Supporting Information
© Copyright Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, 2009
Remarkable Alkali Cation (K+, Cs+)-Induced Dissolution/Reorganization of
Porous Metal–Carboxylate Coordination Networks in Water
Jing-Yun Wu,[a] Miao-Tzu Ding,[a,b] Yuh-Sheng Wen,[a] Yen-Hsiang Liu,*[c] and Kuang-Lieh
Lu*[a]
[a] Institute of Chemistry
Academia Sinica, Taipei 115, Taiwan
[b] Department of Chemistry
National Central University, Taoyuan 320, Taiwan
[c] Department of Chemistry
Fu Jen Catholic University, Taipei 242, Taiwan
Content:
Figure S1.
a) Simulated PXRD pattern of 1·6H2O. b) Experimental PXRD pattern of the reddishcolored samples reassembled from an aqueous solution of 1·6H2O and KCl. c)
Experimental PXRD pattern of the reddish-colored samples reassembled from an
aqueous solution of 3·3H2O and KCl.
Figure S2.
a) Simulated PXRD pattern of 2'·8H2O. b) Experimental PXRD pattern of 2'·8H2O
(the greenish-colored samples reassembled from an aqueous solution of 2·4H2O and
KCl). c) Experimental PXRD pattern of the greenish-colored samples reassembled
from an aqueous solution of 4·3H2O and KCl.
Figure S3.
a) Simulated PXRD pattern of 5·2H2O. b) Experimental PXRD pattern of 5·2H2O. c)
Experimental PXRD pattern of the reddish-colored samples reassembled from an
aqueous solution of 3·3H2O and CsCl.
Figure S4.
a) Simulated PXRD pattern of 6·2H2O. b) Experimental PXRD pattern of 6·2H2O. c)
Experimental PXRD pattern of the greenish-colored samples reassembled from an
aqueous solution of 4·3H2O and CsCl.
Figure S5.
a) Simulated PXRD pattern of 1·6H2O. b) Experimental PXRD pattern of the reddishcolored samples reassembled from an aqueous solution of 5·2H2O and KCl.
2
a
b
c
Figure S1. a) Simulated PXRD pattern of 1·6H2O. b) Experimental PXRD pattern of the reddishcolored samples reassembled from an aqueous solution of 1·6H2O and KCl. c) Experimental PXRD
pattern of the reddish-colored samples reassembled from an aqueous solution of 3·3H2O and KCl.
Comparison of unit cell parameters
a [Å]
b [Å]
c [Å]
α [deg]
β [deg]
γ [deg]
V [Å3]
1·6H2O
15.737(2)
11.9010(14)
9.4667(12)
90
113.293(10)
90
1628.5(4)
crystal from 1·6H2O
in KCl(aq)
15.759(17)
11.905(12)
9.464(11)
90
113.12(3)
90
1633(3)
3
crystal from 3·3H2O
in KCl(aq)
15.691(9)
11.967(7)
9.481(5)
90
113.09(5)
90
1624.0(4)
a
b
c
Figure S2. a) Simulated PXRD pattern of 2'·8H2O. b) Experimental PXRD pattern of 2'·8H2O (the
greenish-colored samples reassembled from an aqueous solution of 2·4H2O and KCl). c)
Experimental PXRD pattern of the greenish-colored samples reassembled from an aqueous solution
of 4·3H2O and KCl.
Comparison of unit cell parameters
crystal from 2·4H2O in KCl(aq)
2·4H2O
(2'·8H2O)
a [Å]
9.4093(10)
15.5259(5)
b [Å]
11.5611(12)
11.8670(3)
c [Å]
13.4812(15)
9.4129(3)
90
90
α [deg]
105.445(7)
113.0890(10)
β [deg]
90
90
γ [deg]
V [Å3]
1413.5(3)
1595.37(8)
4
crystal from 4·3H2O
in KCl(aq)
15.613(19)
11.916(14)
9.467(11)
90
113.04(2)
90
1621(4)
a
b
c
Figure S3. a) Simulated PXRD pattern of 5·2H2O. b) Experimental PXRD pattern of 5·2H2O. c)
Experimental PXRD pattern of the reddish-colored samples reassembled from an aqueous solution
of 3·3H2O and CsCl.
Comparison of unit cell parameters
a [Å]
b [Å]
c [Å]
α [deg]
β [deg]
γ [deg]
V [Å3]
5·2H2O
15.270(3)
6.7028(13)
18.718(4)
90
105.53(3)
90
1846.0(6)
crystal from 3·3H2O
in CsCl(aq)
15.278(14)
6.709(6)
18.689(8)
90
105.55(3)
90
1846(1)
5
3·3H2O
9.5520(19)
11.187(2)
14.087(3)
90
104.11(3)
90
1459.9(5)
a
b
c
Figure S4. a) Simulated PXRD pattern of 6·2H2O. b) Experimental PXRD pattern of 6·2H2O. c)
Experimental PXRD pattern of the greenish-colored samples reassembled from an aqueous solution
of 4·3H2O and CsCl.
Comparison of unit cell parameters
a [Å]
b [Å]
c [Å]
α [deg]
β [deg]
γ [deg]
V [Å3]
6·2H2O
15.169(3)
6.6827(13)
18.579(4)
90
105.33(3)
90
1816.4(6)
greenish crystal from 4·3H2O
in CsCl(aq)
15.221(10)
6.71(4)
18.620(13)
90
105.16(2)
90
1836(1)
6
4·3H2O
9.4829(19)
11.218(2)
13.905(3)
90
104.63(3)
90
1431.3(5)
a
b
Figure S5. a) Simulated PXRD pattern of 1·6H2O. b) Experimental PXRD pattern of the reddishcolored samples reassembled from an aqueous solution of 5·2H2O and KCl.
Comparison of unit cell parameters
a [Å]
b [Å]
c [Å]
α [deg]
β [deg]
γ [deg]
V [Å3]
red crystal from 5·2H2O
in KCl(aq)
15.72(3)
11.90(2)
9.478(18)
90
113.27(5)
90
1630(5)
1·6H2O
15.737(2)
11.9010(14)
9.4667(12)
90
113.293(10)
90
1628.5(4)
7