° and 1100 °C) and primitive magma (1000° to 1200 °C). Using lower values for one or the other, much larger volumes of liquid would be obtained (see Appendix B). If the deep magma source remains active after the catastrophic devitrification event, temperatures continue to increase gradually with each new magma injection. A key difference with the initial phase is that temperatures are high enough for equilibrium crystallization. As temperatures rise, new injections crystallize less than in the initial, kinetically-controlled, phase, and a permanent melt body grows progressively, as in the equilibrium model. The composition of the melt gradually evolves from highly differentiated to primitive, spanning the whole compositional range if the magma source remains active for long enough (Fig. 5). 5. Conditions for the rejuvenation of a thick magma pile by devitrification As explained above, the kinetic model relies on a single function for the crystallization rate that lumps together the nucleation and growth of several mineral phases. Laboratory kinetic data are not sufficient to determine the full function over the whole crystallization interval (Brandeis and Jaupart, 1987b), implying that our numerical model may not be perfectly accurate. Furthermore, the calculations were made for a basalt to take advantage of the relatively large data set available and in particular of the experiments by Pupier et al. (2008). Thus, they cannot be applied directly to other magmas. They do illustrate, however, the basic physical principles for runaway devitrification and allow estimates of the intrusive sheet thicknesses that are required. We also note that crystallization kinetics seem to be Fig. 5. Left: maximum temperature as a function of time for 1 m thick intrusions injected every 40 yr. Right: composition of the non-crystallized fraction at the depth where the temperature is maximum, as a function of time. Until the catastrophic devitrification event, glasses are primitive in composition and hence lavas that can be sampled at the surface are also primitive and associated with new injections at depth. As runaway devitrification proceeds, evolved liquids are formed rapidly. Author's personal copy 42 C. Michaut, C. Jaupart / Tectonophysics 500 (2011) 34–49 more sluggish for more evolved melts, such as andesites for example (Table 4). To evaluate the relevance of the devitrification mechanism in natural conditions, we turn to geological observations and simple thermal calculations. 5.1. Residual glass in mafic intrusions Reduced to its essentials, the mechanism requires that enough residual glass remains after cooling of the initial intrusions for devitrification to elevate temperatures significantly. Data on the amount of residual glass in a number of sills and dykes can be found in many old papers aimed at documenting magmatic differentiation trends. We list a few such determinations in the following, keeping in mind that slow devitrification over large timescales may obliterate interstitial glassy residues. Another important limitation is that all the data pertain to high-level intrusions involving magmas which had already started to degas, as shown by the presence of small vesicles. Degassing generates undercooled melt and hence may trigger early crystallization before emplacement. Thus, the data may well underestimate the amount of glass that can be generated at crustal depths that are appropriate for magma reservoirs. Emplacement at deeper crustal levels would occur in hotter country rock, but the thermal contrast would still be large enough for glass generation (Michaut and Jaupart, 2006). For reference, we note that the base of the Eskdalemuir tholeiitic dyke, in the Southern Uplands of Scotland, whose thickness is about 50 m, contains 42.2% glass (Elliott, 1956). Chilled margins invariably contain much more glass than intrusion interiors and we focus on the latter. The glass fraction is 25% within a 3 m-thick dolerite sill at Dalmeny, Scotland, and 30% within a 15-m wide dolerite dyke at Kinkell, Scotland (including chlorophaeite, a product of late glass alteration) (Walker, 1930). Glass percentages from the central parts of three other basaltic Tertiary Scottish dykes of unreported thicknesses range from 6 to 21% (Walker, 1935). All samples analyzed contain significant amounts of ilmenite and magnetite, some of which seem be due to the late breakdown of the glass (Walker, 1935). Thus, the amount of pristine glass may have been larger than the values quoted. Reviewing data from a large number of basaltic samples, Walker (1935) found that the amounts of glass and pyroxene are anticorrelated, which indicates that the glass was formed when pyroxene was on the liquidus. This illustrates the importance of pyroxene in the kinetically-controlled crystallization sequence, which had already been emphasized by the experiments of Pupier et al., (2008). The ~65 Ma Delakhari sill is part of the Deccan Trap intrusion sequence and exhibits upper and lower chilled zones containing >12% glass (Sen, 1980). Glass is present (about 5 to 10%) throughout the whole intrusion, even though it is quite thick (~200 m). This large sill is noteworthy because it fed eruptive fissures and hence was probably active for an extended length of time, which is not favorable to the formation of glass (Holness and Humphreys, 2003). Interestingly, the pyroxene content is also negatively correlated with the glass content, decreasing from ~ 32% at the center to ~ 27% at the margins. 5.2. Devitrification by clinopyroxene nucleation and growth Several experimental studies illustrate how devitrification proceeds in basaltic glass samples that are heated in controlled conditions. Magnetite and pyroxene are the first mineral phases to appear at temperatures which may be as low as 650 °C (Bandyopadhyay et al., 1983). Yilmaz et al. (1996) have identified two exothermic peaks of crystallization in basaltic glass at 788 °C and 845 °C, corresponding to diopside and augite, respectively. Znidarsic-Pongrac and Kolar (1991) report that the first phase to appear in diabase glass is diopside, at 865 °C, and that crystallization proceeds from magnetite nuclei. Observations on natural glassy basalts confirm that clinopyroxene is indeed the first major phase to crystallize upon devitrification (Fowler et al., 2002; Monecke et al., 2003). Together with the Pupier et al. (2008) experiments, these laboratory studies emphasize the peculiar kinetics of pyroxene crystallization in both the cooling of a melt and the heating of a basaltic glass. Such characteristics take on special significance in the light of the fact that the amounts of glass and pyroxenes are negatively correlated in tholeiite and dolerite sills. 5.3. Amount of glass required for a heating pulse The magnitude of heating induced by devitrification can be calculated without a complete thermal model. Devitrification generates heat locally and hence may raise temperatures over a thick pile rapidly, with only thin thermal boundary layers developing at the top and bottom, so that one may neglect heat loss to the exterior (see Fig. 10). The temperature rise ΔT due to latent heat release by crystallization of a mass fraction ΔΦ of clinopyroxene is: Cp ΔT≈LCpx ΔΦ ð14Þ The latent heat of crystallization of clinopyroxene LCpx is respectively 7.7 × 105 for clinoenstatite and 6.4 × 105 J/kg for diopside (Richet and Bottinga, 1986). Using LCpx = 7 × 105 J/kg, Cp = 1200 J/kg/K, one finds that a temperature rise in the 40–100 °C range, as inferred for the Bishop Tuff and Fish Canyon Tuff for example (Bachmann and Bergantz, 2003; Wark et al., 2007), can be achieved by the crystallization of 7 to 17% glass. With only this amount of glass, however, devitrification consumes all the uncrystallized volume available and no melt is left at the end. In order to generate melt (see Fig. 10), an additional amount of glass is required: to achieve a melt fraction in the 10–20% range, a total of about 20–30% interstitial glass is needed in the complex. This total amount of glass is both expected and observed in thin intrusive magma sheets, as shown above. Melting of roof rocks does not require more glass because it is due to heat from the upper boundary layer of the complex that undergoes complete crystallization (Fig. 10). Experiments show that growth of clinopyroxene crystals from heated basaltic glass occurs at the expense of smaller particles and nuclei (Bandyopadhyay et al., 1983), suggesting that runaway devitrification may lead to pyroxene crystals that are larger than the primary ones that formed during the initial cooling phase. 6. Discussion 6.1. Contrasting features of the two crystallization models For each crystallization model, specific conditions must be met that are difficult to verify in the natural environment. The equilibrium model only works if the magma input rate exceeds a threshold value which is outside the range of values that have been determined in a large number of plutons and volcanic systems, whereas the kinetic one requires that individual intrusive sheets are thinner than a limit value of a few meters. In a similar fashion, the gas-sparging model for the rejuvenation of thick cumulate piles relies on large open-space permeability allowing the flow of large quantities of gas. It is difficult to establish which requirement in this list is met in geological conditions, which makes model validation difficult. We may evaluate which model is most appropriate, however, by comparing their respective merits. Both crystallization models require that a minimum quantity of magma must be accumulated before a permanent melt reservoir can form. They differ greatly, however, in their other characteristics. In the kinetic model, the large amount of latent heat that gets released upon devitrification cannot be evacuated efficiently by conduction. A large temperature rise ensues, leading to a significant amount of evolved melt in a short time. In contrast, in the equilibrium model, latent heat is released progressively, which allows efficient Author's personal copy C. Michaut, C. Jaupart / Tectonophysics 500 (2011) 34–49 heat loss through roof rocks and hence enhances cooling. Thus, the solidus temperature is reached at a later time than in the kinetic model. The difference of timing between the two models increases with decreasing magma input rate (Fig. 4). As a consequence, for the same magma input rate, a much larger magma volume is required to reach the solidus in the equilibrium model than in the kineticallycontrolled one. For the examples in Fig. 3, the difference is significant: with respect to the kinetic model, the equilibrium model requires an additional magma thickness of >1 km. In contrast to the equilibrium model, the kinetic one is insensitive to vagaries of injection rate. This feature manifests itself in several ways. Firstly, there is no critical input rate for the development of a permanent melt reservoir. During the first phase of gradual temperature increase, the amount of latent heat released increases with time, which prevents the establishment of thermal steady-state conditions in the roof region. Secondly, the amount of liquid formed increases with the time between two intrusions, i.e. increases with decreasing input rate (see Appendix B, Fig. 11). This is in sharp contrast with the equilibrium model, which predicts the opposite behaviour, i.e. that the volume of melt generated increases with the input rate and decreases with the time separating two intrusions. 43 contrast across the unstable part of the boundary layer, is typically several tens of degrees (Davaille and Jaupart, 1993). The Makaopuhi data are consistent with ΔTe ≈ 60 K. Magma viscosity μ depends strongly on composition and takes values from about 10 Pa s for mafic melts to more than 108 Pa s for felsic crystal-rich magmas. The heat flux at the top of the intrusion, ϕl, can be estimated from the general scaling law: ϕl = Ra Rac 1 = 3 ΔT k e = dc 2 4 2 αk ΔTe CP ρ g μRac !1 = 3 ð15Þ where Rac ≈ 103 is the critical Rayleigh number for boundary layer instability, α the coefficient of thermal expansion and dc the reservoir thickness. Note that this heat flux is in fact independent of the intrusion thickness because it is determined by the breakdown of a thin thermal boundary layer at the top of the melt body. The heat flux lost by convection decreases from ~30 W m− 2 for μ = 106 Pa s, to 5 W m− 2 for μ = 2 × 108 Pa s (Fig. 6b). Heat is supplied by a new magma addition to a sill complex at average rate ϕb such that: ϕb = ρQ ðCP ΔTb + LÞ ð16Þ 6.2. Cooling regime of thick sills The formation of a permanent melt body requires that magma remains above the solidus between two successive intrusive events. Convective instabilities should develop upon cooling in magma sheets that are thicker than about 10 m (Worster et al., 1990; Davaille and Jaupart, 1993). In such cases, therefore, cooling proceeds by convection, which is much more efficient than conduction. An unstable thermal boundary layer develops at the top of a liquid body that gets cooled from above, which controls the rate of heat loss. Magmas have temperature-dependent viscosity, implying that only the lower part of this boundary layer breaks down, so that the upper, cold and viscous part of this boundary layer remains stagnant and convective breakdown only affects its lower part. The stagnant layer includes both fully solidified magma and part of the melting interval, as shown by theoretical analysis and direct observation in lava lakes (Worster et al., 1990; Davaille and Jaupart, 1993). Scaling for variable viscosity convection as well as temperature oscillations recorded in the Makaopuhi lava lake, Hawaii, indicate that ΔTe, the temperature where ΔTb =TL −T is the temperature drop that is achieved. Using geological rates of injection per unit area derived from Crisp (1984) and relevant values of the different parameters, we find that the convective heat loss overwhelms the amount of heat brought by new intrusions, even for very large viscosities (Fig. 6a and b). For a given input rate, the thicker each intrusive sheet is, the larger the time between two injections is, and hence the more advanced the cooling of each unit is. In such conditions, a permanent melt body cannot be sustained. In this sense therefore, the succession of small but frequent magma increments which cool by conduction is in fact a more efficient heating mechanism than the punctuated emplacement of large magma volumes. From this discussion, we conclude that convection must be prevented for the equilibrium model of reservoir formation to work, which sets an upper limit of about 10 m for the thickness of intrusive sheets. From our previous estimates of kinetic controls on nucleation and growth, this model further requires that intrusive sheets are thicker than ≈4 m. We conclude that the equilibrium model of magma reservoir formation operates in a restricted thickness range. Fig. 6. a) Heat flux released by magma injection as a function of intrusion rate Q, using ΔTb = 300 °C, ρ = 2500 kg/m3 and L = − 4.18 × 105 J kg− 1 in (16). b) Heat lost by convection as a function of melt viscosity, using α = 5 × 10− 5 K− 1, ΔTe = 50 K in Eq. (15). Author's personal copy 44 C. Michaut, C. Jaupart / Tectonophysics 500 (2011) 34–49 6.3. Crystal/melt separation We have so far referred mostly to magma reservoirs that grow from basaltic precursor melts, but the same basic principles also apply to other magma compositions. In fact, we have pointed out that kinetic limitations on crystallization may well be more stringent for andesitic and dacitic melts. For the sake of the present discussion, we rely on the Bishop Tuff system because it has been studied extensively by a large number of authors and also because it shares many features with other systems. The crystal content of the Bishop Tuff rhyolite was generally small and increased as the eruption tapped deeper portions of the reservoir. The large volumes of highly evolved melt were dominantly produced by fractional crystallization (Michael, 1983; Hildreth and Wilson, 2007), implying that an enormous repository of cumulates was left behind in the upper crust. Trace element concentrations vary by large amounts in this melt and delineate strong vertical gradients in the upper part of the reservoir. Such lack of homogenization led Hildreth and Wilson (2007) to postulate that individual magma batches were extracted piecemeal from a thick mush and accumulated at the top of the reservoir without mixing. Using the ages of zircons, one of the earliest phase to crystallize, these authors conclude that the reservoir system developed over at least 105 years. A model for the Bishop Tuff must address two questions: how does evolved melt migrates out of the initial storage zone (where it was generated by crystallization), and how can this melt remain near its liquidus as it ponds beneath the cold roof region? The two models of reservoir formation studied in this paper and the mush rejuvenation model by gas sparging of (Bachmann and Bergantz, 2003) do not specify how evolved melt gets separated from a partially crystallized mushy pile. Model calculations for pervasive porous flow involving compaction of the solid phase as well as local crystal settling suggest small melt migration velocities in the 10− 1– 10− 2 m y− 1 range, implying that it takes 104–105 years to accumulate evolved magma over 1 to 2 km (Bachmann and Bergantz, 2004). These calculations rely on many unknowns and must be taken with precaution, but they do suggest that extraction may proceed at rates that are consistent with the large lifetime of the Bishop Tuff system. More stringent constraints, however, come from mass and heat balance arguments. Regardless of the melt migration mechanism, a key problem is to account for the preservation of a large volume of melt beneath the reservoir roof. Hildreth and Wilson (2007) acknowledge this difficulty and discuss various mechanisms to generate a stably stratified body where convection does not operate. Even without convection, however, cooling will affect a large volume of melt. Over the lifetime of the Bishop Tuff system, which must be 105 years or more, conductive cooling proceeds over a thickness of atleast 2 km, i.e. through the whole volume of rhyolite that got erupted. This rules out the rapid emplacement of a large liquid body at the top of the storage zone a long time before eruption and sets the discussion back to the starting point. For a melt body that grows incrementally against the roof, which is the cooling interface, the problem is analogous to that for the whole magma reservoir and we can use the same arguments as above, and specifically the same thermal balance (Eq. (11)). Incoming melt supplies heat that sustains losses through the roof. Evolved high-silica rhyolite, however, crystallizes over a relatively narrow temperature interval. For ≈10% crystallization, corresponding to the average crystal content of the erupted Bishop Tuff magma, the temperature drop is less than 20 °C and the minimum input rate is at least 0.1 m yr− 1 according to Eq. (11), so that the evolved melt body must have been built up in less than 30,000 years. This is much shorter (by a factor of at least 5) than the lifetime of the Bishop Tuff system (Hildreth and Wilson, 2007). If the precursor melts were dacite or low-silica rhyolite, they must have crystallized by more than 50% before extraction of residual melt took place, and hence they must have been injected at rates which were larger than 0.1 m yr− 1 by a factor of at least two and possibly as much as five, depending on composition. Such rates of magma production are undocumented. An alternative mechanism for melt migration involves flow through veins and channels in an almost rigid crystal mush, i.e. through dyke-like fractures, which proceeds rapidly. Hildreth and Wilson (2007) favour the latter mechanism because it is consistent with piecemeal accumulation of rhyolitic melt at the top of the reservoir. They comment that many granitoid plutons contain veins and dike-like structures filled with evolved liquids and connected to pockets with enhanced melt contents. As discussed in Appendix B, the kinetic model predicts the generation of such pockets within the thick mush zone upon devitrification. The phenomenon is due to the competition between diffusive heat transport and kinetically-driven latent heat release, and has been explained at length by Brandeis et al. (1984). Furthermore, the large local density decrease within the mush due to heating and volatile exsolution driven by crystallization leads to the build-up of an overpressure. The temperature rise alone leads to an overpressure of several MPa. The effect of gas exsolution is more dramatic and likely leads to fracturing (Fig. 7) (see Appendix C for details on the calculations). A key point, of course, is that melt and melt pockets are generated shortly before eruption, which circumvents the thermal difficulty of maintaining a thick magma body at the top of the reservoir for a large length of time. 6.4. Bimodal volcanism Volcanic systems that exhibit a time-progression from primitive to intermediate lavas over large time intervals followed by a voluminous eruption of very evolved melt have been found in different geological settings. Lipman (2007) has described this eruption pattern for the recent calc-alkaline volcanic fields of the western United States. On the whole, Icelandic volcanism is strongly bimodal, with approximately 85% basalt, 12% rhyolite and only 3% intermediate lavas (Einarsson, 1994). Silicic volcanism is confined to central volcanoes and is often associated with caldera formation. Recent petrological studies seem to favour a crustal origin for the evolved melt but Fig. 7. Overpressure evolution following a temperature increase and volatiles exsolution driven by crystallization, for two different values of the initial fraction of crystals Mci = 50 and 70%. Thick lines: solubility law for water in mafic magmas, i.e. n = 0.7 and s = 6.8 × 10− 8; thin lines: solubility law for water in rhyolitic magmas, i.e. n = 0.5 and s = 4.11 × 10− 6. Dashed lines: ΔT = 100 °C, solid lines ΔT = 0. We use Pi = 1.4 × 108 Pa, T = 1000 K, MH2O = 18 × 10− 3 kg mol− 1, R = 8.314 J/mol/K, L = 20 km, h = 5 km, d = 1 km, E/(1 − ν 2 ) = 5 × 10 10 Pa, ρ c = 2800 kg/m 3 , ρ l = 2600 kg/m 3 , α = 3 × 10− 5 K− 1. Author's personal copy C. Michaut, C. Jaupart / Tectonophysics 500 (2011) 34–49 fractionation of a more primitive magma has also been invoked (Geist and Larson, 1995). Bimodal volcanism has been explained in various ways. MourtadaBonnefoi et al. (1999) attributed it to variations of physical properties in a magma reservoir that evolves due to replenishment and eruption, and Marsh (1981) to the sampling efficacy of eruptions. Geist and Larson (1995) argued that bimodal volcanism is a feature of relatively dry magma systems, such that water saturation and exsolution are achieved very late in the differentiation trend. All these explanations rely on the assumption of a large and well-mixed homogeneous melt body, in contradiction with the very framework of the present study. The kinetic model offers an alternative explanation that is consistent with incremental reservoir growth and petrological constraints. In this framework, evolved melts originate in part from partial melting of country rock and in part by fractionation of the parent magma, with proportions that depend on magma and rock compositions. 7. Conclusion All the quantitative models that have been proposed for the thermal evolution of large magma reservoirs suffer from similar deficiencies, namely that they require rather extreme values for their key parameters (thin intrusions for the kinetic model, very large and sustained magma input rates for the equilibrium one, very large permeability values for the gas sparging model). These quantitative models provide insights into possible mechanisms and identify the key variables, but must be treated with caution because they are not yet at the level of sophistication that would allow detailed comparisons with data. Thus, most of the answers must be sought in field observations, which is why we have made an extensive literature search to document the three key features of the kinetic model: the presence and amount of glass in intrusions, the thickness of individual intrusive sheets and finally the behaviour of glass upon devitrification. Our thermal model illustrates the likely long-term consequences of sluggish crystallization kinetics in magma reservoirs that grow by multiple thin injections. One of its key predictions is the occurrence of a late heating phase due to devitrification of residual glass that has accumulated over large lengths of time. Devitrification proceeds by a burst of crystallization occurring as temperatures are rising, which is consistent with deductions from zoning in quartz crystals from the Bishop Tuff (Wark et al., 2007). Alternative explanations relying on input from separate intrusive bodies have been put forward, but they involve complicated heat and material transport processes as well as major changes in the intrusion sequence (Wark et al., 2007). The kinetic model involves only one magmatic system and only one intrusion sequence and makes specific predictions that can be tested. Laboratory data and natural observations point to pyroxene nucleation as a major factor in the evolution of a basaltic sill complex, both in the initial cooling phase that follows emplacement and in the late devitrification phase. Crystallization kinetics are more sluggish in silicic magmas than in basaltic ones but are not documented in sufficient detail for specific predictions. The kinetic model can be reduced to a simple quantitative calculation independently of the full emplacement/crystallization sequence. This allows direct use of field data to evaluate its potential. We find that devitrification of about 20%–30% interstitial glass leads to rapid heating and rejuvenation of a thick solidified sill complex. One key requirement of the kinetic model is that the thickness of individual intrusive sheets does not exceed about 4 m. This limitation is consistent with mechanical constraints on magma emplacement, which are met more easily with thin intrusions than with thick ones. The kinetic model has many appealing features, but it relies on rather scant data on nucleation and growth kinetic rates. Additional laboratory measurements would allow more accurate model predictions. They would also allow us to draw more information from the many disequilibrium features that have been observed in cumulate igneous rocks. 45 Acknowledgements We are grateful to Catherine Annen and an anonymous reviewer for their useful comments and criticisms. Appendix A. Model equations Sills extend over large horizontal distances so that horizontal heat transport can be neglected. Thus, we use the following heat equation for both the sill complex and encasing rocks: ρCP ∂T ∂2 T ∂U = k 2 −ρL ∂t ∂t ∂z ð17Þ where T is temperature, z the vertical coordinate, k thermal conductivity, Cp heat capacity, L latent heat of crystallization and U the melt fraction, see Table 2 for parameter values. In the country rock, successive intrusions can lead to melting, which proceeds at equilibrium. In the sill complex, the non-crystallized fraction U depends on crystallization kinetics. Boundary conditions are as follows. The temperature is set to zero at Earth's surface, and a fixed heat flux is imposed at the base of the computational domain which is much larger than the magma storage zone. Initially, the crust is in equilibrium with ageothermal gradient equal to 15 °C/km. Each sheet is intruded instantaneously at depth ZS. After each injection, the underlying pile is displaced downward, so that the thickness of the roof rocks remains constant. We refer to Michaut and Jaupart (2006) for more details and a discussion of other emplacement sequences. Eq. (17) is solved using different expression for melt fraction U in country rock and in the sill complex. In country rock, melting proceeds at equilibrium and the melt fraction depends only on the phase diagram, i.e. on temperature and composition. Here we consider that the melt fraction is a linear function of temperature over the melting interval: U= T−Tsr Tlr −Tsr ð18Þ where Tsr = 800 °C and Tlr = 1100 °C are the solidus and liquidus temperatures of country rock. In the sill complex, the melt fraction is a function of the rates of nucleation and growth which both depend on undercooling, as specified in the main text. In kinetically-controlled conditions, crystallization may proceed at temperatures that are below the solidus, and hence the solidus temperature shown in Fig. 8 is used only as a reference. The liquidus temperature varies as a function of silica content in the melt (Fig. 8), and is given by, for 0.45 ≤ C ≤ 0.75: Tl = 1000− 20 ðC−Ce Þ 3 ð19Þ where C is the SiO2 content in wt.% in the melt, and Ce = 0.75 is the eutectic composition. The balance in SiO2 content gives: UC = C0 −Cs ð1−UÞ ð20Þ where C0 = 0.47 denotes the initial SiO2 content of the magma and Cs = 0.4 is the SiO2 content in crystals. For simplicity, we neglect changes in the physical properties of the non-crystallized fraction involved in the formation of glass. The glass transition occurs over a temperature interval that varies as a function of composition, pressure and cooling rate, and hence cannot be described by a single temperature (Richet and Bottinga, 1986). However, it is likely to be in the 600–900 °C range for the compositions of the model: for instance it is reported at 630 °C for diopside and 600 °C for obsidian (Richet and Bottinga, 1986; Sturkell and Sigmundsson, Author's personal copy 46 C. Michaut, C. Jaupart / Tectonophysics 500 (2011) 34–49 Fig. 8. Simple phase diagram adopted for the model calculations. Solid lines: liquidus and solidus temperatures as a function of composition in terms of SiO2 content in wt.%. Dashed line: temperature for which the kinetic rate function f is maximum. 1995). Thus, the glass transition is crossed at the time of the sharp temperature rise. Appendix B. Thermal and compositional evolution for thin intrusions We summarize here the thermal and structural evolution of a sill complex developing out of thin intrusions, such that crystallization is kinetically-controlled. More details can be found in Michaut and Jaupart (2006). Thin injections do not crystallize completely and leave a glassy residue. With new intrusions, temperatures increase gradually (Fig. 9). Once the undercooling is small enough crystallization gets reactivated in the complex. Latent heat released by crystallization leads to larger temperatures and hence enhanced crystallization rates. Starting from low temperatures, a temperature rise causes a positive feedback between latent heat release and crystallization. This positive feedback results in rapid heating associated with extensive crystallization and differentiation. The effect of devitrification becomes significant (Figs. 3 and 9) when the increase in temperature due to latent heat release becomes larger than ΔTs ~ 10 °C in Δts ~ 103 yr. Using U = 0.5, such a heating rate is achieved for f(T*) ≥ CPΔTsτk/ ULΔts ~ 2 × 10− 6, i.e. for T* ~ 0.67 or T ~ 700 °C if TL = 1187 °C. This threshold temperature is reached at time t = τck = 374.2 kyr for an injection rate of 0.01 m yr− 1 (Fig. 9). In this scenario, a large amount of latent heat is released in a short devitrification burst. This burst is so rapid that heat cannot be evacuated by conduction through the overlying rocks. Thus, the central part of the sill complex, away from boundary layers at the top and bottom, heats up at a quasi-uniform rate with a quasi-uniform temperature distribution. Thermal boundary layers with significant temperature gradients develop at the upper and lower margins of the complex and some of the latent heat released there gets evacuated to country rock, inducing melting. In the first phase of gradual temperature rise, temperature is maximum at the top of the complex, where new magma gets intruded. Once crystal nucleation and growth get reactivated in the sill complex, runaway devitrification proceeds from top to bottom. For an injection rate Q = 0.025 m/yr at t = 67400 yr, 400 yr after the beginning of the heating pulse, devitrification has affected a thickness of about 900 m (Fig. 10). Residual liquid remains in crystal mush lenses containing 10 to 25 wt % liquid. On Fig. 10, two lenses of crystal mush have been formed one after the other, in association with two separate peaks in the temperature evolution (Fig. 3). The melt is very evolved chemically and is thermally and compositionally homogeneous because it is at the eutectic. At that time, a cumulative thickness of about 60 m of pure melt has been formed. More liquid is present in the complex, however, because of melting in roof rocks. The amount of melt formed by devitrification increases with the time between injections, i.e. with decreasing injection rate (Fig. 11). Indeed, the thickness of the central region, which melts and fractionates during devitrification, increases with the time between two injections. For very low input rates (~1–3 × 10− 3 m/yr), i.e. large replenishment timescales (of the order of several hundreds of years to one thousand years), the amount of liquid formed can represent over several hundreds of meters per unit area, i.e. corresponding to melt volumes involved in the Bishop Tuff and Fish Canyon Tuff. In our model, the solidus temperatures of both evolved magma (1000 °C) and country rock (1100 °C) are relatively high. More melt would be formed if these temperatures were set to lower values. Appendix C. Overpressure in the reservoir Within the rejuvenated magma, overpressure must build up in response to the decrease in density due to heating and volatile exsolution driven by crystallization. To calculate the pressure evolution as crystallization proceeds in the chamber, we modify the model of Tait et al. (1989) to account for thermal expansion and for the presence of crystals in the melt that formed at the time of magma injection. We also consider country rock deformation in a geometrical configuration that is appropriate for sills. Initial conditions are such that the melt is saturated with dissolved water and there is no gas phase. Mass conservation of liquid, crystals and gas are written as follows: Fig. 9. Evolution of the maximum temperature in a sill complex growing at a rate of 1 m every 100 yr (i.e. 0.01 m/yr). At t = τck = 374200 yr, runaway devitrification proceeds and a large reservoir of evolved liquid forms rapidly. mc + ml + mg = M ð21Þ ml + mc = Mli + Mci ð22Þ md = xml ð23Þ mg + md = xi Mli ð24Þ Author's personal copy C. Michaut, C. Jaupart / Tectonophysics 500 (2011) 34–49 47 Fig. 10. Solid lines: temperature as a function of depth in a sill complex formed at a rate of 1 m every 40 yr (0.025 m/yr), after 1685 injections, at t = 67400 yr, 400 yr after the beginning of devitrification. Left: non-crystallized fraction (either glass or liquid depending on the temperature) as a function of depth, right, composition of the non-crystallized fraction in terms of SiO2 content. where M is the total mass (which is constant), Mli and Mci are the initial masses of liquid and crystals, ml, mc and mg are the masses of liquid, crystals and gas, md is the mass of water dissolved in the liquid, x the mass fraction of dissolved water in the liquid. Suffix i stands for initial values. The total volume V at pressure P and temperature T is: where ρc and ρl are the densities of the crystals and liquid. Changes in liquid and crystal volumes due to temperature variations are given by: P−Pi + αðT−Ti Þ Vl ðP; TÞ = Vli ðPi ; Ti Þ 1− β ð28Þ VðP; TÞ = Vl ðP; TÞ + Vc ðP; TÞ + Vg ðP; TÞ Vc ðP; TÞ = Vci ðPi ; Ti Þð1 + αðT−Ti ÞÞ ð29Þ ð25Þ and the initial volume at pressure Pi and temperature Ti is: Vi ðPi ; Ti Þ = Vli ðPi ; Ti Þ + Vci ðPi ; Ti Þ ð26Þ Using the mass conservation (22) at pressure Pi and temperature Ti, we get: Vli ðPi ; Ti Þ = Vl ðPi ; Ti Þ + ðVc ðPi ; Ti Þ−Vci ðPi ; Ti ÞÞ ρc ðPi Þ ρl ðPi Þ ð27Þ where β is the bulk modulus and we assume a thermal expansion coefficient α = 3 × 10− 5 K− 1 for both liquid and crystals. Assuming that the roof region behaves as a thin elastic plate, we calculate the vertical deflection w(x) of a beam of length L and thickness h due to an overpressure ΔP below. The plate is infinitely long in y, pinned at its ends x = 0 and x = L. From Turcotte and Schubert (1982), we have: wðxÞ = ΔPð1−ν2 Þ 2 2 x ðx−LÞ 2Eh3 ð30Þ Author's personal copy 48 C. Michaut, C. Jaupart / Tectonophysics 500 (2011) 34–49 Fig. 11. Volume of liquid formed by runaway devitrification as a function of time between intrusions, for 1 m thick magma sheets. Solid line: volume of liquid formed by fractional crystallization, dashed line: volume of liquid formed by fractional crystallization plus roof melting, using Trs = 800 °C and Trl = 1100 °C for roof rocks. where E is Young's modulus and ν is Poisson's ratio. Integrating the displacement over the plate length leads to the volume change ΔV as a function of magma overpressure ΔP = P − Pi: ΔV V−Vi ð1−ν2 ÞL4 ΔP = = ΔP = Vi V μ 60Eh3 d ð31Þ where μ = 60Eh3d/(1 − ν2)L4, with d the thickness of the mush layer. Following the method of Tait et al. (1989), we obtain, by eliminating V, Vi and Vl in Eq. 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