Catalysts for polyurethane foam

Catalysts for
polyurethane foam
Selection guide
Catalysts for the manufacturing
of polyurethane foam
Our product range includes a substantial number of catalysts to meet todays technical requirements of various foam formulations.
TEGOAMIN® product range
Flexible foam
2
Rigid foam
Products
Chemical description
Ether
TEGOAMIN® 100
Triethylenediamine
HR-foam
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TEGOAMIN® 33
33 % Triethylenediamine
67 % Dipropyleneglycol
TEGOAMIN® AS-33
Acid-blocked TEGOAMIN® 33
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TEGOAMIN® BDE
70 % Bis(2-dimethylaminoethyl)ether
30 % Dipropyleneglycol
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TEGOAMIN® BDE PLUS
Amine blend based on Bis
(2-dimethylaminoethyl)ether
TEGOAMIN® B 75
75 % TEGOAMIN® 33
25 % TEGOAMIN® BDE
TEGOAMIN® DMEA
N,N-Dimethylethanolamine
TEGOAMIN® LDI
Special tertiary amine catalyst
TEGOAMIN® SMP
Special tertiary amine catalyst
TEGOAMIN® PTA
Special tertiary amine catalyst
TEGOAMIN® 41
1, 3, 5-tris (3-[dimethylamino]propyl)hexahydro-s-triazine
TEGOAMIN® PMDETA
N,N,N‘,N‘‘,N‘‘Pentamethyldiethylenetriamine
TEGOAMIN® DMCHA
N,N-Dimethylcyclohexylamine
TEGOAMIN® DMEE
N,N-Dimethylaminoethoxyethanol
TEGOAMIN® DMDEE
2,2‘-Dimorpholinodiethylether
TEGOAMIN® DMP
N,N‘-Dimethylpiperazine
TEGOAMIN® E 5
Special tertiary amine catalyst
TEGOAMIN® E 10
Special tertiary amine catalyst
TEGOAMIN® E 12
Special tertiary amine catalyst
TEGOAMIN® ZE 1
Emission free, special tertiary
amine catalyst
TEGOAMIN® ZE 4
Low emission, special tertiary
amine catalyst
TEGOAMIN® ZE 5
Emission free, special tertiary
amine catalyst (gel).
TEGOAMIN® MEG
33 % Triethylenediamine
67 % Ethyleneglycol
TEGOAMIN® AS MEG
Acid-blocked TEGOAMIN® MEG
Shoe sole systems
Ester-foam
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Most commonly used catalysts for flexible polyether foam (excerpt)
Type of catalyst/Product name
Special performance
Amine catalysts
TEGOAMIN® 33
Preferred as a co-catalyst, catalyzes both the gelling and the blowing reaction.
TEGOAMIN® BDE
Preferred as a very active co-catalyst used to catalyze particularly the blowing reaction.
TEGOAMIN® B 75
Very versatile for all foam densities. Does not need a co-catalyst due to a well
balanced blowing/gelling action.
TEGOAMIN® DMEA
Highly blow-efficient, good co-catalyst, particularly when used with TEGOAMIN® 33.
TEGOAMIN® PTA
Very versatile for all foam densities. Does not need a co-catalyst due to a well
balanced blowing/gelling action.
TEGOAMIN® SMP
Especially well suited for foams in the low and medium density range.
Improves the hardness by about 5 – 10 %.
TEGOAMIN® ZE 1
Emission free, special tertiary amine catalyst.
TEGOAMIN® ZE 4
Low emission, special tertiary amine catalyst.
Metal catalysts
KOSMOS® 29
Stannous octoate, essential for all flexible polyether foams.
KOSMOS® PRO 1
Stannous neodecanoate, 2-Ethylhexanoic acid free alternative to KOSMOS® 29.
KOSMOS® EF
Emission free stannous catalyst for all kind of flexible polyether foams.
Most commonly used catalysts for high resilience foam (excerpt)
Type of catalyst/Product name
Special performance
HR slabstock foam
HR molded foam
Amine catalysts
TEGOAMIN® BDE
Essential for the blowing reaction.
TEGOAMIN® 33
Essential for the gelling reaction.
TEGOAMIN® B 75
Well balanced amine catalyst regarding blowing & gelling reaction.
TEGOAMIN® AS-33
Delayed action version of TEGOAMIN® 33.
TEGOAMIN® MS 40
Low corrosion delayed action version of TEGOAMIN® 33.
TEGOAMIN® ZE 1
Emission free, special tertiary amine catalyst (balanced-gel).
TEGOAMIN® ZE 4
Low emission, special tertiary amine catalyst.
TEGOAMIN® ZE 5
Emission free, special tertiary amine catalyst (gel).
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Metal catalysts
KOSMOS® 19
KOSMOS® 29
Preferably used to accelerate the gelling reaction.
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KOSMOS® PRO 1
Stannous neodecanoate, 2-Ethylhexanoic acid free alternative
to KOSMOS® 29.
KOSMOS® 54
Metal catalyst for cold flow prevention (in combination with
KOSMOS® 29 and ORTEGOL® 204 used for DBTL free
HR-slabstock foams).
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KOSMOS® EF
Emission free stannous catalyst for all kind of HR-slabstock foams.
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Most commonly used catalysts for polyester foam (excerpt)
Product name
Special performance
TEGOAMIN® E 5
Low-fogging alternative to CPE. Contains no ethoxylated nonyl phenol.
TEGOAMIN® E 10
Low-odor alternative to NMM. Contains no ethoxylated nonyl phenol.
TEGOAMIN® E 12
High efficient low-odor catalyst which improves the skin curing.
Contains no ethoxylated nonyl phenol.
All the above amines can be used solely without any need for a co-catalyst.
Most commonly used catalysts for rigid foam (excerpt) 1 )
Preferred type of formulation
Type of catalyst/Product name
Chemical substance
Appliance
Discont.
appl.
Cont.
panel PUR
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Cont.
panel PIR
Low
density
Spray
OCF
Amine catalysts
TEGOAMIN® 33
33 % Triethylenediamine
67 % Dipropyleneglycol
TEGOAMIN® 41
1, 3, 5-tris (3-[dimethyl-amino] propyl)hexa-hydro-s-triazine
TEGOAMIN® BDE
70 % Bis(2-dimethylaminoethyl)ether 30 %
Dipropyleneglycol
TEGOAMIN® BDE PLUS
Amine blend based
on Bis(2-dimethy
laminoethyl)ether
TEGOAMIN® DMCHA
N,N-Dimethylcyclohexylamine
TEGOAMIN® DMDEE
2,2‘-Dimorpholinodiethylether
TEGOAMIN® DMEA
N, N - Dimethylethanolamine
TEGOAMIN® DMEE
N,N-Dimethylaminoethoxyethanol
TEGOAMIN® PMDETA
N,N,N‘,N‘‘,N‘‘-Pentamethyldiethylenetriamine
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Metal catalysts
KOSMOS® 33
Potassium acetate
KOSMOS® 75 LO
Potassium octoate
(low OH version)
KOSMOS® 75 MEG
Potassium octoate
(low viscosity)
KOSMOS® 19
Dibutyltindilaurate
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Catalysts are offered as a regional service.
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Most commonly used catalysts for shoe sole systems (excerpt)
Product name
Special performance
TEGOAMIN® MEG
Polyester shoe sole systems/microcellular polyurethane systems.
TEGOAMIN® AS MEG
Delayed action version of TEGOAMIN® MEG.
KOSMOS® product range
5
Product name
Chemical basis
Special performance
KOSMOS® 29
Stannous octoate
Absolutely essential as co-catalyst for all conventional (hot cured)
flexible polyether foams.
KOSMOS® PRO 1
Stannous neodecanoate
2-Ethylhexanoic acid free alternative to KOSMOS® 29.
KOSMOS® 19.
Dibutyltindilaurate
Preferably used to accelerate the gelling reaction in formulations for
high resilience foams and for special rigid foams.
KOSMOS® 75 MEG/75 LO
KOSMOS® 33
Potassium octoate
Potassium acetate
Catalyzes the trimerization of isocyanates; also used as a catalyst for
rigid foams of the modified isocyanurate (high index) type.
KOSMOS® 54
Special zinc catalyst
Metal catalyst for cold flow prevention (in combination with
KOSMOS® 29 and ORTEGOL® 204 used for DBTL free
HR-slabstock foams).
KOSMOS® EF
Special stannous catalyst
Emission free catalyst for all kind of flexible foam.
www.evonik.com/pu-contacts
For more detailed information or to obtain a brochure which addresses a
specific area of interest, please visit our website.
KOSMOS®, ORTEGOL® and TEGOAMIN® are brands of Evonik
Degussa GmbH.
This information and all further technical advice are based on our present
knowledge and experience. However, it implies no liability or other
legal responsibility on our part, including with regard to existing third
party intellectual property rights, especially patent rights. In particular,
no warranty, whether express or implied, or guarantee of product
properties in the legal sense is intended or implied. We reserve the
right to make any changes according to technological progress or further
developments. The customer is not released from the obligation to conduct
careful inspection and testing of incoming goods. Performance of the
product described herein should be verified by testing, which should
be carried out only by qualified experts in the sole responsibility of a
customer. Reference to trade names used by other companies is neither a
recommendation, nor does it imply that similar products could not be used.
Evonik Nutrition & Care GmbH
Goldschmidtstraße 100
45127 Essen
Germany
08/2015
phone +49 201 173-2464
[email protected]
www.evonik.com/polyurethane-additives