Validation approaches and challenges with wastewater and storm water in the UK Christy White Peter Loughran Mike Newberry Aknowledgements: UKWIR Environment Agency Methodology for the design and permitting of UV irradiation for wastewater disinfection • Identification of disinfection requirements on a site specific basis • Evaluation of the UV dose required to achieve the disinfection requirements • Determination of the design (water quality) envelope for the design This approach is underpinned by the use of validated UV irradiation systems, combined with site specific data, to ensure that the target level of disinfection can be achieved and demonstrated. Disinfection for wastewater discharges Crude sewage Wastewater treatment (no disinfection) E. coli 7 10 cfu/100ml Final Effluent 2 log reduction 105 E. coli cfu/100ml Dilution / dispersion 1 log dilution Receiving Water E. coli 104 cfu/100ml Bathing Water targets: Final effluent discharges require disinfection to achieve Bathing water and Shellfish water quality targets E. coli: 80 cfu/100ml (5.4 log reduction from crude) Intestinal enterococci: 32 cfu/100ml Enterovirus: 4.4 log reduction from crude Shellfish targets E. coli 110 cfu/100ml (5.25 log reduction from crude) Minimum pathogen (virus) reduction through disinfection process: 1 log10 UK wastewater disinfection • Sewage from over 9 million PE (7% of UK population) requires disinfection • Predominantly UV irradiation • 210 sites (approx., up to Amp3) • Annual operating power of circa 60 GWh • Circa 30,000 tonnes CO2e The 10 largest sites • Disinfect over 2,120 Ml/d (3 Million PE) • Estimated annual opex circa £2-3 million • >15,000 lamps, estimated replacement costs of circa £3-5M every 3 years CUMULATIVE OPEX OVER 15 YEARS 60 50 40 30 20 10 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Collaboration through UKWIR project WW17 • No low carbon “silver bullet” alternative to UV irradiation • Analysis of data highlighted: • an “over achievement” of dose in comparison with the permitted condition • the need for a relationship between UV dose and expected performance • the need for more effective dose control • the potential for site specific data to support use of alternative values to EPR 7.01 defaults to determine the target log inactivation Drivers for change Key factors in optimising power use in UV irradiation are: • Selection of the target / operational UV dose • Ability to control to the target dose (turn down / response to changes in WQ, flowrate) Drivers for change 1. Operating costs associated with continuous (final effluent) systems Existing methodology UV dose set by “a dose calculator”, default values & UV system was designed to deliver a “theoretical” (PSS) dose: • no direct relationship between UV dose (PSS) and performance • not appropriate for dose optimisation Environment Agency UV Disinfection - Spreadsheet for the Calculation of the UV Dose for Faecal Coliforms Jun-04 Input data in the yellow boxes can be changed by user. Critical Output is highlighted in blue No constants or coefficients should be changed without reference to Surfacewater Process, Environment Agency Site: 2. Alternative stormwater management solutions Output - Dose Computation Effluent Characteristics Comments Faecal Coliform Conc. (No/100 ml) in the influent US EPA empirical equation designed on high UVT wastewaters • Test Input Suspended Solids conc. (mg/l) 25 UV Intensity (mW/cm^2) Received Dose (mWs/cm^2) UV DIS Faecal Coliforms Enteroviruses 30.70 70.68 5.00 Critical Dose (mWs/cm^2) 70.68 Contact Time (s) 14.14 Default value 5 mW/cm^2 Compute Log-Reductions Required Faecal Coliforms Log reductions achieved by critical dose (mWs/cm^2) Enteroviruses Log-reduction achieved by critical dose Total Required Reduction 5.40 5.40 Reduction achievable through Primary + Secondary treatment 2.00 2.00 See table below for default reductions, or use site-specific values. Initial Dilution or 1.00 1.00 Use minimum values. Use the greater of Initial Dilution and Secondary Dispersion Total 3.00 3.00 2.40 2.40 0 Required by UV Default values for log reductions through conventional treatment Faecal EnteroColiforms viruses Primary + Activated Sludge 2.00 1.50 Primary + Oxidation Ditch 2.00 1.50 Primary + BAFF 1.50 1.00 Percolating Filter 1.50 0.30 4.58 2.40 4.63 4.33 Maximum Achievable Reductions Maximum Log10 Reduction Secondary Dispersion/Mixing dose-response) Consent 95%ile UV Lamps the existing design / permitting process was not applicable to stormwater (water quality, Required UV Doses for Indicators and Targets 2.00E+07 Geomean influent conc. (default 20,000,000) Overview of methodology 1. Site specific testing to determine: • Disinfection requirement (i.e. log removal of target organisms required to meet water quality targets) • Design envelope (UV transmittance vs flow, impact on dose response of various WQ parameters, fouling potential) • Dose-response relationship for target organisms (collimated beam testing) Dose response E.Coli 1.00E+08 E.Coli 5th July E.Coli 4th July 1.00E+06 E.Coli 19th July Geomean Ecoli 1.00E+05 Target concentration /100ml 1.00E+07 1.00E+04 1.00E+03 1.00E+02 1.00E+01 1.00E+00 0 5 10 15 20 25 30 35 40 45 50 55 DOSE (RED) mJ/cm2 60 65 70 75 80 85 Dose-response example Dose – response example UV transmittance Flow to Full Treatment Mean - Inlet Works (l/s) Final Effluent Flow - EA - MEAN (l/s) 500 80 400 60 300 40 200 20 100 flowrate, l/s UV TRANSMISSITY UV CH2 TRANSMISSITY SENSOR 100 0 0 1-Mar-16 0:00:00 1-May-16 4:48:00 1-Jul-16 9:36:00 31-Aug-16 14:24:00 31-Oct-16 19:12:00 1-Jan-17 0:00:00 UV transmittance • Stormwater: >15-20% • Unfiltered final effluent: >30% • Filtered final effluent: >40-50% • Chemically assisted tertiary filtration: >50% • Potential impact of biofilm sloughing (biofilter plants) • Potential impact of trade components can be significant for design UV transmittance and compliance Overview of methodology 2. Specification of UV equipment where dose delivery / performance has been validated Based on achieving desired performance for all target organisms at design conditions: • max flow • minimum UV transmittance e.g Organism Sensitivity, mJ/cm2 per LRV Minimum Validated UV Dose, mJ/cm2 Target log inactivation E. coli 4.8 10.1 2.1 Enterococci 6.7 10.1 1.5 Virus* 20 20 1 *minimum requirement for enterovirus log inactivation for a disinfection process set by EPR 7.01 Overview of methodology 3. Audit reports to demonstrate: • UV dose selection (validated dose permit condition) • dose delivery by selected UV irradiation equipment across design envelope • robust validation (assessment vs UVDGM criteria) Summary • Greater certainty of achieving desired environmental outcome than PSS dose (delivery of validated dose, based on site specific data, to demonstrate performance) • Applicable to stormwater & final effluent discharges (select equipment with appropriate validation envelope) • Opportunity to optimise power & carbon within the limits of turndown of the system • Opportunity to target other specific organisms in the future (e.g. Norovirus) • Provides a level playing field between suppliers / systems to achieve the same performance Considerations for drinking water disinfection Microbial reduction in drinking water Raw water Water treatment Treated water Disinfection Disitribution • What are the challenge organisms in the raw water, how do we quantify them? groundwaters surface waters (reservoirs & rivers) • What level of reduction is provided by upstream treatment processes (if any) ? (USEPA SWTR) • What is the required level of inactivation through disinfection for each organism)? • How much of this can be provided most effectively by UV irradiation / chlorine contact / combination? UV irradiation for potable water • What are the key target organisms for UV irradiation DVGW vs UVDGM • Determining required performance / inactivation • Performance specification • Impact of water quality (UV transmittance) on sizing Target pathogen Hepatitis A Poliovirus Coxsackie virus Adenovirus High High Moderate Resistant 22 (4 log crypto) 34 2 1 <0.5 40 (2 log MS2) >4 34 2 <1 58 (1 log Adenovirus) >4 >4 >2 1 186 (4 log Adenovirus) >4 >4 >4 4 Sensitivity to UV irradiation Log10 inactivation through UV irradiationa validated UV dose based on UVDGM (2006) mJ/cm2 a Log inactivation for Adenovirus is taken from UVDGM, for Hepatitus A virus, Poliovirus and Coxsackie virus the log inactivation given is approximate order of magnitude for comparison purposes only and will be reactor specific. Pathogen Decreasing sensitivity to UV irradiation Cryptosporidium Poliovirus Hepatitis A / Coxsackie virus Human Adenovirus Human Norovirus Increasing sensitivity to chlorine contact What is the impact of UV transmittance on UV system sizing / power / performance? 220 UVT = 90 200 180 UV dose, mJ/cm2 • UVT = 92 160 UVT = 94 140 120 UVT = 96 100 80 UVT = 98 60 40 20 0 20 25 30 35 40 45 Flowrate 50 55 60 65 Summary • Determining disinfection requirements • What is the site specific pathogen challenge(site / catchment specific) • What are the key target organisms • What can be achieved economically using UV irradiation; is it enough? • Specifying performance / UV dose consistently • Organism & target log inactivation • UVGDM / DVGW • Understand impact of UV transmittance on design and operation (e.g. turn down / by-product formation) Design with Community in Mind
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