2014. No.51 Reporting on Today and Tomorrow’s Energy, Environmental and Industrial Technology Featured Article Changing Our Future Society with Nanotechnology and New Materials New Enegy and Industrial Technology Development Organization Toward a Safe, Secure and Prosperous Life Changing Our Future Society with Nanotechnology and New Materials NEDO has been promoting research and development in the fields of new materials and nanotechnology for a long time. As a result, many new materials have been developed and innovation is beginning to take place. New materials will support industries of the future and hold the potential for changing our lives for the better. In this issue we will feature NEDO’s efforts in the areas of materials technology and nanotechnology. C ONTENTS Featured Article Reporting on Today and Tomorrow’s Energy, Environmental, and Industrial Technology 2014. No.51 Changing Our Future Society with Nanotechnology and New Materials ................................................................................... 2 Interview with Takeshi Okada, Director General of NEDO Electronics, Materials Technology and Nanotechnology Department Development of High Value-added Materials Leads to Higher Technology Level of the Manufacturing Industry .......................................................................................................................................... 4 Blending Carbon Nanotubes and Existing Raw Materials Creates New Functions Japanese-born Carbon Nanotubes ............................................................................... 8 Printed Electronics Makes an Eco-Friendly and Convenient Future Life into a Reality Printed Electronics .................................................................................................................. 10 Moving Towards Environmentally-friendly Manufacturing Producing Chemical Materials from Vegetation .......................................... 12 A Search for New Possibilities through Vertical Cooperation Nanotech Challenge Project ............................................................................................ 14 An eco-friendly electrical device that does not use gas with large greenhouse effect p.14-15 Thin and light Braille device p.8-9 By combining pre-existing materials and carbon nanotubes, we are developing new, high-performance materials that had not been feasible to make before with existing materials (Development of Innovative Carbon Nanotube Composite Materials for a Low Carbon Emission Society). With the development of a lightweght and thin Braille device through the use of compound materials with tree resin, it has become possible to attach an electric Braille panel on the surface of such devices as an air conditioner remote control. Through nanotechnology, we are developing a material that can significantly reduce the amount of SF6 gas usage, a gas that is used in the insulator of power devices and has 24,000 times the greenhouse effect as carbon dioxide (Research and Development for Nanotech and Advanced Materials Applications). By replacing SF6 gas used in power devices with compound materials that employ nanotechnology, we can deliver electricity to homes in an environmentally-friendly way. Micro electric generation system that can charge by vibration and doesn’t require batteries p.14-15 Using nanotechnology, we are developing materials that can generate electricity from vibrations around the body semi-permanently (Research and Development for Nanotech and Advanced Materials Applications). A tire air pressure sensor combined with a micro electric generator can keep the driver informed of the car tire status. Making plastic products from plants p.12-13 such as grasses and trees By switching from oil as a raw material for chemical substances to non-edible plants such as grasses and trees, we can solve the problems of oil depletion and global warming (Development of Manufacturing Processes for Chemical Products Derived from Nonedible Plants). Pressure sensor array entry mat notifies a family member when children have returned home p.10-11 Through a sophisticated combination of material technology and printing technology, we are working to manufacture electronic devices that are lightweight and have a large surface area at low-cost and with low energy usage (Development of Materials and Process Technology for Advanced Printed Electronics). We can change the materials used to make familiar plastic products such as shampoo bottles to non-edible plantderived materials. 2 Integrating a large surface area pressure sensor array into a home entry mat can serve many functions, including informing a family member away from home when a child has returned or providing useful information for security, medical or nursing care purposes. 3 NEDO Interview only developing materials technologies, but also supporting collaborative technological development efforts between a variety of companies including materials companies and device companies, with a focus on the final products that will be produced. We believe that NEDO is the only organization that can organize a framework that brings different types of industries together for technological development because of NEDO’s unique identity as a national agency. First of all, what kind of technology is nanotechnology? Okada: It is a technology that controls matter in a domain known as nanometers, that is, 10 to the power of -9 (10-9). In other words, this is technology that manipulates and controls matter on a molecular and atomic scale. When changes are made to matter at the nano-level, properties of matter change and innovative characteristics that previously could not even Supporting Nanotechnology Until be considered appear. Nanotechnology can be used to produce Commercialization novel materials and holds the ability to spark innovation. Since Could you tell us what results have been achieved after working 1992, NEDO has been working on research and development nearly 20 years in the nanotechnology field? in nanotechnology. Okada: For more than two decades, beginning with the What is the significance of NEDO’s efforts in the technological “Atom Technology Project” in 1992, we have supported key development of materials? technology developments in this field through various projects. Okada: The “products” that surround us in everyday life are One representative project to highlight from among those composed of a myriad of substances. For example, liquid crystal would be the “Research and Development for Nanotech displays use multiple film and glass substrates as component and Advanced Materials Applications”. Project applicants materials. One could say that “materials” are the essential foundation for manufacturing. Market Size of Products, Components, and Materials and Market Share of Japanese Companies (Case of Liquid Crystal Displays) In a global context, Japan’s Japanese companies capture a large share of materials sales, but shares of component and final product sales are significantly smaller. material industry has an extremely high level of technical prowess. It Components Products Materials supports the manufacturing industry by offering high-quality parts Color Resist Black Resist and materials that can be used in Color 81.4% 71.3% (85.5 billion yen) (16.5 billion yen) Filters finished products such as cars and communications equipment. NEDO (1,581.2 billion yen) Liquid Crystal Liquid has been engaged in materials Photo Spacer Glass Substrate Crystal Displays research and development to 51% 94.5% (20.7 billion yen) 21% (129.49 billion yen) support the continuous innovations to realize high-quality, high(8992.2 billion yen) Polarizing Plate Polarizing Plate Protective Film functioning materials. Protective Film Polarizing 100% 100% Plates However, when one looks at the (126 billion yen) (149.9 billion yen) 11% position of Japanese enterprises in (851.2 billion yen) the world, their share of the materials Anti-Reflective Film market is high, but the Japanese 94.2% (115.9 billion yen) 58% market share falls as we approach the manufacturing of final products. (Source: Ministry of Economy, Trade and Industry’s 2012 White Paper on Manufacturing Industries (Monodzukuri)). Given this situation, NEDO is not (TAC Film) 4 (Phase difference film with optical compensation) 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 Research and Development for Applications of Advanced Devices and Materials Utilizing Nanotechnology (Nanotech Challenge) (p.14-15) Infrastructure Development to Evaluate Next-generation Advanced Component Development Consortium for Advanced Semiconduct or Materials and Related Technologies Development of Nitride-based semiconductor single Crystal and Epitaxial Growth Technology Rare Metal Substitute Materials Development Project (p.7) Carbon Nanotube Capacitor Development Project Development of Innovative Carbon Nanotube Composite Materials for a Low Carbon Emission Society (p.8-9) Development of Sustainable Hyper Composite Technology Development of Fundamental Technologies for Green-Sustainable Chemical Process Technology Development of Manufacturing Processes for Non-edible Plant-derived Chemicals (p.12-13) Material and Component Area Aiming to expand product share 2005 Energy, Resource, Environment Issues It is well-known that “materials” make a significant contribution to the quality and functionality of final products. Currently, NEDO is promoting the technological development with a focus on nanotechnology and seeking new materials that can contribute to high value-added products. Nanotechnology Information and Acceleration Area Communication Area Development of High Value-added Materials Leads to Higher Technology Level of the Manufacturing Industry Examples of Material-related Projects at NEDO (Nearly 40 materials-related projects over the past 10 years) were required to have a vertical cooperative mechanism linking the upstream organizations that have the innovative nanotechnology seed technology with the downstream organizations that would be responsible for commercialization. This was a new approach. This vertical cooperative mechanism crossing the boundary between different business fields proved successful. Many of the development projects progressed rapidly and I know many cases that have advanced very close to commercialization. (see p. 14). Another case to highlight is “carbon nanotubes (CNT)”. This is a carbon material ordered at the nano-level that displays amazing properties in electrical conductivity, thermal conductivity, and strength. In 1991 CNT was discovered by Dr. Sumio Iijima, who was at NEC (Nippon Electric Company, Ltd.) at the time. NEDO has been engaged in development of this technology from 1998 to the present. In particular, the target of our current program, “Development of Innovative Carbon Nanotube Composite Materials for a Low Carbon Emission Society,” is the “single-walled CNT,” which is difficult to make practical but we are making steady progress in advancing the concept from fundamental technology to product development. Development of Fundamental Evaluation Technology for Next-Generation Chemical Materials Development of Materials and Process Technology for Advanced Printed Electronics (p.10-11) Based on this effort, the arrival of products utilizing singlewalled CNT technology is just around the corner. (see p. 8). Bringing about new materials is challenging and time consuming, and it is not easy for companies to continue on alone. We think that it is NEDO’s role to support technological development efforts of companies on a mid- to long-term perspective. Technology Seed Matching and Technological Development for Our Future Society In terms of nanotechnology development, where does NEDO plan to focus? Okada: As I mentioned earlier, it is important to utilize newly developed materials in products in order to commercialize material technologies. For this reason, NEDO is working to match “materials with new properties” up with “utility”. Director General, NEDO Electronics, Materials Technology and Nanotechnology Department Takeshi Okada Profile Graduated from the Tokyo University Department of Engineering in 1991 with a degree in Aviation Engineering. Past positions include Director of Regional Economy, Chubu Bureau of Economy, Trade and Industry at the Ministry of Economy, Trade and Industry, and Director of IT Project Office, Information Policy Bureau, Commerce and Information Policy Division. After having served as Counselor at the CIO (Chief Information Officer) Office of the Cabinet Secretariat, he has been on loan to the New Energy and Industrial Technology General Development Organization (NEDO) since 2013. 5 Scheme of “Research and Development for Nanotech and Advanced Materials Applications” Responsible for Core Technology Responsible for Device Development Application Responsible for Product Development etc. Example of Research Framework 5 New Industries to Contribute Project Selection • Nanoimprint • Precise beam processing • Thin film growth • Self-organization, self-assembly • Nano space • Nano fiber • Advanced material interface control • Nanomeasurement evaluation Upstream and Downstream Vertical Cooperative Research Framework Leading Research Stage Awarding 100% of cost Stage I Max. 70 million yen annually per project NEDO covers the total project cost Evaluation using Stage Gate Innovative nanotechnology Commercialization Research Stage Awarding 2/3 of cost Stage II Max. 200 million yen annually per project NEDO covers 2/3 of the total project cost Fuel Cells Robotics Information and Communications Technology Health Care Devices & Services Energy and Environmental Devices & Services ※ No new active solicitations for either Stage I or II Specifically, we are working actively to provide matching services by providing samples throughout the duration of projects we support and attending exhibits and industry shows such as “nano tech.” By promoting exchanges within different types of industries, we anticipate expanding the use of developed technologies to a wide array of applications. In addition, we believe it is important to clarify the potential industrial applications in order to encourage commercialization. Thus we listen to the opinions of companies and experts to map out a vision of future society. Then we move on to technology development with a clear focus on the most important industrial applications. Supporting Industry with Innovative Materials Finally, I would like to hear what the outlook on the future of materials looks like. Okada: Materials are the essential technology that supports manufacturing and I think that in order to improve the technological level of our industry, Japan needs to pay attention to this area. Although nanotechnology and materials technology were designated as one of the strategic areas in Japan’s Third Science and Technology Basic Plan, it is not clearly designated as such in the Fourth Plan. However, other Western countries have been aggressively pursuing research and development activities in this area. For example, the US has launched MGI *1 and the EU’s HORIZON 2020*2 designates nanotechnology and materials technology as industry-leading technological priorities. In Asia, South Korea has launched the Third Korean Nanotechnology Initiative. Around the world countries are putting forward clear strategies for technology development in the nanotechnology and materials technology areas. NEDO has also developed a roadmap to create a vision of our future society and to help identify what kind of technology will be needed by when through research of recent technology trends. This roadmap describes our strategy to sustain Japan’s technology level. Although until recently materials development has been mainly focused on the fields of energy, electrics and electronics, we are paying attention to the construction and healthcare fields as we anticipate even more growth in those areas. We will continue our development activities with the goal of supporting the manufacturing industry through the creation of innovative materials using nanotechnology *1 M GI: Material Genome Initiative. One of the major US initiatives in nanotechnology and materials technology. It has a very bold goal to halve the time required from research to commercialization of new materials. *2 HORIZON2020: Research and development program in Europe. Alleviating concerns of Rare Metal Supply with the “Technological Competence as Our Resource” Rare metals are called “industrial vitamins” as they have the effect of enhancing special properties in materials. However, with rare metal prices soaring in 2010 amid a tightening of market supply, procurement of these materials has become an issue. Since 2008, before concerns of rare metal supply came to the attention of the public, NEDO has been strategically promoting the technology development that focuses on rare metals from a range of perspectives. Specifically, we have conducted risk surveys of the supply chain, the supply-demand balance and the impact on industries, and we have set technological development themes for each rare metals and application. In addition, we are actively engaging in international cooperation in this field to advance research and development activities in related areas. For example, NEDO signed an MOU on effective use of rare metals with Ames Laboratory in the U.S. to promote cooperation and information exchange between the two organizations. Under our “Rare Metal Substitute Materials Development Project,” NEDO supports projects that work on 14 themes with NEDO signed a MOU on effective use of rare metals with the U.S. Department of Energy’s Ames Laboratory (September 9, 2013) Dysprosium 40% reduction 40% Platinum group metals reduction Exhaust purification catalysts 6 5 Key Review Points Supply (reserve production ratio) Demand Price (rate of growth) Degree of country concentration Recycling Rate 3 Policy Review Points + Country risk Impact on our domestic industrial competitiveness Availability of technologies to replace metals and reduce amount of usage The risk survey of rare metals was performed using 5 key review points and 3 policy review points to identify target mineral types and goal reduction amounts. 6 rare metals, including tungsten, dysprosium, cerium, indium, and platinum group metals. With regards to cerium, glass polishing pads using 50% less cerium than similar polishing pads have already reached the market. Similarly, we are close to commercializing super hard tools with a 50% reduced use of tungsten compared with conventional tools and no loss in performance. The rising price of rare metals in 2010 was one of the reasons why we launched the “Development of Technology to Reduce Rare Elements Use and Development of Alternative Material.” This project aims to reduce the rare metal supply risk, and NEDO has implemented approximately 60 themes within the project up to the present. We are steadily making progress and anticipate new products to emerge from the project in the future. Going forward NEDO will alleviate concerns about the supply of rare metals by leveraging the “technological competence as our resource.” Primary Products with Reduced Rare Metals Indium Hybrid vehicle motors Ricoh Company, Ltd. developed a prototype of flexible color electronic paper. Risk Survey Structure 50% reduction Liquid crystal televisions Cerium 50% reduction Glass for liquid crystal panels Tungsten 30% reduction Super-hard tools 55% Terbium/Europium reduction Fluorescent lights Single wall carbon nanotubes manufactured by Technology Research Association for Single Wall Carbon Nanotubes (TASC) 7 Blending Carbon Nanotubes and Existing Raw Materials Creates New Functions Japanese-born Carbon Nanotubes Carbon nanotubes, discovered by a Japanese researcher in 1991, are garnering attention as a revolutionary material that enables a variety of novel functions. When mixed with pre-existing materials such as rubber, or polymers resin and metals, the resulting compounds can display astounding properties. NEDO is Electronics, Materials Technology and Nanotechnology Department rapidly developing an array of compound materials that use carbon nanotubes. Shoichi Fujimoto Occupying a central place in the nanotechnology field due to its unique structure and physical properties Carbon nanotubes (CNT) are a tube-shaped nano-material made from carbon that was discovered in Japan. The size of a nanotube is between 1 and 10 nanometers (nm) and is roughly the same size as DNA (diameter of 2 nm). Although invisible to the human eye, since its discovery many fascinating functions of CNT have come to light given its unique structure and physical properties. It has become a central technology in nanotechnology researches. From a structural standpoint, CNT is divided into two types: multi-wall CNT and single wall CNT. Since production of multi-wall CNT is relatively easily produced, million tons are produced around the globe annually, and practical applications as components of batteries and capacitors are advancing. Compared to multi-wall CNT, single wall CNT has many superior qualities, including a larger surface area and extremely high conductivity of electricity and heat. For these reasons, by blending it with a variety of pre-existing materials, we can develop new functional materials with unforeseen levels of performance and unique qualities. For example, when even a small amount of single wall CNT is blended with aluminum, it can conduct heat 2-2.5 times more efficiently than copper, a metal with one of the highest rates of thermal conductivity. For this reason, we anticipate revolutionary applications in lightweight materials with high thermal emissivity, lightweight materials with high durability, and materials for use in highly efficient electronic circuits. Nonetheless, there are significant obstacles that remain in the way of further practical development of single wall CNT technology, given that the techniques necessary to produce, separate and purify single wall CNT, as well as control the physical properties of this kind of composite materials, have not been fully developed yet. Characteristics and Applications of CNT Composite Materials Commercializing Heatsinks for Invertors and Small Actuators Recognizing the challenges, NEDO is developing core technologies for creating CNT-based compound materials, including necessary technologies to control the structure and physical properties of compound materials as well as separate and purify the materials, with a focus on single wall CNT-based technologies. At the same time, we are developing technologies that can be used for simple voluntary safety management of essential nanomaterials with the goal of popularizing single wall CNT. One product that is already close to commercialization is a heatsink for a motor invertor which was developed by combining it with aluminum. We believe that this new component could be utilized as part of aircraft electronic technologies such as the electric hydraulic actuators used in controls. This new compound allows the heat from electronic circuits to escape more efficiently, making it possible to use less electricity to cool them and to extend the life of electronic circuitry. Furthermore, as it is approximately 10% lighter than aluminum, the material will be useful in improving fuel efficiency. In addition, we are currently working towards a commercialization goal to develop applications for invertors for electric motors. Once completed, it is expected that performance will be improved over traditional invertors by as much as 25%. As a result, automobiles and train cars equipped with these invertors will be more environmentally friendly. We are also making progress creating flexible electrical 20nm Single Wall CNT Technology Research Association for Single Wall Carbon Nanotubes (TASC) Rubber with thermal conductive rate similar to iron 3 High electrical conductivity etc. A tubular nanomaterial made from carbon. NEDO and the National Institute of Advanced Industrial Science and Technology (AIST) have developed a highly effective method of creating single wall CNT. It makes it possible to manufacture high quality single wall CNT with characteristics of high purity, high electrical conductivity, and high-specific surface area. 8 Future all-electric airplane (conceptual drawing) Electric hydraulic actuator for flight control Butterfly that flaps its wings (ALPS ELECTRIC CO., LTD.) Carbon fiber compound materials Heatsink of power device eDIPS method The individual minute fibers are single wall CNT. Diagram of single wall CNT Composite material with single wall CNT and aluminum has 2-4 times the high thermal conductive properties of aluminum and releases heat rapidly. Prototype butterfly that flaps its wings. Wing parts use thin, lightweight and highly durable actuators developed with a composite of single wall CNT and tree resin 2 Becomes a semiconductor based on structure 4 High thermal conductivity, Left: aluminum; Right: highly thermal conductive composite material Super-growth method 1 Lightweight and high durability 50nm Thermal transfer experiment (TASC) Examples of Possible Applications of CNT Compound Materials rubber, tree resin, metal and other materials Enlarged photo elements by blending single wall CNT with resin. In actuators that utilize these elements, the power generated is more than 20 times greater than conventional models per unit weight, and it is highly anticipated that the actuators can make drive devices lighter and smaller. Furthermore, we are developing Braille displays and artificial muscles using this actuator, and see practical applications in the near future. In order to expand the possible applications of single wall CNT, NEDO is providing samples of compound materials to a range of industries. We hope that innovative products utilizing these compounds will emerge in the future. High strength materials CNT fibers CNT ink Electronic circuitry parts CNT thin film transistor Transparent electrical conductivity film Electrically conductive rubber Sensor material High performance heat conductive material Transparent conductive film Super-growth method and eDIPS method: Method to combine single wall CNT being developed by this project. Braille device (ALPS ELECTRIC CO., LTD.) Development of a lightweight and thin Braille device was feasible with a composite of single wall CNT and tree resin. 9 Printed Electronics Makes an Eco-Friendly and Convenient Future Life into a Reality Printed Electronics There are organic EL lighting on the ceiling, and a thin, sheet-type display mounted on the wall. An organic EL curtain is hanging in the window. A wireless charging sheet is on the table, and your smartphone and other devices laying on the sheet will be automatically charged wirelessly. All the electricity is generated by a thin, flexible solar panel installed on the roof. In the near future, flexible electronic devices enabled by new printing technology hold Electronics, Materials Technology and Nanotechnology Department Printed electronics refers to electronic circuitry and other electronic devices manufactured using printing technology. Simply put, it is the technique by which things like tablet terminals are created through a printing process. The primary characteristics of printed electronics are that they are thin, lightweight and flexible. For this reason, a wide variety of applications for the technology are expected. In 2010 NEDO launched the “Development of Materials and Process Technology for Advanced Printed Electronics” project and has been supporting both a contract project to develop core technologies for printed electronics and a grant project to develop practically applicable technologies. JAPERA (Japan Advanced Printed Electronics Technology Research Association) is responsible for the contract project, and Ricoh, Toppan Printing, and Dai Nippon Printing were selected for the grant project. Each participant sets its own technological development agenda to work on. 27 Japanese manufacturing companies and one research institution are participating in JAPERA, and their industries Printed electronics manufacturing process (JAPERA) Flexible device (JAPERA) Technology that manufactures flexible electronic devices through printing. High performance is achieved by combining materials and printing technologies in a sophisticated manner. 10 electronics is possible, including lighting and sensors. Since these can be connected to other things, it is possible to attach electronic displays around circular pillars or directly to the surface of a wall, or even make the entire floor a pressure sensitive sensor. In the future, great changes could happen in our homes with printed electronic products placed all around us. We are continuing to advance research and development on this subject, anticipating that printed electronics will help realizing an even more eco-friendly and convenient lifestyle. Kenta Goto the possibility of making our future and our lives ecologically sound and extremely convenient. Promoting Cutting-Edge Research and Development by Gathering Industry Knowledge that requires a highly sophisticated combination of materials, manufacturing processes, machinery and devices, it is not something that anyone could easily duplicate on their own. Also, since this technology makes it possible to manufacture devices via printing, there is the potential to reduce manufacturing costs significantly. As part of the project NEDO is currently engaged, we have been able to produce prototypes of small electronic paper displays and pressure sensors. Ultimately, we plan to make these products with larger surface areas and with higher precision. In addition, a range of other applications for printed range widely from materials and semiconductors to consumer electronics to printing. Since Japan already has a number of companies that have highly advanced technologies in a variety of fields, our goal is to establish printed electronic technologies that will lead the world by gathering their knowledge together. Competitions among countries are becoming fierce in regards to technology development. Application examples of flexible electronic devices Printed electronics makes possible such devices as thin and flexible color electronic paper displays, induction charging sheets (a device that cordlessly charges cell phones or other devices via wireless transmission of energy), and digital signage. In addition, by manufacturing large surface area pressure sensor array, printed electronics could see applications as portable flexible sensors, bed sore prevention sensors for medical and nursing care, and footstep sensors for crime prevention. Technology to bring innovation to the electronics industry One of the reasons why NEDO is putting resources into this area of technology is the need for innovation in the electronics industry. Currently, with regards to products such as liquid crystal displays, since they now can be made relatively easily by setting up manufacturing devices, low-cost products have captured the majority of the market share. However, as printed electronics is a manufacturing method Electronic price tags (TOPPAN PRINTING CO., LTD.) A lightweight, flexible electronic price tag. Although electricity is used when generating the image and letters, no electricity is needed to continue displaying the information, making it a low-energy system. Flexible TFT sheet (JAPERA) Pressure sensor array (Dai Nippon Printing Co., Ltd.) Electronic paper Digital signage (Electronic billboard) Induction charging sheet Flexible sensor Healthcare sensor device Footstep monitoring device 11 Moving Towards Environmentally-friendly Manufacturing Four Features of Cellulose Nano Fiber Producing Chemical Materials from Vegetation (1) Increased strength through surface modification techniques (2) Improved productivity by simplifying the production process (3) Weight reduction via foam molding (4) Various color expressions through the use of pigments NEDO is working on manufacturing chemical materials such as plastic from grasses and trees. We are aiming to develop manufacturing techniques that use non-edible grasses and trees as the raw material rather than edible plants such as corn. We are also developing high performance materials that did Electronics, Materials Technology and Nanotechnology Department not exist before by utilizing high strength “wood fibers.” In the future, the chemical materials that are pervasive in our everyday life may be replaced by Kaoru Hashimoto materials that come from plants. Adapted from M. Harrington, 1996 Cellulose Nano Fiber Cellulose nano fiber can be obtained from plant fiber (cellulose) extracted from wood and unraveled to reach a fine, nano scale. Substituting Plant-derived Materials for Petroleum-based Raw Materials The majority of chemicals such as plastic in use today require petroleum to produce. Accounting for nearly 23% of Japan’s petroleum consumption, the production of chemicals from petroleum uses large quantities of oil resources. Furthermore, the CO2 emissions from the production of chemical products in Japan accounts for about 13% of all industrial emissions and 5% of nationwide CO2 emissions. At the same time, we are encountering such problems as the Cellulose Chemical makers Universities Paper manufacturers Users Petroleum chemicals Engaging in development activities to move away from oil-derived raw materials by having paper manufacturers, chemical makers, universities and users working together. Cellulose-derived intermediate product • Engineering plastic • Thermosetting resin Hemicellulose Wood biomass Lignin Hemicellulose-derived intermediate products Lignin-derived intermediate products • General purpose chemical products • Functional chemical products soaring price of petroleum and the depletion of oil reserves caused by the increasing global demand for oil, and climate change in connection with increased CO2 emissions. For these reasons, NEDO is promoting a project that utilizes raw materials derived from various plants to reduce our reliance on oil as a raw material for chemical products. Production of Chemical Materials from Non-edible Plants Among plants that can be used as raw materials (as known as biomass), there is edible biomass such as corn and sugarcane that can also be food, and there is also non-edible biomass including grasses and trees that are not used as food sources. In order to avoid disrupting the food supply, NEDO is working on a project to make chemical materials from non-edible biomass. In addition, we are working to develop this technology through a vertical cooperative structure with over 20 participating companies and universities, connecting paper manufacturers with access to raw materials, universities that are developing core technologies, and chemical companies. Moving towards practical applications in a wide range of industrial fields, including automobiles, consumer electronics, construction materials and packaging. creating final products with high added value, we can achieve product manufacturing with a competitive cost. Lighter and Stronger Plant Materials for Automobiles One of these products is “cellulose nano fiber (CNF).” It is possible to extract this material through careful unravelling of cellulose, a basic plant fiber, at a nanoscopic scale. CNF has the exceptional characteristic of being 5 times stronger than iron. Through a technique which blends CNF and tree resin developed by the NEDO project, we have successfully developed a composite material that is lightweight and very strong. When this material is used in automobiles, it can significantly reduce the weight of the vehicle chassis and improve fuel efficiency. In fiscal year 2014, a pilot plant designed to offer samples is scheduled to be completed. In the future, we hope to replace the petroleum-derived chemical products currently surrounding us in everyday life with products derived from plant biomass, from plant biomass. Developing a Competitive Manufacturing Process Eucommia ulmoides Crude polyisoprene Furfural Purified polyisoprene • Polyurethane raw material • Impact resistant raw bio-materials, etc. The peel of a seed (Sustainable biomass part) Development of viable ingredient separation technology Development of technology to manufacture intermediate and final chemical products from viable ingredients (catalyst and fermentation technologies) Development of complete manufacturing process from raw materials to final chemical products Project overview: The goal of this project is to establish a manufacturing process for chemical products using viable ingredients extracted from plants. 12 Currently there are a number of practical applications for chemical materials manufactured from edible biomass, but in terms of production from non-edible biomass costs have not reached a point suitable for practical applications despite the rigorous pursuit of research and development activities. For this reason, as part of this project we aim to reduce costs across the entire manufacturing process for chemicals derived from non-edible biomass and we are working to develop a process that effectively utilizes each ingredient of cellulose, hemicellulose and lignin that compose grasses and trees. By enabling the effective use of those three components and 13 stage). Once Stage I was completed, a stage gate review is performed and only promising themes move forward to Stage II. In this way, we can continually support themes that showed exceptional results in Stage I through until they achieve practical applications. Of the 78 topics researched up until now, a number of them are close to achieving practical applications. A Search for New Possibilities through Vertical Cooperation Nanotech Challenge Project Nanotechnology is a fundamental technology that has been the basis of technological innovations in a diverse range of industrial fields including consumer electronics, Electronics, Materials Technology and Nanotechnology Department environment, energy and healthcare. NEDO is promoting research and development projects to accelerate the commercialization of nanotechnology. One example of our Taro Kimura efforts is the “Nanotech Challenge.” Some projects have already achieved excellent results, and several innovations are progressing towards practical applications. Advancing commercialization of seed technologies through vertical cooperation between upstream and downstream organizations Nano Composite Insulation Material (TOSHIBA CORPORATION) Illustration and microscope photographs of nano composite materials. Uniform dispersal of nano particles enables increased insulation properties and better equipment reliability. This reduces SF6 which has an extremely high greenhouse gas effect. SF6 gas Smaller, lighter and no SF6 gas usage 14 Solid insulation system SF6 gas insulation system Components for electric device (switch gear) made from newly developed materials High voltage section (conductor) Switch (vacuum bulb) Nano composite insulating material (surface ground) Strictly controlled, used in sealed tank Metal box Replace SF6 gas with solid insulating material Removal of gasified sulfur hexafluoride (SF6) from switch gear using solid insulation One of those technologies is the nano composite insulating material to create an electric device that is environmentally friendly. Traditional powerdivice needed to use sulfur hexafluoride (SF6) - a gas that has nearly 24,000 times the greenhouse effect as CO2 - for insulation from high voltage components. To reduce the use of SF6, we have developed a nano composite material with high insulation properties by equally dispersing nano particles throughout an epoxy resin used on the periphery of the high voltage components. At Stage I, universities performed materials development and evaluation of the insulation properties. At Stage II, Kunimine Industries and Sanyu Gikou developed mass production technology for the materials. Toshiba took the lead in the project and manage each stage and its participants. Using this newly developed material, we have been successful in producing a prototype electric device model (a switch gear). Currently Toshiba is exploring the possibility of adopting this in its electric device products. Another example is a small-scale vibrating electric generator developed cooperatively by Omron Corporation and Asahi Glass. The device is about the size of a 100 yen coin, and it can efficiently convert minute vibrations into electrical energy. With nanotechnology, it has become possible to acquire electric power from the environment by converting weak vibrations to electricity using a material called electret. Although this power source component is small, it is able to obtain sufficient electricity to operate a sensor. Since there is no need to replace the power source or use an electrical wire, maintenance is extremely easy. We believe that this would be ideal for sensors that monitor the safety of buildings, bridges and roads. In addition, there could be an extremely wide range of applications such as in health, healthcare and welfare devices, as well as portable electronic devices. The third example is an air filter that uses nano fibers. We developed an air purifying filter that uses extremely little energy due to reduced pressure loss that also has dust removal, antibacterial, deodorizing and dehumidifying capabilities. Since it uses nano fibers, this extremely precise filter can catch PM2.5 (particulate matter smaller than Micro Vibration Electric Generator (OMRON Corporation) Small scale device converts minute vibrations into electricity. Semi-permanent, maintenancefree device. Application Examples of Micro Vibration Power Generation One NEDO project that has emphasized the importance of nanotechnology is “Research and Development for Nanotech and Advanced Materials Applications (also known as the “Nanotech Challenge”)”, which was launched in 2005. Although nanotechnology was highly anticipated as a new technology at the time, somehow practical applications did not readily emerge. This was due to a number of problems, such as the long time required to develop practical applications and, despite the wide-range of applications for the technology envisioned, the lack of particular connections between research and the final applications. We began the Nanotech Challenge with the goal of resolving these problems. This project solicited research themes from applicants, and one of the unique aspects of this project was that it required a vertical cooperation between universities and material makers (upstream organization) and product manufacturers (downstream organizations). We believed that facilitating collaboration between different businesses and industries would lead to a better understanding of user needs and accelerate commercialization of seed technology by university and companies. Another unique aspect of the project was how we divided the R&D period into two parts: Stage I (the leading research stage) and Stage II (practical application research Innovative Products Using Nanotechnology will Emerge One after Another in the Future 2.5 micrometers) particles, pollen and even viruse. Due to low pressure loss, it also contributes to reduced energy consumption. We are planning to market the product for a variety of uses, and we are promoting practical applications of the filter that fit the needs of users such as hospitals and food production facilities as well as semiconductor plants. Beyond these technologies, we are continuing to develop a range of products, and in the near future we hope that the project will have an impact on many different fields and lead to products that improve our quality of living. Social Infrastructure • Highways • Railways (rails) • Bridges • BEMS [Building Energy Management Systems] Transportation Devices • Airplanes • Automobiles • Trains • Bicycles Factories • Motors • Robots • Conveyor Belts Living Space • Consumer electronics (washing machines, vacuum cleaners) • Health devices (pedometers, heart rate monitors, blood pressure manometers, blood glucose monitors) • Cell phones • Clocks/Watches • Electric razors • HEMS [Home Energy Management System] • BAN [Body Area Network] Highly Efficient Nano Filter (JAPAN AIR FILTER Co., Ltd.) Exhaust Outside air Ventilation (1) (2) Purified, humidity-controlled air (3) 100nm (1) Nano fiber for odor elimination (100 nm) New product (2) Anti-bacterial nano composite fiber (3) Fluorocarbon polymer nano fiber for humidity control Diagram of filter module structure and electron microscope photograph of nano fiber 15 Domestic Offices Kansai Branch Office Head Office Umeda Dai Building, 6F, 3-3-10 Umeda, Kita-ku Osaka 530-0001 Japan Tel: +81-6-7670-2200 Fax: +81-6-6344-4574 MUZA Kawasaki Central Tower, 16F-20F 1310 Omiya-cho, Saiwai-ku Kawasaki City, Kanagawa 212-8554 Japan Tel: +81-44-520-5100 Fax: +81-44-520-5103 Overseas Offices Washington 2000 L Street, N.W., Suite 605 Washington, D.C. 20036 U.S.A. Tel: +1-202-822-9298 Fax: +1-202-822-9289 Silicon Valley 3945 Freedom Circle, Suite 790 Santa Clara, CA 95054 U.S.A. Tel: +1-408-567-8033 Fax: +1-408-567-9831 Europe 10, rue de la Paix 75002 Paris, France Tel: +33-1-4450-1828 Fax: +33-1-4450-1829 New Delhi 7th Floor, Hotel Le Meridien Commercial Tower, Raisina Road New Delhi 110 001, India Tel: +91-11-4351-0101 Fax: +91-11-4351-0102 Beijing 2001 Chang Fu Gong Office Building Jia-26, Jian Guo Men Wai Street Beijing 100022, P.R. China Tel: +86-10-6526-3510 Fax: +86-10-6526-3513 Bangkok 8th Floor, Sindhorn Building Tower 2 130-132 Wittayu Road, Lumphini Pathumwan Bangkok 10330, Thailand Tel: +66-2-256-6725 Fax: +66-2-256-6727 New Energy and Industrial Technology Development Organization MUZA Kawasaki Central Tower, 1310 Omiya-cho, Saiwai-ku Kawasaki City, Kanagawa 212-8554 Japan Tel: +81-44-520-5100 Fax: +81-44-520-5103 URL: http://www.nedo.go.jp/english/index.html September 2014
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