25/11/2015 How to get that A* grade in Chemistry There are now 32 Medical & 7 Veterinary schools in the UK A few years ago AAA – AAB would have been the standard offer In 2015 grades required range from A*AAa to BBCb Med schools asking for A* grades include:universities state they require an A* grade Cambridge, Oxford, Birmingham, Exeter, Keele & Plymouth Most are now asking for 3 A levels plus a fourth AS Typically AAAb Most will not count General Studies Be careful with Maths and Further Maths Many will accept the Extended Project Qualification (EPQ) or Critical Thinking 1 25/11/2015 As yet it is not totally clear but a consensus is beginning to emerge Almost all will want at least AAA at A level All exams must be taken at one sitting Almost all want at least B in a fourth AS Most will not count General Studies Must include Chemistry Many also want Biology You must do your own research Check the universities you are interested in How to get information Hull-York Southampton 2 25/11/2015 How to get that A* grade All papers will examine content from years 1 and 2 Every question on every paper has to have an assessment objective - called AO AO1 AO2 AO3 Knowledge & understanding 30 – 35% of the marks Application of knowledge 40 – 45% of the marks Analysis, interpretation, evaluation 25 – 30% of the marks To get an A* grade you will need to score 90% 3 25/11/2015 Exam papers will contain Structured questions Free response questions Multiple choice questions Questions will NOT be centred on recall. They will be based around: understanding application of knowledge problem solving more complex calculations Need to stretch students even at AS Students need to read beyond the core syllabus Use sources/questions that stretch them Make absolutely certain the basics are well understood The real key to getting an A* grade is to make sure that you know all the routine stuff well, don’t make silly mistakes and drop marks - develop good exam technique 4 25/11/2015 Oxygen, O2 – easy O O Ozone, O3 – this now becomes A* material and you have to apply your knowledge Compound X has molar mass = 118 g mol-1 and contains 40.68%c, 5.08%H & 54.24%O. Calculate its empirical & molecular formulae. C 1 : : H : O 1.5 : 1 Empirical formula = ?C2H3O2 Straight forward – often 80 -90% score the marks But students will insist on rounding: Compound X is a hydrocarbon with molar mass 68 g mol-1. It contains 88.24% carbon, deduce its molecular formula. C 88.24 : H 11.76 5 25/11/2015 A few years ago students were told the formula of phosphoric acid, H3PO4 and asked for the formula of calcium phosphate Less than 10% got the correct response I get the impression students don’t think its particularly important if a formula is wrong Use periodic table to deduce valency Group 1 2 3 4 5 6 7 Valency 1 2 3 4 3 2 1 You also need to LEARN the valencies of a few common transition elements and: nitrate carbonate sulfate Valency ammonium hydroxide NO3 CO3 SO4 NH4 OH 1 2 2 1 1 1: Write each of the symbols Ca 2: Write the valency at the top right-hand side of the symbols Ca 3: Cross-over the valencies. Write them at the bottom right of the other symbol Ca 4: You now have the formula of the compound OH 2 1 OH ( OH ) Ca(OH)2 Sli de 18 6 25/11/2015 H 3PO4 Symbols on both sides of the equation We have to balance: We also have to balance: Oxidation number on each side of the equation IO3– + ...... I– + ...... H+ Charge on each side of the equation ...... I2 + ...... H2O 7 25/11/2015 Lactic acid, CH3CH(OH)COOH is a naturally occurring acid that reacts with NaOH(aq) to produce the salt sodium lactate, CH3CH(OH)COO-Na+. Citric acid, HOC(COOH)3, is also a naturally occurring acid and forms salts in the same way as lactic acid. Deduce the formula of sodium citrate. Citric acid also reacts with calcium hydroxide. Construct a balanced equation for the reaction. Rules Elements: zero Molecules add up to zero Ions add up to the charge of the ion Order of priority Groups 1,2 & 3 are always +1, +2 and +3 respectively Then apply in order F = -1, H = +1, O = -2, Cl = -1 You should then be able to calculate any others +1 +1 -2 = 0 NaClO It’s a molecule therefore adds up to zero Apply the order of priority Group 7 chemistry – students are expected to know that Cl2 disproportionates. Cl2 + 2NaOH NaClO + NaCl + H2O In a recent exam students were told that under certain conditions Cl2 also reacted with NaOH to form NaClO3 and then asked to construct a balanced equation. Cl2 + NaOH NaClO3 + NaCl 8 25/11/2015 HNO3(aq) + Cu(s) → Cu(NO3)2(aq) + NO(g)+ H2O(l) 0.46g Na(s) reacts with 50 cm3 H2O(l). Calculate the volume of H2(g) and the concentration of the NaOH(aq) solution produced. 40 cm3 of a hydrocarbon was ignited with 500 cm3 of O2(g) and the products cooled to room temperature. The resultant gas mixture, 420 cm3, was passed through a solution of NaOH(g) and the volume of gas dropped to 260 cm3. Determine the molecular formula of the hydrocarbon? 9 25/11/2015 % chlorine atoms 75% easy!! 25% 35 37 m/z (35 x 75) + (37 x 25) = 2625 + 925 = 3550 = 35.5 100 100 100 BUT It will not be based on recall It might be mathematically based It might be an extension of the syllabus content It might be based on information given The next questions aren’t on the syllabus but you are supplied with enough information to answer the question 10 25/11/2015 Carbonyl compounds that have at least one H on a C adjacent to the C=O can undergo a condensation reaction. + C H 3C OH O O CH 3 H 3C N aO H cat C CH 3 Propanone H 3C O C CH CH 2 C CH 3 3 2-methyl-2-hydroxypentan-4-one Use this information and your knowledge of other reactions to suggest how ethanal could be converted into butane-1,3-diol. GOOD EXAM TECHNIQUE 11 25/11/2015 12 25/11/2015 Book 1 covers modules 1 to 4 which are taught in the first year of the course Revision guide – summarises essential topics and provides insight into what examiners are looking for. Practice questions that cover the syllabus topic by topic 13 25/11/2015 At the end of each chapter there are practice questions which are graded as: * easy, ** moderate, *** difficult **** challenging If you can do this in your head ….. you are better thantoI am Multiple choice questions are new most of the exams and there aren’t You have to practice questions a lot of old questions to practice. At the end of each chapter there are 10 multiple choice questions to try/practice. In the two textbooks there are over 300 multiple choice questions to try. Other sources of help 14 25/11/2015 15 25/11/2015 Each question is worth 1 mark There are around 27 questions & only 30 minutes to answer them all And you cannot use a calculator Our genes evolved for a Stone Age life style. Therefore, we must adopt Stone Age habits if we are to be healthy. Write a unified essay in which you address the following: Explain the logical connexion between the two sentences. What might be the practical implications if we were to agree with the reasoning? Discuss the extent to which the argument is valid. 16 25/11/2015 17 25/11/2015 18
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