Material Safety Data Sheet Iodine Crystals POCD SCIENTIFIC MATERIAL SAFETY DATA SHEET Section 1: IDENTIFICATION IODINE CRYSTALS Synonyms – Iodine sublimed Product Code – IOD/500 Recommended use – Laboratory reagent. Point of Care Diagnostics t/a POCD Scientific ABN: 93 067 939 824 Unit 14/76 Reserve Rd Artarmon NSW 2064 1800 640 075 | 02 9437 1399 Australian Emergency Services: 000 (24 hours) Australian Poisons Information Centre: 131 126 (24 hours) Section 2: HAZARDS IDENTIFICATION Classified as a Hazardous substance according to criteria of NOHSC. Classified as a Dangerous (Class 8 – Corrosive) good according to the ADG Code for the Transport of Dangerous Goods by Road and Rail. R Phases S Phases R20/21 – Harmful by inhalation and in contact with skin. R34 – Causes burns. R50 – Very toxic to aquatic organisms. S1/2 – Keep locked up and out of reach of children. S22 – Do not breathe dust. S24/25 – Avoid contact with skin and eyes. S29 – Do not empty into drains. Section 3: COMPOSITION INFORMATION Chemical Name Iodine CAS Number 7553-56-2 Concentration 100% Section 4: FIRST AID MEASURES Eye contact Skin contact Inhalation Ingestion First aid facilities Advice to Doctor Date of issue: May 2011 Flush eyes with copious amounts of water for at least 15 minutes. Seek medical attention. Remove contaminated clothing and wash area with soap and water. Seek medical attention. Remove patient to fresh air. Apply artificial respiration if patient is not breathing and seek urgent medical attention. DO NOT induce vomiting. If a minor amount is swallowed dilute stomach by consuming copious amounts of water or milk. Seek urgent medical attention. Eye wash station, safety shower and First Aid kit. Treat symptomatically. Page 1 of 4 Material Safety Data Sheet Iodine Crystals Section 5: FIREFIGHTING MEASURES Suitable extinguishing media Hazards for combustion products Special protective precautions and equipment for fire fighters Hazchem code Carbon Dioxide, dry chemical, water spray or foam. Toxic gases may be emitted. Wear SCBA (Self-Contained Breathing Apparatus) and full protective clothing. 2X Section 6: ACCIDENTAL RELEASE MEASURES Emergency procedures Clean up methods Wear SCBA (Self-Contained Breathing Apparatus) and full protective clothing. Do not breathe dust. Ensure adequate ventilation. Sweep up or vacuum, place in a suitable container for disposal. Wash spill site. Do not allow contamination of drains and waterways. Section 7: HANDLING AND STORAGE Precautions for safe handling Conditions of safe storage Use in fume hood or well-ventilated area to avoid contact with eyes, skin and clothing. Avoid prolonged or repeated exposure. Prevent dust production where possible and practice good personal hygiene. Store in a cool, dry, well-ventilated place, removed from direct sunlight, acetaldehyde, chlorine, fluorine, ammonia, metals and reducing agents, heat sources and foodstuffs. Ensure containers are corrosion resistant and adequately labelled, protected from physical damage and sealed when not in use. Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION National exposure standards Biological Limit Values Engineering Controls Personal Protective Equipment Threshold Limit Value (TWA ) = 1 mg/m3 ( Iodine ) ( Peak Limitation ) Exposure Standards (TWA) is the time-Weighted average airborne concentration over an eight-hour working day, for a five day working week over an entire working life. According to current knowledge this concentration should neither impair the health, nor cause undue discomfort to, nearly all workers. No limits allocated. Use in a fume hood or very well-ventilated area only. Wear suitable protective clothing, safety glasses or chemical resistant goggles to prevent eye contact and gloves. If working within a confined area use a suitable respirator at all times. Section 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance Odour pH Vapour pressure Vapour density Boiling point Melting point Solubility Specific gravity Information for flammable materials Violet/Black Rhombic crystals Pungent Not relevant 0.31mmHg @ 25⁰C 9g/L 184.4⁰C 113.5⁰C Water soluble 4.93 Non-flammable Section 10: STABILITY AND REACTIVITY Chemical stability Date of issue: May 2011 Stable under normal recommendations of use and storage. Page 2 of 4 Material Safety Data Sheet Iodine Crystals Conditions to avoid Incompatible materials Hazardous decomposition products Hazardous reactions Direct sunlight and incompatibles. Incompatible with acetaldehyde, chlorine, fluorine, ammonia, metals (e.g. magnesium, antimony, lithium, sodium) and reducing agents (e.g. phosphorus). Toxic gases may be emitted. Polymerisation will not occur. Section 11: TOXICOLOGICAL INFORMATION HEALTH EFFECTS Acute: Eye contact Skin contact Inhalation Ingestion Corrosive nature can cause burns, pain, tearing and blurred vision. Prolonged contact can cause permanent damage. Can cause redness, irritation, pain and burns. Can cause irritation to the mucous membranes and cause burns to the respiratory tract. Can cause burns to the mucous membranes of the mouth, throat and stomach. Symptoms include abdominal pain, fever, diarrhoea and vomiting. Section 12: ECOLOGICAL INFORMATION Ecotoxicity Persistence and degradability Mobility Environmental fate (exposure) Bioaccumulative potential Very toxic to aquatic organisms. Not available Not available Prevent contamination of drains and waterways. Not available Section 13: DISPOSAL CONSIDERATIONS Disposal methods and containers Special precautions Sweep up and seal in suitable containers for disposal according to local authority guidelines. Do not allow entry into drains and waterways and avoid inhalation and skin contact. Section 14: TRANSPORT INFORMATION Classified as dangerous goods by the criteria of the Australian Dangerous Goods Code. UN Number UN Proper shipping name Class and subsidiary risk Packing group Special precautions Hazchem code 1759 Corrosive solid, n.o.s 8 II 2X Section 15: REGULATORY INFORMATION Poison Schedule: 6 This material is a Class 8 Corrosive Substance according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. Class 8 - Corrosive Substances are incompatible in a placard load with any of the following: - Class 1, Explosives - Class 4.3, Dangerous When Wet Substances - Class 5.1, Oxidising Agents & Class 5.2 - Organic Peroxides - Class 6, Toxic Substances (where the Toxic substances are cyanides and the corrosives are acids), - Class 7, Radioactive Substances and are incompatible with food and food packaging in any quantity. Date of issue: May 2011 Page 3 of 4 Material Safety Data Sheet Iodine Crystals Section 16: OTHER INFORMATION Release Information Date of preparation Issue Number 14 June 2011 1 References 1. 2. 3. 4. National Occupational Health and Safety Commission, Approved Criteria for Classifying Hazardous rd Substances (NOHSC:1008); Australian Government Publication Service: Canberra (2004), 3 Edition. National Occupational Health and Safety Commission, List of Designated Hazardous nd Substances (NOHSC:10005); Australian Government Publication Service: Canberra (1999), 2 Edition. National Transport Commission Australian Code for the Transport of Dangerous Goods by Road and th Rail (ADG Code); Canprint: Canberra (2007), Volume 1, 7 Edition. Standards Australia, Dangerous Goods Initial Emergency Response Guide: Australian Handbook (SAA/SNZ HB76); Homebush (2004). Copyright © 2011 Point of Care Diagnostics Australia Pty Ltd Date of issue: May 2011 Page 4 of 4
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