Sept 12_14 - Blogs at UMass Amherst

The “Extremely Explosive” Carbonyl Diazide
Molecule
X. Zeng, M. Gerken, H. Beckers, and H. Willner, “Synthesis
and Characterization of Carbonyl Diazide, OC(N3)2,”
Inorg Chem.
Inorg.
Chem 2010,
2010 49,
49 9694-9699.
9694 9699
Compare the bond lengths of sodium azide to hydrogen
azide, NaN3 and HN3
A) HNN-N < NaNN-N < HN-NN
B)) HNN-N < HN-NN < NaNN-N
C) NaNN-N < HN-NN < HNN-N
D) NaNN-N < HN-NN = HNN-N
E) HN-NN = HNN-N < NaNN-N
Thanks to Margret J. Geselbracht, Reed College
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Wed, Sept 14
14-Sep
p
Ch 3 73-78
HW:
Predict bond polarity; predict boiling points
EH; relate electronegativity to structure
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ƒ Propose at least three resonance structures for
OC(N3)2
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H
N
N
H
N
N
N
(-1)
(-1)
(+1)
N
N
N
C
(+1)
N
(+1)
N
N
N
(-1)
O
(+1)
N
(-1)
14
N
N
C
N
N
C
N
(+1)
N
N
N
C
N
(-1)
(-1)
(+1)
N
N
O
O
(+1)
N
O
(+1)
N
N
N
N
(-1)
(-1)
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carbonyl diazide, OC(N3)2
The structure of carbonyl diazide, OC(N3)2 , is
exactly what you would predict from Lewis
structures and VSEPR theory.
theory
Use your skills to rank order the following bond
angles: NNN, NNC, NCO
A) NNN < NNC < NCO
B)) NNC
C < NCO
CO < NNN
C) NCO < NNN < NNC
D) NCO = NCN < NNN
16
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Rank the bond
angles
A)) ClSCl
l l < FSF
B) FSF < ClSSl
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Which electron cloud picture corresponds to H2O?
A
B
C
D
E
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