Block:________ Name: Chemistry 11 Date:_______________ Trends Activity Assignment Atomic Radius: the distance from the center of the nucleus to the outer most electrons in an atom. Ionic Radius: the distance from the center of the nucleus to the outer most electrons in an ion. Ionization Energy: the energy needed to remove an electron. First ionization energy is the energy needed to remove the first electron from an atom. The first ionization energy is always the lowest. Electronegativity: the ability to attract an electron in a chemical bond. Most commonly measured with the Pauling Scale, where 0 represents the least ability and 4 is the greatest ability to attract electrons in chemical bonds. Electron Affinity: the energy change associated with gaining an electron. Effective Nuclear chargelZeff): a measure of the pull of the protons in the nucleus on the valence electrons in an atom/ion. Zeff = atomic number shielding electrons Note: shielding electrons for our purposes are the inner electrons that block some of the pull of the nucleus on the electrons that are farther out. — Example: Oxygen Zeff = atomic number Zeff = 82 Zeff = +6 — shielding electrons Use the provided periodic table to answer the questions below. 1. a) As you go from hydrogen down a column, what happens to the dius? Increases ecreases b) Draw Bohr diagrams for hydrogen, lithium and sodium. Calculate the effective nuclear charge for each atom and use this information to explain the atomic radius trend. ac- cYn- QcQ k’Ls OI\& y1 cc-kQ- ç) rnôce Icic tm €Lcn ckk, i4& scici G( 2. a) As you go from lithium across a row what happens to the atomic radius? ( b) Draw Bohr diagrams for lithium, beryllium and boron. Calculate the effective nuclear charge for each of the three elements and use these values to explain the atomic radius trend. çç nccecs Cifc r-ec Xe&n Th doc, rrv-kkinc What unit is ionization energy measured in? k (k’o 3& TR. 3. ,c \icc ci- ftri3S -QSc’ 4. a) As you go from hydrogen down a column, what happens to the ionization ener es? Increase ecreases b) Using your Bohr diagrams from question #1, explain this trend. V Tk. ‘io.kn OV iN oe e\ec esS 4c2kQ5z. coc ies erc ucJis m (\ bs ccc rCc-p 4 c C 4 C C D C-. 2 ci) > .. j I ot .; . ; ci) cCc-i). i) I LL ci) -d ci) C4 o 0) 0-’ .1 H C E ( I Cl) - .b rJ) +=. ci) ci .ci) Cl) ci 0.) 44 C Cl) Cl) a) 4 C 0 — 0 >-. C) •;s — >.. 0 Cl) V --) ci) . . N 0 -I ..- C C4 0.) C., ci) 0 > ci •-. 0.) ci) 0) c -[ I - - ci 0 - 0) . I-ci — Cl) -. a) o ci) C) C) > Th2 -t C(I .4- 10. a) Compare the atomic radii for metals and the ionic radii for their positive ions. Are the radii for the ions or atoms larger? cc O( (or\c mJLe-c ce - (oie ir,ctc ccxcf) *‘cir, -c ckQ b) Explain the above trend (N \J_ 14. cve ccilic iorS C1c5 ks4 zc. 4 c oc cn 11. a) Compare the atomic radii for non-metals and the ionic radii for their negative ions. Are the radii for the ions or atoms larger? rncdr \coc b) Explain the above trend -4he cNS O’XQA c)o.4\ c-,c”r\Q -4 ckcrs mDc- r,cV cMz’\ 4 cvcnS . 1 -Ococ\ -k \accc- mc cJ-cr c3 C) 12. On the periodic table below, draw arrows on the sides (going up or down and left or right) to summarize the trends of atomic radius, ionization energy, electronegativity, and metallic character. ÷ — cL -“i’ T Do the next 3 questions using your own periodic table listed on the provided periodic table. — based on the trends — not the values 13. Indicate which atom in each pair would have larger atomic radius. e. Ci f. ,eoi( ) g. h. Fe ori) a. Li o) b. Ca or Ni c. (jor B d. 0 oI 14. Indicate which ion in each pair would have smaller ionic radius. a.cr 02 b. (aor 1 c. i3rP 3 15. Indicate which atom or ion in each pair would have larger ionization energy. a.Na 0 b. Be r a c. Ar rF d. CuorRa 16. Explain why there would be a large jump in ionization energy between the secon1 and 4c third ionization energies for magnesium. (bc o kx*c ce(vvenQ cv dec.rc\r \4\- icLL, C)t C 4 L’O\A C\Q ‘o c4 3c
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