OFFICIAL (NO MAKINGS REQUIRED) National Waste Programme LLW Problematic Waste Technology Optioneering Summary Report NWP/REP/130 – Issue 1 – August 2016 A company owned by UK Nuclear Waste Management Ltd Old Shore Road, Drigg, Holmrook, Cumbria, United Kingdom CA19 1XH Company Registration No. 05608448 OFFICIAL (NO MARKINGS REQIRED) OFFICIAL (NO MARKINGS REQUIRED) NWP/REP/130 Issue 1 – Aug 2016 Page 2 of 33 Name Role Originator: Rebecca Cummings National Programme Coordinator Checker: Helen Cassidy National Programme Implementation Manager Approver: Hannah Kozich Head of National Programme Document history Issue Date Amendments 1 August 2015 First Issue OFFICIAL (NO MARKING REQUIRED) OFFICIAL (NO MARKINGS REQUIRED NWP/REP/130 Issue 1 – Aug 2016 Page 3 of 33 LLW Repository Ltd National Waste Programme Glossary ALARP: as low as reasonably practicable BAT: best available technique HAW: High Activity Waste LAW: Low Activity Waste ILW: Intermediate Level Waste LLW: Low Level Waste LLWR: Low Level Waste Repository NWP: National Waste Programme PCB: polychlorinated biphenyl Problematic waste: a waste which has no disposal or management route currently available, where disposal means final disposal, as opposed to interim disposal or storage. R&D: research and development TEPCO: Tokyo Electric Power Company Holdings Ltd. THOR: thermal oxidation-reduction TRL: Technology Readiness Level WAC: Waste Acceptance Criteria OFFICIAL (NO MARKING REQUIRED) OFFICIAL (NO MARKINGS REQUIRED NWP/REP/130 Issue 1 – Aug 2016 Page 4 of 33 LLW Repository Ltd National Waste Programme Executive summary This report is a summary of a January 2015 optioneering report on problematic low level waste, which was commissioned by the National Waste Programme (NWP) and produced by Hyder Consulting (UK) Ltd. The summary has been produced for publication in the public domain. LLW Repository Ltd, with the assistance of the waste producers, has compiled a problematic waste inventory of low level waste (LLW). This report is based on waste producers’ knowledge of the waste items and available disposal options at the time of the data gathering exercise (financial year 2014/15). The primary focus of the study was to align waste streams with technological solutions for their treatment and to identify technology gaps that prevent application of the techniques. Of the 177 problematic LLW waste streams initially identified in the January 2015 report, 100 were identified as Priority Waste Streams, being of highest importance to the waste producers. The top four waste streams identified through the prioritisation exercise in 2014/15 were: Contaminated oil and oil contaminated materials Inorganic and organic ion exchange resins Radium Surface contaminated items These waste streams were not chosen just because of their importance to waste producers (e.g. there is a large volume of them or they are highly problematic) but also because the optioneering available to these waste streams also covers the majority of technologies relevant across all the waste streams. The study identified: Optimum technologies for managing all the key waste streams based on an assessment of attributes relevant to the development, implementation and application of the technologies. Technology gaps and recommendations on progressing and implementing the technologies in order to facilitate earlier management of the waste and its removal from the orphan waste inventory. That better characterisation is needed for a significant number of the waste streams. With improved characterisation, a proportion may be able to be managed through existing waste routes and removed from the Inventory. That wastes from different producers could be collated and processed together; either when waste technologies are applicable to several waste types or where wastes of similar OFFICIAL (NO MARKING REQUIRED) OFFICIAL (NO MARKINGS REQUIRED NWP/REP/130 Issue 1 – Aug 2016 Page 5 of 33 LLW Repository Ltd National Waste Programme characteristics are present at different facilities, which has the potential to open new routes higher up the waste hierarchy. “Technology maps” were produced for the waste groups identified to illustrate the technologies available for the management of these wastes and the gaps to deployment of those technologies, for example the identification of further R&D required. This report is intended to provide an oversight of the technologies available for managing items in the problematic waste inventory, specifically the four most problematic waste streams, and to highlight how viable these technologies would be. This summary report provides a concise overview of the technology mapping work undertaken in FY 2014/15 It should be noted that the summary does not look at the volume or the schedule of arisings of particular problematic waste streams, and therefore it is not intended to drive investment decisions. OFFICIAL (NO MARKING REQUIRED) OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 6 of 33 LLW Repository Ltd National Waste Programme Contents Glossary .......................................................................................................................... 3 Executive summary ........................................................................................................ 4 1. 2. Problematic waste inventory ................................................................................ 7 1.1. What is problematic waste? ................................................................. 7 1.2. Waste groups ......................................................................................... 7 Waste management technologies ........................................................................ 9 2.1. 3. Waste technology matrix .................................................................... 10 Waste stream options .......................................................................................... 15 3.1. Methodology ........................................................................................ 15 3.2. Results ................................................................................................. 15 3.3. Key waste streams- conclusions ....................................................... 18 3.3.1. Contaminated oils and materials contaminated with oils ................................ 18 3.3.2. Inorganic and organic ion exchange resins .................................................... 18 3.3.3. Radium .......................................................................................................... 19 3.3.4. Surface contaminated wastes ........................................................................ 19 4. Closing technology gaps .................................................................................... 20 5. Additional actions to be undertaken .................................................................. 20 6. Recommendations ............................................................................................... 20 Appendix 1 – Wiring diagrams for key waste streams .............................................. 21 OFFICIAL (NO MARKING REQUIRED) OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 7 of 33 LLW Repository Ltd National Waste Programme 1. Problematic waste inventory 1.1. What is problematic waste? The study defines a problematic waste as: ‘a waste which has no disposal or management route currently available, where disposal means final disposal, as opposed to interim disposal or storage.’ Problematic wastes may be: • Current or future arisings • Inadequately characterised waste • Problematic in terms of its chemical characteristics such as mercury wastes • Items failing the discrete item limit specified in the Low Level Waste Repository (LLWR) waste acceptance criteria (WAC) • Either raw, fully, or partially conditioned wastes where the conditioning is incompatible with treatment or disposal • Mixed - and potentially inseparable - wastes • Difficult to access waste • Boundary waste (low activity waste (LAW) and high activity waste (HAW)) • Bespoke or unique wastes arising from a single site • Difficult or impossible to transport (e.g. there may be no approved containers for transport) • Unable to be managed or disposed of due to a lack of a treatment plan at the site of origin. 1.2. Waste groups In 2014/15 a waste inventory prioritisation exercise was conducted for LAW, based on the 2014/15 problematic waste inventory. This exercise involved representatives from those organisations who had declared wastes in the inventory. OFFICIAL (NO MARKING REQUIRED) OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 8 of 33 LLW Repository Ltd National Waste Programme Waste producers were asked to identify problematic waste streams that were either high volume or of particular relevance to their organisations’ strategy for waste minimisation and programmes for decommissioning or operations. The highest priority waste streams were agreed by all stakeholders, these are: 1. 2. 3. 4. 5. 6. Waste failing the discrete item limit (within the LLWR WAC) Contaminated oil and oil contaminated material. Inorganic and organic ion exchange resins Radium Surface contaminated items Asbestos Four of these priority waste streams were considered in detail by the technology mapping process: Contaminated oil and oil contaminated material. Inorganic and organic ion exchange resins Radium Surface contaminated items It was recognised that waste failing the discrete item limit was a broad waste group (covering wastes with diverse physical, chemical, and radiological characteristics) and that an improved data set was required to enable effective and technically robust technology mapping A project to support optioneering for management of radiologically contaminated asbestos was run in parallel during 2015; for purposes of clarity technology mapping for asbestos has not been included in this study. OFFICIAL (NO MARKING REQUIRED) OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 9 of 33 LLW Repository Ltd National Waste Programme 2. Waste management technologies The study identified and considered a significant number of technologies that are employed in the nuclear industry and in non-nuclear waste producing industries for the priority problematic waste groups. Technologies applicable to the retrieval, treatment, processing and eventual disposal of the wastes were assessed and the main opportunities, requirements, and risks required to progress the techniques are described later in this report. The waste technologies reviewed were extensively detailed in the original report and given a ‘Technology Readiness Level’ (TRL) rating based on the contemporary TRL scale: TRL 1 Basic principles observed and reported. TRL 2 Technology concept and/or application formulated. TRL 3 Analytical and experimental critical function and/or characteristic proofof-concept. TRL 4 Technology basic validation in a laboratory environment. TRL 5 Technology basic validation in a relevant environment. TRL 6 Technology model environment. TRL 7 Technology prototype demonstration in an operational environment. TRL 8 Actual Technology completed and qualified through test and demonstration. TRL 9 Actual Technology qualified through successful mission operations (and fully commissioned deployment at a nuclear facility). or prototype demonstration in a relevant Table 1: Technology readiness levels at 2014/15 The assigned TRLs relate to the technology itself and not their specific application to the individual problematic waste streams; even if a technology is listed as a higher TRL, there may still be R&D requirements and barriers preventing direct application to specific wastes. Some of the technologies that have been considered for the problematic LLW streams are commercially available for HAW (e.g., the Alkaline Hydrolysis Plant at Sellafield for oil). There are potential implications in sending LLW to HAW facilities, such as the possibility of producing ILW secondary waste from processing LLW, which needs further consideration. OFFICIAL (NO MARKING REQUIRED) OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 10 of 33 LLW Repository Ltd National Waste Programme 2.1. Waste technology matrix For the study, an optioneering exercise was completed scoring the relevant technologies against each problematic waste stream reported in the 2014/15 problematic waste inventory and scoring them against six weighted attributes: the TRL, completeness (whether any additional pre or posttreatment is needed), alignment with the waste hierarchy, BAT & environmental factors, nuclear safety & ALARP, and implementation costs. The optioneering scoring output is not included within the report but the waste technology matrix in table 2 overleaf presents a summary of the findings; it maps the problematic wastes identified by waste producers to the technologies options identified to the priority waste groups. A red, amber & green coding has been applied, to visually present the technologies that are deemed more appropriate; green being most relevant, red being least relevant but feasible. Unscored (white) options are deemed not to be relevant or suitable for management of that specific waste group. OFFICIAL (NO MARKING REQUIRED) CHEMICAL TECHNOLOGIES SDG3 Rustoleum Sprayable coating Floor coating Rust remover Nitric acid Sulphuric acid LLW Repository Ltd Granite Block Pumps/Valves Na/K Vessels contaminated with explosives Whessoe tank bases Surface contaminated tanks Encapsulated liquor Ra contaminated waste Calcium fluoride Pyrochemical Slag Clinoptilolite Resin beads Chromatography resins Misc. resin Zeolite resin U Active Resin Dovex resin Resin immersed in water Encapsulated resins Filter residues PWTP fine filters Fine filters Metal gauge filters Cd lined polythene box Cd sheeting Metals Mild steel Sea disposal packages Cemented water treatment sludge Oil soaked waste Hazardous oils/chemicals Oil/water/glycol mix Oil, absorbent, grease and oily water Oily water Oily sludge Paraffin Oil Waste Group OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 11 of 33 National Waste Programme Table 2:Waste technology matrix Acid digestion Acid washing Alcohol washing Alkaline hydrolysis Amalgamation with Zn or Cu Arvia Calcination & sintering Carbonation Caustic process Modulox Chemical decontamination sol. Chemisorbing surface wipes Detergent solutions Dissolution Distillation Electro-chemical treatment OFFICIAL (NO MARKING REQUIRED) HIGH TEMP TECHNOLOGIES CHEMICAL SDG3 Rustoleum Sprayable coating Floor coating Rust remover Nitric acid Sulphuric acid LLW Repository Ltd Granite Block Pumps/Valves Na/K Vessels contaminated with explosives Whessoe tank bases Surface contaminated tanks Encapsulated liquor Ra contaminated waste Calcium fluoride Pyrochemical Slag Clinoptilolite Resin beads Chromatography resins Misc. resin Zeolite resin U Active Resin Dovex resin Resin immersed in water Encapsulated resins Filter residues PWTP fine filters Fine filters Metal gauge filters Cd lined polythene box Cd sheeting Metals Mild steel Sea disposal packages Cemented water treatment sludge Oil soaked waste Hazardous oils/chemicals Oil/water/glycol mix Oil, absorbent, grease and oily water Oily water Oily sludge Paraffin Oil Waste Group OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 12 of 33 National Waste Programme Filtration Metal hydrides Oxidation Pinhole filtration Salt extraction Samms Solidification Solvent extraction process Stabilisation using sulphur Supercritical water oxidation Thermochemical treatment Water vapour –nitrogen Wet oxidation Incineration Melting Molten salt oxidation Plasma treatment Pyrolysis OFFICIAL (NO MARKING REQUIRED) PHYSICAL IMMOBILSATION TECHNOLOGIES SDG3 Rustoleum Sprayable coating Floor coating Rust remover Nitric acid Sulphuric acid LLW Repository Ltd Granite Block Pumps/Valves Na/K Vessels contaminated with explosives Whessoe tank bases Surface contaminated tanks Encapsulated liquor Ra contaminated waste Calcium fluoride Pyrochemical Slag Clinoptilolite Resin beads Chromatography resins Misc. resin Zeolite resin U Active Resin Dovex resin Resin immersed in water Encapsulated resins Filter residues PWTP fine filters Fine filters Metal gauge filters Cd lined polythene box Cd sheeting Metals Mild steel Sea disposal packages Cemented water treatment sludge Oil soaked waste Hazardous oils/chemicals Oil/water/glycol mix Oil, absorbent, grease and oily water Oily water Oily sludge Paraffin Oil Waste Group OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 13 of 33 National Waste Programme Spray burning Steam reforming Vitrification Cementation Compaction in clay Drying agents Geopolymerisation Macroencapsulation Microencapsulation Nochar polymers Organic polymers Blasting Compaction / supercompaction Drying Electrothermal cutting Freezing Hot isostatic pressing Laser ablation OFFICIAL (NO MARKING REQUIRED) OTHER TECHNOLOGIES SDG3 Rustoleum Sprayable coating Floor coating Rust remover Nitric acid Sulphuric acid LLW Repository Ltd Granite Block Pumps/Valves Na/K Vessels contaminated with explosives Whessoe tank bases Surface contaminated tanks Encapsulated liquor Ra contaminated waste Calcium fluoride Pyrochemical Slag Clinoptilolite Resin beads Chromatography resins Misc. resin Zeolite resin U Active Resin Dovex resin Resin immersed in water Encapsulated resins Filter residues PWTP fine filters Fine filters Metal gauge filters Cd lined polythene box Cd sheeting Metals Mild steel Sea disposal packages Cemented water treatment sludge Oil soaked waste Hazardous oils/chemicals Oil/water/glycol mix Oil, absorbent, grease and oily water Oily water Oily sludge Paraffin Oil Waste Group OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 14 of 33 National Waste Programme Mechanical cutting Mechanical separation Reactive strippable coating Seal in polyethylene container Segregation Shredding Freon cleaning Limit of Content Microwave treatment Owl process Dew drops Plasma vitrification OFFICIAL (NO MARKING REQUIRED) OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 15 of 33 LLW Repository Ltd National Waste Programme 3. Waste stream options 3.1. Methodology The output of the waste management optioneering exercise undertaken for the waste reams in the 2014/15 problematic waste inventory was analysed to identify the relevant treatment technologies for each waste group. The commercial availability and readiness of each technology was then assessed to identify the key gaps and actions needed for technology implementation. This analysis was expanded for the four priority waste streams and was converted into a series of technology wiring diagrams for each waste route summarising opportunists, requirements and risks to technology deployment. 3.2. Results The table overleaf summarises the Technology Assessment Output for the waste streams. Table 3 provides a summary of the relevant treatment technologies. Key gaps/opportunities/actions o realise technology implementation and where relevant (i.e. for the four priority waste streams) reference to the relevant technology wiring diagrams options for the priority waste groups presented in section 3.3. OFFICIAL (NO MARKING REQUIRED) OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 16 of 33 LLW Repository Ltd National Waste Programme Table 3: Technology Assessment Output Group Relevant Treatment Technology* Action (a) Contaminated oil and oil contaminated material (one of the 4 key waste streams) i. Further characterisation of all waste streams, to identify and consolidate See Appendix 1 problematic status. ii. Additional characterisation necessary before technologies aligned with specific waste streams iii. How much of the oil waste is limited by alpha content – this needs to be determined and is not clear from the inventory details iv. Individual waste streams may require pre, post-treatment. This is to be determined at a later stage, once characterisation is progressed and improved. v. Energy from waste options should be considered further. vi. Additional information needed to determine PCB content as this would limit some options Check LLWR disposal route and options for disposal N/A (b) Historically conditioned waste (c) Mild steel limit of content acid washing chemical decontamination solutions blasting i. Further characterisation and planning required to identify and consolidate N/A problematic status and to identify disposal option or treatment, if necessary. ii. Chemical decontamination or physical decontamination options most appropriate acid washing chemical decontamination solutions blasting i. Further characterisation required to identify and consolidate problematic status N/A and identify disposal option or treatment, if necessary. ii. Chemical decontamination or physical decontamination options most appropriate acid washing chemical decontamination solutions blasting Further characterisation required to identify and consolidate problematic status and N/A identify disposal option or treatment, if necessary. super compaction acid washing chemical decontamination solutions cementation organic polymers incineration pyrolysis compaction/super compaction incineration pyrolysis steam reforming Further characterisation and planning required to identify and consolidate N/A problematic status and to identify disposal option or treatment, if necessary. (d) Metals (e) Cadmium sheeting (f) Metal gauge filters (g) Fine filters (h) Filter residues (i) Organic and inorganic ion exchange resins (one of the 4 key waste streams) incineration pyrolysis electrochemical treatment (Arvia) steam reforming (THOR) acid washing (e.g. OWL process) Wiring Diagram ID Variation approval may be sought from LLW Repository Ltd. N/A Further characterisation and planning required to identify and consolidate N/A problematic status and to identify disposal option or treatment, if necessary. i. THOR Process (steam reforming) was designed for resins. See Appendix 1 ii. Potential volume reduction techniques may be applied (being investigated at EDF), although LLW to ILW consideration required. iii. There may be a relaxation of LLW Repository Ltd requirements on accepting complexants. This needs further consideration on a waste stream specific level. OFFICIAL (NO MARKING REQUIRED) OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 17 of 33 LLW Repository Ltd National Waste Programme Group Relevant Treatment Technology* Action Wiring Diagram ID (j) Pyrochemical slag hot isostatic pressing cementation N/A (k) Radium contaminated waste cementation limit of content limit of content cementation acid washing chemical decontamination solutions blasting i. Further information needed on the nature of the contamination – consider surface decontamination techniques against the contaminant nuclides then landfill. ii. Further information needed on the nature of the contamination – consider surface decontamination techniques against the contaminant nuclides then landfill. i. Investigate option of using LLW facility at Dounreay. ii. Further characterisation to determine whether the waste is ILW or LLW. Full compliance with the UK LLW Management Strategy (Ref.6) is relevant to this issue and requires further consideration. This could be a political issue rather than a waste one. iii. If it is ILW, regulatory involvement would be necessary so waste can be treated via an appropriate ILW route. Further characterisation and planning required to identify and consolidate problematic status and to identify disposal option or treatment, if necessary. Further characterisation and planning required to identify and consolidate problematic status and to identify disposal option or treatment, if necessary. (one of the 4 key waste streams) (l) Encapsulate liquor (m) Surface contaminated waste (one of the 4 key waste streams) (n) Whessoe tank bases (o) Vessel contaminated with explosives (p) Sodium/Potassium (q) Pumps / valves (r) Granite block (s) Other Sellafield waste segregation blasting chemical decontamination solutions segregation chemical decontamination solutions pyrolysis vitrification cementation chemical decontamination solutions detergent solutions chemical decontamination solutions detergent solutions blasting cementation See Appendix 1 N/A See Appendix 1 i. Further characterisation and planning required to identify the extent of N/A contamination and LLW status before disposal option or treatment decision made. ii. Further test of application of blasting, given historic issues encountered at Studsvik when blasting tank vessels Further characterisation and planning required identifying and consolidating N/A problematic status and the extent of explosive contamination before considering disposal option or treatment, if necessary. Further characterisation and planning required to identify and consolidate N/A problematic status and to identify disposal option or treatment, if necessary. i. Further characterisation and planning required to identify and consolidate N/A problematic status and to identify disposal option or treatment, if necessary. ii. This may not be a problematic waste. Further identification of the waste forms and characterisation required to identify N/A and consolidate problematic status and to identify specific disposal options or treatments, if necessary. Further identification of the waste forms and characterisation required to identify N/A and consolidate problematic status and to identify specific disposal options or treatments, if necessary. OFFICIAL (NO MARKING REQUIRED) OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 18 of 33 LLW Repository Ltd National Waste Programme 3.3. Key waste streams- conclusions The outputs of the technology mapping and deployment gap analysis for the key waste streams are summarised below. 3.3.1. Contaminated oils and materials contaminated with oils The majority of the priority waste streams are identified as contaminated oil or oil contaminated material and a large proportion of this waste oil is not clearly characterised. Several oil treatment technologies are in operation and available to the UK nuclear industry and these should be further considered to establish potential disposal solutions. Emerging technologies have also been identified, and whilst of lower TRL, treatment solutions may exist in the near future through the development of these techniques with support from the NDA and supply chain and should therefore be further investigated. The key requirements to progress the problematic waste oil and removal from the problematic waste inventory relates to improved characterisation of the waste, in particular alpha, tritium and PCB content, relevant to acceptance criteria via known disposal routes. From having this information, final decisions can be made regarding treatment solutions. Based on existing knowledge of the waste oil treatment technologies, the waste streams were optioneered and the most appropriate treatment solutions for contaminated oil or oil contaminated material were identified as incineration, pyrolysis, electrochemical treatment, steam reforming, acid washing, Nochar polymers and the Dew Drops process. The steps in processing the oil waste via these routes are outlined in wiring diagrams in the appendix. Thermal treatment of oil, in particular incineration scored highest in the optioneering exercise. Barriers related to the application of incineration relate to alpha content and limits associated with existing disposal routes through the LLW Repository Ltd Waste Services Contract and potentially existing facilities at waste producer sites. Another consideration is ensuring that the residue generated can be disposed of. The oils can be incinerated but disposal of the ash is necessary, to ensure it is suitable for disposal at LLWR. 3.3.2. Inorganic and organic ion exchange resins A number of organic and inorganic resin wastes appeared in the problematic waste stream. There is limited information available for the resins and it is clear that further characterisation is necessary. The resin waste streams were optioneered and the most appropriate treatment solutions were identified as incineration, pyrolysis and steam reforming (e.g. Studsvik THOR process). The limiting factors are waste stream specific and waste treatment depends on further characterisation of the individual resin problematic waste streams. OFFICIAL (NO MARKING REQUIRED) OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 19 of 33 LLW Repository Ltd National Waste Programme Alternative solutions were discussed, including the application of cementation using the resins as a fixant although there are potential challenges as such conditioned wastes may fail the discrete item limit for disposal at LLWR. The potential to treat the waste as ILW was also discussed but it is uncertain whether this approach is applicable for the resins in the problematic waste stream. 3.3.3. Radium Cementation and the application of organic polymers were considered during the optioneering; however, the impact of Ra decay to Rn gas was raised as a concern due to its mobility and potential impact. Further understanding of waste form evolution and off gassing would be needed before application of these techniques. 3.3.4. Surface contaminated wastes The optioneering of surface contaminated wastes enabled a significant number of technologies to be assessed. These technologies are considered central to waste management solutions across the nuclear industry and the chance to consider them as part of the assessment exercise presented an excellent opportunity to capture these important techniques. The highest scoring treatment techniques were acid washing, chemical decontamination solutions and blasting. Reactive strippable coating also scored highly but as this technique could generate ILW it is not considered suitable in this instance. Acid washing is a well-established technique in relation to trials, the chemistry, and associated requirements. The technique is, however, waste stream dependent and considered costly, therefore it is more applicable for larger waste streams. Alternatives such as compaction or cutting would be more suitable for smaller volume waste streams, coupled with encapsulation and disposal. OFFICIAL (NO MARKING REQUIRED) OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 20 of 33 LLW Repository Ltd National Waste Programme 4. Closing technology gaps On the whole, the key technologies identified have a high TRL and it is not anticipated that significant research and development work would be needed to implement the processes. They would, however, require appropriate business case development and justifications. It is recommended that at least one of the relevant technologies is TRL 9 for each key waste stream. 5. Additional actions to be undertaken In addition to closing the technology gap for a single technology for each key waste stream, waste producers might consider: 6. Addressing the need for improved waste stream characterisation data Contacting relevant waste producers (e.g. Dounreay) to discuss the application of the wet oxidation technique for treatment of oil waste at their facility Regulatory acceptance checking in relation to the secondary bio-waste associated with the Dew Drops technique associated with oil waste processing Accessing further detail in relation to the microwave technique and its application at TEPCO in Japan. Recommendations Based on analysis of the problematic waste inventory, it is clear that a significant number of the waste streams could be removed from the problematic waste inventory through improved characterisation. This would lead to waste being assigned disposal via existing routes. A characterisation programme is therefore recommended for the problematic waste streams categorised as such because of limited characterisation data. It is noted that for all waste streams, that a central factor in identifying and applying a treatment solution relates to the business case, in particular cost benefit analysis. Our findings suggest that there are solutions available for the majority of the assessed problematic waste streams; the limiting factor relates to the low volume of waste within the inventory and the likely waste volume reduction achieved from the development and application of a particular technology. It is therefore recommended that consolidation of wastes from several sites is considered so consignments of larger volumes are sent for treatment and disposal, comprising like wastes and mixed wastes where appropriate. For the identified key technologies, which have been aligned with the problematic waste streams, it is recommended that additional work is undertaken to establish the latest developments with respect to the identified technology gaps and waste stream specific opportunities, requirements and risks identified. OFFICIAL (NO MARKING REQUIRED) OFFICIAL NWP/REP/130 Issue 1 – Aug 2016 Page 21 of 33 LLW Repository Ltd National Waste Programme Appendix 1 – Wiring diagrams for key waste streams For the key waste streams analysed, wiring diagrams were developed to present the findings for the most appropriate technologies as defined through the assessment. These wiring diagrams serve as further illustration of the details captured in table xx and are a useful tool to highlight key stages and requirements for processing the waste. Wiring diagrams have been generated for oils, encapsulated resin and surface contaminated items. These show the key stages in progression of the waste from storage to disposal and are contained within the appendix. The TRL related to individual waste stream-specific stages is given and wiring diagrams indicate the pathway of the associated radioactivity. This is represented by the red line running through each process. Opportunities, requirements and risks are identified and are dependent upon the technique and the waste stream under consideration. 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