Date of Issue: 02/2015
Page 1 of 2
iso-Propylmagnesium Chloride / Lithium Chloride,
typ. 14 % solution in THF (typ. 1.3 M)
PRODUCT
iso-Propylmagnesium Chloride / Lithium Chloride, typ. 14 % solution in THF (typ. 1.3 M)
Product No. 408450
CAS-No. 1068-55-9
EINECS-No. 213-947-1
FURTHER
INGREDIENTS
Lithium Chloride
CAS-No. 7447-41-8 EINECS-No. 231-212-3
THF
CAS-No. 109-99-9 EINECS-No. 203-726-8
APPLICATION
Reagent for halogen/magnesium exchange reactions.
APPEARANCE
yellowish to dark brown liquid
FORMULA
C 3 H 7 ClMg / LiCl
PHYSICAL
PROPERTIES
Molecular weight:
102.85 g/mol
Density:
0.98 g/ccm (at 20 °C)
Boiling Point:
66 °C for THF
Flash Point:
-21.5 °C for THF
Thermal Stability:
crystallisation below around 5 °C
SPECIFICATION
iso-Propyl-MgCl
13.0 – 15.0 %
ratio LiCl / iso-Propyl-MgCl
0.9 - 1.1
METHOD OF
ANALYSIS
Acidimetric titration of the hydrolized product for the determination of assay as total base.
Detailed description available on request.
HANDLING
iso-Propylmagnesium Chloride / Lithium Chloride should only be handled under inert gas
atmosphere. Avoid contact with eyes, skin and clothes as well as inhalation. Never add
water, acids or oxidizing materials. In case of fire use dry extinguishers based on sodium
chloride or limestone powder, never use water or CO2 . Pay attention to the Safety Data Sheet.
The abov e details hav e been compiled to the best of our knowledge
on the basis of thorough tests and with regard to the current state
of our long practical experience. No liabilities or guarantees deriv ing
f rom or in connection with this leaf let can be imputed to us.
Reproduction, in whole or in part, only with our express permission.
® registrated trademark
www.rockwoodlithium.com
Europe:
Rockwood Lithium GmbH
Fax: +49 69 40126-72000
Americas:
Rockwood Lithium Inc.
Fax: +1 704 734-2718
Asia:
Rockwood Lithium Japan K.K.
Fax: +81-3-6434-5623
Product No. 408450
Date of Issue: 02/2015
Page 2 of 2
STORAGE
iso-Propylmagnesium Chloride / Lithium Chloride should be stored in tightly closed
containers under exclusion of air and humidity. As material tends to crystallize at lower
temperatures, it should be stored above 10 °C. Under these conditions, stable over
practically unlimited periods. Recommended retest date: six months after date of delivery.
TRANSPORT
REGULATIONS
UN-No.:
3399
Rail/Road (RID/ADR):
Class 4.3
PG I
Label 4.3 and 3
Sea (IMDG-Code):
Class 4.3
PG I
Label 4.3 and 3
Air (IATA-DGR):
Class 4.3
PG I
PAX forbidden
CAO 494
GHS HAZARD
PICTOGRAMS
H&P Phrases: See Safety Data Sheet
SIGNAL WORD
Danger
PACKING
Glass bottles of 100, 250, 500 and 1,000 ml. Steel bottles with volumes of 7.4, 27, 127 or 450
l. For safety reasons these are filled to a maximum of 90 %. Steel drums up to 200 l.
TIME OF DELIVERY
To be agreed upon.
FURTHER RELATED
DOCUMENTS
Brochure ''Turbo Grignards-Li powered metalation''
Trifold ''Halogen-Metal-Exchange Reactions''
Safety Data Sheet.
The abov e details hav e been compiled to the best of our knowledge
on the basis of thorough tests and with regard to the current state
of our long practical experience. No liabilities or guarantees deriv ing
f rom or in connection with this leaf let can be imputed to us.
Reproduction, in whole or in part, only with our express permission.
® registrated trademark
www.rockwoodlithium.com
Europe:
Rockwood Lithium GmbH
Fax: +49 69 40126-72000
Americas:
Rockwood Lithium Inc.
Fax: +1 704 734-2718
Asia:
Rockwood Lithium Japan K.K.
Fax: +81-3-6434-5623