Page 1 of 3 MATERIAL SAFETY DATA SHEET SECTION 1 - IDENTIFICATION OF THE MATERIAL AND SUPPLIER Material Name: Catalogue Number: Other Names: Recommended Use: Supplier Name: Street Address: Telephone Number: Emergency Contact: Autoradiography Emulsion NTB. P8895666. PCD NTB Photographic Chemical for Industrial use only. ProSciTech 1/11 Carlton Street, Kirwan, Qld. 4817 Australia (07) 4773 9444 Fax Number: (07) 4773 2244 (07) 4773 9444 8:30am – 5:00pm, Monday to Friday SECTION 2 - HAZARDS IDENTIFICATION Not classified as hazardous according to criteria of NOHSC. NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS Hazard Classification: Hazardous and/or Dangerous Nature: Risk Phrases: Safety Phrases: S24/25 Avoid contact with skin and eyes. SECTION 3 - COMPOSITION /INFORMATION ON INGREDIENTS SUBSTANCE: Chemical Identity: Common Name(s): CAS Number(s): Autoradiography Emulsion NTB PCD NTB - MIXTURE: Ingredients Water Silver Bromide Gelatins Glycerol Methanol Saponin Cas Number(s) 7732-18-5 7785-23-1 9000-70-8 58-81-5 67-56-1 74499-23-3 Proportion (%) 80-85 5-10 1-5 1-5 <1 <1 SECTION 4 - FIRST AID MEASURES Drink 1 to 2 glasses of water, seek medical attention. NEVER give anything by mouth to an unconscious person. Flush with plenty of water. Seek medical attention if symptoms occur. Eye: Remove contaminated clothing and shoes. Wash affected area with soap and water. Skin: Wash clothing before reuse, wash shoes thoroughly or dispose of them. If inhaled remove person/people to fresh air. Treat symptomatically, seek medical aid. Inhaled: Eyebath/eyewash & Safety shower. First Aid Facilities: Medical Attention & Special Treatment: Treat symptomatically and supportively. ADDITIONAL INFORMATION: Silver Bromide: Excessive absorption of silver compounds from CHRONIC overexposure may result in argyria, a bluish-gray discolouration of the skin, eyes and mucous membranes. Swallowed: SECTION 5 - FIRE FIGHTING MEASURES Suitable Extinguishing Media: Use extinguishing method appropriate for surrounding fire. Hazards from Combustion Products: Hydrogen bromide, nitrogen oxides and carbon oxides. Precautions for Fire Fighters: Wear appropriate protective equipment for surrounding fire. Not specified. Hazchem Code: SECTION 6 - ACCIDENTAL RELEASE MEASURES Emergency Procedures: Not available. Containment and clean up: Page 2 of 3 Prevent spillage from entering drains/sewage systems. Absorb with vermiculite or other inert material and place into a suitable sealable container for proper disposal. Clean spill area with water to remove residual traces. SECTION 7 - HANDLING & STORAGE Precautions for Safe Handling: Avoid breathing mist or vapour from heated material at concentrations great tan the exposure limits. Avoid contact with eyes, skin and clothing. Ensure adequate ventilation in area when in use. Wash thoroughly after handling. Conditions for Safe Storage: Keep container tightly closed. Keep refrigerated. Keep away from Incompatible Materials (see Section 10). SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION National Exposure Standards: Glycerol: TWA 10mg/m3 Methanol: TWA 200ppm, STEL 2550ppm Silver Bromide: 0.1mg/m3 No biological limit allocated. Biological Limit Values: Engineering Controls: Good general ventilation (typically 10 air changes per hour) should be used. Use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. Personal Protective Equipment: Respiratory: If airborne concentrations are above recommended exposure limits an approved respirator must be worn. Recommended: N95 Particulate Filter, and should comply with Worksafe Australia standard AS/NZS 1716:1994. Eye protection: Wear safety glasses with side shields or goggles. Skin and Body protection: Wear impervious gloves and protective clothing (appropriate to minimise risk of exposure). SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES Appearance: Odour: pH: Vapour pressure (mm of Hg at 25°C): Vapour density: Boiling point/range (°C): Freezing/melting point (°C): Solubility: Specific gravity or density: Flash Point: Flammable (explosive) limits: Ignition temperature: Additional Information: Solid Gel. Odourless. 6 Not available. Not available. BP: > 100 °C MP: > 40°C Dispersable. Not available. None. Not available. Not available. SECTION 10 - STABILITY AND REACTIVITY Chemical stability: Conditions to avoid: Incompatible Materials: Hazardous Decomposition Products: Hazardous Reactions: Stable under normal conditions of use. Not available. None with common materials and contaminants the material may contact with. Hydrogen bromide, nitrogen oxides and carbon oxides. Will not occur. SECTION 11 - TOXICOLOGICAL INFORMATION Exposure and Health Effects: Silver Bromide: Excessive absorption of silver compounds from CHRONIC overexposure may result in argyria, a bluish-gray discolouration of the skin, eyes and mucous membranes. Ingestion: Expected to be a low ingestion hazard. Inhalation: Page 3 of 3 Expected to be a low hazard if used in accordance with recommended handling. Skin Contact: May cause allergic reaction. Eye Contact: No specific hazard known - may cause transient irritation. Human/Animal data: Not available. None Carcinogenicity: SECTION 12 – ECOLOGICAL INFORMATION Ecotoxicity: Persistence and degradability: Mobility: Additional Information: Waste treatment organisms EC50: > 100 mg/l Readily biodegradable. Potential Bioaccumulation: log Pow < 1. Not available. COD: ~ 77 g/l BOD: ~ 46g/l SECTION 13 - DISPOSAL CONSIDERATIONS Disposal Methods: Dispose of in accordance with Local, State and Federal law. Use a licensed chemical disposal agency. Special Precautions: Recover silver before disposal. SECTION 14 - TRANSPORT INFORMATION UN Number: UN Proper Shipping Name: Class and Subsidiary risk: Packing Group: Special Precautions for User: Hazchem Code: Not regulated. Not regulated. Not regulated. Not regulated. Not available. Not specified. SECTION 15 - REGULATORY INFORMATION Poison Schedule Number: None allocated. SECTION 16 - OTHER INFORMATION Date of preparation of MSDS: Comments: July 10 List of Publications referenced when creating this MSDS; - Hazardous Substances Information System Consolidated Lists: Safe Work Australia. - APPROVED CRITERIA FOR CLASSIFYING HAZARDOUS SUBSTANCES [NOHSC:1008(2004)] 3rd Edition: National Occupational Health and Safety Commission. - Dangerous Goods - Initial Emergency Response Guide (SAA/SNZ HB76:1997). - IATA Dangerous Goods Regulations. - Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOHSC:1003(1995)]. - Australia Standard for the Uniform Scheduling of Drugs and Poisons [SUSPD] (Australian Government Department of Health and Ageing). This Material Safety Data Sheet (MSDS) has been prepared in compliance with the National code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC:2011(2003)]. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this MSDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Material Safety Data Sheets as new information becomes available. Copies may be made for non-profit use. … End of MSDS …
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