A Look at Nuclear Science and Technology Larry Foulke Atomic and Nuclear Physics – The Einstein Connection 2.6 Calculations Example Problem (Easy) Krypton-85 has a half-life of roughly 11 years. It’s decay constant is equal to: a. 0.063 yrs-1 b. 7.62 yrs c. exp [-11(t)] d. 11 years Example Problem (Easy) Krypton-85 has a half-life of roughly 11 years. It’s decay constant is equal to: a. 0.063 yrs-1 * b. 7.62 yrs c. exp [-11(t)] d. 11 years 0.693 λ= = 0.063 yr −1 11 yrs Example Problem (Medium) What is the time required for U-235 to decay by 1%? Example Problem (Medium) What is the time required for U-235 to decay by 1%? Half − life of U − 235 is 7.04x10 8 years 0.693 −10 −1 Decay constant = = 9.83x10 yr 7.04x10 8 yrs Now decay by 1% (not decay to 1%) n(t) −(9.83x10 −10 )t = 0.99 = e n(0) ln(0.99) = −0.01005 = −9.83x10 −10 (t) or t = 1.021x10 7 yrs Example Problem (Harder) The age of the earth is estimated to be 4.5 billion years. What was the enrichment of U-235 in natural uranium when the earth was formed? Example Problem (Harder) The age of the earth is estimated to be 4.5 billion years. What was the enrichment of U-235 in natural uranium when the earth was formed? Half − life of U − 235 is 7.04x10 8 years U - 235 decay constant = 0.693 = 9.8438x10 −10 yr −1 8 7.04x10 yrs Half − life of U − 238 is 4.5x10 9 years U - 238 decay constant = 0.693 −10 −1 = 1.5400x10 yr 4.5x10 9 yrs .72 = 60.41 0.011918 −10 9 99.2745 99.2745 = N 238 (0)e−(1.5400 x10 )(4.5 x10 ) = N 238 (0)e−0.693or N 238 (0) = = 198.52 0.5 N 235 (0) N 235 (0) + N 238 (0) = 60.41 + 198.52 = 258.93 or = 23.3% N 235 (0) + N 238 (0) 0.72 = N 235 (0)e −(9.8438 x10 −10 )(4.5 x10 9 ) = N 235 (0)e−4.4297 or N 235 (0) = Example Problem Gamma rays interact with Be-9 to produce “photoneutrons.” What is the threshold gamma energy to make this reaction happen? The reaction is: Use the following mass data: Example Problem Gamma rays interact with Be-9 to produce “photoneutrons.” What is the threshold gamma energy to make this reaction happen? The reaction is: 9 Be + γ → 8 Be + 1n0 Use the following mass data: 9 Be = 9.012182 amu; γ = 0 mass 8 Be = 8.005305 amu; 1n0 = 1.008665 amu so LHS = 9.012182 amu and RHS = 9.013970 amu Mass difference = 9.013970 − 9.012182 = 0.001788 amu Mass increases so that requires energy to be supplied The amount of energy is (0.001788 amu)(931.5MeV / amu) = 1.666Mev Example Problem The energy released by the following reaction is most nearly: 235 U + 1 n -> 2 1 n + 138 Cs + 96 Rb 92 0 0 55 37 a. b. Useful data Element 235 U 92 c. Atomic mass (amu) 235.043922 138 Cs 55 137.91101 96 Rb 37 95.93427 1 n 0 1.008665 d. 177 MeV 931.5 MeV 236.05 MeV 200 MeV Example Problem The energy released by the following reaction is most nearly: 235 U + 1 n -> 2 1 n + 138 Cs + 96 Rb 92 0 0 55 37 a. Useful data Element 235 U 92 Atomic mass (amu) 235.043922 138 Cs 55 137.91101 96 Rb 37 95.93427 1 n 0 1.008665 b. c. d. 177 MeV 931.5 MeV 236.05 MeV 200 MeV LHS : 235.043922 + 1.008665 = 236.052587 RHS : 2(1.008665) + 137.91101 + 95.93427 = 235.86261 Mass loss = 236.052587 − 235.86261 = 0.189977 amu Mass is lost so energy is released = (0.189977 amu)(931.5MeV / amu) = 176.96 MeV Example Problem Given that the mass of a proton is 1.007825 amu and the mass of a neutron is 1.008665 amu, the mass of a deuterium atom (H-2) is __________. a. 4.032980 amu b. 3.025155 amu c. 2.016490 amu d. 2.014102 amu Example Problem Given that the mass of a proton is 1.007825 amu and the mass of a neutron is 1.008665 amu, the mass of a deuterium atom (H-2) is __________. a.4.032980 amu b.3.025155 amu c.2.016490 amu d.2.014102 amu * According to mass defect, the sum of the constituents of an atom is great than the observed mass of the given atom. Answer (c) is equal to the sum of the constituents, (a) and (b) are greater than the sum, and (d) is less than the sum; therefore, (d) is the correct answer. Example Problem Sodium-22 has a half-life of 2.604 years. Calculate the activity of a 10 gram sample of pure Na-22. a. 7.2840×1022 decays/sec b. 7.2840×1018 decays/sec c. 5.0793×1015 decays/sec d. 2.3085×1015 decays/sec Example Problem Sodium-22 has a half-life of 2.604 years. Calculate the activity of a 10 gram sample of pure Na-22. a. 7.2840×1022 decays/sec b. 7.2840×1018 decays/sec c. 5.0793×1015 decays/sec d. 2.3085×1015 decays/sec* N Na22 atoms = gm 10gm N av atoms / mole = x6.023x10 23 atoms / mole gm / mole 22gm / mole N Na22 atoms = 2.738x10 23 decay constant = λ = ( 0.693 −9 = 8.45x10 sec 7 (2.604yr ) 3.15x10 sec/ yr Activity = λ N Na22 = 8.45x10 −9 ( ) )(2.738x10 )= 2.31x10 23 15 dis / sec Example Problem The Transportation Security Administration stopped a suspicious passenger and found some radioactive material on the individual. A 1000 gm sample is found to have an activity of 2.3×1012 Becquerels. The sample is most likely: a) Sr-90 b) Pu-239 c) U-235 d) Cs-137 Example Problem 11. The Transportation Security Administration stopped a suspicious passenger and found some radioactive material on the individual. A 1000 gm sample is found to have an activity of 2.3×1012 Becquerels. The sample is most likely: a)Sr-90 1000gms Pu − 239 (6.023x10 atoms / mole)= 2.52x10 atoms 239 gms / mole b)Pu-239 * Activity = λ N c)U-235 2.3x10 Bq = 2.3x10 dis / sec d)Cs-137 2.3x10 dis / sec = λ (2.52x10 atoms ) 23 12 12 12 24 2.3x1012 dis / sec = 9.13x10 −13 sec −1 = λ= 24 2.52x10 atoms 0.693 T1/2 = = 7.59x1011 sec = 24,100 yrs −13 −1 9.13x10 sec which is close to the half − life of Pu − 239 24
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