Geo-Mar Lett DOI 10.1007/s00367-011-0267-6 ORIGINAL Evidence for climatic and oceanographic controls on terrigenous sediment supply to the Indian Ocean sector of the Southern Ocean over the past 63,000 years Madhusudhanan C. Manoj & Meloth Thamban & Natani Basavaiah & Rahul Mohan Received: 15 April 2011 / Accepted: 17 November 2011 # Springer-Verlag 2011 Abstract Multiple proxy studies on sediment core SK 200/22a from the sub-Antarctic sector of the Indian Ocean revealed millennial-scale fluctuations in terrigenous input during the last 63,000 years. The marine isotope stages 1 (MIS 1) and MIS 3 are characterized by generally low concentrations of magnetic minerals, being dominated by fine-grained magnetite and titanomagnetite. Within the chronological constraints, periods of enhanced terrigenous input and calcite productivity over the last 63,000 years are nearly synchronous with the warming events recorded in Antarctic ice cores. An equatorward shift of the westerly wind system in association with a strengthening of the Antarctic Circumpolar Current (ACC) system may have promoted windinduced shallow-water erosion around oceanic islands, leading to enhanced terrigenous input to the core site. Major ice-rafted debris events at 13–23, 25–30, 45–48 and 55–58 ka BP are asynchronous with δ18O and carbonate productivity records. This out-of-phase relation suggests that ice-sheet dynamics and ACC intensity were the primary factors influencing ice rafting and terrigenous input to the Indian sector of the Southern Ocean, with only limited support from sea-surface warming. M. C. Manoj (*) : M. Thamban : R. Mohan National Centre for Antarctic and Ocean Research, Headland Sada, Vasco-da-Gama, Goa 403 804, India e-mail: [email protected] N. Basavaiah Indian Institute of Geomagnetism, New Panvel, Navi Mumbai, India Introduction Palaeoceanographic studies over the last few decades have shown that processes occurring in the Southern Ocean and in the large Antarctic ice sheets have played a crucial role in defining Earth’s climate (Kennett and Barron 1992). The Antarctic Circumpolar Current (ACC), regarded as a key system in understanding the influence of biogeochemical cycling on the global climate, connects three large ocean basins (Atlantic, Indian and Pacific) and allows transfer of water, salts, heat and other properties and constituents (Nozaki and Alibo 2003). An important feature of the southern hemisphere is the mid- to high-latitude westerly wind system which drives the clockwise ACC. This has a large impact on the Southern Ocean hydrography, sea ice distribution and biologic productivity, and hence plays a significant role in modulating atmospheric CO2 concentrations (Sigman and Boyle 2000; Toggweiler et al. 2006). The ACC is characterized by several circumpolar fronts, which separate regions of relatively uniform water-mass properties and coincide with strong current cores (Orsi et al. 1995; Sparrow et al. 1996). Like the other parts of the Southern Ocean, the Indian Ocean sector is characterized by three major fronts: the Subtropical Front (STF), the SubAntarctic Front (SAF) and the Polar Front (Rintoul and England 2002; Anilkumar et al. 2007; Fig. 1). Both the STF and the SAF are located north of the Crozet and Kerguelen plateaus where they form a frontal zone (Gamberoni et al. 1982; Dezileau et al. 2000), the advection of water masses being driven by the ACC. The major water masses playing a significant role in this region are the Antarctic Bottom Water (AABW), the Circumpolar Deep Water (CDW) and the Antarctic Intermediate Water. The AABW originates near the Antarctic continent and flows Geo-Mar Lett northwards to infill the deep basins at a depth greater than 3,600 m (Orsi et al. 1999). The CDW is the main water mass involved in the formation of all other water masses occurring between 2,000 and 3,600 m water depth, and it rises sharply to shallower depths south of the frontal zone. The CDW within the ACC (ACC-CDW) allows stronger advection with widespread effects on sediment transport and deposition in the Indian sector of the Southern Ocean (Dezileau et al. 2000). Because the Southern Ocean encircles the West and East Antarctic ice sheets, and thus represents a junction box of the global conveyor-belt circulation, marine proxy records from the Southern Ocean provide information on changes in biogenic productivity, sea ice cover, iceberg rafting and deep-ocean circulation (e.g. Berger and Wefer 1996; Filippelli et al. 2007; Anderson et al. 2009). Enhanced input of magnetic materials during cold marine isotope stages, for example, has been attributed to more efficient erosion and transportation by the ACC (Pudsey and Howe 1998; Mazaud et al. 2010). Terrigenous sediment composition in the Atlantic and Indian Ocean sectors of the Southern Ocean is dominated by silt- and clay-sized material with small proportions of sand and gravel delivered by icebergs and/ or sea ice (Diekmann et al. 2004; Diekmann 2007). Within the Indian Ocean sector, much of the observed ice-rafted debris (IRD) consist primarily of volcanic tephra which are transported and deposited by sea ice/icebergs, with quartz fragments forming an additional component (Kanfoush et al. 2002; Nielsen et al. 2007). Accordingly, besides the Antarctic ice-sheet dynamics, changes in IRD deposition in the Southern Ocean may also reflect iceberg survivability and sea ice melting (Carter et al. 2002). Using a wide array of proxies, elevated detrital fluxes to the region have been found to be related to the combined effects of low sea level, increased glaciogenic input, long-distance aeolian supply and enhanced current transport (e.g. Kolla et al. 1976; Bareille et al. 1994; Gaiero et al. 2004; Latimer et al. 2006; Diekmann 2007; Hillenbrand et al. 2008). Environmental magnetic parameters of deep-sea sediments have been used as proxy indicators for changes in palaeoclimate and marine palaeoenvironments before (e.g. Robinson et al. 1995; Verosub and Roberts 1995). However, knowledge about the sources of the magnetic minerals, the influence of diagenesis and environmental conditions is also important for reconstructing the palaeoclimatic history (Bloemendal et al. 1992). The magnetic parameters, in combination with other palaeoenvironmental proxies such as IRD, calcium carbonate content and oxygen isotope records, are useful palaeoceanographic indicators in marine sedimentary records (Bloemendal et al. 1988, 1992). Within this global palaeoclimatic and palaeoenvironmental context, the purpose of the present study was to evaluate environmental magnetic parameters as palaeoclimatic proxy indicators, along with other proxy parameters, to reconstruct the late Quaternary climate history of the region and to compare this with other global palaeoclimatic records on the basis of a sediment core (SK 200/22a) collected from the sub-Antarctic regime of the Indian Ocean sector of the Southern Ocean as part of a long-term multidisciplinary program. Materials and methods A 7.54-m-long sediment core (SK 200/22a) was collected from the Indian Ocean sector of the Southern Ocean at 43° 42′S/45°04′E from a water depth of 2,730 m onboard ORV Sagar Kanya (Fig. 1). The core was sampled onboard at 1 cm intervals for the first 200 cm and at 2 cm intervals below this. To a depth of 115 cm the core consisted of alternating layers of calcareous white to grey sandy silt/clay, followed by a dark greyish band dominated by silty clay between 130 and 148 cm, and by light-grey clays below this band. Subsamples were stored in clean, labelled low-density polyethylene bags, proper care being taken to avoid external and cross-sample contamination. Measurements of mass-specific magnetic susceptibility (χ) were carried out at the Indian Institute of Geomagnetism (IIG), Navi Mumbai, using a MFK1-FA Multi-function Kappabridge. Duplicate measurements were performed at low (0.976 kHz) and high (15.616 kHz) frequencies on all samples. Frequency-dependent susceptibility (χfd) was calculated from the difference in χ at the two frequencies divided by the low-frequency χ, i.e. c fd ¼ ½ðc L c H Þ=c L 100%. Anhysteretic remanent magnetization (ARM), with a peak alternating field of 100 mT and decreasing amplitude, was imposed on a steady field of 0.1 mT, the remanence being measured with a Molspin spinner magnetometer. Isothermal remanent magnetization (IRM) was achieved by placing the samples in increasing magnetic fields at room temperature using a Molspin pulse magnetizer. The IRM acquired at 1.5 T is referred to here as the saturation isothermal remanent magnetization (SIRM). A MMPM9 pulse magnetizer (Magnetic Measurements Ltd.) was used for inducing IRMs. All remanent magnetization measurements were made using an AGICO Molspin spinner magnetometer. The S-ratio f½ð1 IRM0:3T =IRM1T Þ=2 100g reflects variations in the coercivity spectrum of magnetic mineral assemblages and, therefore, the magnetic mineralogy (Bloemendal et al. 1988). The magnetic remanence acquired at low (soft IRM) and high (hard IRM) applied magnetic fields of the sediment was also measured. The L-ratio was calculated by taking the ratio between hard IRM and IRMAF@100mT (hard IRM/ IRMAF@100mT; Liu et al. 2007). The magnetic mineralogy was investigated on representative samples by (1) measuring the temperature dependence of magnetic susceptibility using Geo-Mar Lett Fig. 1 Study area and location map showing the position of core SK 200/22a relative to those of important oceanographic fronts and the winter sea ice limit in the Indian Ocean sector of the Southern Ocean (based on Park et al. 1993; Labeyrie et al. 1996; Anilkumar et al. 2007). PF Polar Front, SAF Sub-Antarctic Front, STF Subtropical Front an AGICO KLY-4S Kappabridge with an attached CS3 furnace in an argon atmosphere, and (2) stepwise thermal demagnetization of SIRM using a MMTD80 furnace (Magnetic Measurements Ltd.) between 100 and 700°C in steps of 25 and 50°C. Detailed sedimentological and microscopic studies were carried out on the coarse fraction to determine the origin and transport modes of the detrital flux. For this purpose, the coarse fraction (grain size >125 μm) in every 2 cm interval sample was studied under a binocular microscope, and 300– 400 terrigenous grains were counted to quantify the IRD fraction in the sediment (Baumann et al. 1995; Stoner et al. 1996; Nielsen et al. 2007). Inorganic carbon (IC) analyses were carried out using a TOC Analyser (Shimadzu TOC-V series SSM-5000A), and the CaCO3 content (weight%) was calculated with high precision (±5%) using the equation % CaCO3 0%IC×8.33. Oxygen isotope measurements were performed at selected depths on ~20 clean Neogloboquadrina pachyderma tests using an Isotope Ratio Mass Spectrometer (Isoprime, GV Instruments). The estimated Geo-Mar Lett external precision using a laboratory standard (Z-Carrara marble) was ±0.05‰. Chronological control was obtained by accelerator mass spectrometry (AMS) radiocarbon (14C) dating at selected intervals using the planktonic foraminifers Globigerina bulloides and/or Neogloboquadrina pachyderma. The age model is based on linear interpolation between the dated horizons. Because the radiocarbon ages at the depth intervals of 248–250 and 448–450 cm were close to or above the critical limit of 14C dating (≥40 ka BP), they were omitted in the chronological reconstruction. All radiocarbon ages were calibrated to calendar ages using the Calib 6 program of Stuiver et al. (2005), and all dates cited in the text thus refer to calendar years (Table 1, Fig. 2). The depth versus age relationships along with the estimated sedimentation rates are illustrated in Fig. 2. Age controls beyond the limits of the conventional radiocarbon dating technique were estimated by correlating the oxygen isotope data with the SPECMAP (Martinson et al. 1987) and LR04 δ18O stack (Lisiecki and Raymo 2005), and also with the age models derived from the geomagnetic correlation and foraminiferal assemblages at site MD94-103 from the midlatitudinal southern Indian Ocean to the east of the Kerguelen Plateau (Mazaud et al. 2002; Sicre et al. 2005), as well as the stacked δ18O record from the Drake Passage (Bae et al. 2003). As evident from Fig. 3, the 7.54 metres of the sediment core represent the past ~63,000 years, comprising the marine isotope stages 1 (MIS 1) to early MIS 4. Thus, the sedimentation rates of various intervals in the core vary from 4 to 16 cm/1,000 years, and are highest for sediments deposited during the last glacial maximum (LGM; Fig. 2). Results Bulk magnetic properties Magnetic concentration The Holocene (MIS 1) is characterized by low values of χ, χARM and SIRM (Fig. 4), whereas the glacial intervals (MIS Table 1 AMS 14C ages determined on planktonic foraminifer samples from core SK 200/22a, and calibrated ages after Stuiver et al. (2005) 2 and MIS 4) show relatively high χ, χARM and SIRM values. The last deglaciation (Termination I) indicates a rapid increase in χ, χARM and SIRM values, with the most substantial increase between 18.5 and 13 ka BP. The χARM values fluctuate between 9 and 24×10–8/kg during the early Holocene but are very high (up to 347×10–8/kg) during the early deglacial period (Fig. 4). The χARM and SIRM values show similar variations, but with extremely high values during the early deglacial period in MIS 2 and during the late MIS 4. To investigate the glacial–interglacial change in the concentration of magnetite, the magnetite accumulation rate (AR(mag)) was calculated using the age model. The AR(mag) record resembles the bulk χ record (Fig. 5), suggesting that the variations in magnetic concentration principally reflect changes in the flux of magnetite to the study area. Magnetic grain size The variations in the magnetic grain-size parameters traced by χfd%, χARM/χ, SIRM/χ and χARM/SIRM show similar trends (Fig. 4). The χfd%, which reflects the concentration of superparamagnetic grains in the sediment, fluctuates between 3 and 6%, and largely follows the trends of the χARM/ χ and SIRM/χ profiles. A uniform effective magnetic grain size is attested by the strong nonlinear relation between high and low values of χ with SIRM and ARM (Fig. 6a, b). Such strong relationships indicate that the systematic changes in χARM/χ and SIRM/χ with magnetite content are not due to the changes in the magnetic grain size. Magnetic mineralogy Throughout the core, the S-ratio remains high, ranging from 0.92 to 0.96 (Fig. 4). The hard IRM and soft IRM values vary in similar manner as the magnetic mineral concentration parameters such as χ, χARM and SIRM. The high Sratio and high soft IRM values suggest that the mineralogy is dominated by fine-grained low-coercivity magnetite and titano-magnetite. Liu et al. (2007) have demonstrated that the estimation of the L-ratio (IRMAF@300mT/IRMAF@100mT) helps to decipher the actual mineral contributing to the hard IRM records. In the present study, the L-ratio is seen to be Depth interval in core (cm) Lab code Radiocarbon age (years BP) Calibrated age (years BP) 8–10 76–78 128–130 144–146 180–182 X8398 B7710A X8399 X8400 B7711 2,635±36 8,822±46 10,943±70 13,881±68 17,186±88 2,764±16 9,929±151 12,885±98 17,124±200 20,636±295 248–250 448–450 B7712 B7714 35,090±630 45,400±2,300 40,051±953 49,279±2,953 Geo-Mar Lett Fig. 2 Age model for core SK200/22a. Radiocarbon control points are shown with error bars. The circle denotes the SPECMAP control point independent of the hard IRM, as revealed by the relatively constant values in Fig. 7. The lack of correlation between the L-ratio and hard IRM indicates that there is no significant change in the coercivity of antiferromagnetic minerals; in turn, this implies common sediment provenance. Therefore, the hard IRM record of the core is predominantly controlled by fluctuations in the concentration of hematite, whereas the contribution of goethite is insignificant. Thermal studies of representative samples of MIS 1 to MIS 4 display similar χ–T curves (Fig. 8a–d), χ decreasing gradually with increasing heating before dropping sharply at 580°C, which is typical for magnetite. Only in the Holocene sediment sample (Fig. 8a) does the trend line for heating initially increase slightly (up to 260°C) before reversing. The trend lines also show two minor changes in slope at ~300°C and above 580°C. The three changes in the slope of χ at ~300, 580 and ~675°C suggest the presence of titano-magnetite, magnetite and hematite respectively. On cooling, the curves are shown to be irreversible, the formation of magnetite now being indicated at temperatures less than 400°C and that of hematite at temperatures above 400°C. During SIRM thermal demagnetization (Fig. 8e), the sudden change in the IRM slope at 580°C reflects magnetite, whereas the presence of titano-magnetite and hematite is revealed by smaller changes in the IRM slope at ~300 and ~675°C respectively. events at 13–23 ka BP, as well as less prominent events at 25–30, 45–52 and 55–58 ka BP (Fig. 9). During MIS 2 the ice-rafting events are synchronous with the bulk magnetic record. The microscopic study of the IRD fractions in core SK200/22a revealed a dominance of tephra/ash material with additional quartz fragments. The tephra mostly comprise volcaniclastic materials consisting of sub-rounded to elongate vesicular black and brown fragments. The IRD record shows a good correlation with the high-coercivity hematite during the ice-rafting events (Fig. 10). Carbonate and δ18O records The carbonate content varies between 0.03 and 53.12%, with low values during the MIS 2 and late MIS 4, and high values during the MIS 1 and MIS 3 (Fig. 10). Carbonate content increases during the warming events, as represented by the δ18O record, and shows similar fluctuations with magnetic concentration during the MIS 2 and MIS 3. The δ18O record of N. pachyderma varies between 1.37 and 3.65‰, with heavier δ18O values during the glacial period (Fig. 10). Discussion and conclusions Ice-rafted debris Changes in bulk magnetic properties and their relation to terrigenous input during the late Quaternary Several IRD pulses were recorded in the sediment core SK200/22a. The IRD record revealed major ice-rafting The temporal variations in the values of χ, χARM and SIRM indicate that MIS 1 and MIS 3 are characterized by low Geo-Mar Lett Fig. 3 Comparison between the age records of core SK 200/22a, core MD94-103 from the Indian sector of the Southern Ocean (Mazaud et al. 2002; Sicre et al. 2005) and the LR04 δ18O stack (Lisiecki and Raymo 2005) magnetic concentrations, whereas higher concentrations are observed during the early deglacial period of MIS 2 and during the MIS 4 (Fig. 4). Although the hard IRM and soft IRM records show similar temporal variations (Fig. 4) throughout the core, hard IRM values are much lower, suggesting that low-coercivity minerals like magnetite dominate the magnetic record compared to the high-coercivity hematite. Therefore, the MIS 4, and certain intervals of MIS 3, is characterized by increased magnetic concentrations of coarser-grained magnetite and titano-magnetite, whereas the contribution by hematite is reduced. Such periods of increased concentration of magnetic minerals in the Southern Ocean have been attributed to enhanced terrigenous input and ice-rafting episodes (Diekmann 2007). Therefore, the downcore profiles of bulk magnetic parameters at the core site suggest that the total terrigenous influx to the Indian Ocean sector of the Southern Ocean increased substantially during the late MIS 2, MIS 4, and the early intervals of MIS 3. Fine-grained magnetic minerals dominate during MIS 1 and early MIS 3, suggesting a reduced erosion capacity of the currents or increased supply of fine-grained magnetic minerals. Lower values of magnetic grain-size parameters within MIS 2, MIS 4, and certain intervals of MIS 3 may also be indicative of selective dissolution of fine-grained ferromagnetic components during early diagenesis (Karlin 1990; Rolph et al. 2004). The nonlinear positive Geo-Mar Lett Fig. 4 Trends of the environmentally significant environmental magnetic parameters which represent magnetic concentration, grain size and mineralogy in core SK200/22a. The isotope stages are shaded relationships of χ with SIRM and ARM (Fig. 6a, b) suggest that the magnetic parameters principally depict the variations in concentration of magnetic minerals, and only to a very limited extent the changes in magnetic mineralogy and grain size during the past ~63,000 years. A comparison between the proxy records for magnetic concentration (χ, χARM and SIRM) and magnetic grain size (χfd%, χARM/χ, SIRM/χ and χARM/SIRM) suggests that increased magnetic mineral concentrations are associated with the coarsening of the magnetic grain size and vice versa. Mazaud et al. (2007) have proposed that changes of the magnetic grain size, with smaller grain sizes at the time of minimal deposition, are due to modulations in the ACC-CDW current which erodes and transports the magnetic grains in this region. The sediment grain-size distribution of the core supports this contention: the silt fraction, which is the major component, shows increased percentages of up to 90% during the MIS 2, MIS 4, and certain intervals of MIS 3, suggesting strong bottom current activity in these periods. Relationships between terrigenous input, ice rafting and carbonate productivity A comparison of the magnetic record with the N. pachyderma δ18O, IRD and carbonate records reveals that terrigenous influx, ice rafting, sea-surface temperature (and/or Geo-Mar Lett Fig. 5 Magnetite accumulation rate (AR(mag)) and magnetic susceptibility (χ) versus age in core SK 200/22a salinity) and carbonate productivity at the core site are apparently interrelated. Within the chronological uncertainties, the major ice-rafting events recorded in the present core are nearly synchronous with those of other studies from the Southern Ocean (Labeyrie et al. 1986; Grobe and Mackensen 1992; Kanfoush et al. 2000; Carter et al. 2002). Whereas major ice-rafting events are clearly reflected in the magnetic concentration record (tracing the terrigenous influx to the core site), some events are not synchronous with it, few of these not even showing up in the IRD record (Fig. 10). Such out-of-phase relations between terrigenous flux and IRD is not surprising because IRD represents only one component of the terrigenous influx, the total terrigenous input to the Southern Ocean being controlled by several oceanographic and climatic factors. Low-coercivity minerals like magnetite are the dominant component of the magnetic record representing the total terrigenous input to the study site. Other studies have reported that such magnetic minerals are generally not associated with coarse-grained IRD materials (Bareille et al. 1994; Mazaud et al. 2007). Such an interpretation is consistent with the grain size of the core, the IRD fraction being a minor (<15%) and the silt fraction a dominant (up to 95%) component of the sediment (Fig. 9). However, records of high-coercivity hematite (represented by hard IRM) show better correlation with the IRD profile (Fig. 10), suggesting that the coarse-grained hematite minerals are more associated with ice rafting. During the largest ice-rafting event of the last deglaciation, the IRD and the magnetic mineral concentration (both magnetite and hematite) are positively correlated (p<0.001), suggesting that the sea-surface warming (and related ice rafting) and the current strength simultaneously increased significantly. It is therefore proposed that the early deglacial warming and associated strengthening of the ACC-CDW in the Southern Ocean (Dezileau et al. 2000; Mazaud et al. 2007) had a strong influence on the terrigenous input to the Indian sector of the Southern Ocean. Comparisons between magnetic records and IRD data also support the contention that ice rafting explains only a minor part of the terrigenous influx, and that a significant portion appears to have been derived either from enhanced aeolian activity or from wind enhancement of the ACC. In this context, aeolian input to the Indian Ocean sector of the Southern Ocean has been reported to be subordinate to material supplied by wind forcing of the ACC (Diekmann 2007). However, Pugh et al. (2009) revealed that periods of increased magnetic susceptibility of sediments from the circum-ACC belt in the Southern Ocean are well correlated with the dust records from Antarctic ice cores. The comparison between magnetic proxy data of the present core and dust concentration at ODP site 1090, which is located in the Atlantic sector of the sub-Antarctic zone (Martínez-Garcia Geo-Mar Lett a Fig. 7 Correlation between the L-ratio and hard IRM of core SK200/22a b Fig. 6 Correlations of a anhysteretic remanent magnetization (ARM) versus magnetic susceptibility (χ) and b saturation isothermal remanent magnetization (SIRM) versus magnetic susceptibility (χ) of core SK200/22a et al. 2011), suggests that, with the exception of MIS 4 and early MIS 3, the terrigenous record from the present site was not influenced by direct dust input (Fig. 9). The most significant dust source to Antarctica and the Southern Ocean is the Patagonian desert (Gaiero et al. 2007; Sugden et al. 2009; Wolff et al. 2010). The results of the present study are consistent with earlier reports suggesting that aeolian dust was not a major contributor to the enhanced terrigenous supply to the southern Indian Ocean in the past (Bareille et al. 1994; Mazaud et al. 2010). Wind-driven current erosion in shallow waters around volcanic islands and ridges during periods of strengthened ACC could be an important additional mechanism for the enhanced terrigenous input to the core site. It should, however, not be discounted that during MIS 4 and early MIS 3 Patagonian dust may have been increasingly mobilized by enhanced Westerlies (Gaiero et al. 2004, 2007) and deposited in the study region. The variations in the magnetic grain size, with coarser material at the time of maximum concentration during MIS 2 and MIS 4, and finer material at the time of minimal concentration during MIS 1 and MIS 3, also suggest a modulation of the terrigenous input in the study region by the intensity of the ACC-CDW current. In fact, Mazaud et al. (2007, 2010) proposed that erosion processes associated with sea-level fluctuations had significantly contributed to changes in terrigenous input to the southern Indian Ocean. During glacial periods (MISs 2 and 4), the velocity of the ACC seems to have increased (Carter et al. 2000; Neil et al. 2004; Mazaud et al. 2010), which may have led to the winnowing of finer magnetic grain sizes. During the last deglaciation the ACC-CDW flow stabilized and was accompanied by an increased sorting of the sediment (Howe and Pudsey 1999). Such a process could have increased the supply of terrigenous material to the study site. The low and uniform values in magnetic concentration parameters during MIS 1 indeed reveal a reduced terrigenous input during the postglacial period. In the Southern Ocean, especially north of the Polar Front, temporal variations in carbonate contents as well as accumulation rates were shown to have increased during interglacials compared to glacial stages (Howard and Prell 1994; Bareille et al. 1998; Chase et al. 2003). The comparison between δ18O and carbonate records reveals that throughout the last ~63,000 years the calcite record fluctuated in tandem with the sea-surface temperature and/or salinity (Fig. 10). Studies from the SAF region of the Indian sector of the Southern Ocean report that the carbonate records are essentially indicative of calcite productivity and terrigenous dilution (Marsh et al. 2007). In general, an inverse relationship between magnetic concentration and Geo-Mar Lett Fig. 8 Magnetic mineralogy of dated samples from SK200/22a, showing the relationships between susceptibility and temperature during heating (solid lines) and cooling (dotted lines) in panels a–d, and the relationship between the thermal demagnetization of saturation isothermal remanent magnetization (SIRM) and temperature in panel e carbonate content during MIS 1 and MIS 4 indicates a possible dilution of terrigenous material by carbonates during these intervals. The carbonate content and magnetic mineral concentration records show similar fluctuations during MIS 2 and MIS 3 (Fig. 10). Although the amplitude of the variability between the carbonate and magnetic record is different during the early deglaciation within MIS 2, the timing of the increase in carbonate content matches well with the magnetic and IRD records. The synchronicity between the carbonate and magnetite records during MIS 2 and MIS 3 suggests that a common factor influenced both the magnetic and the carbonate profile during these time intervals. This factor seems to be the millennial climate oscillation which evidently controlled the input of finegrained terrigenous material and calcite productivity at the core site over the past ~63,000 years. In contrast, the carbonate content and IRD records during MIS 2 and MIS 3 do not show any significant relationships. Geo-Mar Lett Fig. 9 Relationships of N. pachyderma δ18O, saturation isothermal remanent magnetization (SIRM), ice-rafted debris (IRD) and silt records of SK200/22a with dust accumulation rate at ODP site 1090 (Martínez-Garcia et al. 2011) The major ice-rafting events at the core site are characterized by significantly lower carbonate content, indicating decreased calcite productivity, carbonate dilution by enhanced terrigenous sediments and/or enhanced carbonate Geo-Mar Lett Fig. 10 Correlations between the SK200/22a records (δ18O, SIRM, hard IRM, IRD and carbonate content) and the Antarctic (Byrd and EDML) as well as Greenland (NGRIP) δ18O ice core records. Climatic events like the Antarctic Cold Reversal (ACR), Antarctic Isotope Maximum (AIM), Antarctic warming events (A1–A4) as well as Heinrich events (HEs) are also indicated. Major events in terms of δ18O, magnetic concentration, IRD, and carbonate content of SK 200/22a are shaded dissolution during these intervals. The reduced carbonate contents during IRD events seem to be the result of enhanced dilution by terrigenous material, as the relation between ice rafting and biological productivity in the Southern Ocean seems to be equivocal, with many IRD events asynchronous with increased foraminiferal abundances (Kanfoush et al. 2002). Periods of increased IRD accumulation may indicate the equatorward migration of the Polar and Sub-Antarctic fronts (Cook and Hays 1982; Howard and Prell 1994; Bareille et al. 1994). Equatorward shifting of the frontal regimes, and its influence on ice rafting in the Southern Ocean during glacial periods, has previously been reported by Howard and Prell (1994), Bareille et al. (1994) and Kanfoush et al. (2002). While sea ice could be a dominant delivery mechanism of tephra/ash to the study region from volcanic islands, quartz grains could have been transported by icebergs (Bareille et al. 1998; Thamban et al. 2005). A stronger ACC due to stronger glacial winds would thus have transported increased amounts of sedimentary material to the region. A strengthening of the wind-driven Geo-Mar Lett system would also have enhanced the eddy system in this part of the Southern Ocean, leading to increased erosion and transport of terrigenous material to the core site. Timing of depositional events and Antarctic climate linkages The correlation between Southern Ocean sedimentary records and ice records from Greenland and Antarctica have been used to interpret millennial-scale climate changes as well as climatic synchronicity or asynchronicity (Mazaud et al. 2002, 2007; Lamy et al. 2004; Sachs and Anderson 2005; Barrows et al. 2007). Records from the SE Pacific show a clear ‘Antarctic timing’ of the last glacial and deglacial events (Lamy et al. 2004, 2007), whereas the records from other parts of the Southern Ocean are equivocal (Andres et al. 2003). The oxygen isotope record and the carbonate content of core SK 200/22a show similar fluctuations throughout the past ~63,000 years. To understand the timing of the events with respect to global climate records, the SK 200/22a records are compared here with Antarctic (Byrd and EPICA Dronning Maud Land) and Greenland (North GRIP) ice core records (Fig. 10; Blunier and Brook 2001; EPICA Community Members 2006). Within the chronological uncertainties, the δ18O and carbonate records have revealed the presence of the Antarctic Cold Reversal at 12.4–14.1 ka BP, the early deglacial warming event (Termination I) as well as the major interstadials depicted in Antarctic ice core records. Major warming events in these records are well correlated with the Byrd ice core δ18O record for warm events A2–A4 but not for A1. However, the records of the present study are not in phase with the Greenland ice core records (Fig. 10), and it is therefore suggested that the climatic evolution and calcite production at the core site essentially followed the Antarctic climatic events. Compared to the oceanic proxy data (δ18O, carbonate content), the terrigenous proxy data (magnetic records, IRD) revealed certain differences during MIS 4 and MIS 3. The magnetic parameters (dominantly represented by fine sand and silt particles) fluctuate in similar manner, suggesting a remarkably increased terrigenous input during the early deglaciation (13–19 ka BP), and less prominent but nevertheless significant pulses at 21–23, 26–30, 33–35, 45– 48.5, 54–56 and 59–62 ka BP. Within the chronological uncertainties, many of these events can be considered as being synchronous with the Antarctic ice core records. In general, increased terrigenous input to the core site occurred during southern hemispheric warming events. Recent studies have identified that north–south linkages were widespread during the late Quaternary through a bipolar seesaw mechanism (Blunier and Brook 2001; Lamy et al. 2007). The bipolar seesaw is manifested by an out-of-phase millennial-scale climatic pattern of atmospheric and oceanic changes which are systematically linked to rapid meridional displacements of sea ice, westerly winds and the ACC system (Stocker and Johnsen 2003; Lamy et al. 2007; Mazaud et al. 2007). However, it is not possible to confirm the hemispheric synchronicity/asynchronicity in the present case because the prominent terrigenous event at 54–56 ka BP was out of phase with the Antarctic warming event A4 (Fig. 10). Moreover, there are no significant ice-rafting events after the Antarctic warming events A1 and A2, which indicates that ice-rafting events are predominantly influenced by the ice-sheet dynamics. Studies from the South Atlantic region showed that, unlike the northern hemisphere, the southern hemispheric IRD records for the last glacial period were controlled by changes in sea-surface temperature and sea ice conditions, rather than Antarctic ice-sheet dynamics (Carter et al. 2002; Nielsen et al. 2007). However, the findings of the present study suggest that most of the IRD pulses occurred when the sea-surface temperatures were possibly colder (more positive δ18O values), some of the ice-rafting events even preceding the warming events (Fig. 10). Only the last deglacial ice-rafting event (13–19 ka BP) correlates with the early warming after the LGM. The present study thus suggests that the ice-sheet dynamics and the intensity of the ACC dominantly controlled IRD deposition in the Indian sector of the Southern Ocean and that the sea-surface temperature had only a secondary influence. 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