RESEARCH PROJECTS AT UTT Sommaire Material Flow Information and Analysis of Mercury-containing Products....................................................................... 2 Development of optical nanosensors using block copolymers ........................................................................................ 3 Dynamic simulation by finite element of the female bust deformability......................................................................... 4 Project :3D modeling of 3D structure with a measuring arm (laser) ................................................................................ 5 Project :Development of a crumpling machine ................................................................................................................ 5 Project :LCA (Life Cycle Analysis) of crumpled paper sheets ............................................................................................ 6 Project : Hypergraph modeling of the crumpling process of flexible sheet for CAD application ..................................... 6 Project :Descriptive modeling of the crumpling process of flexible sheet ....................................................................... 7 Project :LCA (Life Cycle Analysis) comparison of non food products based on agro-resources....................................... 7 Characterisation of mechanical behaviour of a nanocrystalline layer using micro-dots and instrumented nanoindentor ............................................................................................................................................................................ 8 Surface Mechanical Attrition Treatment (SMAT) ............................................................................................................. 9 1 Material Flow Information and Analysis of Mercury-containing Products Junbeum KIM, Ph.D. Assistant Professor CREIDD Research Centre on Environmental Studies & Sustainability University of Technology of Troyes, 12 rue, Marie Curie, BP 2060, Troyes 10010, France, Email: [email protected] Although mercury use is decreasing, mercury continues to pose a serious risk to human health and the environment. Mercury and its compounds are recognized as highly toxic substances. Mercury-discharging sources can be divided mainly into two types of facilities. One is intentional facilities which produce mercury-containing products such as batteries, lamps and thermostats by intentionally using mercury, and the other is unintentional facilities that discharge mercury via processes. Coal combustion, incineration and nonferrous metal production facilities are belonging to the unintentional facilities. Material flow analysis is “a systematic assessment of the flows and stocks of materials within a system defined in space and time” (Brunner and Rechberger, 2004). In this study, we will study about background of mercury material and its flow information. We will select some mercury contained products and study their materials flows from its manufacture, import, distribution, disposal throughout its recovery. Also we will study below items; - Collection, transportation, treatment and storage of mercury-contained waste products (e.g., blood pressure gauge, thermometer, compact fluorescent lamp, and battery) - Collection, transportation, treatment and storage of industrial waste (incinerator waste ash, wastewater sludge etc. which are including mercury) - Regulation and categories of waste by mercury contained concentration and types etc. Figure 1. Concept of mercury material flow information and analysis [1] UNEP (United Nations Environment Programme), Global Mercury Assessment 2013, Sources, Emissions, Releases and Environmental Transport [2] Paul H. Brunner and Helmut Rechberger, Practical Handbook of Material Flow Analysis, Lewis Publishers, 2004. [3] http://www.ec.gc.ca/lcpe-cepa/default.asp?lang=en&n=86e14658-1 2 Development of optical nanosensors using block copolymers Scientfic Supervisor: Thomas MAURER Host Institution: Laboratoire de Nanotechnologie et d’Instrumentation Optique(LNIO)/ Université de Technologie de Troyes (UTT) Address : 12 rue Marie Curie, 10000 TROYES email : [email protected] Tel : +33 (0) 3 25 75 97 11 Fax : +33 (0) 3 25 71 84 56 Description of the research project: Context For the past fifteen years, the investigations of the Localized Surface Plasmon Resonance (LSPR) for 50nm-100nm Au nanoparticles has opened new perspectives for optical nanosensors. Indeed, there is not any longer the need of using a prism in order to excite plasmons. The application possibilities are all the more numerous as the fundamental studies go to the direction of single molecule sensing. What is at stake today is the development of such large scale and low cost devices. Scientific aim The scientific aim is here to use copolymers as ecthing masks for Reactive Ion Etching (RIE) in order to fabricate arrays of Au nanocylinders [1]. The idea consists in using PS-PMMA copolymers and in organizing them into domains after annealing. This organization into domains will be controlled by AFM. Then, since the two polymers are not attacked with the same speed by the plasma during the RIE procedure, it will conduct to the creation of a etching mask (made of holes). The next step is the attack of the Au under-layer via the holes during another RIE process. Finally, this process should allow the fabrication of arrays of Au cylinders over large surfaces [2]. The interest of such a process is that it does not require expensive technology and paves the way for large-scale production. Once the optical nanosensors is made by the young scientist, sensing tests will be led in order to detect small quantities of different molecules. [1] K. Asakawa and A. Fujimoto, Appl. Opt. 44 (2005) N°34 [2] C. K. Kang et al., Current Applied Physics 9 (2009) 197-200 3 Dynamic simulation by finite element of the female bust deformability Professor Abel Cherouat GAMMA3 - Advanced Automatic Mesh Generation Techniques University of Technology of Troyes, 12 rue, Marie Curie, BP 2060, Troyes 10010, France, Email: [email protected] Objectives: Modeling the behavior of female busts on static or dynamic and take into account the different biological components of the breast. The numerical simulation of the deformability of breast enable the development of new techniques for corsetry confections or new medical equipment, especially for the detection of breast cancer. In this project, we hope to develop numerical simulation CATIA-COMSOL or ABAQUS or breast-static and dynamics that takes into account the components (skin, fat, glands or fibers and suspensory ligaments of Cooper) under the effect of gravity laoding. 4 Project :3D modeling of 3D structure with a measuring arm (laser) ROHMER Serge, Center of Research and Interdisciplinary Studies on Sustainable Development, [email protected] Prerequisite: Mechanical engineering, 1 student The main objective is to develop a procedure for the 3D modeling of crumpled papers, in order to create a batabase of references crumpled surfaces. Crumpling is a folding action derived from origami techniques. A single paper sheet can be folded and crumpled to create three-dimensional structures (Fig. 1). In order to understand the behavior of crumpled structures, we firstly would like to reshape thecrumpled surfaces with a 3D measuring arm (Fig. 2). The student will define: the technical support to immobilize the crumpled structures, the operational procedure to capture the points of the structures, and the procedure for the 3D treatment of the points to reshape the surfaces. Fig. 1. Crumpled structures Fig. 2. 3D Measuring process Project :Development of a crumpling machine ROHMER Serge, Center of Research and Interdisciplinary Studies on Sustainable Development, [email protected] Prerequisite: Mechanical Engineering Maximum 2 students Crumpling is a new origami technique to fold papers by creating crease patterns (Fig. 1). The objective is to develop a machine to crumple paper sheet based on a concept developed at the CREIDD lab. The student will be in charge of the development of the technical solutions based on the Value Engineering approach. The student(s) will define the functional specification, will propose concept of prototypes, and finally will create a virtual prototype of the machine to simulate its functioning. (a) folded (b) unfolded Fig.4. Flexible packaging based on crumpled paper 5 Project :LCA (Life Cycle Analysis) of crumpled paper sheets ROHMER Serge, Center of Research and Interdisciplinary Studies on Sustainable Development. [email protected] Prerequisite :Eco-design, LCA, environmental assessment, SIMAPRO maximum 2 students Crumpling is a new origami technique to fold papers by creating crease patterns (Fig. 1); such structures can be used for packaging. This technique has been developed by CREIDD and some partners. The main objective of this project is to assess the environmental impacts of crumpled structures by developing a simplified environmental tool. The student will have to define the state of the art on paper production and environmental assessment of paper production. He will propose a simplified Life Cycle Analysis for the generic evaluation of environmental impacts of crumpled structures. Fig. 1. Crumpled structures Project : Hypergraph modeling of the crumpling process of flexible sheet for CAD application ROHMER Serge, Center of Research and Interdisciplinary Studies on Sustainable Development. [email protected] Prerequisite : based method, CAD, face adjacency graph (FAG) 1 student Crumpling is a new origami technique to fold papers by creating crease patterns (Fig. 1); such structures can be used for packaging. This technique has been developed by CREIDD and some partners. The main objective is to propose a modeling of the crumpling process based on a labeled hypergraph representation for CAD applications. The hypergraph modeling uses the concepts of adjacency, superposition, morphocopy relations between faces of a crumpled structure. Fig. 1. Crumpled structures 6 Project :Descriptive modeling of the crumpling process of flexible sheet ROHMER Serge, Center of Research and Interdisciplinary Studies on Sustainable Development. [email protected] Prerequisite : industrial process modeling, video analysis Maximum 2 students Crumpling is a new origami technique to fold papers by creating crease patterns; such structures can be used for packaging. This technique has been developed by CREIDD and some partners. The main objective is to create a descriptive modeling of the crumpling process based on the analysis of videos of origami during their folding process. Fig. 1. Cage used for the video of the crumpling process performed by an operator Project :LCA (Life Cycle Analysis) comparison of non food products based on agro-resources ROHMER Serge, Center of Research and Interdisciplinary Studies on Sustainable Development. [email protected] Prerequisite: Eco-design, LCA, environmental assessment, SIMAPRO 1 student The project contains sub-objectives : - state of the art of non food products based on agro-resources, - state of the art of scientific papers on LCA studies of products based on agro-resources, - choice of an industrial sector (packaging or construction, …), - comparative analysis of the LCA of product in the associated industrial sector, - Analysis of the comparison (trends of the environmental impacts, …). 7 Characterisation of mechanical behaviour of a nanocrystalline layer using microdots and instrumented nano-indentor Surface Mechanical Attrition Treatment (SMAT – patented treatment in 2000 by our lab LASMIS) is a recently developed promising technique to generate a nanocrystallised layer on the surface of metallic components. As a strong refinement of the grain size can lead to a significant increase of strength due to the Hall-Petch relationship, the nanocrystalline layer induced by SMAT is very attractive. The difficulty is to characterise the mechanical behaviour of this nanocrystalline layer itself (thickness between 30 and 50 m composed of nano-grains). In this work, a nanocrystallised layer will be synthetized at the surface of 316L stainless steel by means of SMAT. Micro-dots will be then realised using a new technique based on chemically synthetized mask (patent pending). Both lithography and etching techniques will be combined. This part will be conducted in collaboration with the LNIO (nanofab activity). Finally, the mechanical behaviour of the nanocrystalline layer will be characterised performing compressive tests on the micro-dots thanks to instrumented nano-indentor machine (all these equipments are available in our university). This project is part of the national CNRS “risk” topic. For more information, please contact Mrs Delphine Retraint Tel.: +33 3 25 71 56 68; fax: +33 3 25 71 56 75. E-mail address: [email protected] 8 Surface Mechanical Attrition Treatment (SMAT) Due to its excellent corrosion resistance and its biocompatibility, austenitic 316L stainless steel is a widely used material in environments such as the petrochemical, chemical, nuclear, and food industries. However, in its coarsegrained (CG) state, austenitic stainless steel possesses relatively low strength and poor wear resistance that make it unsuitable for many structural applications. It is well known that a strong refinement of the grain size can lead to additional increase of strength due to the Hall–Petch relationship. So, with the emergence of methods to produce nanostructures, new routes to enhance properties of metals and alloys are arising. Among them, the recently developed surface mechanical attrition treatment (SMAT – patented treatment in 2000 by our lab LASMIS) appears as a promising technique to generate a nanocrystallised layer on the surface of metallic materials. SMAT provides an alternative approach to effectively upgrade the global properties of engineering materials and this, without change of the chemical composition. As SMAT is simple, flexible and low cost, this technique is potentially very useful in industrial applications. In this work, a nanocrystallised layer will be synthetized at the surface of 316L stainless steel by means of SMAT performed at different temperatures. Investigations of the SMATed microstructure (optical and electron microscope observations, X-ray diffraction measurements), the residual stresses and the micro-hardness will be carried out (all the equipments are available in our university). In a second step, the influence of the SMAT on the mechanical properties of the treated steel specimens will be studied (tensile and/or fatigue tests). For more information, please contact Mrs Delphine Retraint Tel.: +33 3 25 71 56 68; fax: +33 3 25 71 56 75. E-mail address: [email protected] 9
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