SOP / K2SO4 Mannheim Oven Best Process Know-how, Partners and Strategy for Successful Business Process Description cheminée The process for the manufacture of Potassium Sulphate is based on following chemical reactions: 2 KCl + H2SO4 -> K2SO4 + 2 HCl The process involves following main stages: Continuous reaction of Potassium Chloride and Sulphuric Acid in a vertical indirectly heated oven equipped with a central mixing device. Potassium Sulphate produced is neutralised with Calcium Carbonate, cooled and stored before conditioning. Hydrochloric gas escaping from the oven is cooled down and absorbed into washing towers. Hydrochloric acid is concentrated to 30-33%. démister HCl BAC H2SO4 tour HCl entrée eau refroidissement HCl pompe doseuse H2SO4 HCl 31% Vis d'introduction KCl gaz chauds refroidisseur HCl gaz sortie eau HCl gaz TREMIE KCl FOUR Elévateur à godet SULFATE CaCO3 poudre doseur KCl Vis transport KCl décharge K2SO4 vers stock Capacity & Quality (see table) groupe entrainement mélangeur arrivée gaz naturel foyer gaz chauds Capacity as required by client. Typically 10’000 MTPY per Mannheim Oven Applications ∗ 91 % for Specialty fertilizers (non-grain uses, e.g., tobacco, citrus fruits, grapes, potatoes), ∗ 8 % for Potassium supplement to animal feeds, ∗ 1 % for Industrial applications (accelerator in gypsum board, flash suppressant in explosives and pharmaceuticals) Process Advantages and Features Product Specification Typical K2O content ≥ 50.0% - Cl content ≤ 1.0% Humidity ≤ 1.0% Free acid(in H2SO4) ≤ 1.5% Water in solution ≤ 1.0% Particle size: • • • • Efficient and reliable technology Low capital cost Premium Product with Low chloride SOP <0.5% ClAccording to local conditions, HCl can be: ∗ Sold on local market ∗ Neutralized ∗ Further processed to CaCl2, DCP, PPA, TSP, PAC, FeCl3 or others Scope of Supply & Services • • • • • • Project management Pre-feasibility and feasibility study (bankable file) Know-how, basic and detailed engineering Start-up and commissioning Personnel training Equipment delivery AD PROCESS STRATEGIES SARL RUE CHAPOIERE 9 CH-1201 GEEVA SWITZERLAD eau refroidissement 3 %≥ 2mm 60%≤ 0.1 mm Typical Specific Consumptions KCl (< 1mm) 97 % purity 0.870 T/T H2SO4 98,5 % 0.575 T/T CaCO3 (fine) 25 Kg/T Electric Power 50 -70 KWh/T Natural Gas 55 -65 Nm3 /T Cooling Water (18°C) ©2009 AD Process Strategies SARL We assume no responsibility for and give no guarantees, undertakings or warranties concerning the accuracy, completeness or up to date nature of the information provided on this document at the time and do not accept any liability whatsoever arising from any errors or omissions. 90 m3 /T Phone : +41 22 548 12 49 Fax : +41 22 545 75 12 Email : [email protected] WWW : www.adpro-stg.com
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