How sharp is the sharp Archean Moho? Example from eastern Superior Province. Vadim Levin, Jill A. VanTongeren, Andrea Servali Department of Earth and Planetary Sciences, Rutgers University This article has been accepted for publication and undergone full peer review but has not been through the copyediting, typesetting, pagination and proofreading process which may lead to differences between this version and the Version of Record. Please cite this article as doi: 10.1002/2016GL067729 ©2016 American Geophysical Union. All rights reserved. Abstract: The Superior Province of North America has not experienced major internal deformation for nearly 2.8 Gyr, preserving the Archean crust in its likely original state. We present seismological evidence for a sharp (less than 1 km) crust-mantle boundary beneath three distinct Archean terranes, and for a more vertically extensive boundary at sites likely affected by the 1.2 – 0.9 Ga Grenville orogeny. At all sites crustal thickness is smaller than expected for the primary crust produced by melting under higher mantle potential temperature conditions of Archean time. Reduced thickness and an abrupt contrast in seismic properties at the base of the undisturbed Archean crust are consistent with density sorting and loss of the residues through gravitational instability facilitated by higher temperatures in the upper mantle at the time of formation. Similar sharpness of crust-mantle boundary in disparate Archean terranes suggests that it is a universal feature of the Archean crustal evolution. Key Points: 1. Teleseismic receiver functions used to measure Moho thickness in eastern Superio Province. 2. Sharp (~1 km) Moho likely is an original feature of Archean continental crust formation 3. Density sorting and delamination due to high mantle potential temperature explain sharp Archean Moho ©2016 American Geophysical Union. All rights reserved. Introduction: The transition from the seismically slower material of the crust to the faster material of the mantle, rarely accessible for direct sampling, bears the (somewhat shortened) name of its discoverer Andrija Mohorovičić, and has been a subject of seismological studies for over a century (Prodhel et al., 2013). A degree of ambiguity remains in associating the change in seismic speed at the Moho with a change in lithology at the crust-mantle boundary (O’Reilly et al., 2013). Nevertheless, Earth’s crust is most commonly delineated by seismological means (e.g., Cook et al., 2010). In global surveys (e.g. Christensen and Mooney, 1995) and regional studies (e.g. Yuan, 2015) the depth to the Moho within stable continents is ~40 km, with oldest areas (cratons) having systematically smaller values. A recent survey of diverse seismological definitions of the Moho (Abbott et al., 2013) argues for systematic differences in its character as a function of the continental consolidation age, with the oldest Archean-age cratonic crust having a larger fraction of “sharp” Moho observations. Criteria used for the “sharp” designation depend on the methods in specific studies, and include confident detection of PmP reflected waves in controlled seismic source profiles, as well as shapes of P-to-S converted phases from distant earthquakes. Here we use the teleseismic receiver function technique to probe Moho structure at six sites within the eastern Superior Province of North America. We present evidence for the Moho being sharp (~1km) within all undisturbed Archean terranes, even those with different formation ages and compositions, and notably more diffuse (> 4 km) near the ~1.0 Ga Grenville Front. We also confirm that the crust is thinner than the global average. In both its thickness, and the vertical extent (sharpness) of the Moho, the Superior Province crust differs from the typical continental crust generated in the Phanerozoic. ©2016 American Geophysical Union. All rights reserved. Regional Setting The Superior Province is the largest of the Archean cratons (Card, 1990), made up of terranes with origin dates as early as 3.3 Ga, assembled mainly during 2.72 Ga and 2.68 Ga collisional events (Percival et al., 2007), and further modified as late as 2.51 Ga (Moser et al., 2008). Seismic studies of the Superior province (e.g., Calvert et al., 1995; Calvert and Ludden, 1999; Mereu, 2000; Musacchio et al., 2004; Darbyshire et al., 2007) showed its crust to be 40 km or less, with velocities typical of felsic lithology, and with many instances of “sharp” Moho. We investigate the vertical extent of the crust-mantle transition in three different terranes within the eastern part of the Superior Province (Fig. 1). Two stations (WEMQ and NMSQ) are located within the La Grande terrane, which contains the oldest rocks of the eastern Superior Province, with 3.3 Ga to 2.9 Ga continental basement, and juvenile magmatic rocks emplaced between 2.75 and 2.70 Ga. One station (YOSQ) is located within the Opinaca subprovince in late Archean paragneiss (Reed et al., 2005). Further to the south, three stations (MATQ, LSQQ, CHGQ) are within the Abitibi granite-greenstone belt, known for its abundance of komatiitic lavas considered by some to be indicative of plume-sourced oceanic plateaus in the Archean (Fan and Kerrich, 1997). Station MATQ is located on a sequence of late Archean volcanic rocks, whereas stations LSQQ and CHGQ have experienced post-Archean events. LSQQ is located directly on top of a dike from the late Proterozoic Abitibi dike swarm (1141±1 Ma), and CHGQ is only 30 km west of the 1250-980 Ma Grenville front (Reed et al., 2005). Measuring Moho sharpness We investigate the vertical extent, or sharpness, of the Moho transition using ©2016 American Geophysical Union. All rights reserved. observations of shear (S) waves present in the coda of first-arriving compressional (P) waves from distant earthquakes. The receiver function (RF) analysis technique (Ammon, 1991) assumes that such S waves originate by the process of mode conversion from P waves at a contrast in seismic properties. The constraint on the vertical extent of the boundary comes from the consideration of the pulse shape of a P-to-S converted wave. Figures 2a&b illustrate expected effects of the vertical profile of seismic velocities across the crust-mantle transition. Three cases are considered: an instantaneous increase, a 4 km wide gradual increase, and a 5 km wide sequence of layers with alternating properties. At frequency 0.25 Hz (corresponding to S wavelengths ~15 km, Figure 2b) resulting time series are virtually identical. Differences emerge as higher frequencies (shorter wavelengths) are introduced. A vertically instantaneous change yields a pulse with progressively diminishing width. A smooth vertical gradient results in a pulse with a characteristic width that does not change after a certain limit is reached. Finally, a complex crust-mantle transition zone results in a set of distinct pulses arising from individual contrasts within it. We adopt the wavelength of the P-to-S converted wave that departs from the simple pulse shape as a measure of the boundary width. This approach is similar to the consideration of pulse shapes of waves reflected from closely spaced boundaries (Widess, 1973), which informs a widely accepted ¼ wavelength rule for the vertical resolution of seismic reflection data. The time separation between two vertically propagating P-to-S converted waves from horizontal boundaries separated by h (Figure 2c) will be , where Vp,Vs are constant velocities of P and S waves between the boundaries, and . If we set then , where is the wavelength of the P-to-S converted wave, for =1.75. Simulated P-to-S converted waves in Figure 2a show that a departure from the simple pulse ©2016 American Geophysical Union. All rights reserved. shape becomes obvious at the f =1 Hz corresponding to km, a wavelength commensurate with the width of the velocity transition. This observation is more in line with the h~P/2 estimate (P – P wavelength) proposed by Bostock (1999) and based on amplitudes of mode-converted waves in zones of generalized velocity heterogeneity. In our context this will yield h~ measure of the converting boundary width. Data and Analysis Continuously operating seismic observatories in the Superior Province (Figure 1) provide data for the study. We select groups of nearby earthquake sources (see Supplement Figure 1) from datasets containing between 90 and 140 records per site. All records chosen for one site in the frequency domain are stacked to form a single RF time series. All sources used to form this RF have similar ray parameters and backazimuths, eliminating possible distortions of the converted wave pulse shape due to lateral changes in Moho properties and variations in the incidence angle. We use a multitaper spectral correlation variant of the RF technique that affords an exceptional resolution of higher frequency RF components (Park and Levin, 2000). For each site, the RF time series with different frequency content (Figure 3) are constructed in order to examine the resulting pulse shapes of the P-to-S converted waves from the Moho (designated Pms). We identify the highest frequencies at which these pulses appear “pure” (i.e. as predicted by an abrupt change in properties, Figure 2a), evaluate their wavelengths, and derive two estimates of the vertical distance over which seismic properties change, an optimistic one assuming a constant velocity layer (i.e., a conservative one assuming a complex vertical transition (i.e. ), and ). Results. With the exception of the site CHGQ discussed in more detail below, all sites within ©2016 American Geophysical Union. All rights reserved. the Superior Province show a simple Pms phase, with delay times in the 4.3 – 4.5 s range (Figure 3). At three locations (WEMQ, YOSQ, MATQ) Pms phases display a progressive decrease in width with increasing f. The highest usable frequency in our dataset is f~3 Hz, and the corresponding ~1.2 km. At site NMSQ the Pms pulse does not decrease in width for f>1.75 Hz, and at site LSQQ the highest frequency where the Pms pulse retains its pure shape is f=1 Hz. Consequently, ~2.1 km for NMSQ, and ~3.7 km for LSQQ. Our estimates for the maximum vertical extent over which seismic properties change at the Moho are ~0.7 km for sites WEMQ, YOSQ and MATQ; ~1.2 km for site NMSQ; and ~2.2 km for site LSQQ. Using a more conservative approach ( these estimates are 1.2 km, 2.1 km and 3.7 km, respectively. At site CHGQ there appears to be two positive pulses with properties similar to the Pms phase at lower frequencies (e.g., 1 Hz), one at ~3.7 s and another at ~6.2 s. At higher frequencies additional phases appear between them. Examination of the full dataset (Supplementary Figure 1) shows that the pulse at 3.7 s is seen from most directions, and thus is more likely to represent the P-to-S conversion at the crust-mantle boundary. This pulse loses its pure shape for f>0.5Hz, or ~7.4 km, and thus our estimates of Moho width here are 4.3 - 7.4 km. Presence of additional converted phases in 4 – 6 s time window points to considerable complexity of the uppermost mantle down to depths of at least 50 km. The PmS delay is a measure of the crustal thickness, the calculation of which is based on an assumption of Vp =6.5 km/s (e.g. stacking velocity of Calvert and Ludden, (1999) for the Superior Province), and Vp/Vs = 1.75 (see Supplementary Material for discussion). Using these values we obtain crustal thickness values for the eastern Superior Province of 34.9 36.5km (Supplementary Table 1). Choosing global-average values of Vp=6.454 km/s and Vp/Vs=1.768 (Christensen and Mooney, 1995) reduces these estimates by ~1 km, while adopting values from controlled-source studies of the Abitibi province (Vp~6.6 km/s and ©2016 American Geophysical Union. All rights reserved. Vp/Vs=1.72; Mereu, 2000) increases them by 1.6-1.9 km (Supplementary Table 1). Stacking of direct and multiply scattered Ps phases in RF timeseries provides a way to estimate Vp/Vs and crustal thickness (Zhu and Kanamori, 2000), with an assumption of either Vp or Vs value. Applying this technique (often called H-k stacking) to our data we obtain tight constraints on the Moho depth, while Vp/Vs ratio is variable (Supplementary Figure 2). While a choice of Vp value strongly influences the estimate of the crustal thickness, for Vp<6.8 km/s our data favor crustal thickness values under 40 km at all sites (Supplementary Table 2). Discussion Estimates of Moho sharpness rely on the ability to resolve RFs at high frequencies (Park and Levin, 2000). In their review of controlled source reflection studies in Canada, Cook et al. (2010) defined the Moho as “sharp” or “diffuse” using patterns of near-vertically reflected waves. In cases of “sharp” Moho (e.g., at the northern end of Abitibi-Opatica line near our site NMSQ, Figure 13 in Cook et al., (2010), originally from Calvert and Ludden, (1999)) the change from strong reflectivity (in the crust) to no reflectivity (supposedly in the mantle) takes place over ~0.2 s of two-way time. For a range of compressional wave speeds of 6.7 – 7.5 km/s at the bottom of the crust (Musacchio et al., 2004), this translates into ~0.7 km of vertical distance, close to our optimistic estimate for site NMSQ, Clarity and prominence of the PmP Moho reflection is another commonly used indicator of a "sharp" Moho in controlled seismic source studies (cf. Abbott et al., 2013). In western Superior Province Musacchio et al. (2004) report a PmP phase being best observed in the 2-6 Hz pass-band, with a corresponding shortest wavelength in the lower crust of ~1.1 1.2 km, calculated as , where Vp= 6.7 - 7.5 km/s. According to the 1/4 wavelength measure of Widess (1973), this implies a velocity transition over ~0.3 km or less. Although ©2016 American Geophysical Union. All rights reserved. the frequency range of our current RF data is not sufficient to detect boundaries separated by 300 m, the behavior of the PmS pulse at site WEMQ (Figure 3) is suggestive – it becomes progressively narrower with each increase of frequency. Given enough bandwidth in the earthquake sources, RF resolution may be brought closer to that of controlled source studies. At three locations we estimate the transition between the cratonic crust of the eastern Superior Province and its lithospheric mantle as being ~1 km thick. Our results are very similar for three locations with different early histories. Common to the Abitibi terrane, which is dominantly mafic volcanics, and the La Grande and Opinaca terranes, which are dominated by granitoids (Figure 1, and Percival et al., 2007) is the lack of tectonic activity after their incorporation into the Superior province. Sites with considerably more diffuse (4-7 km) crust-mantle transition are LSQQ and CHGQ. Both have experienced post-Archean crustal reworking such as dike emplacement and extensive faulting related to Grenville-age continent-continent collision. A plausible interpretation of our findings is that the Superior Province Moho was initially sharp, and was subsequently disturbed by tectonic events in the Proterozoic. This disturbance did not relax over the subsequent ~1 Gyr. Thus, a sharp Moho is likely an original feature of craton formation and stabilization in the Archean. Many researchers suggest that mantle potential temperature in the Archean was up to 250°C higher than today (Davies, 1992; 2009; Korenaga, 2008a,b; Herzberg et al,. 2010; Brown, 2007). Under these conditions the mantle is expected to melt to a greater extent, thereby producing primary picritic-basaltic crust up to 40 km in thickness (Herzberg et al., 2010; Herzberg and Rudnick, 2012). One consequence of the uniformly thick crust may have been the inhibition of subduction sensu stricto by extreme bending stresses (e.g., Korenaga, 2006; Davies, 2009). However, preserved crust of the cratons is significantly smaller than the 41.1 km modern continental average of Christensen and Mooney (1995), and seismic imaging yields convincing evidence of subduction episodes during the Archean (e.g. Calvert ©2016 American Geophysical Union. All rights reserved. et al., 1995; Chen et al., 2009). Furthermore, the predominant TTG composition of the cratonic crust (Moyen and Martin, 2012) likely requires multiple episodes of re-melting of the primary picritic-basaltic crust (Johnson et al., 2014). In contrast to preserved Archean cratonic crust, juvenile continental crust developed in modern island arcs has a very different seismic structure, with higher absolute values of compressional velocity, and a gradual change to upper mantle values over a distance of multiple km (e.g. Holbrook et al., 1999; Kodaira et al., 2010). The expected RF signature of a sample profile through the juvenile arc crust is illustrated in Supplementary Figure 3. In order to transition from juvenile island arc to modern continental crust, a significant portion of the lower crust and the mantle lithosphere must be removed (e.g. Jagoutz et al., 2011; Jagoutz and Schmidt, 2013). Examples of lithospheric instability during the Phanerozoic are inferred from exposed terranes of island arcs, such as the Kohistan and Talkeetna arc sections (Jagoutz and Kelemen, 2015). In Talkeetna, a ~100-400 m thick section of dense garnet gabbro crust is the only remaining density-unstable lithology present under a 40 km thick crustal section of granites and gabbronorites (Greene et al., 2006). It is proposed that a further 10-12 km of the original crust were delaminated from the Talkeetna arc section prior to obduction (Greene et al., 2006; Jull and Kelemen, 2001; Kelemen et al., 2004; Behn and Kelemen, 2006). Jagoutz and Behn (2014) show that density sorting, and removal of density-unstable material, occurs in the modern day crust on 0.5-5 Myr time-scales, and that higher Moho temperatures (e.g. ~1000°C in Talkeetna relative to ~700-800°C for Kohistan) allow for a sharper Moho by this density sorting process. Thus, delamination of density-unstable volumes of primary Archean crust is a plausible scenario to yield thinner Archean crust with an abrupt lower boundary (e.g. Hamilton, 2013). The transition from density-stable to density-unstable crustal lithology is ©2016 American Geophysical Union. All rights reserved. pressure and composition dependent, corresponding roughly to the appearance of garnet in the stable phase assemblage. Johnson et al. (2014) modeled the stability of primary crust using the appropriate compositions for high MgO picrites and basalts from the Archean, and showed that the removal of dense mafic lower crust by Rayleigh-Taylor instability occurs rapidly in undifferentiated crust at mantle potential temperatures greater than 1550°C. Lighter crustal material left behind after an episode of gravitational removal of dense residues is likely to form an abrupt contrast with the underlying mantle. This conclusion is supported by the similarity of Moho sharpness and crustal thickness in all Archean terranes investigated here, regardless of dominant lithology, and suggests that the process of granitization does not disrupt or alter the Moho signature. Conclusions At a set of locations broadly distributed within the eastern Superior Province we use high-quality records of P-to-S converted waves from distant earthquakes to quantify the length-scale of the contrast in seismic properties delimiting the bottom of the crust. Our estimates of the vertical extent of the Moho boundary range from less than 1 km in undisturbed crust to over 7 km near major post-Archean tectonic boundaries. We find short vertical transition (< 1km) from the crust to the mantle in all Archean terranes probed, regardless of their formation age or crustal lithology (basaltic vs. granitic). This finding suggests that the sharp Moho observed in Archean cratons is a first order feature, likely related to higher mantle potential temperatures resulting in hot (1000°C) Moho temperatures during their formation. Our data also show that regions affected by Grenville-age tectonism have a more diffuse Moho, suggesting that disturbances to the originally sharp Moho are unable to relax on the >1 Gyr time scale. Our observations of sharp Moho and relatively thin crust in the Archean terranes of ©2016 American Geophysical Union. All rights reserved. the eastern Superior Province are consistent with density sorting of the crust under the conditions of higher mantle potential temperatures in the Archean. The formation of a sharp Moho transition must be a primary and ubiquitous feature of Archean craton formation and stabilization. Acknowledgements This work was supported by the NSF Earthscope grant EAR-1147831 and the Aresty Center for Undergraduate Research, and made possible by the open data policy of the Canadian National Data Centre for Earthquake Seismology and Nuclear Explosion Monitoring. Discussions with C. Herzberg, O. Jagoutz , W. Menke and M. Bostock, as well as reviews by Andrew Hynes and anonymous, helped us sharpen the arguments. Figures were drawn using GMT (Wessel and Smith, 1995). References Abbott D. H., W. D. Mooney, J. A. VanTongeren, 2013, The character of the Moho and lower crust within Archean cratons and the tectonic implications, Tectonophysics 609 (2013) 690–705 Ammon, C.J., 1991, The isolation of receiver effects from teleseismic P waveforms: Seismological Society of America Bulletin, v. 81, p. 2504–2510. Behn, M.D. and P.B. Kelemen, 2006, The stability of arc lower crust: Insights from the Talkeetna Arc section, south-central Alaska and the seismic structure of modern arcs, J. Geophys. Res. 111, B11207, doi:10.1029/2006JB004327 Bostock, M. G., 1999, Seismic waves converted from velocity gradient anomalies in the Earth's upper mantle, Geophys. J. Int. 138, 747-756 Brown, M. Metamorphic conditions in orogenic belts: A record of secular change, 2007. Int. Geol. Rev. 49, pp. 193-234 Calvert, A. J., E. W. Sawyer, W. J. Davis & J. N. Ludden, 1995. Archean subduction inferred from seismic images of a mantle suture in the Superior Province, Nature, 375, 670-674 Calvert, A. J., and J. N. Ludden (1999), Archean continental assembly in the southeastern Superior Province of Canada, Tectonics, 18(3), 412–429. ©2016 American Geophysical Union. All rights reserved. Card, K.D., 1990, A review of the Superior Province of the Canadian Shield, a product of Archean accretion. Precambrian Res. 48, 99–156. Chen, C.-W., S. Rondenay, R. L. Evans and D. B. Snyder, Geophysical detection of relict metasomatism from an Archean (~3.5 Ga) subduction zone, 2009, Science, 326, 1089-1091 Christensen, N.I., Mooney, W.D., 1995. Seismic velocity structure and composition of the continental crust: a global view. J. Geophys. Res. 100, 9761–9788. Cook, F.A., White, D.J., Jones, A.G., Eaton, D.W.S., Hall, J., Clowes, R.M., 2010. How the crust meets the mantle: LITHOPROBE perspectives on the Mohorovicic discontinuity and crust–mantle transition. Can. J. Earth Sci. 47, 315–351. Clowes, R. N., 2010, Initiation, development, and benefits of Lithoprobe — shaping the direction of Earth science research in Canada and beyond, Canadian Journal of Earth Sciences, 47( 4), pp. 291-314(24) Darbyshire, F.A., Eaton, D.W., Fredericksen, A.W., Ertolahti, L., 2007. New insights into the lithosphere beneath the Superior Province from Rayleigh wave dispersion and reciever function analysis. Geophys. J. Int. 169, 1043–1068. Davies, G. F. (1992). On the emergence of plate tectonics. Geology, 20(11), 963-966. Davies, G. F. (2009). Effect of plate bending on the Urey ratio and the thermal evolution of the mantle. Earth and Planetary Science Letters, 287(3), 513-518. Fan, J., and R. Kerrich. 1997, Geochemical characteristics of aluminum depleted and undepleted komatiites and HREE-enriched low-Ti tholeiites, western Abitibi greenstone belt: a heterogeneous mantle plume-convergent margin environment." Geochimica et Cosmochimica Acta 61.22, pp. 4723-4744. Greene, A. R., DeBari, S. M., Kelemen, P. B., Blusztajn, J., & Clift, P. D. (2006). A detailed geochemical study of island arc crust: the Talkeetna arc section, South–Central Alaska. Journal of Petrology, 47(6), 1051-1093. Hamilton, 2013. Evolution of the Archean Mohorovičić discontinuity from a synaccretionary 4.5 Ga protocrust, Tectonoph. Volume 609, Pages 706–733 Herzberg, C., Rudnick, R., 2012. Formation of cratonic lithosphere: an integrated thermal and petrological model. Lithos 149, 4–15. Herzberg, C., Condie, C., Korenaga, J., 2010. Thermal history of the Earth and its petrolog ical expression. Earth Planet. Sci. Lett. 292, 79–88. Holbrook, W. S., D. Lizarralde, S. McGeary, N. Bangs, J. Diebold, 1999. Structure and composition of the Aleutian island arc and implications for continental crustal growth, Geology, 1999; v. 27; no. 1; p. 31–34 Jagoutz, O., Müntener, O., Schmidt, M. W., & Burg, J. P. (2011). The roles of flux-and decompression melting and their respective fractionation lines for continental crust ©2016 American Geophysical Union. All rights reserved. formation: evidence from the Kohistan arc. Earth and Planetary Science Letters, 303(1), 2536. Jagoutz, O. and M. W. Schmidt, 2012. The formation and bulk composition of modern juvenile continental crust: the Kohistan arc. Chemical Geology, 298-299, 78-96. Jagoutz, O. and P. Kelemen, 2015. Deep Petrological Processes and Structure of Island Arcs. Annual Review of Earth and Planetary Science, Vol 43, 12.1-12.42 Jagoutz, O. and M. Behn, 2013. Foundering of lower arc crust as an explanation for the origin of the continental Moho. Nature, 504, 131-134. Johnson, T. E., Brown, M., Kaus, B. J. P. and VanTongeren, J. A., 2014, Delamination and recycling of Archaean crust caused by gravitational instabilities, Nature Geoscience 7, 47–52 Jull, M. and P.B. Kelemen, 2001. On the conditions for lower crustal convective instability, J. Geophys. Res. 106, pp. 6423-6446 Kelemen PB, Hanghøj K, Greene A. 2004. One view of the geochemistry of subductionrelated magmatic arcs, with an emphasis on primitive andesite and lower crust. In Treatise on Geochemistry, Vol. 3: The Crust, ed. RL Rudnick, pp. 593–659. Oxford, UK: Pergamon. 1st ed. Kodaira, S., Noguchi, N., Takahashi, N., Ishizuka, O., Kaneda, Y., 2010. Evolution from fore‐ arc oceanic crust to island arc crust: a seismic study along the Izu–Bonin fore arc. J. Geophys. Res. 115. Korenaga, J., 2006. Archean geodynamics and the thermal evolution of Earth, in Archean Geodynamics and Environments, edited by K. Benn, J.-C. Mareschal, and K. Condie, AGU Geophysical Monograph Series 164, p.7-32 Korenaga, J., 2008a, Urey ratio and the structure and evolution of Earth’s mantle, Rev. Geophys., 46, RG2007, doi:10.1029/2007RG000241. Korenaga, J., 2008b, Plate tectonics, flood basalts, and the evolution of Earth’s oceans, Terra Nova, 20, 419-439 Levin, V. and J. Park, P-SH conversions in a flat-layered medium with anisotropy of arbitrary orientation. GJI, 131, pp 253-266, 1997. Musacchio, G., D. J. White, I. Asudeh, and C. J. Thomson, 2004. Lithospheric structure and composition of the Archean western Superior Province from seismic refraction/wide-angle reflection and gravity modeling, J. Geophys. Res., 109, B03304, doi:10.1029/2003JB002427. Mereu, R. F., 2000. The complexity of the crust and Moho under the southeastern Superior and Grenville provinces of the Canadian Shield from seismic refraction – wide-angle reflection data, Can. J. Earth Sci. Vol. 37, pp. 439-458 Moser, D., J. R. Bowman, J. Wooden, J. W. Valley, F. Mazdab, Noriko Kita, Creation of a continent recorded in zircon zoning, Geology, v. 36, pp. 239-242 ©2016 American Geophysical Union. All rights reserved. Moyen, J. F., & Martin, H. (2012). Forty years of TTG research. Lithos, 148, 312-336. O’Reilly, S. Y. and Griffin, W. L. Moho vs crust–mantle boundary: Evolution of an idea , Techonoph. v. 609, pp. 535–546 Park, J., and V. Levin, 2000. Receiver functions from multiple-taper spectral correlation estimates, BSSA, v90, pp. 1507-1520 Percival, J.A., 2007, Geology and metallogeny of the Superior Province, Canada, in Goodfellow, W.D., ed., Mineral Deposits of Canada: A Synthesis of Major Deposit-Types, District Metallogeny, the Evolution of Geological Provinces, and Exploration Methods: Geol. Assoc.Canada, Mineral Deposits Div., Spec. Pub. No. 5, p. 903-928. Prodhel C, B. Kennet, I. M. Artemieva, H. Thybo, 2013. 100 years of seismic research on the Moho, Tectonoph. 609 pp. 9–44 Reed, John Calvin, Brian E. Tucholke, and John Oliver Wheeler, 2005. Decade of North American Geology: Geologic Map of North America: Perspectives and Explanation. Geological Society of America Widess, M. B., 1973, How thin is a thin bed, Geophysics, 38, pp 1176-1180, 1973 Wessel, P., and W. H. F. Smith, 1991, Free software helps map and display data, Eos Trans. AGU, 72, 441, doi:10.1029/ 90EO00319. Yuan, H. Secular change in Archaean crust formation recorded in Western Australia, Nature Geoscience 8, 808–813 (2015) Zhu, L. & Kanamori, H. Moho depth variation in southern California from teleseismic receiver functions. J. Geophys. Res. 105, 2969–2980 (2000) ©2016 American Geophysical Union. All rights reserved. Figure 1. A map of sites studied (circles) with the outlines of tectonic boundaries (from Clowes et al., 2010). The locator map (inset) shows the study area as a red box. Four-letter codes designate seismic observatories. Numbers next to sites show ranges of Moho thickness, in km. ©2016 American Geophysical Union. All rights reserved. Figure 2. (a) Synthetic RFs computed in 1D layered velocity structures using a reflectivity algorithm of Levin and Park, (1997). Time series are shaded according to the model (instant step – light grey, linear gradient – grey, complex structure – solid). The shortest wavelength is computed as , where f is highest frequency, and VS = 3.7 km/s. An inset in (b) shows the P-to-S wave pulse for f=3 Hz. (b) Values of shear wave speed for three vertical profiles at the crust-mantle boundary used to produce synthetic RFs. (c) Raypaths and waveforms of two P-to-S converted waves from closely spaced boundaries. ©2016 American Geophysical Union. All rights reserved. Figure 3. Observed RF arranged by frequency content for 6 locations within the Superior Province. Pms pulses with progressively diminishing width are found at sites WEMQ, MATQ and YOSQ. Sites NMSQ and LSQQ show pulses that have a simple shape up to f=1.75 Hz and f=1Hz, respectively (marked by stars). Site CHGQ displays frequency dependence of the Pms pulse suggesting complexity in the crust-mantle transition zone. ©2016 American Geophysical Union. All rights reserved.
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