Catalysts for polyurethane foam Selection guide Catalysts for the manufacturing of polyurethane foam Our product range includes a substantial number of catalysts to meet todays technical requirements of various foam formulations. TEGOAMIN® product range Flexible foam 2 Rigid foam Products Chemical description Ether TEGOAMIN® 100 Triethylenediamine HR-foam • • TEGOAMIN® 33 33 % Triethylenediamine 67 % Dipropyleneglycol TEGOAMIN® AS-33 Acid-blocked TEGOAMIN® 33 • • • • TEGOAMIN® BDE 70 % Bis(2-dimethylaminoethyl)ether 30 % Dipropyleneglycol • • TEGOAMIN® BDE PLUS Amine blend based on Bis (2-dimethylaminoethyl)ether TEGOAMIN® B 75 75 % TEGOAMIN® 33 25 % TEGOAMIN® BDE TEGOAMIN® DMEA N,N-Dimethylethanolamine TEGOAMIN® LDI Special tertiary amine catalyst TEGOAMIN® SMP Special tertiary amine catalyst TEGOAMIN® PTA Special tertiary amine catalyst TEGOAMIN® 41 1, 3, 5-tris (3-[dimethylamino]propyl)hexahydro-s-triazine TEGOAMIN® PMDETA N,N,N‘,N‘‘,N‘‘Pentamethyldiethylenetriamine TEGOAMIN® DMCHA N,N-Dimethylcyclohexylamine TEGOAMIN® DMEE N,N-Dimethylaminoethoxyethanol TEGOAMIN® DMDEE 2,2‘-Dimorpholinodiethylether TEGOAMIN® DMP N,N‘-Dimethylpiperazine TEGOAMIN® E 5 Special tertiary amine catalyst TEGOAMIN® E 10 Special tertiary amine catalyst TEGOAMIN® E 12 Special tertiary amine catalyst TEGOAMIN® ZE 1 Emission free, special tertiary amine catalyst TEGOAMIN® ZE 4 Low emission, special tertiary amine catalyst TEGOAMIN® ZE 5 Emission free, special tertiary amine catalyst (gel). TEGOAMIN® MEG 33 % Triethylenediamine 67 % Ethyleneglycol TEGOAMIN® AS MEG Acid-blocked TEGOAMIN® MEG Shoe sole systems Ester-foam • • • • • • • • • • • • • • • • • • • • • • • • • • • Most commonly used catalysts for flexible polyether foam (excerpt) Type of catalyst/Product name Special performance Amine catalysts TEGOAMIN® 33 Preferred as a co-catalyst, catalyzes both the gelling and the blowing reaction. TEGOAMIN® BDE Preferred as a very active co-catalyst used to catalyze particularly the blowing reaction. TEGOAMIN® B 75 Very versatile for all foam densities. Does not need a co-catalyst due to a well balanced blowing/gelling action. TEGOAMIN® DMEA Highly blow-efficient, good co-catalyst, particularly when used with TEGOAMIN® 33. TEGOAMIN® PTA Very versatile for all foam densities. Does not need a co-catalyst due to a well balanced blowing/gelling action. TEGOAMIN® SMP Especially well suited for foams in the low and medium density range. Improves the hardness by about 5 – 10 %. TEGOAMIN® ZE 1 Emission free, special tertiary amine catalyst. TEGOAMIN® ZE 4 Low emission, special tertiary amine catalyst. Metal catalysts KOSMOS® 29 Stannous octoate, essential for all flexible polyether foams. KOSMOS® PRO 1 Stannous neodecanoate, 2-Ethylhexanoic acid free alternative to KOSMOS® 29. KOSMOS® EF Emission free stannous catalyst for all kind of flexible polyether foams. Most commonly used catalysts for high resilience foam (excerpt) Type of catalyst/Product name Special performance HR slabstock foam HR molded foam Amine catalysts TEGOAMIN® BDE Essential for the blowing reaction. TEGOAMIN® 33 Essential for the gelling reaction. TEGOAMIN® B 75 Well balanced amine catalyst regarding blowing & gelling reaction. TEGOAMIN® AS-33 Delayed action version of TEGOAMIN® 33. TEGOAMIN® MS 40 Low corrosion delayed action version of TEGOAMIN® 33. TEGOAMIN® ZE 1 Emission free, special tertiary amine catalyst (balanced-gel). TEGOAMIN® ZE 4 Low emission, special tertiary amine catalyst. TEGOAMIN® ZE 5 Emission free, special tertiary amine catalyst (gel). • • • • • • • • • • • • • • Metal catalysts KOSMOS® 19 KOSMOS® 29 Preferably used to accelerate the gelling reaction. • KOSMOS® PRO 1 Stannous neodecanoate, 2-Ethylhexanoic acid free alternative to KOSMOS® 29. KOSMOS® 54 Metal catalyst for cold flow prevention (in combination with KOSMOS® 29 and ORTEGOL® 204 used for DBTL free HR-slabstock foams). • KOSMOS® EF Emission free stannous catalyst for all kind of HR-slabstock foams. • • 3 Most commonly used catalysts for polyester foam (excerpt) Product name Special performance TEGOAMIN® E 5 Low-fogging alternative to CPE. Contains no ethoxylated nonyl phenol. TEGOAMIN® E 10 Low-odor alternative to NMM. Contains no ethoxylated nonyl phenol. TEGOAMIN® E 12 High efficient low-odor catalyst which improves the skin curing. Contains no ethoxylated nonyl phenol. All the above amines can be used solely without any need for a co-catalyst. Most commonly used catalysts for rigid foam (excerpt) 1 ) Preferred type of formulation Type of catalyst/Product name Chemical substance Appliance Discont. appl. Cont. panel PUR • • Cont. panel PIR Low density Spray OCF Amine catalysts TEGOAMIN® 33 33 % Triethylenediamine 67 % Dipropyleneglycol TEGOAMIN® 41 1, 3, 5-tris (3-[dimethyl-amino] propyl)hexa-hydro-s-triazine TEGOAMIN® BDE 70 % Bis(2-dimethylaminoethyl)ether 30 % Dipropyleneglycol TEGOAMIN® BDE PLUS Amine blend based on Bis(2-dimethy laminoethyl)ether TEGOAMIN® DMCHA N,N-Dimethylcyclohexylamine TEGOAMIN® DMDEE 2,2‘-Dimorpholinodiethylether TEGOAMIN® DMEA N, N - Dimethylethanolamine TEGOAMIN® DMEE N,N-Dimethylaminoethoxyethanol TEGOAMIN® PMDETA N,N,N‘,N‘‘,N‘‘-Pentamethyldiethylenetriamine • • • • • • • • • • • • • • • • • • • • • • • • • Metal catalysts KOSMOS® 33 Potassium acetate KOSMOS® 75 LO Potassium octoate (low OH version) KOSMOS® 75 MEG Potassium octoate (low viscosity) KOSMOS® 19 Dibutyltindilaurate 1) • • • • Catalysts are offered as a regional service. 4 Most commonly used catalysts for shoe sole systems (excerpt) Product name Special performance TEGOAMIN® MEG Polyester shoe sole systems/microcellular polyurethane systems. TEGOAMIN® AS MEG Delayed action version of TEGOAMIN® MEG. KOSMOS® product range 5 Product name Chemical basis Special performance KOSMOS® 29 Stannous octoate Absolutely essential as co-catalyst for all conventional (hot cured) flexible polyether foams. KOSMOS® PRO 1 Stannous neodecanoate 2-Ethylhexanoic acid free alternative to KOSMOS® 29. KOSMOS® 19. Dibutyltindilaurate Preferably used to accelerate the gelling reaction in formulations for high resilience foams and for special rigid foams. KOSMOS® 75 MEG/75 LO KOSMOS® 33 Potassium octoate Potassium acetate Catalyzes the trimerization of isocyanates; also used as a catalyst for rigid foams of the modified isocyanurate (high index) type. KOSMOS® 54 Special zinc catalyst Metal catalyst for cold flow prevention (in combination with KOSMOS® 29 and ORTEGOL® 204 used for DBTL free HR-slabstock foams). KOSMOS® EF Special stannous catalyst Emission free catalyst for all kind of flexible foam. www.evonik.com/pu-contacts For more detailed information or to obtain a brochure which addresses a specific area of interest, please visit our website. KOSMOS®, ORTEGOL® and TEGOAMIN® are brands of Evonik Degussa GmbH. This information and all further technical advice are based on our present knowledge and experience. However, it implies no liability or other legal responsibility on our part, including with regard to existing third party intellectual property rights, especially patent rights. In particular, no warranty, whether express or implied, or guarantee of product properties in the legal sense is intended or implied. We reserve the right to make any changes according to technological progress or further developments. The customer is not released from the obligation to conduct careful inspection and testing of incoming goods. Performance of the product described herein should be verified by testing, which should be carried out only by qualified experts in the sole responsibility of a customer. Reference to trade names used by other companies is neither a recommendation, nor does it imply that similar products could not be used. Evonik Nutrition & Care GmbH Goldschmidtstraße 100 45127 Essen Germany 08/2015 phone +49 201 173-2464 [email protected] www.evonik.com/polyurethane-additives
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