Chapter 1 Introduction The advancement in the subject of fluid dynamics was started in 1755 when Euler gave his famous equations of fluid flow for ideal (inviscid) fluids in his paper entitled ”General principles of the motion of fluids”. Fluid dynamics is a subset of that science that looks at the materials which are in motion. Hydrodynamics looks specifically at liquids in motion. Fluid dynamics refers to a subcategory of the science of fluid mechanics, with the other subcategory being fluid statics, which deals with fluids that are at rest while fluid dynamics is concerned with fluids that are in motion. Any matter in a gas or liquid state can be considered as a fluid. Fluid dynamics is governed by the laws of conservation which states that the total amount of energy, mass, and linear momentum in a closed system remain constant, and that energy and mass can neither be created nor destroyed. They may change forms but cannot disappear. This law constitute some of the most basic assumptions in science. Another governing principle of fluid dynamics is the continuum assumption, also called the continuum hypothesis. Fluids are known to be composed of microscopic, discret particles, thus this hypothesis states that they are continuous, and that their properties vary evenly throughout. The history of fluid dynamics can be found in Rouse and Ince (1957) and Tokaty (1971). Anderson (1997) presented the history of both fluid dynamics and aerodynamics. 1.1 Scope and Motivation The stretching surface in a quiescent or moving fluid is important in number of industrial manufacturing processes that includes both metal and polymer sheets. An interesting fluid mechanical application is found in polymer extrusion processes, where the object 8 CHAPTER 1. INTRODUCTION 9 on passing between two closely placed vertical solid blocks is stretched in a region of fluid-saturated porous medium. The stretching imparts a unidirectional orientation to the extrudate, thereby improving its mechanical properties. The liquid is meant to cool the stretching sheet whose property depends greatly on the rate at which it is cooled and stretched in porous medium. The fluid mechanical properties desired for the outcome of such a process depends mainly on the rate of cooling and the stretching rate. It is important that proper cooing fluid is chosen and flow of the cooling liquid caused due to the stretching sheet can be controlled so as to arrive to the desired properties for the outcome. As a result, one has to pay considerable amount of attention for both flow and heat transfer characteristic of the cooling fluid. The quality of the final product depends on the rate of heat transfer at the stretching surface. The temperature distribution, thickness and width reduction are function of draw ratio and stretching distance. It is worth mentioning that there are several practical applications in which significant temperature differences between the body surface and the ambient fluid exist. The temperature differences cause density gradients in the fluid medium and free convection effects become more important in the presence of gravitational force. There arise some situations where the stretching sheet moves vertically in the cooling liquid. In this situation, the fluid flow and the heat transfer characteristic are determined by two mechanisms namely, the motion of stretching sheet and the buoyancy force. Convection heat transfer and fluid flow through porous medium is a phenomenon of great interest from both theoretical and practical point of view because of its applications in many engineering and geophysical fields such as geothermal and petroleum resources, solid matrix heat exchanges, thermal insulation drying of porous solids, enhanced oil recovery, cooling of nuclear reactors and other practical interesting designs. The possible use of porous media adjacent to surfaces to enhance heat transfer characteristics have lead to extensive research in heat transfer and flows over bodies embedded in a porous media. Physically, the problem of mixed convection flow past a stretching sheet embedded in a porous medium arise in some metallurgical processes which involve the cooling of continuous strips or filaments by drawing them through quiescent fluid and the rate of cooling can be better controlled and final product of desired characteristics can be achieved if the strips are drawn through porous media. A new dimension is added to the study of mixed convection flow past a stretching sheet embedded in a porous medium by considering the effect of thermal radiation. Radiative heat transfer flow is very important in manufacturing industries for the design CHAPTER 1. INTRODUCTION 10 of reliable equipments, nuclear plants, gas turbines and various propulsion devices for aircraft, missiles, satellites and space vehicles. Also, the effect of thermal radiation on the forced and free convection flows are important in the content of space technology and processes involving high temperature. Thermal radiation effect plays a significant role in controlling heat transfer process in polymer processing industry. The quality of the final product depends to a certain extent on heat controlling factors. Also, the effect of thermal radiation on flow and heat transfer processes is of major important in the design of many advanced energy convection systems which operate at high temperature. Thermal radiation occurring within these systems is usually the result of emission by the hot walls and the working fluid. Thermal radiation effects become more important when the difference between the surface and the ambient temperature is large. Thus thermal radiation is one of the vital factors controlling the heat and mass transfer. Another important effect of considering thermal radiation is to enhance the thermal diffusivity of the cooling liquid in the stretching sheet problem. Thus the knowledge of radiation heat transfer in the system can perhaps lead to a desired product with sought characteristics. The study of magnetohydrodynamic (MHD) flow of an electrically conducting fluid in the boundary layer flow due to the stretching of the sheet is of considerable interest in modern metallurgical and metal-working process. Many metallic materials are manufactured after they have been refined sufficiently in the molten state. Therefore, it is a central problem in metallurgical chemistry to study the heat transfer on liquid metal which is perfect electric conductor. Thus a careful examination of the needs in the system suggests that it is advantageous to have a controlled cooling system. An electrically conducting liquid can be regulated by external means through a variable magnetic field. The problem is a prototype for many other practical problems also, similar to those of polymer extrusion processes. The thermal-diffusion and diffusion-thermo effects are interesting macroscopically physical phenomenon in fluid mechanics. The heat transfer caused by concentration gradient is called the diffusion-thermo or Dufour effect. On the other hand, mass transfer caused by temperature gradients is called Soret or thermal diffusion effect. Thus Soret effect is referred to species differentiation developing in an initial homogeneous mixture submitted to a thermal gradient and the Dufour effect referred to the heat flux produced by a concentration gradient. Usually, in heat and mass transfer problems the variation of density with temperature and concentration give rise to a combined buoyancy force under natural convection. The heat and mass transfer simultaneously affect each other that create CHAPTER 1. INTRODUCTION 11 cross-diffusion effect. Soret and Dufour effects have been found to appreciably influence the flow field in mixed convection boundary layer over a vertical surface embedded in a porous medium. In many practical applications mass transfer takes place by diffusive operations which involve the molecular diffusion of species in the presence of two types of chemical reactions namely, homogeneous and heterogeneous. The diffusive species can be generated or absorbed due to different types of chemical reaction with the ambient fluid which can greatly affect the properties and quality of finished products. Thus the study of heat and mass transfer in the presence of chemical reaction is of great practical importance to engineers and scientists in many branches of science and engineering. In view of the above mentioned applications, it is important to study the boundary layer viscous flow over moving surface in porous media with heat and mass transfer considering various aspects of the physical properties of the fluid in the Ph.D. thesis work. Numerical methods is employed to solve the momentum, energy and mass-diffusion equations by considering effects of thermal radiation, variable viscosity and thermal conductivity, buoyancy force, magnetic and electric field, viscous dissipation and Ohmic heating, non-uniform heat source/sink, non-Darcy (or second order quadratic drag) effects in the porous medium. Also, two different types of boundary conditions for heat transfer analysis, namely the prescribed surface temperature (PST) and the prescribed surface heat flux (PHF) conditions are considered for the problems investigated in the thesis, more emphasis is given on the effects of thermal radiation on heat and mass transfer problems in porous medium of constant porosity and on related work with Soret and Dufour effects with first-order chemical reaction. Motivated by the above studies, in the present study emphasis is given on MHD convective heat and mass transfer from a vertical stretching sheet embedded in a porous medium considering Darcy and Darcy-Forchheimer-Brinkman flow models. The flow is subjected to a transverse magnetic field normal to the plate. The problem addressed here is a fundamental one that arise in many practical situations such as polymer extrusion process. Highly non-linear momentum and heat transfer equations are solved numerically using fifth-order Runge-Kutta Fehlberg method with shooting technique. The effects of various parameters on the velocity and temperature profiles as well as on local skin-friction co-efficient and local Nusselt number are presented graphically and in tabulated form. The effect of thermal radiation, variable viscosity, viscous dissipation and Ohmic heating on MHD non-Darcy mass diffusion of species over a continuous stretching sheet with electric CHAPTER 1. INTRODUCTION 12 and magnetic fields subject to a transverse magnetic field normal to the plate would also be taken up. Two different types of boundary conditions for heat transfer analysis, namely the prescribed surface temperature (PST) and the prescribed surface heat flux (PHF) conditions are considered. It is also important to study the unsteady two-dimensional MHD non-Darcian mixed convection heat and mass transfer past a semi-infinite vertical permeable plate embedded in a porous medium in the presence of Soret and Dufour effects with suction or injection, thermal radiation and first-order chemical reaction. The problems are important in many practical situations such as polymer extrusion process and would also be useful in magnetic material processing and chemical engineering systems. 1.2 Classification of Fluids Fluids are in general classified in the following categories: 1.2.1 Ideal and Real Fluids The ideal fluids are those which are incapable of sustaining any tangential force (shearing stresses) or action in the form of shear but the normal force (pressure) acts between the adjoining layers of fluid. This means that an ideal fluid offers no internal resistance to change its shape. Ideal fluids are also known as inviscid fluids or perfect fluids or frictionless fluids. Those fluids which have low viscosity such as air, water etc. may be treated as ideal fluids. Real fluids are known as viscous fluids. A fluid is said to be viscous when normal as well as shearing stresses exist. Due to shearing stress a viscous fluid offers resistance to the body moving through it as well as between the particles of the fluid itself. Heavy oils and syrup may be treated as viscous fluids. Water and air flow much easier than syrup and heavy oil which demonstrate the existence of a property of the fluid which controls the rate of fluid flow. This property of fluids is known as viscosity or internal friction. Viscous fluids when compared with ideal fluids may be characterized by the following two properties: (i) When a viscous fluid flows along a well it adheres to the wall i.e., the layer of fluids is in immediate contact with the wall and has no velocity relative to it, (ii) shearing stresses arises whenever the fluid properties are distorted. The viscosity, CHAPTER 1. INTRODUCTION 13 which is also known as an internal friction, of a fluid is that characteristic of the real fluid which is capable to offer resistance to shearing stress. 1.2.2 Newtonian and Non-Newtonian Fluids A fluid in which the components of the stress tensor are linear functions of the first spatial derivatives of the velocity components. These functions involve two material parameters taken as constants throughout the fluid, although depending on ambient temperature and pressure. The constant ratio of the shearing stress τ to the rate of shear is the viscosity of the liquid i.e., τ = µ ∂u , when µ is the viscosity of the fluid. In common terms, this ∂y means the fluid continues to flow, regardless of the forces acting on it. For example, water is Newtonian, because it continues to exemplify fluid properties no matter how fast it is stirred or mixed. If the fluid viscosity varies with the rate of deformation, then it is said to NonNewtonian fluid. Non-Newtonian fluids are characterized by different features, such as viscosity and elasticity for example, the viscosity of polymeric liquids changes with the shear rate, so it is known as non-Newtonian fluids. Thus Non-Newtonian fluids are those in which there is no shear stress and there exists a non-linear relation between τ and 1.3 Types of flows 1.3.1 Steady and Unsteady Flows ∂u . ∂y If a flow is such that the properties at every point in the flow do not depend upon time then it is called a steady flow. Mathematically, for steady flows ∂P ∂t = 0, where P = P (x, y, z) is any property like pressure, velocity or density. Unsteady or non-steady flow is one in which the properties do depend on time. 1.3.2 Laminar and Turbulent Flows Laminar flow is referred to as streamline or viscous flow. In laminar flow, (i) layers of fluid flowing over one another at different speeds with virtually no mixing between layers, (ii) fluid particles move in a definite path or streamlines, and (iii) viscosity of the fluid plays a significant role. CHAPTER 1. INTRODUCTION 14 Turbulent flow is characterized by the irregular movement of particles of the fluid. The particles travel in irregular paths with no observable pattern and no definite layers. 1.3.3 Compressible and Incompressible Flows A compressible fluid is one in which the fluid density changes when it is subjected to high pressure-gradients. For gasses, changes in density are accompanied by changes in temperature which complicates the analysis of the compressible flow. In a compressible fluid, the imposition of a force at one end of a system does not result in an immediate flow throughout the system. Instead, the fluid compresses near where the force was applied, i.e., its density increases locally in response to the force. The compressed fluid expands against neighbouring fluid particles causing the neighbouring fluid itself to compress and setting in motion a wave pulse that travels throughout the system. An incompressible fluid is one in which the fluid density does not change with pressure. Liquid and gas may be modeled as incompressible fluids in both microscopic and macroscopic calculations. 1.3.4 Viscosity of Fluids A real fluid flowing in a pipe experiences frictional forces due to friction with the walls of the pipe which results in friction within the fluid itself and there by converting some of its kinetic energy into thermal energy. The frictional forces that try to prevent different layers of fluid from sliding past each other are called viscous forces. Viscosity is a measure of a fluid resistance to relative motion within the fluid. We can measure the viscosity of a fluid by measuring the viscous drag between two plates. The viscosity of fluids depend strongly on temperature. The viscosity of a liquid decreases with increasing temperature and viscosity of liquid increases with increasing temperature. In liquids viscosity is due to the cohesive forces between the molecules and in gases the viscosity is due to collisions between the molecules. If the viscosity is a constant, independent of flow speed, then the fluid is termed a Newtonian fluid. 1.4 Flow Through Porous Media Studies on flow through porous media has attracted considerable research attention in recent years because of its several important applications notably in the flow through CHAPTER 1. INTRODUCTION 15 packed beds, extraction of energy from the geothermal regions, filtration of solids from liquids, flow of liquids through ion-exchange beds, the evaluation of the capability of heat removal from particulate nuclear fuel debris that may result from accident in a nuclear reactor and in chemical reactors for economical separation or purification of mixtures. A porous medium of volume is a fixed solid matrix with a connected void space through which a fluid can flow or consists of solid particles (which are deformable or nondeformable) so that fluid can flow through voids and passages. Let Vv be the volume of voids. When fluid flows through the interconnected voids and passages of a porous medium V , the walls of these voids and passages from small tunnels through which fluid can flow. The study of motion of fluid in a porous medium on pore scale is called microscopic scale. The study of fluid flow at microscopic scale is complicated and unrealistic because of the complexity of the micro-geometry of porous media. A more realistic approach to study dynamics of flow through porous media is under the assumption of continuum macroscopic phenomena. Usually the spacial averages are used to transfer properties of porous media from microscopic scale to macroscopic scale. Therefore, the definition of porosity and permeability is essential. 1.4.1 Porosity Most important geometrical property of the porous media is to porosity. The rheological properties of fluids often change with the geometry, of the porous medium, thus it is important to measure the porosity. Porosity is defined as the percentage of a volume of medium that is empty space that contributes to the fluid flow. Mathematically it is the ratio between the unit volume of void space Vv to the total volume containing both fluid and solid which may be either sphere or cube. Then the porosity, ϵ, of such porous medium is defined as ϵ= Vv void volume = total volume V (1.1) where 0 < ϵ < 1. If Vv = V then it is the case for free fluid. 1.4.2 Permeability Flow through a porous medium in the macroscopic continuum approach is described by the Darcy’s law. For an anisotropic porous medium Darcy’s law can be expressed as qi = −Kij ∂h ∂xi (1.2) CHAPTER 1. INTRODUCTION 16 where qi (i = 1, 2, 3) is the Darcy velocity, Kij , a tensor, the hydraulic conductivity of porous media and h is the water head at a point xi which depends on the pressure p and density ρ and is a macroscopic quantity. for an isotropic porous medium, Kij reduces to a scalar K and then the Darcy law, given by Eq. (1.2), becomes qi = −K ∂h , ∂xi (i = 1, 2, 3) (1.3) The hydraulic conductivity κ of the porous medium depends on the properties of both solid and fluid aspect of porous media and given by κ= kρg µ (1.4) where k is the permeability having dimension of (Length)2 , g is the gravity and ρ is the density and µ is the viscosity. Thus permeability measures quantitatively the ability of the porous medium to permit fluid flow. 1.4.3 Darcy’s Law In fluid dynamics and hydrology, the observation of Henry Darcy (1856) on the public water supply at Dijon and experiments on steady flow suggested Darcy’s law which is analogous to Fourier’s law in the field of heat conduction, or Fick’s law in diffusion theory. κ − → q = ∇P µ (1.5) → where − q is the filtration velocity or Darcy flux and ∇P is the pressure gradient vector. This value of the filtration velocity (Darcy flux), is not the velocity which the water travelling through the pores is experiencing. The porosity ϵ is very small in a densely packed porous medium. The usual Darcy equation is valid in a densely packed porous medium saturated with laminar flow, which is written as k − → → q = − (∇p + ρ− g ). µ (1.6) Under the following two approximations, the basic equations of motion in porous media are valid: (i)The saturated porous medium is homogeneous and isotropic so that the porosity and permeability are constant. The porous medium is assumed to consist of sparsely distributed particles so that viscous shear and inertial effects play an important role in addition to Darcy resistance. CHAPTER 1. INTRODUCTION 17 (ii) The usual MHD approximations are valid even in flow through porous media. Limitations: Darcy model takes into account of the frictional force which is offered due to the presence of solid particles to the fluid rather than the boundary and internal effects. 1.4.4 Brinkman Model Henry P. G. Darcy (1803–1858), Director of public works in Dijon has worked on the design and execution of a municipal water supply system. He discovered a law known as ’Darcy law’ which states that as the rate of flow is proportional to pressure drop through a bed of fine particles. It is Mathematically expressed as κ dP − → Q =− µ dx (1.7) where κ represents the permeability of the material, Q is a volumetric flow rate per unit cross-sectional area. The total effect, as the fluid slowly percolates through the porous of the medium, must be represented by a macroscopic law which is applicable to masses of fluid large compared with the dimensions of the porous structure of a medium (Lapwood, 1948), which is the basic of Darcy law. One of the approximate boundary layer type of equations in a porous medium is the Brinkman model. Brinkman model consists of → → viscous term ν∇2 − q in addition to the Darcy resistance term (µ/κ)− q in the momentum equation. 1.4.5 Darcy-Forchheimer Model → − Darcy equation (1.6) is linear in the seepage velocity − q . It holds when → q is sufficiently small which means that the Reynolds number of the flow is based on a typical pore or − particle diameter is of order unity or smaller. As → q increases, the transition as Reynolds number is increased in the range 1 to 10 so that the flow in the pores is still laminar. Thus the breakdown is linearity is due to the fact that the drag is formed due to solid → → √ b |− q |− q obstacles which is comparable with the surface drag due to friction of the form ρC in addition to linear drag µ→ − q. κ b Thus according to Joseph et al. (1982) the appropriate modification to Darcy’s equation is to replace (1.6) by → µ→ ∂− q → → → = −∇p − − q − cb k −1/2 ρ|− q |− q + ρ− q ∂t κ (1.8) CHAPTER 1. INTRODUCTION 18 where cb is the drag coefficient and other quantities have the same meaning as defined earlier Eq. (1.8) is known as Darcy-Forchheimer equation and the quadratic drag term in Eq. (1.8) represents inertia. 1.4.6 Darcy-Lapwood-Forchheimer Model → → In a densely packed porous medium of large velocity, inertia term ρ(− q .∇)− q is added to the Darcy-Forchheimer equation (1.8). It is called Darcy-Lapwood-Forchheimer equation given by ( → ∂− q ) µ → ρCb − − → → → q − √ |→ q |→ q + ρ− g. (1.9) + (− q .∇)− q = −∇p − − ∂t k k → → The term ρ(− q .∇)− q was first considered by Lapwood (1948). In the case of sparsely ρ packed porous media the porosity, ϵ, is large but less than unity so one has to take into account of boundary large effect. 1.4.7 Darcy-Lapwood-Forchheimer Brinkman Model Brinkman (1947) was the first to propose the momentum equation with boundary layer effect, known as Darcy-Lapwood-Forchheimer-Brinkman equation namely, ρ ( − ∂→ q ) µ → ρCb − − → → → → e 2− q − √ |→ + (→ q .∇)− q = −∇p − − q |− q − µ∇ q + ρ− g. ∂t k k (1.10) where µe is called effective viscosity or Brinkman viscosity and all other quantities are defined earlier. 1.5 Stretching Sheet Flow The flow produced due to stretching of an elastic flat sheet which moves in its plane with velocity varying with the distance from a fixed point due to the application of a stress are known as stretching flow. The production of sheeting material arises in a number of industrial manufacturing processes and includes both metal and polymer sheets. In the manufacturing of the latter, the material is in a molten phase when thrust through an extrusion die and then cools and solidifies some distance away from the die before arriving at the cooling stage. The tangential velocity imported by the sheet induces motion in the surrounding fluid, which alters the convection of the sheet. Similar situation prevails during the manufacture of plastic and rubber sheets where it is often necessary to blow a gaseous medium through the not yet solidified material, and where the stretching force CHAPTER 1. INTRODUCTION 19 depends upon time. Another example that belongs to this class of problems is the cooling of a large metallic plate in a bath, which may be an electrolyte. In this class the fluid flow is induced due to shrinking of the plate. Glass blowing, continuous casting and spinning of fibers also involve the flow due to stretching surface. Due to very high viscosity of the fluid near the sheet, one can assume that the fluid is affected by the sheet but not vice versa. 1.6 Boundary Layer Flow At the beginning of the 20th century L. Prandtl has given a new dimension to fluid mechanics by introducing viscosity in the fluid. It was noted by him that in the thin region near the solid boundary, the viscous interactions have a significant effects on fluid motion, whereas far away from the solid boundary, viscous interactions were not that significant in order to determine the flow field. Before this the viscosity effects were completely ignored in ideal flow solutions and the equations describing viscous interaction were very complex. The Navier-Stokes equations behave well for small Reynold’s number whereas for higher values of Reynold’s number the non-linear term are insignificant. The flow past a body can be divided into a thin region very near to the body called the boundary layer where the viscosity is important and the remaining region where the viscosity is insignificant. These equations are highly non-linear, second order and elliptic in space so there arises great mathematical difficulties in the solution of the boundary layer equations. By assuming a thin boundary layer, several terms are negligible and the elliptic equation become parabolic. 1.7 Magnetohydrodynamic (MHD) Flow It is concerned with the study of the motions of electrically conducting fluids and their interactions with magnetic fields. Magnetohydrodynamics (MHD) is relatively new and important branch of fluid dynamics. When a conducting fluid moves through a magnetic field, an electric field and consequently current may be induced and in turn the current interacts with the magnetic field to produce a body force. According to Faraday, when a conductor carrying an electric current moves in a magnetic field, it experiences a force tending to move it at right angles to the electric field and conversely, when a conductor moves in a magnetic field, a current is induced in the conductor in a direction mutually at CHAPTER 1. INTRODUCTION 20 right angles to both the field and the direction of motion. In the case when the conductor is electromagnetic forces of the same order of magnitude as the hydrodynamical and inertial forces. Thus these electromagnetic forces are taken into account in the equation of motion in addition to other forces. The set of equations which describe MHD are a combination of the Navier-Stokes equations of fluid dynamics and Maxwell’s equations of electromagnetism. These differential equations are required to be solved simultaneously. The interaction of moving conducting fluids with electric and magnetic fields provides for a rich variety of phenomena associated with electro-fluid-mechanical energy conversion. Effects from such interactions can be observed in liquids, gases, two-phase mixtures, or plasmas. Numerous scientific and technical applications exist, such as heating and flow control in metals processing, power generation from two-phase mixtures or seeded high temperature gases, magnetic confinement of high-temperature plasmas even dynamos that create magnetic fields in planetary bodies. Several terms have been applied to the broad field of electromagnetic effects in conducting fluids, such as magneto-fluid mechanics, magneto-gas-dynamics, and the more common one used here magnetohydrodynamics, or MHD. 1.8 Convection Convection is the movement of molecules within fluids (i.e. liquids, gases). It cannot take place in solids, since neither bulk current flows nor significant diffusion can take place in solids. Convection is one of the major modes of heat transfer and mass transfer. Convective heat and mass transfer take place through both diffusion the random Brownian motion of individual particles in the fluid and by advection, in which matter or heat is transported by the larger-scale motion of currents in the fluid. In the context of heat and mass transfer, the term ”convection” is used to refer to the sum of advective and diffusive transfer. Convection also includes fluid movement both by bulk motion (advection) and by the motion of individual particles (diffusion). However in some cases, convection is taken to mean only advective phenomena. For instance, in the transport equation, which describes a number of different transport phenomena, terms are separated into convective and diffusive effects. Convective heat transfer is a mechanism of heat transfer occurring because of bulk motion (observable movement) of fluids. Heat is the entity of interest being advected (carried), and diffused (dispersed). CHAPTER 1. INTRODUCTION 1.8.1 21 Natural Convection Natural convection, or free convection, occurs due to temperature differences which affect the density, and thus relative buoyancy, of the fluid. Heavier (more dense) components will fall while lighter (less dense) components rise, leading to bulk fluid movement. Natural convection occurs, only in a gravitational field. Natural convection is more likely and/or more rapid with a greater variation in density between the two fluids and a larger distance through the convecting medium. Convection will be less rapid with more rapid diffusion (thereby diffusing away the gradient that is causing the convection) and a more viscous (sticky) fluid. 1.8.2 Forced Convection When the density difference is created by some means due to which circulation takes place then it is known as forced convection. In forced convection, also called heat advection, fluid movement results from external surface forces such as a fan or pump. Forced convection is typically used to increase the rate of heat exchange. Many types of mixing also utilize forced convection to distribute one substance within another. Forced convection also occurs as a by-product to other processes, such as the action of forced convection may produce results more quickly than free convection. For instance, a convection oven works by forced convection, as a fan which rapidly circulates hot air forces heat into food faster than would naturally happen due to simple heating without the fan. 1.9 Conduction Conduction is the transfer of heat between two bodies or two parts of the same body through molecules. This type of heat transfer is governed by Fourier’s Law which states that Rate of heat transfer is linearly proportional to the temperature gradient. For 1-D heat conduction qk = −k 1.9.1 dT . dx (1.11) Thermal Conductivity Thermal conductivity, κ, is the property of a material that indicates its ability to conduct heat. It appears primarily in Fourier’s Law for heat conduction. Conduction is the most significant means of heat transfer in a solid. By knowing the values of thermal CHAPTER 1. INTRODUCTION 22 conductivities of various materials, one can compare how well they are able to conduct heat. The higher the value of thermal conductivity, the better the material is at conducting heat. On a microscopic scale, conduction occurs as hot, rapidly moving or vibrating atoms and molecules interact with neighbouring atoms and molecules, transferring some of their energy (heat) to these neighboring atoms. In insulators the heat flux is carried almost entirely by phonon vibrations. 1.9.2 Thermal Radiation Thermal radiation is electromagnetic radiation from an object that is simply caused by its temperature. It rapidly increases in power, and also increases in frequency, with increasing temperature. A black body is an object that absorbs all electromagnetic radiation that falls onto it. For this case there are formulas for the power as a function of temperature, etc. For example, spacecraft may have thermal radiators, also called heat radiators to lose excess heat. They tend to be reflective to avoid absorption of solar radiation energy. e.g. the space shuttle has heat radiators mounted on the inner surfaces of the payload bay doors, and so are kept open while the Shuttle is in orbit. Examples of thermal radiation are an incandescent light bulb emitting visible-light, infrared radiation emitted by a common household radiator or electric heater, as well as radiation from hot gas in outer space. A person near a raging bonfire feels the radiated energy of the fire, even if the surrounding air is very cold. Thermal radiation is generated when thermal energy is converted to electromagnetic radiation by the movement of the charges of electrons and protons in the material. Sunlight is solar electromagnetic radiation generated by the hot plasma of the Sun, and this thermal radiation heats the Earth by the reverse process of absorption, generating kinetic, thermal energy in electrons and atomic nuclei. The Earth also emits thermal radiation, but at a much lower intensity and different spectral distribution because it is cooler. The balance between heating by incoming solar radiation and cooling by the Earth’s outgoing radiation is the primary process that determines Earth’s overall temperature. If a radiation-emitting object meets the physical characteristics of a black body in thermodynamic equilibrium, the radiation is called black body radiation. The emitted frequency spectrum of the black body radiation is described by a probability distribution depending only on temperature given by Planck’s law of black-body radiation. Wien’s displacement law gives the most likely frequency of the emitted radiation, and the Stefan-Boltzmann law determines the radiant intensity. CHAPTER 1. INTRODUCTION 23 In engineering, thermal radiation is considered one of the fundamental methods of heat transfer, although it does not involve the transport of heat. The characteristics of thermal radiation depends on various properties of the surface it is emanating from, including its temperature, its spectral absorptivity and spectral emissive power, as expressed by Kirchhoff’s law. 1.10 Literature Review 1.10.1 Effects of Mixed Convection in a Porous Medium The mixed (combined forced and free) convection arises in many natural and technological processes, depending on the forced flow direction, the buoyancy forces may aid (aiding or assisting mixed convection) or oppose (opposing mixed convection) the forced flow, causing an increase or decrease in heat transfer rates. The problem of mixed convection resulting from the flow over a heated vertical plate is of considerable theoretical and practical interest. Convection heat transfer and fluid flow through porous medium is a phenomenon of great interest from both theoretical and practical point of view because of its applications in many engineering and geophysical fields such as geothermal and petroleum resources, solid matrix heat exchanges, thermal insulation drying of porous solids, enhanced oil recovery, cooling of nuclear reactors and other practical interesting designs. The possible use of porous media adjacent to surfaces to enhance heat transfer characteristics have lead to extensive research in heat transfer and flows over bodies embedded in a porous media. Physically, the problem of mixed convection flow past a stretching sheet embedded in porous medium arise in some metallurgical processes which involve the cooling of continuous strips or filaments by drawing them through quiescent fluid and the rate of cooling can be better controlled and final product of desired characteristics can be achieved if the strips are drawn through porous media. The possibility of obtaining similarity solutions for mixed convection boundary-layer was first considered by Sparrow et al. (1959) who showed that the boundary-layer equations could be reduced to a system of ordinary differential equations. Sparrow and Lee (1976) were the first to study the problem of mixed convection boundary layer flow about a horizontal circular cylinder. In view of this, Cheng and Minkowycz (1977) presented similarity solutions for free thermal convection from a vertical plate embedded in a fluid-saturated porous medium for situations where the wall temperature is a power-law function of the CHAPTER 1. INTRODUCTION 24 distance along the plate. Rudraiah and Veerabhadraiah (1978) studied effect of buoyancy force on the free surface flow past a permeable bed. Bejan and Khair (1985) studied the heat and mass transfer by natural convection in a porous medium. Lai (1991) investigated coupled heat and mass transfer by mixed convection from an isothermal vertical plate in a porous medium. The effect of wall fluid blowing on the coupled heat and mass transfer boundary layer flow over a vertical plate was investigated by Lai and Kulacki (1991). Comprehensive reviews of the convection through porous media have been reported by Nield and Bejan (1992) and by Ingham and Pop (1998). Bejan et al. (1995) analyzed the nonsimilar solutions for mixed convection on a wedge embedded in a porous medium. Gorla and Kumari (1996) studied the mixed convection in non-Newtonian fluids along a vertical plate in a porous medium. Yih (1998) studied the uniform lateral mass flux effect on natural convection of non-Newtonian fluids over a cone in a porous media. Kumari et al. (2000) studied the mixed convection flow over a vertical wedge embedded in a highly porosity porous medium. Merkin and Pop (2002) obtained similarity solutions of mixed convection boundary-layer flow over a vertical semi-infinite flat plate in which the free stream velocity is uniform and the wall temperature in inversely proportional to the distance along the plate. Aly et al. (2003) examined the mixed convection boundarylayer flow over a vertical surface embedded in a porous medium. Rudraiah et al. (2003) presented a review work on nonlinear convection in porous media. In (2006), Guedda studied the multiple solutions of mixed convection boundary-layer approximations in a porous medium. Shivakumara et al. (2006) investigated onset of surface-tension-driven convection in superposed layers of fluid and saturated porus medium. Ling et al. (2007) have studied the numerical solutions of steady mixed convection boundary layer flow over a vertical impermeable flat plate in a porous medium saturated with water at 40 C when the temperature of the plate varies as xm and the velocity outside boundary varies as x2m , where x measures the distance from leading edge of the plate. Ishak et al. (2008) presented the problem of mixed convection boundary layer flow over a vertical surface embedded in a thermally stratified porous medium assuming that the external velocity and surface temperature to vary as xm , where x is measured from the leading edge of the vertical surface and m is a constant. Shivakumara et al. (2009) analyzed natural convection in a vertical cylindrical annulus using a non-Darcy equation. Most of the earlier studies on porous media have used the Darcy’s law which states that the volume averaged velocity is proportional to the pressure gradient and is limited to relatively low velocities and small porosity. However, for relatively high velocity flow CHAPTER 1. INTRODUCTION 25 situations, the Darcy’s law is inadequate for representing the flow behavior correctly since it does not account for the resulting inertia effects of the porous medium. In this situation, the pressure drop has a quadratic relationship with the volumetric flow rate. The high flow situations is established when the Reynolds number based on the pore size is greater than unity. Thus to model a real physical situation such as a non-uniform porosity distribution, it is, therefore, necessary to include the non-Darcian effects in the analysis of convective transport in a porous medium. The inertia effect is expected to be important at higher flow rate and it can be accounted for through the addition of a velocity-squared term in the momentum equation, which is known as the Forchheimer extension. The Brinkman extension is usually used to shed light on the importance of boundary effects. Brinkman (1947, 1948) combines the viscous penetration dominated flow (Stoke’s flow) with the Darcy flow. These non-Darcian effects include nonuniform porosity distribution and thermal dispersion. Vafai and Tien (1981) arrive at a semi-empirical momentum equation. Vafai and Tien (1982) discussed the importance of these two effects in flows over surfaces embedded in a porous media. The Darcy-Forchheimer (DF) model is probably the most popular modification to Darcian flow utilized in similarity inertia effects. A numerical study based on the Forchheimer-Brinkmann-extended Darcy equation of motion has also been reported recently by Beckermann et al. (1986). Hong et al. (1987) investigated the effects of non-Darcian and nonuniform on vertical plate natural convection in porous media. Inertia effect is accounted through the inclusion of a velocity squared term in the momentum equation, which is known as Forchheimer’s extension. An analysis of the Brinkman equation as a model for flow in porous media is given by Durlofsky and Brady (1987). Non-Darcian convection in cylindrical packed beds was studied by Hunt and Tien (1988). Nakayama et al. (1989) presented a similarity solution for the non-Darcy free convection from a non isothermal curved surface in a fluid saturated porous medium. Flow transitions in buoyancy-induced non-Darcian convection in a porous medium heated from below was analyzed by Kladias and Prasad (1990). For the problem of mixed convection flow over a vertical plate embedded in a non-Newtonian fluid saturated porous medium, Wang et al. (1990) obtained similar and integral solutions. Ramanaiah and Malarvizhi (1991) investigated the non-Darcy axisymmetric free convection on permeable horizontal surfaces in a saturated porous medium. The problem of non-Darcy mixed convection along a vertical wall in a saturated porous medium was analyzed by Lai and Kulacki (1991). Hadim and Chen (1993) carried out a numerical study of buoyancy-aided mixed convection in an isothermally heated vertical channel CHAPTER 1. INTRODUCTION 26 filled with a fluid saturated porous medium. Chen et al. (1996) analyzed the non-Darcy mixed convection along non isothermal vertical surfaces in porous media. The effects of non-Darcian surface tension on free surface transport in porous media was studied by Chen and Vafai (1997). They employed the Darcy- Brinkman-Forchheimer model. The problem of mixed convection heat and mass transfer in a fluid-saturated porous media was studied by Rami et al. (2001) considering the Darcy-Forchheimer model. Elbashbeshy (2003) studied the mixed convection along a vertical plate embedded in non-Darcian porous medium with suction and injection. The non-similar non-Darcy mixed convection flow over a non-isothermal horizontal surface which covers the entire regime of mixed convection flow starting from pure forced convection to pure free convection flow has been studied by Kumari and Nath (2004). Pal and Shivakumara (2006) studied the mixed convection heat transfer from a vertical heated plate embedded in a sparsely packed porous medium. 1.10.2 Flow Over a Stretching Sheet During past several years considerable interest has been evinced in the study of steady flows of a viscous incompressible fluid driven by a linearly stretching surface through a quiescent fluid. Such flow situations are encountered in a number of industrial processes e.g. the cooling of metallic plates in a cooling bath, the aerodynamic extrusion of plastic sheets, polymer sheet extruded continuously from a dye and heat-treated materials that travel between feed and wind-up rolls or on a conveyer belt possesses the characteristics of a moving continuous surfaces. During the manufacturing of these sheets, the mixture which is issued from a slit is subsequently stretched to achieve the desired thickness. Finally, this sheet solidifies while it passes through effectively controlled cooling system in order to acquire the top-grade final product. Apparently, the quality of such a sheet is definitely influenced by heat and mass transfer between the sheet and fluid. During its manufacturing process, a stretched sheet interacts with the ambient fluid both thermally and mechanically. Sakiadis (1961) introduced in his pioneering work, the study of boundary layer flow over a continuous solid surface moving with constant velocity. It is usually assumed that the sheet is inextensible, but in some different studies such as in the polymer industry it is necessary to deal with the stretching sheet as mentioned by Crane (1970). The heat and mass transfer of viscous fluids over an isothermal stretching sheet with suction or blowing have been extended by Gupta and Gupta (1977). Rajagopal CHAPTER 1. INTRODUCTION 27 et al. (1984) studied the flow of a viscoelastic fluid over a stretching sheet. Dutta et al. (1985) have investigated the temperature distribution in the flow over a stretching sheet with uniform wall heat flux. Chen and Char (1988) studied this linearly stretching sheet problem with suction or blowing for a power-law surface temperature as well as a power-law surface heat flux. It is worth mentioning that there are several practical applications in which significant temperature differences between the body surface and the ambient fluid exist. The temperature differences cause density gradients in the fluid medium and free convection effects become more important in the presence of gravitational force. There arise some situations where the stretching sheet moves vertically in the cooling liquid. In this situation, the fluid flow and the heat transfer characteristic are determined by two mechanisms namely, the motion of stretching sheet and the buoyancy force. The thermal buoyancy generated due to heating/cooling of a vertically moving stretching sheet has a large impact on the flow and heat transfer characteristics than when it is moving horizontally. Mahaparta and Gupta (2002) analyzed Heat transfer in stagnation-point flow towards a stretching sheet. Ali and AI-Yousef (2002) studied the laminar mixed convection boundary-layers induced by a linearly stretching permeable surface. Vajravelu and Cannon (2006) studied the fluid flow over a nonlinearly stretching sheet. Liu (2006) analyzed the flow and heat transfer of viscous fluids saturated in porous media over a permeable non-isothermal stretching sheet. Cortell (2007) gave a numerical analysis of momentum and mass transfer characteristics in two viscoelastic fluid flows influenced by a porous stretching sheet, namely, second-grade and second-order non-Newtonian. Prasad et al. (2010) analyzed the mixed convection heat transfer over a non-linear stretching surface with variable fluid properties. 1.10.3 Effects of Variable Viscosity and Thermal Conductivity Newton’s law of viscosity states that shear stress is proportional to velocity gradient. Thus the fluids that obey this law are known as Newtonian fluids. Numerous work has been undertaken in recent past. However, it is well known that the physical properties of fluid may change significantly with temperature. For lubricating fluids, heat generated by the internal friction affects the viscosity of the fluid, thus the fluid viscosity can no longer be assumed constant. The increase of temperature leads to a local increase in the transport phenomena by reducing the viscosity across the momentum boundary layer due to which heat transfer at the wall is also affected. Thus in order to predict most accurately CHAPTER 1. INTRODUCTION 28 the flow behaviour, it is important and necessary to take into account the variation of viscosity with temperature. In mixed convection heat transfer takes place under conditions when there are large temperature differences within the fluid thus it becomes necessary to consider the effects of variable fluid properties. The effect of variation of viscosity to study the instability of flow and temperature fields are discussed by Kassoy and Zebib (1975), Gray et al. (1982). Lai and Kulacki (1990) analyzed the effects of variable viscosity on convective heat transfer along a vertical surface in a saturated porous medium. A theoretical investigation of the temperature-dependent fluid viscosity influence for the forced convection flow through a semi-infinite porous medium bounded by an isothermal flat plate was presented by Ling and Dybbs (1992). Pop et al. (1992) studied the effect of variable viscosity on flow and heat transfer to a continuous moving flat plate. Kafoussian and Williams (1995) investigated on free forced convective boundary layer flow past a vertical isothermal flat plate considering temperature-dependent viscosity of the fluid. Elbashbeshy and Bazid (2000) studied the effect of a temperature-dependent viscosity on heat transfer over a continuous moving surface. The effect of variable viscosity on non-Darcy, free or mixed convection flow on a horizontal surface in a saturated porous medium was studied by Kumari (2001). The case of visco-elastic fluid flow and heat transfer over a stretching sheet with variable viscosity studied by Abel et al. (2002). Pantokratoras (2002, 2004) studied the effects of variable viscosity on the laminar heat transfer flow of Newtonian fluids along a vertical/flat plate for various flow conditions. Recently, Ghaly and Seddeek (2004) have studied the Chebyshev finite difference method for the effects of chemical reaction, heat and mass transfer on laminar flow along a semi infinite horizontal plate with temperature dependent viscosity. The influence of variable viscosity on forced convection heat transfer over a flat plate in a porous medium is examined by Seddeek (2005). Pantokratoras (2006) made a theoretical study to investigate the effect of variable viscosity on the classical Falkner-Skan flow with constant wall temperature and obtained results for wall shear stress and the wall heat transfer for various values of ambient Prandtl numbers varying from 1 to 10000. Jayanthi and Kumari (2007) studied the effect of variable viscosity on non-Darcy free or mixed convection flow on a vertical surface in a non-Newtonian fluid saturated porous medium. Hayat and Ali (2008) studied the effect of variable viscosity on the peristaltic transport of a Newtonian fluid in an asymmetric channel. Palani and Kim (2010) analyzed the numerical study on a vertical plate with variable viscosity and thermal conductivity. Hassanien and Rashed (2011) analyzed the non-Darcy free convection flow CHAPTER 1. INTRODUCTION 29 over a horizontal cylinder in a saturated porous medium with variable viscosity, thermal conductivity and mass diffusivity. Botong Li et al. (2011) analyzed the heat transfer in pseudo-plastic non-Newtonian fluids with variable thermal conductivity. 1.10.4 Effects of Magnetic Field and Electric Field The study of magnetohydrodynamic (MHD) flow of an electrically conducting fluid due to the stretching of the sheet is of considerable interest in modern metallurgical and metalworking processes. Many metallic materials are manufactured after they have been refined sufficiently in the molten state. The study of the flow and heat transfer in an electrically conducting fluid permeated by a transverse magnetic field is of special interest and has many practical applications in manufacturing processes in industry. Study of MHD heat transfer field can be divided into two classes, in the first class the electromagnetic fields use to control the heat transfer as in the convection flows and aerodynamic heating, while in the second class the heating is produced by electromagnetic fields for example in generators, pumps, etc. In the present study the first class is used. The study of flow and heat transfer of an electrically conducting fluid in the presence of magnetic field i.e. magnetohydrodynamic flow past a heated surface have applications in manufacturing processes such as the cooling of the metallic plate, nuclear reactor, extrusion of polymers, etc. In many metallurgical processes such as drawing of continuous filaments through quiescent fluids, and annealing and tinning of copper wires, the properties of the end product depend greatly on the rate of cooling involved in these processes. Therefore, it is central problem in metallurgical chemistry to study the heat transfer on liquid metal which is perfect electric conductor. Thus a careful examination of the needs in the system suggests that it is advantageous to have a controlled cooling system. An electrically conducting liquid can be regulated by external means through a variable magnetic field. Liquid metals have high thermal conductivity and are used as coolants in addition to it they have high electrically conductivity hence are susceptible to transverse magnetic field. Many practical applications of convective heat transfer exist, for examples, in chemical factories, in heaters and coolers of electrical and mechanical devices, in lubrication of machine parts, etc. Recently, several researchers have focused their attention to the problem of combined heat and mass transfer in an MHD free convection flow due to the fact that free convection induced by a simultaneous action of buoyancy forces resulting from thermal and mass CHAPTER 1. INTRODUCTION 30 diffusion is of considerable interest in nature and in many industrial applications. The magnetohydrodynamic problem was first studied by Pavlov (1974) who investigated the MHD flow over a stretching wall in an electrically conducting fluid, with an uniform magnetic field. Rudraiah et al. (1975) studied Hartmann flow of a conducting fluid past a permeable bed in the presence of a transverse magnetic field with an interface at the surface of the permeable bed. Chakrabarti and Gupta (1979) studied the hydromagnetic flow and heat transfer over a stretching sheet. Vajravelu and Nayfeh (1992) studied the hydromagnetic flow of a dusty fluid over a stretching sheet. Vajravelu and Rollins (1992) studied heat transfer in an electrically conducting fluid over a stretching surface taking into account the magnetic field only. Malashetty and Leela (1992) have studied the Hartmann flow characteristic of two fluids in horizontal channel. Keeping in mind some specific industrial applications such as in polymer processing technology, numerous attempts have been made to analysis the effect of transverse magnetic field on boundary layer flow characteristics (Andresson (1992), Char (1994) and Lawrence and Rao (1995)). Takhar et al. (1996) studied the radiation effects on MHD free convection flow for a non gray-gas past a semi-infinite vertical plate. Bakier and Gorla (1996) investigated the effect of thermal radiation on mixed convection from horizontal surfaces in saturated porous media. Magnetohydrodynamic mixed convection from a vertical plate embedded in a porous medium was presented by Aldoss et al. (1995). Aldoss and Ali (1997) studied mixed convection from a horizontal circular cylinder embedded in electrically conducting fluid and exposed to a transverse magnetic field in a porous medium. The study of two phase flow and heat transfer in an inclined channel has been made by Malashetty and Umavathi (1997). Chamkha (1998) presented an analysis on unsteady hydromagnetic flow and heat transfer from a non-isothermal stretching sheet in a porous medium. Seddeek (2001) studied the thermal radiation and buoyancy effects on MHD free convection heat generation flow over an accelerating permeable surface with temperature dependent viscosity. Seddeek (2002) analyzed the effects of magnetic field, variable viscosity and non-Darcy effects on forced convection flow about a flat plate with variable wall temperature in the porous medium. Abo-Eldahab and Abd El Aziz (2004) studied the effect of Ohmic heating on mixed convection boundary layer flow of a micropolar fluid from a rotating cone with power-law variation in surface temperature. Abo-Eldahab and Abd El-Aziz (2005) studied MHD three-dimensional flow over a stretching sheet in a non-Darcian heat generation or absorption effects. Mukhopadhyay et al. (2005) studied the effects of variable viscosity on the MHD boundary layer flow over a CHAPTER 1. INTRODUCTION 31 heated stretching surface. Ali (2006) studied the effect of variable viscosity on mixed convection heat transfer along a vertical moving surface. Ishak et al. (2006) studied magnetohydrodynamic stagnation point flow towards a stretching vertical sheet. In view of this, Damesh et al. (2006) analyzed magnetohydrodynamics (MHD) forced convection heat transfer from radiative surfaces in the presence of a uniform transverse magnetic field with conductive fluid suction or injection from a porous plate. Afify (2007) studied the effects of variable viscosity on non-Darcy MHD free convection along a non-isothermal vertical surface in a thermally stratified porous medium. Salem (2007) studied the problem of flow and heat transfer of all electrically conducting visco-elastic fluid having temperature dependent viscosity as well as thermal conductivity fluid over a continuously stretching sheet in the presence of a uniform magnetic field for the case of power-law variation in the sheet temperature. In all above works effect of electric field has been neglected which is also one of the important parameters to alter the momentum and heat transfer characteristics in a Newtonian boundary layer flow. Aydyin and Kaya (2007) analyzed the mixed convection of a viscous dissipating fluid about a vertical flat plate. Mahmoud (2007) studied the thermal radiation effects on MHD flow of a micropolar fluid over a stretching surface with variable thermal conductivity. Abel and Mahesha (2008) studied the heat transfer in MHD viscoelastic fluid flow over a stretching sheet with variable thermal conductivity, non-uniform heat source and radiation. Pal (2008) studied the MHD flow and also heat transfer past a semi-infinite vertical plate embedded in a porous medium of variable porosity. The problems of coupled heat and mass transfer in MHD two-dimensional flow, the effects of Ohmic heating have not been studied by previous authors. However, it is more realistic to include this effect to explore the impact of the magnetic field on the thermal transport in the boundary layer. Abel et al. (2008) studied momentum and heat transfer characteristics in an incompressible electrically conducting viscoelastic boundary layer flow over a linear stretching sheet in the presence of viscous and Ohmic dissipations. The use of magnetic field that influences heat generation/absorption process in electrically conducting fluid flows has important engineering applications. Kumar and Gupta (2009) considered the unsteady MHD and heat transfer of two viscous immiscible fluids through a porous medium in a horizontal channel. Prasad et al. (2009) examined the influence of variable fluid properties on the hydromagnetic flow and heat transfer over a nonlinearly stretching sheet. Rahman and Salahuddin (2009) have studied effects of a variable electric conductivity and temperature-dependent viscosity on magnetohydro- CHAPTER 1. INTRODUCTION 32 dynamic heat and mass transfer flow along a radiative isothermal inclined surface with internal heat generation. Hsiao (2010) studied the heat and mass mixed convection for MHD visco-elastic fluid past a stretching sheet with ohmic dissipation. Pal (2010) studied the mixed convection heat transfer in the boundary layers on an exponentially stretching surface with magnetic field. Sharma and Singh (2010) analyzed the effects of variable thermal conductivity, viscous dissipation on steady MHD natural convection flow of low Prandtl number fluid on an inclined porous plate with Ohmic dissipation. Mohamed Abd El-Aziz (2010) studied the temperature dependent viscosity and thermal conductivity effects on combined heat and mass transfer in MHD three-dimensional flow over a stretching surface with Ohmic heating. Prasad et al. (2010) studied the mixed convection heat transfer over a non-linear stretching surface with variable fluid properties. Makinde and Onyejekwe (2011) analyzed numerical study of MHD generalized Couette flow and heat transfer with variable viscosity and electrical conductivity fluid. Recently, Kumar and Gupta (2011) studied the MHD free-convective flow of micropolar and Newtonian fluids through porous medium in a vertical channel. 1.10.5 Effects of Viscous Dissipation Viscous dissipation plays a significant role in natural convection in various devices that are subjected to large variations of gravitational force or that operate at high rotational speeds (Gebhart (1962)). Gebhart and Mollendorf (1969) analyzed the effect of viscous dissipation in external natural convection considering exponential variation of wall temperature through a similarity solution. A comment was made by Fand and Brucker (1983) that the effect of viscous dissipation might become significant in case of natural convection in porous medium in connection with their experimental correlation for the heat transfer in external flows. The validity of the comment was tested for the Darcy model by Fand et al. (1986), both experimentally and analytically while estimating the heat transfer coefficient from a horizontal cylinder embedded in a porous medium. Viscous dissipation acts as a heat source and generates appreciable temperature in the medium. Nakayama and Pop (1989) considered the effect of viscous dissipation on the Darcian free convection over a non-isothermal body of arbitrary shape embedded in porous media. Murthy and Singh (1997) studied viscous dissipation on non-Darcy natural convection from a vertical flat plate in a porous media saturated with Newtonian fluid. They concluded that a significant decrease in heat transfer is observed with inclusion of viscous dissipation effect. CHAPTER 1. INTRODUCTION 33 El-Amin (2003) analyzed the combined effect of viscous dissipation and Joule heating on MHD forced convection over a non-isothermal horizontal cylinder embedded in a fluid saturated porous medium. In the porous medium, it is interpreted as the rate at which mechanical energy is converted into heat in a viscous fluid per unit volume was studied by Bejan (2004). The mathematical analysis is confined to studying the dissipation effect using a steady, 1-D energy equation, on the basis of the equation form analogy given by Bejan (2004) for the inclusion of viscous dissipation effects. The effect of viscous dissipation in natural convection along a heated vertical plate studied by Pantokratoras (2005). Seddeek (2006) studied the influence of viscous dissipation and thermophoresis on DarcyForchheimer mixed convection in a fluid saturated porous media. Duwairi et al. (2007) investigated viscous dissipation and Joule heating effects over an isothermal cone in a saturated porous media. Many non-Newtonian liquids are highly viscous such that the irreversible work due to viscous dissipation can, in some instances, becomes quite important, this motivated researchers to study the viscous dissipation phenomena in non-Newtonian fluid saturated porous media. Aydin and Kaya (2007) studied the mixed convection of a viscous dissipating fluid about a vertical flat plate. Cortell (2008) analyzed the effects of viscous dissipation and radiation on the thermal boundary layer over a nonlinearly stretching sheet. Kairi and Murthy (2011) studied the effect of viscous dissipation on natural convection heat and mass transfer from vertical cone in a non-Newtonian fluid saturated non-Darcy porous medium. Abel et al. (2011) studied the MHD flow, and heat transfer with effects of buoyancy, viscous and Joules dissipation over a nonlinear vertical stretching porous sheet with partial slip. Cortell (2011) analyzed the suction, viscous dissipation and thermal radiation effects on the flow and heat transfer of a power-law fluid past an infinite porous plate. 1.10.6 Effects of Thermal Radiation A new dimension is added to the study of mixed convection flow past a stretching sheet embedded in a porous medium by considering the effect of thermal radiation. Thermal radiation effect plays a significant role in controlling heat transfer process in polymer processing industry. The quality of the final product depends to a certain extent on heat controlling factors. Also, the effect of thermal radiation on flow and heat transfer processes is of major important in the design of many advanced energy convection systems which operate at high temperature. Thermal radiation occurring within these systems is CHAPTER 1. INTRODUCTION 34 usually the result of emission by the hot walls and the working fluid. Thermal radiation effects become more important when the difference between the surface and the ambient temperature is large. Thus thermal radiation is one of the vital factors controlling the heat and mass transfer. Another important effect of considering thermal radiation is to enhance the thermal diffusivity of the cooling liquid in the stretching sheet problem. Thus the knowledge of radiation heat transfer in the system can perhaps lead to a desired product with sought characteristics. In many new engineering areas processes (such as fossil fuel combustion energy processes, solar power technology, astrophysical flows, and space vehicle re-entry) occur at high temperatures so knowledge of radiation heat transfer beside the convective heat transfer play very important role and cannot be neglected. Also, thermal radiation on flow and heat transfer processes is of major importance in the design of many advanced energy conversion systems operating at high temperature. The Rosseland approximation is used to describe the radiative heat flux in the energy equation. Also, the effect of thermal radiation on the forced and free convection flows are important in the content of space technology and processes involving high temperature. Viskanta and Grosh (1962) have considered boundary layer flow in thermal radiation absorbing and emitting media. If the radiation is taken into account in some industrial applications such as glass production and furnace design and in space technology applications (such as propulsion system, plasma physics, cosmical flight aerodynamics rocket and geophysics) then the governing equations become quite complicated and hold to be solved. However, Cogley et al. (1968) showed that, in the optically thin limit, the fluid does not absorb its own emitted radiation, but the fluid does absorb radiation emitted by the boundaries. In the processes involving high temperatures and in the context of space technology, the effects of radiation are of vital importance. Also, recent developments in hypersonic flights, missile reentry, rocket combustion chambers, power plants for inter-planetary flights, gas cooled nuclear reactors, nuclear power plants, gas turbines, propulsion devices for air-craft, satellites and space vehicles have focused attention on thermal radiation as a mode of energy transfer and emphasize the need for improved understanding of radiative heat transfer in these processes. In addition, radiative heat and mass transfer flow plays an important role in manufacturing industries in the design of reliable equipment, nuclear power plants, gas turbines and various propulsion devices for air-craft, satellites and space vehicles as well as many other astrophysical and cosmic studies. Based on these applications, England and Emery (1969) studies the thermal radiation effect of an optically thin gray gas bounded by a stationary vertical plate. Plumb CHAPTER 1. INTRODUCTION 35 et al. (1981) was the first to examine the effect of horizontal cross-flow and radiation on natural convection from vertical heated surface in saturated porous media. Ali et al. (1984) have considered natural convection-radiation interaction in the boundary layer flow over semi-infinite horizontal surface considering grey-gas that emits and absorbs but does not scatter thermal radiation. Ibrahim and Hady (1990) have investigated mixed convection-radiation interaction in boundary layer flow over a horizontal surface. Rosseland diffusion approximation had been utilized in this investigation of convection flow with radiation. Gorla and Pop (1993) studied the effects of radiation on mixedconvection flow over vertical cylinders. Hossain and Takhar (1996) have investigated the radiation effect on mixed convection boundary layer flow of an optically dense viscous incompressible fluid along a vertical plate with uniform surface temperature. The effects of thermal dispersion and lateral mass flux on non-Darcy natural convection over a vertical flat plate in a fluid saturated porous medium were studied by Murthy and Singh (1997). Mansour (1997) analyzed combined forced convection and radiation interaction heat transfer in the boundary layer flow over flat plate immersed in porous medium of variable viscosity. Raptis (1998) analyzed radiation and free convection flow through a porous medium using Rosseland approximation for the radiative heat flux. Raptis and Perdikis (1999) solved analytically the governing equations to study the effects of thermal radiation and free convection flow past a moving vertical plate. The effect of radiation on the free convection heat transfer problem was studied by Hossain et al. (1999) considering suction boundary condition and used Rosseland approximation to describe the radiative heat flux in the energy equation. Mansour and El-Amin (1999) studied the effects of thermal dispersion on non-Darcy axisymmetric free convection in a saturated porous medium with lateral mass transfer. Mohammadein and Ei-Amin (2000) studied the problem of thermal dispersion-radiation effects on non-Darcy natural convection in a fluid saturated porous medium. Israel-Cookey et al. (2003) investigated the influence of viscous dissipation and radiation on the problem of unsteady magnetohydrodynamic free convection flow past an infinite vertical heated plate in an optically thin environment with time-dependent suction. Pop et al. (2004) investigated theoretically steady two-dimensional stagnation-point flow of an incompressible fluid over a stretching sheet by taking into account of the thermal radiation effects. Abel et al. (2005) performed analysis to study the effect of buoyancy force and thermal radiation in MHD boundary layer visco-elastic fluid flow over a continuously moving stretching surface embedded in a porous medium. Siddheshwar and Mahabaleswar (2005) CHAPTER 1. INTRODUCTION 36 studied the MHD flow and also heat transfer in a viscoelastic liquid over a stretching sheet in the presence of radiation. They have assumed that stretching of the sheet be proportional to the distance from the slit. They used Keller box method to solve the nonlinear equations. Rashad (2007) studied thermal radiation effects on free convection flow of Newtonian fluid-saturated porous medium in the presence of pressure work and viscous dissipation using regular three-parameter perturbation analysis. The effect of chemical reaction and thermal radiation absorption on unsteady MHD free convection flow past a semi-infinite vertical permeable moving surface with heat source and suction was analyzed by Ibrahim et al. (2008). Pal (2009) analyzed heat and mass transfer in two-dimensional stagnation-point flow of an incompressible viscous fluid over a stretching vertical sheet in the presence of buoyancy force and thermal radiation. Hassanien and Alarabi (2009) studied the non-Darcy unsteady mixed convection flow near the stagnation point on a heated vertical surface embedded in a porous medium with thermal radiation and variable viscosity. Ali et al. (2011) studied the unsteady MHD natural convection from a heated vertical porous plate in a micropolar fluid with Joule heating, chemical reaction and radiation effects. Singh et al. (2011) analyzed the effects of thermophoresis on hydromagnetic mixed convection and mass transfer flow past a vertical permeable plate with variable suction and thermal radiation. Turkyilmazoglu (2011) studied the thermal radiation effects on the time-dependent MHD permeable flow having variable viscosity. Recently, Hayat et al. (2011) analyzed the radiation effects on MHD flow of Maxwell fluid in a channel with porous medium. 1.10.7 Effects of Non-uniform Heat Source/Sink Yih (1998) studied the heat source/sink effect on MHD mixed convection in stagnation flow on a vertical permeable plate in porous media. Kamel (2001) studied the unsteady MHD convection through porous medium with combined heat and mass transfer with heat source/sink. Chamkha (2000) analyzed the thermal radiation and buoyancy effects on hydromagnetic flow over an accelerating permeable surface with heat source or sink. Yih (2000) studied the viscous and Joule heating effects on non -Darcy MHD natural convection flow over a permeable sphere in porous media with internal heat generation. Emad et al. (2004) have included the effect of non-uniform heat source with suction/blowing, but confirm to the case of viscous fluid only. Eldahab and Aziz (2004) have included the effect of non-uniform heat source with suction/blowing, but confirm to the case of viscous CHAPTER 1. INTRODUCTION 37 fluid only. In most of the investigations involving the heat transfer, we observe that either the prescribed constant surface temperature (PST) or the prescribed constant wall heat flux (PHF) boundary condition is assumed. Seddeek (2007) analyzed the heat and mass transfer on a stretching sheet with a magnetic field in a visco-elastic fluid flow through a porous medium with heat source or sink. Pal and Malashetty (2008) have presented similarity solutions of the boundary layer equations to analyze the effects of thermal radiation on stagnation point flow over a stretching sheet with internal heat generation or absorption. The study of heat source/sink effects on heat transfer is very important in view of several physical problems. Aforementioned studies include only the effect of uniform heat source/sink (i.e. temperature dependent heat source/sink) on heat transfer. If the final product that is obtained after cooling needs to be non-uniform in terms of properties warranted by an application, then variable PHF case is appropriate. Furthermore, heat generation/absorption may be important in weak electrically conducting polymeric liquids due to the nonisothermal situation and also due to the cation/anion salts dissolved in them. Ali (2007) analyzed the effect of lateral mass flux on the natural convection boundary layer induced by a heated vertical plate embedded in a saturated porous medium with an exponential decaying heat generation. Layek et al. (2007) investigated the structure of the boundary layer stagnation-point flow and heat transfer over a stretching sheet in a porous medium subject to suction or blowing and in the presence of internal heat generation or absorption by using a similarity analysis. Abel et al. (2007) have investigated heat transfer in a viscoelastic fluid past a stretching sheet with non-uniform heat source. Abel et al. (2007) investigated on non-Newtonian boundary layer flow past a stretching sheet taking into account of non-uniform heat source and frictional heating. Abel and Mahesha (2008) studied the magnetohydrodynamic boundary layer flow and heat transfer characteristic of a non-Newtonian viscoelastic fluid over a flat sheet with variable thermal conductivity in the presence of thermal radiation and non-uniform heat source. They have reported that the combined effect of variable thermal conductivity, radiation and non-uniform heat source have significant impact in controlling the rate of heat transfer in the boundary layer region. Abel et al. (2009) studied the effect of non-uniform heat source on MHD heat transfer in a liquid film over an unsteady stretching sheet. Pal and Chatterjee (2010) analyzed the heat and mass transfer in MHD non-Darcian flow of a micropolar fluid over a stretching sheet embedded in a porous media with non-uniform heat source and thermal radiation. Zheng et al. (2011) studied the analytic solutions of unsteady boundary flow CHAPTER 1. INTRODUCTION 38 and heat transfer on a permeable stretching sheet with non-uniform heat source/sink. Mahantesh et al. (2011) analyzed the heat transfer in MHD viscoelastic boundary layer flow over a stretching sheet with thermal radiation and non-uniform heat source/sink. Recently, Pal (2011) studied the combined effects of non-uniform heat source/sink and thermal radiation on heat transfer over an unsteady stretching permeable surface. 1.10.8 Effects of Soret and Dufour The effect of diffusion-thermo and thermal-diffusion of heat and mass has been developed by Chapman and Cowling (1952) and Hirshfelder et al. (1954) from the kinetic theory of gases. Sparrow et al. (1964) have considered diffusion-thermo effects in stagnationpoint flow of air with injection of gases of various molecular weights into the boundary layer. Thermal diffusion or Soret effect corresponds to species differentiation developing in an initial homogeneous mixture submitted to a thermal gradient. On the other hand, diffusion-thermo or Dufour effect corresponds to the energy flux caused by a concentration gradient in a binary fluid or mixture. The Dufour effect was found to be of order of considerable magnitude such that it cannot be ignored (Eckert and Drake, (1972)). Kafoussias and Williams (1995) considered the boundary layer flows in presence of Soret and Dufour effects associated with thermal diffusion and diffusion thermo for the mixed forced-natural convection problem. Anghel et al. (2000) analyzed the Dufour and Soret effects on free convection boundary-layer over a vertical surface embedded in a porous medium. Singh and Kumar (2001) studied the MHD free convection and mass transfer flow with heat source and thermal diffusion. Postelnicu (2004) has examined Soret and Dufour effects on combined heat and mass transfer in natural convection boundary layer flow in a Darcian porous medium in the presence of transverse magnetic field. Alam and Rahman (2005, 2006) analyzed the Dufour and Soret effects on mixed and free convection heat and mass transfer flow past a vertical porous flat plate embedded in a porous medium in absence/presence of variable suction, respectively. In many studies, Dufour and Soret effect are neglected on the basis that they are of a smaller order of magnitude than the effects described by Fourier’s and Fick’s. Thermal-diffusion (Soret) and diffusion-thermo (Dufour) effects have been found to appreciably influence the flow field in mixed convection boundary-layer over a vertical surface embedded in a porous medium. Alam and Rahman (2006) investigated the Dufour and Soret effects on mixed convection flow past a vertical porous flat plate with variable suction. Alam et al. (2006) have stud- CHAPTER 1. INTRODUCTION 39 ied the Dufour and Soret effects on steady free convection and mass transfer flow past a semi-infinite vertical porous plate in a porous medium. Alam et al. (2007) studied the diffusion-thermo and thermal-diffusion effects on free convective heat and mass transfer flow in a porous medium with time dependent temperature and concentration. Chamkha and Ben-Nakhi (2008) considered the mixed convection flow with thermal radiation along a vertical permeable surface immersed in a porous medium in the presence of Soret and Dufour effects. Mohamed Abo El-Aziz (2008) have investigated the combined effects of thermal-diffusion and diffusion-thermo on MHD heat and mass transfer over a permeable stretching surface with thermal radiation. El-Aziz (2008) investigated the combined effects of thermal-diffusion and diffusion-thermo on MHD heat and mass transfer over a permeable stretching surface with thermal radiation. Maleque (2009) studied Soret effect on convective heat and mass transfer past a rotating porous disk and he neglected the Dufour effect. Rani and Kim (2009) studied a numerical study of the Dufour and Soret effects on unsteady natural convection flow past an isothermal vertical cylinder. Ahmed (2009) investigated the Dufour and Soret effects on free convective heat and mass transfer over a stretching surface considering suction or injection. Recently, numerical study of free convection magnetohydrodynamic heat and mass transfer due to a stretching surface under saturated porous medium with Soret and Dufour effects was also discussed by Anwar Beg et al. (2009). Postelnicu (2010) analyzed the heat and mass transfer by natural convection at a stagnation point in a porous medium considering Soret and Dufour effects. Hayat et al. (2010) analyzed the heat and mass transfer for Soret and Dufours effect on mixed convection boundary layer flow over a stretching vertical surface in a porous medium filled with a viscoelastic fluid. Recently, Pal and Chatterjee (2011) investigated mixed convection MHD heat and mass transfer past a stretching sheet with Ohmic dissipation Soret and Dufour effects considering micropolar fluid. Recently, Anjali and Uma (2011) analyzed the Soret and Dufour effects on MHD slip flow with thermal radiation over a porous rotating infinite disk. 1.10.9 Effects of Chemical Reaction The chemical reaction can be codified as either a heterogeneous or a homogeneous process. This depends on whether it occurs at an interface or as a single-phase volume reaction. A few representative fields of interest where combined heat and mass transfer with a chemical reaction and thermal radiation plays an important role are design of chemical CHAPTER 1. INTRODUCTION 40 processing equipment, cooling towers, etc. In many transport processes existing in nature and industrial applications in which heat and mass transfer is a consequence of buoyancy effects caused by diffusion of heat and chemical species. The study of such processes is useful for improving a number of chemical technologies, such as polymer production and food processing. In nature, the presence of pure air or water is impossible. Some foreign mass may be present either naturally or mixed with the air or water. The presence of a foreign mass in air or water causes some kind of chemical reaction. During a chemical reaction between two species, heat is also generated. In most cases of chemical reaction, the reaction rate depends on the concentration of the species itself. Anjalidevi and Kandasamy (1999) studied the effects caused by chemical-diffusion mechanisms and the inclusion of a general chemical reaction of order n on the combined forced and natural convection flows over a semi-infinite vertical plate immersed in an ambient fluid. They stated that the presence of pure air or water is impossible in nature and that some foreign mass may be present either naturally or mixed with air or water. Mulolani and Rahman (2000) studied laminar natural convection flow over a semi-infinite vertical plate under the assumption that the concentration of species along the plate follows some algebraic law with respect to chemical reaction. They obtained similarity solutions for different order of reaction rates and Schmidt number. Muthucumaraswamy and Ganesan (2001) studied the effect of the chemical reaction and injection on flow characteristics in an unsteady upward motion of an isothermal plate. Prasad et al. (2003) studied the influence of reaction rate on the transfer of chemically reactive species in the laminar, non-Newtonian fluid immersed in porous medium over a stretching sheet. They concluded that the effect of chemical reaction is to reduce the thickness of concentration boundary layer and to increase the mass transfer rate from the sheet to the surrounding fluid and that this effect is more effective for zero and first-order reactions than second-order and third-order reactions. A reaction is said to be first-order if the rate of reaction is directly proportional to concentration itself. The problem of combined heat and mass transfer of an electrically conducting fluid in MHD natural convection adjacent to a vertical surface is analyzed by Chen (2004) by taking into account the effects of Ohmic heating and viscous dissipation but neglected chemical reaction of the species. Ghaly and Seddeek (2004) have investigated the effect of chemical reaction, heat and mass transfer on laminar flow along a semi-infinite horizontal plate with temperature dependent viscosity. Kandasamy et al. (2005) investigated the effects of chemical reaction, heat source and thermal stratification CHAPTER 1. INTRODUCTION 41 on heat and mass transfer in MHD flow over a vertical stretching surface. The problem of diffusion of chemically reactive species of a non-Newtonian fluid immersed in a porous medium over a stretching sheet was considered by Akyildiz et al. (2006). Raptis and Perdikis (2006) considered the problem of the steady two-dimensional flow of an incompressible viscous and electrically conducting fluid over a non-linearly semi-infinite stretching sheet in the presence of a chemical reaction and under the influence of a magnetic field. Postelnicu (2007) studied the influence of chemical reaction on heat and mass transfer by natural convection from vertical surfaces in porous media considering Soret and Dufour effects. Afify (2007) analyzed the effects of Temperature-Dependent Viscosity with Soret and Dufour Numbers on Non-Darcy MHD Free Convective Heat and Mass Transfer Past a Vertical Surface Embedded in a Porous Medium. Kandasamy and Palanimani (2007) carried out an analysis on the effects of chemical reactions, heat, and mass transfer on non-linear magnetohydrodynamic boundary layer flow over a wedge with a porous medium in the presence of Ohmic heating and viscous dissipation. Seddeek et al. (2007) analyzed the effects of chemical reaction and variable viscosity on hydromagnetic mixed convection heat and mass transfer for Hiemenz flow through porous media with radiation. El-Amin et al. (2008) studied the effects of chemical reaction and double dispersion on non-Darcy free convection heat and mass transfer. Alam et al. (2009) studied transient magnetohydrodynamic free convective heat and mass transfer flow with thermophoresis past a radiative inclined permeable plate in the presence of a variable chemical reaction and temperature-dependent viscosity. Mohamed and Abo-Dahab (2009) presented for the effects of chemical reaction and thermal radiation on hydromagnetic free convection heat and mass transfer for a micropolar fluid via a porous medium bounded by a semi-infinite vertical porous plate in the presence of heat generation. Pal and Talukdar (2010) analyzed the buoyancy and chemical reaction effects on MHD mixed convection heat and mass transfer in a porous medium with thermal radiation and Ohmic heating. Das (2011) analyzed the effect of chemical reaction and thermal radiation on heat and mass transfer flow of MHD micropolar fluid in a rotating frame of reference. Recently, Pal and Talukdar (2011) studied the combined effects of Joule heating and chemical reaction on unsteady magnetohydrodynamic mixed convection of a viscous dissipating fluid over a vertical plate in porous media with thermal radiation.
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