Impact Objective • Engineer new materials for various applications through innovative manufacturing, green engineering, formulation engineering and interface engineering Sustainable innovations research Based at Imperial College London, the Future Materials Group is an innovative team of researchers headed up by Dr Koon-Yang Lee, who discusses the Group’s multidisciplinary approach to sustainable materials development below Can you please begin by introducing yourself? I am a Lecturer in Composite Manufacturing in the Department of Aeronautics at Imperial College London (ICL). In January 2015, I founded the Future Materials Group (FMG), a young and dynamic research group focusing on (nano)cellulose-based materials, polymer (nano)composites, sustainable composites, emulsions and foams. In what way do you work across chemistry, physics, materials science and engineering? My research is highly multidisciplinary, with an emphasis on tailoring the interface between two (or more) phases to bridge the gap between chemistry, physics, materials science and engineering. The focus and application areas of my research include cellulose and nanocellulose engineering; design and fabrication of renewable polymer composites and cellulose nanocomposites; surface and interface engineering to improve performance of high performance polymer (nano)composites; life cycle assessment of composite materials; particle-stabilised emulsions and foams; novel manufacturing techniques for polymer foams; and reusing, recycling and upcycling waste materials. Why do you think it is important that research is undertaken into new materials made from renewable resources? From a mass balance point of view, Earth is a closed system. We live in a world where resources are finite and it is important to meet our needs today without compromising the ability of our future generations to meet their own needs. One way to achieving this is to ensure that any materials will fit into the concept of a circular bioeconomy. Therefore, it is vital that research into new engineering materials should be developed with sustainability or renewability in mind such that a circular bioeconomy can be achieved. What do you consider are the main sustainability challenges that need to be addressed through materials research? To achieve a truly sustainable future, we need to produce bio-derived materials that can compete with or replace petroleumderived commodity and engineering polymers. These materials should also be produced using greener production processes. However, the main sustainability challenge is that the performance of bioderived polymers still trails traditional petroleum-based polymers. How is FMG working to overcome these challenges? My research group takes a composite approach, such as combining bio-derived polymers with bio-based reinforcements, to produce sustainable materials, with a focus on applying green engineering principles, including reducing the use of solvents, energy and focus on simple manufacturing concepts. The idea behind this is to bridge the cost-property-performance gap between bio-derived materials and conventional petroleum-derived polymers. How do you envision the new materials developed by FMG will ultimately impact the renewable resources market? The work conducted in FMG focuses not only on developing new sustainable materials but also on showing the possibilities of what can be achieved with current bio-based materials. This will introduce various forms of alternatives to the renewable resources market, expanding the current choices of sustainable materials for various applications. This may motivate the industry to replace their petroleumderived materials with sustainable materials and hence help to realise a truly sustainable society. Looking ahead to the next five years, what research plans are in the pipeline for FMG? There are multiple research plans in the pipeline. We have recently received funding from the Engineering and Physical Sciences Research Council (EPSRC) to collaborate with Dr Tom Ellis in ICL’s Department of Bioengineering to grow high performance composites. My group will also expand our research in the area of foam-templated biobased epoxy macroporous polymers. FMG is also in collaboration with Aeropowder Ltd to upcycle waste feathers from the poultry industry. www.impact.pub 77 Advancing nanocellulose knowledge for a greener future The Future Materials Group based at Imperial College London is working towards creating a more sustainable future by exploring the potential of nanocellulose using innovative engineering processes The Future Materials Group (FMG), which was established in 2015 by Head of the Group Dr Koon-Yang Lee, is working on multidisciplinary research that aims to create a more sustainable society. Lee’s research focuses on the manufacturing and development of novel composite materials with an emphasis on tailoring the interface between two or more phases to bridge the gap between chemistry, materials science and engineering. He is thus well placed to lead FMG, whose work is supported by Engineering and Physical Sciences Research Council (EPSRC) grants and the EU (Climate-KIC). INNOVATIVE MANUFACTURING FMG’s research activities seek to create a circular bioeconomy and thus concern the development of new materials for various applications. These activities are driven by four main engineering processes: innovative manufacturing, whereby the team develops simple and cost-effective manufacturing solutions to novel materials; green engineering, through which the researchers seek to instil the valuable concept of reduce, reuse and recycle in materials development; formulation engineering, which means that the team utilises the fundamentals of physics, chemistry and materials science to enhance materials properties; and interface engineering, by which the team is tailoring the interface between two phases to maximise the performance of materials. The research is linked by principles of innovation and sustainability. The idea is to ensure resources for future generations 78 www.impact.pub are not depleted. The researchers apply green engineering principles to produce environmentally friendly and high performance materials. The key foci in this domain are bacterial cellulose and nanofibrillated cellulose, paper- and nanopaper-based composites, natural fibrereinforced polymer composites, and using waste and recycled materials as resources. EXPLOITING THE POTENTIAL OF NANOCELLULOSE The first project is called ‘Cellulose “Nanopaper” as Building Blocks for Sustainable Materials’, which began in January 2015 and funded by the UK Engineering and Physical Science Research Council (EPSRC). This work aims to develop the next generation of nanocellulosereinforced polymers applying green engineering principles to reduce the use of solvents and energy, as well as introduce simple manufacturing concepts to produce sustainable nanocomposites that are truly high performance for high volume structural applications. The project is concentrating on the use of ultra-low grammage or high performance cellulose ‘nanopapers’ as the building blocks for sustainable composite materials. The researchers expect that such truly green and high performance nanofibre composites will find wider applications, for instance in the composite, plastic electronics and flexible display industries. Lee explains that the major driver for utilising nanocellulose as reinforcement is the possibility to exploit the stiffness and strength of cellulose crystals. ‘Theoretical calculations and numerical simulations estimated that the stiffness and strength of cellulose crystals are as high as 180 GPa and 22 GPa, respectively. Raman spectroscopy and X-ray diffraction have also shown experimentally that single nanocellulose fibre possesses a tensile stiffness of between 100 and 160 GPa,’ says Lee. ‘Thus, nanocellulose fibres could potentially serve as replacement for glass fibres, given their low toxicity and density (~1.5 g cm-3), for the production of high performance sustainable composites.’ The aim is to develop the next generation of nanocellulose-reinforced polymers, applying green engineering principles to reduce the use of solvents and energy, as well as introduce simple manufacturing concepts to produce sustainable nanocomposites that are truly high performance for high volume structural applications. Lee explains that one of the ideas explored in this strand of research was to use cellulose nanopaper as reinforcement for polymers: ‘The main motivation behind this is that cellulose nanopapers can be easily produced using conventional papermaking processes. In addition to this, cellulose nanopapers could be processed into sustainable composites easily using commercially available composite manufacturing technologies. The end users of the outcome of this grant are likely to be materials manufacturers in the automotive, packaging and perhaps the paper industries.’ The second project is entitled ‘GrowYour-Own Composites: Programming Diverse Material Properties for Defence Project Insights FUNDING The Future Materials Group’s research is supported by both Engineering and Physical Sciences Research Council (EPSRC) grants and the European Union (Climate-KIC). Nanocellulose fibres could potentially serve as replacement for glass fibres, given their low toxicity and density into Engineered Bacterial Cellulose’, which is a collaborative effort with Dr Tom Ellis from Imperial College London and will draw to a close in mid 2019. It focuses on developing genetic manipulation methods and a synthetic biology toolkit for Komagataeibacter rhaeticus. This will be the first toolkit of note for bacteria that produce cellulose in high yields. The researchers wish to use synthetic biology methods to modify the production of bacterial cellulose from K. rhaeticus so that the bacterial cultures would produce programmable cellulose composites that have diverse and highly desired material properties. The intention is that they can use synthetic biology tools and expand this toolkit with further features such as genome editing and light-based control, which will enable them to alter and control bacteria at the DNA level, thus meaning that they can be made to secrete modified bacterial cellulose with different bulk properties, such as altered hydrophobicity. In FMG, Lee will focus on optimising the structure-property relationship of these composites produced by bacteria. In a past research project, completed in collaboration with Professor Alexander Bismarck, entitled ‘Nanocellulose Binders for Fibre Preforms: Creating the Building Blocks of High Performance Sustainable Composites’, FMG successfully developed an elegant, intrinsically scalable and costeffective technology for binding fibres together in order to create an in-plane non-woven fibre mat utilising bacterial nanocellulose, with no extra chemical steps involved during the production. The process developed by the team was advantageous in that short, long and even continuous fibres can be utilised to produce fibre preforms, which can be utilised in conventional composite making processes. NOVEL BIO-BASED FOAMS Whilst much of FMG’s research is centred on nanocellulose, one strand of the Group’s work is seeking to determine how environmentally friendly foams can be developed. Lee explains that this is an area that holds much potential: ‘It is really interesting to engineering new materials and micro-structures that can be used in very diverse applications.’ The basis behind their work is starting with a liquid rather than a hard block of foam and forming it into any shape. ‘Our method of using liquid based foam results in a truly waste-free manufacturing process.’ Lee’s team is currently looking into synthesising novel foam micro-structures that will lead to higher specific properties. REACHING OUT FMG places a strong emphasis on outreach and public engagement and strives to ensure its work has a valid, far-reaching output. For example, it works with the wider community and industrial partners to ensure its research activities will reach a wider audience. The team collaborates widely with academia and industry with a view to sharing knowledge and techniques in the name of expanding and furthering research. Lee believes that these collaborations help circumvent major challenges such as sourcing raw materials and expertise in materials characterisations: ‘These are resolved via the numerous collaborations my research group has with various research groups and institutes within the department, the College and around the world.’ Looking ahead, FMG will continue working on its ongoing projects. There are also plans in the pipeline to expand its research in the area of foam-templated bio-based epoxy macroporous polymers, as well as upcycling waste avian feathers. With the constant need for innovative, sustainable materials for an abundance of applications, FMG is filling and will continue to fill an important gap in the renewable materials field. RESEARCH FOCUS • Sustainable materials engineering: Bacterial cellulose and nanofibrillated cellulose, paper- and nanopaper-based composites, natural fibre-reinforced polymer composites, and using waste and recycled materials as resources • Emulsions and foams engineering: Surfactant- and particle-stabilised fluidfluid systems, emulsion and foam as templates for porous materials, high performance macroporous polymers, and membranes for advanced separation applications CONTACT Koon-Yang Lee Head of the Future Materials Group T: +44 2075945150 E: [email protected] W: http://www.imperial.ac.uk/futurematerials-group GROUP HEAD BIO Dr Koon-Yang Lee is Lecturer in Composite Manufacturing in the Composites Centre of the Department of Aeronautics, Imperial College London (ICL). His work focuses on the manufacturing and development of novel composite materials, specifically on tailoring the interface between two (or more) phases to bridge the gap between chemistry, materials science and engineering. Lee holds a US patent, has (co-)authored 37 peer-reviewed journal articles, and authored eight invited book chapters and six confidential industrial technical reports. His expertise is in the manufacturing of cellulose (nano) composites, hierarchical composites, polymer foams and life cycle assessment of composite materials. Lee has been widely recognised for his research excellence, winning the Dudley Newitt Prize in 2012 (awarded by ICL) and the Student Achievement Award in 2011 (awarded by the BioEnvironmental Polymer Society). www.impact.pub 79
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