Naming of Compounds according to the IUPAC rules ©copyright by James B. Condon (2013) all rights reserved. ©Some of the graphics are supplied by Corel Corporation with their permission. Use of these materials by others is encouraged provided these notices are not altered. Naming is broken down into 5 principal classes: 1) binary compounds: a metal with a non-metal a) with metals of Group 1, 2 and 3* b) other metals 2) ternary compounds of a metal and a polyatomic ion. a) with metals of Group 1, 2 and 3* b) other metals 3) binary hydrogen compounds a) as acids in water solution b) as a gas 4) ternary acids 5) nonmetal-nonmetal compounds 1) Naming of binary metal-nonmetal compounds: First name the metal and then the nonmetal (including H) with the ending “ide”. For metals other than groups 1, 2 and 3*, enter the oxidation number after the metal name: Examples for group 1, 2 and 3 metal: Na2O CaS YN ScH3 = sodium oxide = calcium sulfide = yttrium nitride = scandium hydride * The actual rule is that for combinations for which there is only one compound, the oxidation number 1) Naming of binary metal-nonmetal compounds: First name the metal and then the nonmetal (including H) with the ending “ide”. For metals other than groups 1, 2 and 3*, enter the oxidation number after the metal name: Examples metal other than group 1, 2 and 3: FeO Cu2S CuO NiO2 = iron II oxide = copper I sulfide = copper II oxide = nickel IV oxide * The actual rule is that for combinations for which there is only one compound, the oxidation number is not written. Naming of metal-polyatomic ion compounds: First name the metal with oxidation number (groups 1, 2 and 3 without) and then the polyatomic ion. Look at the polyatomic ion chart. At the top is the prefixes and suffixes for the columns and on the left is the root word to use. The prefixes and suffixes for these compounds (salts) are in the top row. Naming of metal-polyatomic ion compounds: ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Naming of metal-polyatomic ion compounds: ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Example: What is the name of the ClO 3– ion? 1) Read the root name from the row ClO3– is in. chlor 2) Read the ion prefix and suffix from the column label. (Prefix for this is blank.) Naming of metal-polyatomic ion compounds: ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Example: What is the name of the ClO 3– ion? 1) Read the root name from the row ClO3– is in. chlorate 2) Read the ion prefix and suffix from the column label. (Prefix for this is blank.) Naming of metal-polyatomic ion compounds: ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Example: What is the name of NaClO 3? Do step 1) and 2) chlorate Naming of metal-polyatomic ion compounds: ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Example: What is the name of NaClO 3? Do step 1) and 2) sodium chlorate and put the metal name with it. (Group I - no ON) Naming of metal-polyatomic ion compounds: ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Example: What is the name of FePO 2? phosph Naming of metal-polyatomic ion compounds: ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Example: What is the name of FePO 2? hypophosphite Naming of metal-polyatomic ion compounds: ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Example: What is the name of FePO 2? Iron III hypophosphite Why III? PO 23– is –3 so Fe must be +3 charge and therefore has an ON of +3. Naming of metal-polyatomic ion compounds: ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Example: What is the name of Sn(ClO 4)2? Note the parenthesis indicate that ClO4 is a unit, i.e. a polyatomic ion. Specifically this is then the polyatomic ion ClO4–. Naming of metal-polyatomic ion compounds: ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Example: What is the name of Sn(ClO 4)2? Each ClO4–. has a single negative charge. There are two ClO4–s for 2 negative charges Therefore to balance, the “Sn” must be Sn2+. Naming of metal-polyatomic ion compounds: ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Example: What is the name of Sn(ClO 4)2? Tin II _____?______ Naming of metal-polyatomic ion compounds: ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Example: What is the name of Sn(ClO 4)2? Tin II chlor Naming of metal-polyatomic ion compounds: ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Example: What is the name of Sn(ClO 4)2? Tin II perchlorate Naming of binary hydrogen compounds that is hydrogen combined with a nonmetal. As a gas: Start the name with “hydrogen”. Then add the name of the non-metal with the “ide” ending as is done with the metal non-metal compounds. Examples: HCl(g) H2S(g) HBr(g) HI(g) hydrogen chloride hydrogen sulfide hydrogen bromide hydrogen iodide Naming of binary hydrogen compounds that is hydrogen combined with a nonmetal. In solution: Use the prefix “hydro” and the suffix “ic” and finish with the word “acid”. Examples: HCl(aq) HI(aq) H2S(aq) HBr(aq) hydrochloric acid hydroiodic acid hydrosulfuric acid hydrobromic acid Naming of ternary acids. (ternary = 3 different atoms) This comes, again, from the polyatomic ion chart. ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Use the information in italics for the acids. prefix root suffix “acid” Naming of ternary acids. (ternary = 3 different atoms) This comes, again, from the polyatomic ion chart. ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Use the information in italics for the acids. prefix root suffix “acid” Example: What is the name of H 2SO4? On the chart replace each “–” with a leading “H”. Naming of ternary acids. (ternary = 3 different atoms) This comes, again, from the polyatomic ion chart. ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Use the information in italics for the acids. prefix root suffix “acid” Example: What is the name of H 2SO4? sulfur note italic part is used here. Naming of ternary acids. (ternary = 3 different atoms) This comes, again, from the polyatomic ion chart. ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Use the information in italics for the acids. prefix root suffix “acid” Example: What is the name of H 2SO4? sulfuric acid Naming of ternary acids. (ternary = 3 different atoms) This comes, again, from the polyatomic ion chart. ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Use the information in italics for the acids. prefix root suffix “acid” Example: What is the name of H 2SO2? Naming of ternary acids. (ternary = 3 different atoms) This comes, again, from the polyatomic ion chart. ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Use the information in italics for the acids. prefix root suffix “acid” Example: What is the name of H 2SO2? sulfur Naming of ternary acids. (ternary = 3 different atoms) This comes, again, from the polyatomic ion chart. ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Use the information in italics for the acids. prefix root suffix “acid” Example: What is the name of H 2SO2? hyposulfurous acid Naming of ternary acids. (ternary = 3 different atoms) This comes, again, from the polyatomic ion chart. ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Use the information in italics for the acids. prefix root suffix “acid” Example: What is the name of HClO4? Naming of ternary acids. (ternary = 3 different atoms) This comes, again, from the polyatomic ion chart. ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Use the information in italics for the acids. prefix root suffix “acid” Example: What is the name of HClO4? chlor Naming of ternary acids. (ternary = 3 different atoms) This comes, again, from the polyatomic ion chart. ions a ci d s c h lo r b rom io d s u l f(u r ) n it r p h o s p h (o r ) c a rbon h y p o . . .i t e h y p o .. .o u s . . . ite . . . o us . . . a te . . . ic p e r . . . a te p er . . . ic C lO – B rO – IO – S O 22 – C lO 2– B r O 2– IO 2 – S O 32– N O 2– P O 33– C lO 3 – B rO 3– IO 3 – S O 42 – N O 3– P O 43 – C O 32– C lO 4– B rO 4– IO 4 – P O 23 – Use the information in italics for the acids. prefix root suffix “acid” Example: What is the name of HClO4? perchloric acid Naming of non-metal with non-metals. 1) Name both non-metals 2) Place the number of each in front of the non-metals with Greek names for the number. 3) Place the ending “ide” on the second non-metal. 4) For the first non-metal, if it has the ending “ine” replace this with an “o”. The Greek numbers: 1 - mono 4 - tetra 2 - di 5 - penta 3 - tri 6 - hexa 7 - hepta 8 - octa 9 - ennea 10 - deca Naming of non-metal with non-metals. 1) Name both non-metals 2) Place the number of each in front of the non-metals with Greek names for the number. 3) Place the ending “ide” on the second non-metal. 4) For the first non-metal, if it has the ending “ine” replace this with an “o”. The Greek numbers: 1 - mono 4 - tetra 2 - di 5 - penta 3 - tri 6 - hexa 7 - hepta 8 - octa 9 - ennea 10 - deca Example: Name the compound P4O10. 4 - phosphorous 10 - oxygen Naming of non-metal with non-metals. 1) Name both non-metals 2) Place the number of each in front of the non-metals with Greek names for the number. 3) Place the ending “ide” on the second non-metal. 4) For the first non-metal, if it has the ending “ine” replace this with an “o”. The Greek numbers: 1 - mono 4 - tetra 2 - di 5 - penta 3 - tri 6 - hexa 7 - hepta 8 - octa 9 - ennea 10 - deca Example: Name the compound P4O10. 4 - phosphorous 10 - oxygen tetraphosphorous decaoxide translate and end with “ide”. Naming of non-metal with non-metals. 1) Name both non-metals 2) Place the number of each in front of the non-metals with Greek names for the number. 3) Place the ending “ide” on the second non-metal. 4) For the first non-metal, if it has the ending “ine” replace this with an “o”. The Greek numbers: 1 - mono 4 - tetra 2 - di 5 - penta 3 - tri 6 - hexa 7 - hepta 8 - octa 9 - ennea 10 - deca Example: Name the compound Cl2O3. 2 - chlorine 3 - oxygen Naming of non-metal with non-metals. 1) Name both non-metals 2) Place the number of each in front of the non-metals with Greek names for the number. 3) Place the ending “ide” on the second non-metal. 4) For the first non-metal, if it has the ending “ine” replace this with an “o”. The Greek numbers: 1 - mono 4 - tetra 2 - di 5 - penta 3 - tri 6 - hexa 7 - hepta 8 - octa 9 - ennea 10 - deca Example: Name the compound Cl2O3. 2 - chlorine 3 - oxygen Notice that “ine” is replaced with “o”. dichloro trioxide Naming of non-metal with non-metals. 1) Name both non-metals 2) Place the number of each in front of the non-metals with Greek names for the number. 3) Place the ending “ide” on the second non-metal. 4) For the first non-metal, if it has the ending “ine” replace this with an “o”. The Greek numbers: 1 - mono 4 - tetra 2 - di 5 - penta 3 - tri 6 - hexa 7 - hepta 8 - octa 9 - ennea 10 - deca Example: Name the compound SO3. 1- sulfur 3 - oxygen Naming of non-metal with non-metals. 1) Name both non-metals 2) Place the number of each in front of the non-metals with Greek names for the number. 3) Place the ending “ide” on the second non-metal. 4) For the first non-metal, if it has the ending “ine” replace this with an “o”. The Greek numbers: 1 - mono 4 - tetra 2 - di 5 - penta 3 - tri 6 - hexa 7 - hepta 8 - octa 9 - ennea 10 - deca Example: Name the compound SO3. 1- sulfur 3 - oxygen sulfur trioxide “mono” is not normally used - except for: Naming of non-metal with non-metals. 1) Name both non-metals 2) Place the number of each in front of the non-metals with Greek names for the number. 3) Place the ending “ide” on the second non-metal. 4) For the first non-metal, if it has the ending “ine” replace this with an “o”. The Greek numbers: 1 - mono 4 - tetra 2 - di 5 - penta 3 - tri 6 - hexa 7 - hepta 8 - octa 9 - ennea 10 - deca Exceptions that use “mono”: CO - carbon monoxide NO - nitrogen monoxide SiO - silicon monoxide plus a few more that are not too common The End
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