Chem 112 Homework --------------------------------------------------------------------------------------------------------------------------------------------- Nuclear: Complete the following homework problems (both the textbook and the multiple choice problems) by Sunday, Sept. 14 . Quiz 2 in Angel is due at 11:55 PM on Monday night, Sept. 15, 2014. You will have 2 attempts. Textbook Homework Problems: Chemistry Atoms First, First Edition, by Burdge and Overby: Chapter 20, 20.5, 20.25, 20.27, 20.31, 20.35, 20.81, 20.101, 20.17, 20.19, 20.87, 20.59 ----------------------------------------------------------------------------------------------------------------------------------Multiple Choice Homework Problems 1. Which combination of number of protons, number of neutrons and isotope symbol is correct? Number of protons Number of neutrons A. 54 88 142 54 B. 144 54 144 54 3. 230 90 Th→24 He+ yx M Symbol A. B. C. D. E. Mn Xe C. 17 46 63 46 D. 47 156 109 47 Ag E. 98 151 249 98 Cf € Pd A. B. C. D. E. x = 226, y = 90 x = 230, y = 88 x = 226, y = 88 x = 228, y = 86 x = 234, y = 92 4. Which of the following isotopes is most likely to be a positron emitter? 25 A. B. C. D. E. 105 2. 45 Rh has a neutron to proton ratio slightly higher than needed to place it on the belt of stability. The type of radioactive decay it is likely to undergo is: In the following nuclear reaction, what are the values of x and y? 5. α emission β emission electron capture positron emission none of the above 6. € Si Mg 32 Si 25 Mg 28 Si 27 Which of the following types of nuclear decay results in an increase in the nuclear charge? A. alpha emission B. positron emission C. beta emission D. electron capture E. gamma emission When 235 92 U is bombarded with one neutron, fission occurs and the products are 94 three neutrons, 36 K and € A 139 56 Ba B € 141 56 Ba 1.00 C 139 58 Ce 0.80 D 139 54 Xe E 142 53 I 1.20 Mass of Mo € 9. The nuclear decay of 88Mo is shown in the graph below. What is the rate constant for the decay? 0.60 0.40 0.20 0.00 € 0 € 7. 55 25 5 10 15 20 Time (minutes) Mn can be prepared by electron capture from which isotope? € € € € A 55 24 B 55 26 C 56 25 D 56 23 E 56 26 A B. C. D. E. Cr Fe Mn 10. V Fe € 8. The half-life of 239 Pu is 24,000 years What wastes generated today (~year 2000) will be present in the year 3000? A B. C. D. E. 0.95 0.92 1.03 0.97 0.90 The 14C/12C ratio in a wooden artifact is 1/8 the 14C/12C ratio in today’s atmosphere. How old is the artifact? (t1/2 for 14C = 5,700 years) A. B. C. D. E. €fraction of the 239Pu present in nuclear 11. 0.04 min−1 0.50 min−1 1.03 min−1 0.09 min−1 0.10 min−1 45,600 years 17,100 years 700 years 1,900 years 11,400 years A wooden artifact from China has a 14C activity of 24 counts/min. as compared to an activity of 31.7 count/min. for modern (contemporary) wood. What is the age of the artifact? (The half-life for 14C is 5700 years.) A. B. C. D. E. 1700 years 2300 years 4600 years 3750 years 4340 years 12. A rock contains 0.313mg of 206Pb for each milligram of 238U. The half-life for the decay of 238U to 206Pb is 4.5 × 109 yr. How long ago was the rock formed? A. B. C. D. E. 13. −2.3 × 109 years 2.8 × 109 years 1.8 × 109 years 1.2 × 109 years 4.3 × 109 years 60 A B C D E 235 A. Pure 92 U is used as the fuel in the reactor. B. If allowed to overheat, the reactor can explode like a nuclear bomb. C. Water is never used as a coolant for the € reactor core. D. Heat is initially supplied to the reactor core to start the chain reaction. E. The control rods present in the reactor absorb excess neutrons. Cl is a β-emitter with a half-life of 3.00 × 105 yr. The β-activity of a sample of NaCl is 1.20 disintegrations per second. How many atoms of 36Cl are in the sample, assuming that 36Cl is the only source of βdecay? 3.25 × 1021 9.81 × 1017 6.02 × 1023 1.64 × 1013 Insufficient information to answer. 15. How much energy must he supplied to break a single 6Li nucleus into separated protons and neutrons? (Masses: 6Li = 6.01347 amu; 1 H = 1.00728 amu; 1n, = 1.00867 amu) A. B. C. 3.09 × 1012 J 1.54 × 10−3 J 5.14 × 10−9 J 9.117 × 10−28 J 8.206 × 10−11 J 4.940 × 10−13 J 2.735 × 10−19 J 2.735 × 10−16 J 17. Which one of the following statements concerning the nuclear reactor is correct? 36 A. B. C. D. E. 5.14 × 10−12 J 3.09 × 1015 J 16. What is the binding energy of 27 Co ? The mass of 60Co nucleus is 59.9338amu. Potassium-40 decays to argon-40 with a half-life of 1.27 x 109 years. What is the age of a rock in which the mass ratio of argon-40 to potassium-40 is 3.6? A. B. C. D. E. 14. 1.08 × 109 years 1.39 × 109 years 1.41 × 109 years 1.56 × 109 years 2.00 × 109 years D. E 18. Carbon-11 is used in medical imaging. The half-life of this radioisotope is 20.4 min. What percentage of a sample remains after 60.0 min? A. B. C. D. E. 71.2 % 5.28 % 13.0 % 34.0 % 2.94 % Quiz 2 Nuclear 1. E 2. B 3. C 4. A 5. C 6. A 7. B 8. D 9. E 10. B 11. B 12. E 13. B 14. D 15. D 16. B 17. E 18. C
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