Liquids and Solids and Intermolecular Forces.notebook August 12, 2015 higher higher lower Intermolecular Forces Oct 67:38 AM Oct 67:55 AM (1) Consider the statement: "As H2O changes from a liquid form to a gaseous form, the HO bonds of the water are breaking." Support or refute this statement with a complete explanation. (2) Oct 29:51 AM Oct 117:33 AM H2O molecule LiCl crystal Show the interactions of components of LiCl (aq) in a beaker. Include only one formula unit of LiCl and no more than 10 molecules of water. Include: Identity of ions butane (symobl and charge) & proper orientation of particles. Oct 28:28 AM butanone butanol LiCl (aq) Oct 117:34 AM 1 Liquids and Solids and Intermolecular Forces.notebook August 12, 2015 Oct 39:57 AM Oct 32:22 PM Oct 117:35 AM Oct 310:24 AM H2O molecule MgCl2 crystal Show the interactions of components of MgCl2 (aq) in a beaker. Include only one formula unit of MgCl2 and no more than 12 molecules of water. Include: Identity of ions (symbol and charge) & proper orientation of particles. Oct 28:28 AM MgCl2 (aq) Oct 72:24 PM 2 Liquids and Solids and Intermolecular Forces.notebook August 12, 2015 Sketch a solution of aqueous ammonia, NH3, showing (1) identity of the substances and (2) the correct orientation of those substances. Show no less than 2 NH3 and no less than 4 H2O particles. Also, indicate the intermolecular force(s) present. N O H H H H H Note: Use to show intermolecular attractions NH3 (aq) Oct 28:28 AM Oct 117:35 AM Oct 117:36 AM Oct 117:37 AM Fill in the red lines and describe the e- when prompted Oct 67:55 AM Oct 108:26 AM 3 Liquids and Solids and Intermolecular Forces.notebook Oct 108:25 AM August 12, 2015 Oct 108:26 AM 1) A liquid whose molecules are held together by which of the following forces would be expected to have the lowest boiling point? (A) Ionic bonds (B) London dispersion forces (C) Hydrogen bonds (D) Metallic bonds (E) Network bonds 2) Which of the following lists of species is in order of increasing boiling points? (A) H2 , N2 , NH3 (B) N2 , H2 , NH3 (C) NH3 , H2 , N2 (D) NH3 , N2 , H2 (E) H2 , NH3 , N2 Oct 108:26 AM Oct 118:09 AM 1) Which of the compounds listed below would require the greatest energy to separate it into ions in the gaseous state? (A) NaCl (B) NaI (C) MgO (D) Na2O (E) MgCl2 2) Which of the molecules listed below has the largest dipole moment? (A) Cl2 (B) HCl (C) SO3 (D) NH3 (E) N2 Oct 118:12 AM Oct 108:28 AM 4 Liquids and Solids and Intermolecular Forces.notebook Oct 108:31 AM August 12, 2015 Oct 108:28 AM (a) Draw the Lewis electron-dot diagram for Ethyne. (b) Which of the four molecules has the shortest carbon-tocarbon bond? Explain. (c) Ethanoic Acid is given below. What is the geometry around C x and Cy? (d) Consider the statement, "As ethanol boils, energy goes into breaking C-C bonds, C-H bonds, C-O bonds, and O-H bonds." Is this statement true or false? Justify your answer. (e) Identify a compound from the table above that is nonpolar. (f) Ethanol is completely soluble in water, whereas ethanethiol is slightly soluble. Explain in terms of intermolecular forces. Oct 810:16 AM Oct 108:32 AM Oct 810:28 AM Oct 810:26 AM 5 Liquids and Solids and Intermolecular Forces.notebook August 12, 2015 (A) CO2 (B) H2O (C) SO2 (D) NO2 (E) O2 1) In this molecule, oxygen forms sp 3 hybrid orbitals. 2) This molecule contains one unpaired electron. 3) This molecule contains no pi ( π) bonds. 4) Oxygen has an oxidation state of zero in this molecule. Oct 128:00 AM Oct 108:28 AM 1) If the carbontocarbon bond in C2H6 is found to have a bond energy of 350 kJ/mol and a bond length of 1.5 angstroms. Explain what the relative bond energy and length of the carbonto carbon bond for C2H4 would be. 2) A pure sample of KClO3 (FW = 123.5) is found to contain 71 grams of chlorine atoms. What is the mass of the sample? (A) 122 grams (B) 170 grams (C) 209 grams (D) 245 grams (E) 293 grams Oct 108:27 AM 2 Oct 128:08 AM 1) The first ionization energy for magnesium is 730 kJ/mol. The third ionization energy is 7700 kJ/mol. What is most likely the value for the second ionization energy? (A) 490 kJ/mol (B) 1400 kJ/mol (C) 4200 kJ/mol (D) 7100 kJ/mol (E) 8400 kJ/mol 2) Which of the following groups below is (are) listed in order from lowest to highest melting point? I. KI, LiF, BeO II. F 2, Cl2, Br2 III. K, Na, Li Oct 128:11 AM Oct 138:16 AM 6 Liquids and Solids and Intermolecular Forces.notebook August 12, 2015 2008 Form A Practice Exam Question Oct 138:11 AM Oct 138:21 AM Oct 138:16 AM Oct 138:18 AM Oct 138:20 AM Oct 138:18 AM 7 Liquids and Solids and Intermolecular Forces.notebook August 12, 2015 Oct 188:18 AM Oct 188:20 AM Oct 138:26 AM Oct 188:24 AM Oct 188:12 AM Oct 178:16 AM 8 Liquids and Solids and Intermolecular Forces.notebook August 12, 2015 Unknown Lab BaCl2 NaCl NH4Cl Pb(NO3)2 AgNO3 CoCl2 Can only use to identify: • Appearance • H2 O • 1M Na3 PO4 • 1M NaOH • 1M KI Oct 198:27 AM Oct 199:11 AM Oct 199:12 AM Oct 199:12 AM 9
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