Bonding Adhesive BA-90 - MSDS

LEXCAN MATERIAL SAFETY DATA SHEET
DATE PREPARED: 09/15/14
SECTION 1 – CHEMICAL PRODUCT & COMPANY IDENTIFICATION
PRODUCT NAME
BA-90 BONDING ADHESIVE
SUPPLIER NAME AND ADDRESS
EMERGENCY TELEPHONE NUMBER:
Lexsuco 2010 Corporation
52 Bramwin Court
Brampton, Ontario L6T 5G2
Tel: 905.792.8300
Fax: 905.792.8305
CANUTEC 613-996-6666 (24 hours every day)
Chemical Formula:
General Use:
Regulatory Information Number:
Tel: 1-877-792-8308
Mixture
Contact Bonding Adhesive
SECTION 2 – HAZARDS IDENTIFICATION
H
F
R
HMIS
1
4
0
PPE†
†Sec. 8

Emergency Overview 
Danger – Highly flammable liquid and vapour
Warning – Causes skin irritation
Warning – Causes eye irritation
Warning – May be harmful if swallowed and enters airway
Danger – May damage fertility or the unborn child
Warning – May cause an allergic skin reaction
Warning – Suspected of causing genetic defects (skin)
Warning – May cause drowsiness and dizziness
Warning – May cause damage to organs (liver, kidney, ear) through prolonged or repeated exposure
Potential Health Effects
Primary Entry Routes: Skin contact, skin absorption, eye contact, inhalation, ingestion.
Target Organs:
Acute Effects
Inhalation: throat irritation on short-term exposure to liquid or vapour. Aspiration into lungs can cause chemical pneumonitis,
which can be fatal.
Eye: irritation on short-term exposure to liquid or vapour.
Skin: irritation on short-term exposure to liquid or vapour.
Ingestion: ingestion can cause gastrointestinal irritation
Carcinogenicity: IARC, NTP, and OSHA do not list this product as a carcinogen.
Medical Conditions Aggravated by Long-Term Exposure: Respiratory symptoms associated with pre-existing lung disorders
and pre-existing heart disorders may be aggravated by exposure to this material.
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Chronic Effects: Overexposure may result in headache, dizziness, fatigue, nausea, and possible unconsciousness, even
asphyxiation. Moderate irritation of skin, eyes and mucous membranes of upper respiratory tract on prolonged/repeated contact.
Dermatitis and defatting of the skin. Chronic exposure may cause reversible liver and kidney injury.
Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system
damage. Repeated exposure to Toluene has been associated with high frequency hearing loss based on animal tests.
SECTION 3 – INFORMATION ON INGREDIENTS
Hazardous Ingrdients
Acetone
Solvent Naptha(SN), Light Aliphatic (LA), (Heptane)
Toluene
Xylene
Magnesium Oxide
Additional Ingredients
Polychloroprene
Phenolic Resin
CAS #
67-64-1
64742-89-8
108-88-3
1330-20-7
1309-48-4
% wt
5-10
15-40
30-60
1-5
0.5-1.5
Proprietary
Proprietary
SECTION 4 – FIRST AID MEASURES
Inhalation: Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing.
Get medical attention immediately.
Eye Contact: Immediately flush eyes with running water for at least 15 minutes. Get medical attention.
Skin Contact: Immediately flush skin with running water and remove contaminated clothing. Wash exposed area with soap and
water. Get medical attention.
Ingestion: Do not induce vomiting. Get medical attention immediately.
Note to Physicians: This product contains several organic solvents (Toluene, Heptane, Acetone and Xylene).
Special Precautions/Procedures: Whenever possible, remove the worker from the source of contamination.
SECTION 5 – FIRE FIGHTING MEASURES
Flash Point: -4°F (-20°C)
Flash Point Method: CC
Autoignition Temperature: 433.4°F (223°C)
LEL: 1.1% v/v
UEL: 12.8% v/v
Flammability Classification: Division 2
Extinguishing Media: In case of fire, use dry chemical, carbon dioxide, or foam. Water may not be effective as an extinguishing
agent. Water fog or spray may be used to provide a smothering effect on fire and to cool fire-exposed containers and surrounding
combustibles. Do not use a solid stream of water because it can scatter and spread the fire.
Unusual Fire or Explosion Hazards: Extremely flammable. Store and use away from all sources of heat, flame, or sparks. Do
not smoke while applying. Vapours are heavier than air and may travel along ground or may be moved by ventilation and ignited
by pilot lights, other flames, sparks, heaters, smoking, electrical motors, static discharge, or other ignition sources at location
distant from material handling point and flashback. All containers should be grounded when material is transferred.
Hazardous Combustion Products: Toxic gases or vapours, such as carbon monoxide, carbon dioxide, hydrogen cyanide, or
oxides of nitrogen may be released in a fire.
Fire-Fighting Instructions: This product contains solvents that are dangerous fire and explosion hazards when exposed to heat
or flame. Fire fighters should wear self-contained breathing apparatus and full protective clothing with a full face piece operated
in the positive pressure demand mode.
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing
apparatus (SCBA) with a full face piece operated in pressure-demand or positive-pressure mode.
SECTION 6 – ACCIDENTAL RELEASE MEASURES
Spill /Leak Procedures: Remove all sources of ignition. Avoid breathing vapours. Use self-contained breathing apparatus in
enclosed area. Ventilate area. Contain and remove with inert absorbent materials and non-sparking tools.
Containment: For large spills, dike far ahead of liquid spill for later disposal. Do not release into sewers or waterways.
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Cleanup: Clean-up spill as soon as possible. Collect any excess material with absorbent pads, sand or other inert noncombustible absorbent materials. Place into appropriate waste containers for later disposal. Comply with all laws and regulations.
Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120).
SECTION 7 – HANDLING & STORAGE
Handling Precautions: Use away from all sources of heat, flame, or sparks. Do not smoke while using. Handling equipment
must be grounded to prevent sparking. Handle with non-sparking tools. Wash with soap and water before eating or drinking.
Launder contaminated clothing. KEEP OUT OF REACH OF CHILDREN.
Storage Requirements: Keep containers cool, dry, and store way from all sources of heat, flame, and sparks. Keep containers
tightly closed and store with adequate ventilation. Do not pressurize, cut, weld, or grind the containers or empty containers which
may contain residual product and solvent vapours that may ignite explosively.
SECTION 8 – EXPOSURE CONTROL & PERSONAL PROTECTION
Hazardous Ingredients:
Engineering Controls: Do not use in enclosed areas without proper explosion-proof ventilation. General and local exhaust
ventilation must be sufficient to control vapour concentrations and keep the PEL below 100 ppm.
Ventilation: Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs. Local
exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source.
Administrative Controls:
Respiratory Protection: A NIOSH approved respirator must be used if vapour concentration is 100 ppm or above.
Protective Clothing/Equipment: Permeation resistant gloves (that meet ANSI/ISEA 105-2005) recommended. Glasses or
goggles recommended. Industrial shoes to protect feet from adhesive contact. Long sleeves, long trousers to protect skin from
adhesive contact. Protective skin creams or emollients useful.
Safety Stations: Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in work area.
Contaminated Equipment: Separate contaminated work clothes from street clothes. Launder before reuse. Remove this material
from your shoes and clean personal protective equipment.
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before
eating, drinking, smoking, using the toilet, or applying cosmetics.
SECTION 9 – PHYSICAL & CHEMICAL PROPERTIES
Physical State: Liquid
Appearance and Odour: Yellowish liquid with strong
hydrocarbon odour.
Odour Threshold: Not available
Vapour Pressure: 6.7 mm Hg at 400 °F (204 °C)
Vapour Density (Air=1): 2.0-3.7
Specific Gravity (H2O=1, at 4 °C/39°F): 0.84
PH: N/A
MSDS – BA-90 Bonding Adhesive
Water Solubility: Negligible
Boiling Point (°C): 56-139 (133-282°F)
Freezing/Melting Point(°C): -48 (-54°F)
% Volatile: 79-83
Evaporation Rate(nBuAc=1): 0.6-8.3
VOC: 656 gpl
Flash Point: -4°F (-20°C)
Flash Point Method: CC
Autoignition Temperature: 433.4°F (223°C)
LEL: 1.1% v/v
UEL: 12.8% v/v
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SECTION 10 – STABILITY & REACTIVITY
Stability: Stable.
Possibility of Hazardous Reactions: Will not occur.
Chemical Incompatibilities: Strong oxidizing agents, acids, bases.
Conditions to Avoid: Heat, sparks, and flames; ignition sources.
Hazardous Decomposition Products: Toxic gases or vapours such as carbon monoxide, carbon dioxide, or oxides of nitrogen
may be released in a fire.
SECTION 11 – TOXICOLOGICAL INFORMATION
Toxicity Data:
Eye Effects: Irritating
Skin Effects: Irritating
Acute Inhalation Effects: Product toxicity has not been determined.
Following are the component data:
TC50:
Toluene: Rat > 26,700 ppm 1 hr; Mouse 400 ppm 24 hr
Acetone: Rat > 20,700 ppm 8 hr
Heptane: Human TCLo: 1000 ppm/6 minutes
Acute Oral Effects: Product toxicity has not been determined. Following
are component data:
LD50:
Toluene: Rat 5000 mg/kg
Acetone: Rate 5,800 mg/kg
Mouse 3,000 mg/kg
Rabbit 5,340 mg/kg
SN-LA(Heptane): Rat, ivn, 222 mg/kg
Chronic Effects: May cause skin sensitization in some people.
Carcinogenicity: Not listed in IARC or NTP.
Mutagenicity: Some evidence in animal exposure to Toluene
Teratogenicity: Some evidence in animal exposure to Toluene
SECTION 12 – ECOLOGICAL INFORMATION
Ecotoxicity: Not known
Environmental Fate: Not known
Environmental Degradation: Not known
Soil Absorption/Mobility: Not known
SECTION 13 – DISPOSAL CONSIDERATIONS
Disposal: Dispose of in accordance with all local, state, and federal regulations.
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SECTION 14 – TRANSPORT INFORMATION
DOT Transportation Data (49 CFR 172.101):
Shipping Name: Adhesives, 3, UN1133,
II
Shipping Symbols: Flammable
Hazard Class: 3
ID No.: UN1133
Packing Group: II
Label: red Flammable Liquid label
required
Special Provisions (172.102): 149, B52,
IB2, T4, TP1, TP8
Packaging Authorizations
a) Exceptions: 173.150
b) Non-bulk Packaging: 173.173
c) Bulk Packaging: 173.242
Quantity Limitations
a) Passenger, Aircraft, or Railcar: 5L
b) Cargo Aircraft Only: 60L
Vessel Stowage Requirements
a) Vessel Stowage: B
b) Other: ---
SECTION 15 – REGULATORY INFORMATION
EPA Regulations:
RCRA Hazardous Waste Number (40 CFR 261.33): Not listed
RCRA Hazardous Waste Classification (40 CFR 261): Not classified
TSCA (Toxic Substances Control Act) Status:
TSCA (United States) – The intentional ingredients of this product are listed.
CERCLA Hazardous Substance RQ – 40 CFR 302.4 (a)
Component
RQ (lbs)
Toluene
1000
Xylenes (O-, M-, P- Isomers)
100
Acetone
5000
CERCLA RQ – 40 CFR 302.4 (b)
Materials with a “listed” RQ may be reportable as an “unlisted hazardous substance”. See 40 CFR 302.5 (b).
SARA 311/312 Codes:
Immediate (X)
Delayed (X)
SARA 313 Components (40 CFR 372.65):
Section 313 Component(s)
Toluene
Xylene
Fire (X)
Reactive ( )
CAS Number
108-88-3
1330-20-7
Sudden Release of Pressure ( )
%
30 – 60
1–5
SARA EHS (Extremely Hazardous Substance) (40 CFR 355): Not listed, Threshold Planning Quantity (TPQ)
OSHA Regulations:
Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A): Not listed
OSHA Specifically Regulated Substance (29 CFR 1910): None listed
EPA Accidental Release Prevention (40 CFR 68): None listed
State Regulations:
California Proposition 65:
The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of
1986: This product contains the following substance(s) known to the State of California to cause reproductive harm:
Toluene
Delaware Air Quality Management List:
Chemical Name
Toluene
Xylene
Acetone
MSDS – BA-90 Bonding Adhesive
DRQ:
1000
100
5000
State?
Must be reported to the DRQ
N
Must be reported to the DRQ
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Massachusetts Hazardous Substances List:
Chemical Name
Toluene
Xylene
Acetone
SN-LA(Heptane)
CAS #
108-88-3
1330-20-7
67-64-1
64742-89-8
Codes
2, 4, 5, 6, F7, F8
2, 4, F8, F9
2, 4, 5, 6, F8, F9
2, 4, 5, 6
Michigan Critical Materials Registry:
Chemical Name
Toluene
Xylene
CAS #
108-88-3
1330-20-7
Report
---
Minnesota Hazardous Substance:
Chemical Name
Toluene
Xylene
Acetone
SN-LA(Heptane)
Codes
ANO
ANO
ANO
ANO
Hazards
skin
----
Carcinogen?
No
No
No
No
New Jersey RTK Label Information:
Chemical Name
CAS #
Toluene
108-88-3
Xylenes
1330-20-7
Substance #
1866
2014
DOT #
1294
1307
New York List of Hazardous Substances:
Chemical Name
RQ – Air
Toluene
1000
Xylene
1000
Acetone
5000
RQ – Land
1
1
1
Note
Pennsylvania RTK Label Information
Chemical Name
CAS #
Benzene, Methyl
108-88-3
Benzene, Dimethyl
1330-20-7
2-Propanone
67-34-1
SN-LA(Heptane)
64742-89-8
Washington Air Contaminant:
TWA (ppm):
100 (Toluene)
TWA (mg):
375 (Toluene)
STEL (ppm):
150 (Toluene)
STEL (mg):
560 (Toluene)
Ceiling (ppm):
None listed
Ceiling (mg):
None listed
Skin:
None listed
Class
---
TPQ
---
EHS
none
none
none
Code
E
E
E
--
750 (Acetone)
1800 (Acetone)
1000 (Acetone)
2400 (Acetone)
SECTION 16 – OTHER INFORMATION
The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company
or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their
circumstances.
Reference: The information herein is presented in good faith and believed to be correct as of the date hereof. Information is
based upon supplier issued material safety data sheets and may be subject to error. If apprised of changes, updated MSDS will
be promptly issued. Users must make their own determination regarding the suitability of the product for their own purposes
prior to use.
Prepared By:
Lexsuco 2010 Corporation
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