03/15/17 CHEM 4 Quiz 3 (20 points) ANSWER KEY Name 1. (4 points) Provide a term or a name that matches each of the word descriptions below. The average mass of all atoms of a particular element found in nature. atomic weight A collection of atoms each of which has in its nucleus a specific number of protons (the same for each atom in the collection). chemical element An electrically neutral group of atoms held together by chemical bonds acting as the smallest independent particle of a chemical substance. molecule A chemical substance that is made of atoms of at least two different elements. chemical compound A characteristic of an atom that indicates the sum of the numbers of protons and neutrons in its nucleus. mass number A subatomic particle residing in the nucleus of the atom and carrying no electric charge. neutron 2. (4 points) (a) Perform the following conversions. (You do not have to show your work.) 0.670 6.70×105 mg = 8.00×1013 8.00×107 µm2 = kg nm2 4.00 0.000400 km = 2.70×107 pm3 = 2.70×10−23 dm cm3 (b) Compare by placing >, <, =, or ≈ between the two entries in each pair. 1 ft3 > 1000 mm3 1 m2 1L < 1L > 1000 kg/m3 1 ft2 = 1 g/cm3 10 cm ≈ 4 in 1L = 10 dL 1 g/mL = 1 kg/L 1 mL > 100 µL PLEASE TURN OVER!!! 3. (4 points) The temperature of dry ice (sublimation temperature at normal pressure) is – 109°F. Is this higher or lower than the temperature of boiling ethane (a component of bottled gas), which is –88°C? Show all the steps of your work. °C = (°F − 32) / 1.8 = (−109 − 32) / 1.8 = −78.3°C −78.3°C > −88°C The temperature of dry ice is higher than the temperature of boiling ethane. 4. (4 points) Although there is only one naturally occurring isotope of gold, 197Au, the atomic weight of gold given in the modern periodic table is 196.96655, but not 197. Explain. 197 is the mass number of gold-197 isotope (the only isotope found in nature); it is an exact number and an integer as it represents the sum of the numbers of protons and neutrons present in each atom of gold. 196.96655 amu is the mass of gold atoms relative to the mass of carbon-12 atoms with the exact mass of 12 amu. Carbon-12 atom is the modern standard for the atomic mass scale; there no other atom with the mass expressed as an exact number. The only way 197 and not 196.96655 would appear in the periodic table below the Au symbol is to make the standard by assigning exactly 197 amu to one gold-197 atom. 5. (4 points) Gold is the most malleable of all metals; a single gram of it can be beaten into a sheet of one square meter. What would be the thickness of such sheet of gold in millimeters? Show all the steps of your work. Each measured or calculated number should have a unit. The final answer should be recorded with the proper number of significant digits. Volume = Mass / Density = 1.00 g / (19.3 g/cm3) = 0.0518 cm3 Volume = Area × Thickness = 1.00×104 cm2 × Thickness = 0.0518 cm3 Thickness = 0.0518 cm3 / (1.00×104 cm2) = 5.18×10−6 cm = 5.18×10−5 mm = = 0.0000518 mm
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