Hazardous Waste in California Presentation 7: Non‐RCRA Listed Hazardous Waste Presentation 7: Non‐RCRA Listed Hazardous Waste HAZARDOUS WASTE IN CALIFORNIA Non-RCRA Listed Hazardous Wastes V 1.0 © Lion Technology Inc. Subdivision (a) of Appendix X is a numerical list of chemicals arranged alphabetically by their common chemical names • If the material has a synonym it is listed next to it separated by a comma Example: Acetone, Propanone (I) © Lion Technology Inc. The Non-RCRA Lists of Hazardous Wastes There are two non-RCRA hazardous waste lists: 1. The “M List” 2. Appendix X of Chapter 11 of CCR, Title 22, Div. 4.5 © Lion Technology Inc. © 2014 Lion Technology Inc., Lafayette, NJ 07848 Page 1 Presentation 7: Non‐RCRA Listed Hazardous Waste Hazardous Waste in California, continued The M List The M List contains materials that have any intentionally-added mercury and will be discarded • Includes, but is not limited to, novelties, switches, and lamps [22 CCR 66261.50] © Lion Technology Inc. The M List There are two columns on the list: • Column 1 – waste code • Column 2 – description of the hazardous waste The M List does not contain hazard codes [22 CCR 66261.50] © Lion Technology Inc. The M List Mercury-containing equipment, when recycled, may be managed as universal waste • The M-listed waste code would apply if a generator was disposing instead of recycling mercury-containing equipment [22 CCR 66273.4] © Lion Technology Inc. © 2014 Lion Technology Inc., Lafayette, NJ 07848 Page 2 Presentation 7: Non‐RCRA Listed Hazardous Waste Hazardous Waste in California, continued Chapter 11, Appendix X Appendix X is a list of chemicals and wastes that California presumes to be hazardous because it presumes that they will exhibit one or more hazardous waste characteristics Non-RCRA Listed Hazardous Wastes [22 CCR Div. 4.5, Ch. 11, App. X] V 1.0 © Lion Technology Inc. Chapter 11, Appendix X, Subdivision (a) List of Chemicals Subdivision (a) of Appendix X is a numerical list of chemicals arranged alphabetically by their common chemical names • • IfIf the the material material has has aa synonym synonym itit is is listed listed next next to to itit separated separated by by aa comma comma Example: Acetone, Propanone (I) • Acetone, Propanone (I) [22 CCR Div. 4.5, Ch. 11, App. X] © Lion Technology Inc. Chapter 11, Appendix X, Subdivision (b) The Non-RCRA Lists of Hazardous Wastes List of Common Wastes Subdivision (b)non-RCRA of Appendix X contains a listlists: of There are two hazardous waste generic of wastes, for example: 1. Thetypes “M List” •2.Asbestos Appendixwaste X of Chapter 11 of CCR, • Ashes Title 22, Div. 4.5 • Laboratory waste • Paint remover or stripper • Spent acids/caustics [22 CCR Div. 4.5, Ch. 11, App. X] © Lion Technology Inc. © 2014 Lion Technology Inc., Lafayette, NJ 07848 Page 3 Presentation 7: Non‐RCRA Listed Hazardous Waste Hazardous Waste in California, continued Chapter 11, Appendix X, Subdivision (c) List of Electronic Wastes Subdivision (c) of Appendix X contains a list of electronic wastes, for example: • CRTs • LCDs Non-RCRA Listed Hazardous Wastes • Plasma TVs • Portable DVD players with LCDs May be managed as universal waste if recycled [22 CCR Div. 4.5, Ch. 11, App. X] V 1.0 © Lion Technology Inc. Chapter 11, Appendix X Presumed to be Hazardous If you have a(a) Subdivision waste of Appendix listed in X Appendix is a numerical X, or alist of chemicals chemical in the arranged Appendix alphabetically is in your waste, by their you common must presume chemical the waste namesis hazardous unless you otherwise (i.e., prove doesn’t • If can the prove material has a synonym it isitlisted next pose characteristic) to ita separated by a comma • Proof can be: Example: Acetone, Propanone (I) Generator knowledge Analysis [22 CCR Div. 4.5, Ch. 11, App. X] © Lion Technology Inc. Chapter 11, Appendix X The Non-RCRA Lists of Hazardous Wastes Presumed to be Hazardous If the generator can prove hazardous the material doeslists: not There are two non-RCRA waste pose any“M hazardous waste characteristics, 1. The List” then the material is NOT a hazardous waste 2. Appendix X identified of Chapteron11Appendix of CCR, X even though it’s Title 22, Div. 4.5 [22 CCR Div. 4.5, Ch. 11, App. X] © Lion Technology Inc. © 2014 Lion Technology Inc., Lafayette, NJ 07848 Page 4 Presentation 7: Non‐RCRA Listed Hazardous Waste Hazardous Waste in California, continued Chapter 11, Appendix X Hazard Codes The hazard code is included on the list, in parentheses, after the chemical or waste name • A chemical or waste may have many hazard codes • Code explains why California believes the chemical or waste is hazardous [22 CCR Div. 4.5, Ch. 11, App. X] © Lion Technology Inc. Chapter 11, Appendix X Hazard Codes The hazard codes on Appendix X are slightly different then those of the F, K, P and U Lists • C = Corrosive • I = Ignitable • R = Reactive • X = Toxic [22 CCR Div. 4.5, Ch. 11, App. X] © Lion Technology Inc. Chapter 11, Appendix X Hazard Codes Example 3. Acetone, Propanone (I) Acetone listed on Appendix X because it is ignitable 34. Ammonium hydroxide (X,C) Ammonium hydroxide listed on Appendix X because it is toxic and corrosive © Lion Technology Inc. © 2014 Lion Technology Inc., Lafayette, NJ 07848 Page 5 Presentation 7: Non‐RCRA Listed Hazardous Waste Hazardous Waste in California, continued Chapter 11, Appendix X Hazard Codes Example For what hazards is zinc nitrate included in Chapter 11, Appendix X? (check all that apply) C I R X © Lion Technology Inc. Chapter 11, Appendix X Hazard Codes The “*” Some chemicals are identified in subdivision (a) of Appendix X with an “*” • Wastes containing chemicals identified with an “*” are presumed to be “extremely hazardous wastes” unless the generator can prove otherwise [22 CCR Div. 4.5, Ch. 11, App. X] © Lion Technology Inc. © 2014 Lion Technology Inc., Lafayette, NJ 07848 Page 6 Presentation 7: Non‐RCRA Listed Hazardous Waste PRESENTATION 7: NON‐RCRA LISTED HAZARDOUS WASTE References © 2014 Lion Technology Inc., Lafayette, NJ 07848 Page 8 Presentation 7: Non‐RCRA Listed Hazardous Waste TITLE 22, DIVISION 4.5 Div.Chapter 4.5, Ch. 11,11—Identification App. X 0 and Listing of Hazardous Waste APPENDIX X—LIST OF CHEMICAL NAMES AND COMMON NAMES FOR HAZARDOUS WASTES AND HAZARDOUS MATERIALS (a) This subdivision sets forth a list of chemicals which create a presumption that a waste is a hazardous waste. If a waste consists of or contains a chemical listed in this subdivision, the waste is presumed to be a hazardous waste unless it is determined that the waste is not a hazardous waste pursuant to the procedures set forth in section 66262.11. The hazardous characteristics which serve as a basis for listing the chemicals are indicated in the list as follows: (X) toxic, (C) corrosive, (I) ignitable and (R) reactive. A chemical denoted with an asterisk is presumed to be an extremely hazardous waste unless it does not exhibit any of the criteria set forth in section 66261.110 and section 66261.113. Trademark chemical names are indicated by all capital letters. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. Acetaldehyde (X,I) Acetic acid (X,C,I) Acetone, Propanone (I) Acetone cyanohydrin (X) Acetonitrile (X,I) *2-Acetylaminofluorene, 2-AAF (X) Acetyl benzoyl peroxide (X,I,R) *Acetyl chloride (X,C,R) Acetyl peroxide (X,I,R) Acridine (X) *Acrolein, Aqualin (X,I) *Acrylonitrile (X,I) *Adiponitrile (X) *Aldrin; 1,2,3,4,10,10-Hexachloro1,4,4a,5,8,8a-hexahydro-1,4,5,8-endo-exodimethanonaphthalene (X) *Alkyl aluminum chloride (C,I,R) *Alkyl aluminum compounds (C,I,R) Allyl alcohol, 2-Propen-1-ol (X,I) Allyl bromide, 3-Bromopropene (X,I) Allyl chloride, 3-Chloropropene (X,I) 20. 21. 22. 23A. 23B. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. Allyl chlorocarbonate, Allyl chloroformate (X,I) *Allyl trichlorosilane (X,C,I,R) Aluminum (powder) (I) Aluminum chloride (X,C) *Aluminum chloride (anhydrous) (X,C,R) Aluminum fluoride (X,C) Aluminum nitrate (X,I) *Aluminum phosphide, PHOSTOXIN (X,I,R) *4-Aminodiphenyl, 4-ADP (X) *2-Aminopyridine (X) *Ammonium arsenate (X) *Ammonium bifluoride (X,C) Ammonium chromate (X,I) Ammonium dichromate, Ammonium bichromate (X,C,I) Ammonium fluoride (X,C) Ammonium hydroxide (X,C) Ammonium molybdate (X) Ammonium nitrate (I,R) Ammonium perchlorate (I,R) Ammonium permanganate (X,I,R) Ammonium persulfate (I,R) Ammonium picrate (I,R) Ammonium sulfide (X,C,I,R) n-Amyl acetate, 1-Acetoxypentane (and isomers) (X,I) n-Amylamine, 1-Aminopentane (and isomers) (X,I) n-Amyl chloride, 1-Chloropentane (and isomers) (X,I) n-Amylene, 1-Pentene (and isomers) (X,I) n-Amyl mercaptan, 1-Pentanethiol (and isomers) (X,I) n-Amyl nitrite, n-Pentyl nitrite (and isomers) (X,I) *Amyl trichlorosilane (and isomers) (X,C,R) Aniline, Aminobenzene (X) Anisoyl chloride (X,C) Anthracene (X) Antimony (X) Antimony compounds (X) *Antimony pentachloride (X,C,R) *Antimony pentafluoride (X,C,R) Antimony pentasulfide (X,I) Antimony potassium tartrate (X) Antimony sulfate, Antimony trisulfate (X,I) Antimony trichloride, Antimony chloride (X,C) © 2014 Lion Technology Inc., Lafayette, NJ 07848 Page 8 Presentation 7: Non‐RCRA Listed Hazardous Waste * 748. 749. 750. 751. 752. 753. 754. 755. 756. 757. 758. 759. 760. 761. 762. 763. 764. 765. 766. 767. 768. 769. 770. 771. 772. 773. 774. 775. 776. 777. 778. 779. 780. 781. 782. 783. 784. 785. 786. * * * * Trimethylamine, TMA (X,I) Trinitroanisole; 2,4,6-Trinitrophenyl methyl ether (I,R) 1,3,5-Trinitrobenzene, TNB (I,R) 2,4,6-Trinitrobenzoic acid (I,R) Trinitronaphthalene, Naphtite (I,R) 2,4,6-Trinitroresorcinol, Styphnic acid (I,R) 2,4,6-Trinitrotoluene, TNT (X,I,R) *tris(1-Aziridinyl) phosphine oxide, Triethylenephosphoramide, TEPA (X) Tungstic acid and salts (X) Turpentine (X,I) Uranyl nitrate, Uranium nitrate (X,I,R) Urea nitrate (X,I,R) n-Valeraldehyde, n-Pentanal (and isomers) (X,I) Vanadic acid salts (X) Vanadium oxytrichloride (X,C) *Vanadium pentoxide, Vanadic acid anhydride (X) Vanadium tetrachloride (X,C) Vanadium tetraoxide (X) Vanadium trioxide, Vanadium sesquioxide (X) Vanadyl sulfate, Vanadium sulfate (X) Vinyl acetate (I,X) *Vinyl chloride (X,I) Vinyl ethyl ether (I) Vinylidene chloride, VC (X,I) Vinyl isopropyl ether (I) *Vinyltrichlorosilane (X,C,I,R) VX, O-Ethyl methyl phosphoryl N,N-diisopropyl thiocholine (X) *WEPSYN 155, WP 155, Triamiphos, para(5-Amino-3-phenyl-1H-1,2,4-triazol-1-yl)N,N,N',N'-tetramethyl phosphonic diamide (X) Xylene, Dimethylbenzene (ortho,meta,para) (X,I) Zinc (powder) (I) Zinc ammonium nitrate (X,I) *Zinc arsenate (X) *Zinc arsenite (X) Zinc chloride (X,C) Zinc compounds (X) *Zinc cyanide (X) Zinc nitrate (X,I,R) Zinc permanganate (X,I) Zinc peroxide, Zinc dioxide (X,I,R) 787. 788. 789. 790. 791. *Zinc phosphide (X,I,R) Zinc sulfate (X) Zirconium (powder) (I) *Zirconium chloride, Zirconium tetrachloride (X,C,R) Zirconium picramate (I) (b) This subdivision sets forth a list of common names of wastes which are presumed to be hazardous wastes unless it is determined that the waste is not a hazardous waste pursuant to the procedures set forth in section 66262.11. The hazardous characteristics which serve as a basis for listing the common names of wastes are indicated in the list as follows: (X) toxic, (C) corrosive, (I) ignitable and (R) reactive. Acetylene sludge (C) Acid and water (C) Acid sludge (C) AFU Floc (X) Alkaline caustic liquids (C) Alkaline cleaner (C) Alkaline corrosive battery fluid (C) Alkaline corrosive liquids (C) Asbestos waste (X) Ashes (X,C) Bag house wastes (X) Battery acid (C) Beryllium waste (X) Bilge water (X) Boiler cleaning waste (X,C) Bunker Oil (X,I) Catalyst (X,I,C) Caustic sludge (C) Caustic wastewater (C) Cleaning solvents (I) Corrosion inhibitor (X,C) Data processing fluid (I) Drilling fluids (X,C) Drilling mud (X) Dyes (X) Etching acid liquid or solvent (C,I) Fly ash (X,C) Fuel waste (X,I) Insecticides (X) Laboratory waste (X,C,R,I) Lime and sulfur sludge (C) Lime and water (C) Lime sludge (C) © 2014 Lion Technology Inc., Lafayette, NJ 07848 Page 9 Presentation 7: Non‐RCRA Listed Hazardous Waste Lime wastewater (C) Liquid cement (I) Mine tailings (X,R) Obsolete explosives (R) Oil and water (X) Oil Ash (X,C) Paint (or varnish) remover or stripper (I) Paint thinner (X,I) Paint waste (or slops) (X,I) Pickling liquor (C) Pigments (X) Plating waste (X,C) Printing Ink (X) Retrograde explosives (R) Sludge acid (C) Soda ash (C) Solvents (I) Spent acid (C) Spent caustic (C) Spent (or waste) cyanide solutions (X,C) Spent mixed acid (C) Spent plating solution (X,C) Spent sulfuric acid (C) Stripping solution (X,I) Sulfonation oil (I) Tank bottom sediment (X) Tanning sludges (X) Toxic chemical toilet wastes (X) Unrinsed pesticide containers (X) Unwanted or waste pesticides - an unusable portion of active ingredient or undiluted formulation (X) Waste epoxides (X,I) Waste (or slop) oil (X) Weed Killer (X) (c) This subsection sets forth a list of electronic wastes that are presumed to be hazardous wastes and that are “covered electronic device[s]” pursuant to chapter 8.5 of part 3 of division 30 of the Public Resources Code section 42460 et seq., if they have a viewable screen size [as defined in sec. 66260.201, subsec. (b)(3)(C)] greater than four inches, unless it is determined that the electronic waste is not a hazardous waste pursuant to the procedures set forth in section 66262.11. The hazardous characteristic that serves as a basis for listing the common names of electronic wastes is toxicity. (1) Cathode ray tube (CRT)-containing devices (CRT devices); (2) CRTs; (3) CRT-containing computer monitors; (4) Liquid crystal display (LCD)-containing laptop computers; (5) LCD-containing desktop monitors; (6) CRT-containing televisions; (7) LCD-containing televisions (excluding LCD projection televisions); (8) Plasma televisions (excluding plasma projection televisions); (9) Portable DVD players with LCDs. © 2014 Lion Technology Inc., Lafayette, NJ 07848 Page 10 Presentation 7: Non‐RCRA Listed Hazardous Waste TITLE 22, DIVISION 4.5 Chapter 11—Identification 0 and Listing of Hazardous Waste California Hazardous Waste Number M003 Lamps that contain intentionally-added mercury and products (or devices) with lamps that contain intentionally-added mercury. A lamp is defined as the bulb or tube portion of an electric lighting device. A lamp is specifically designed to produce radiant energy, most often in the ultraviolet, visible, and infrared regions of the electromagnetic spectrum. Products from which all mercurycontaining lamps have been removed are not included in this category. This listing does not apply to vehicles that contain mercury-added lamps. M004 Mercury-added novelties, as defined in section 66273.9 (other than novelties with mercury switches, which meet the listing description for M002, and novelties with mercury-containing lamps, which meet the listing description for M003). Includes, but is not limited to, novelties painted with mercury-containing paints. Article 4.1—Additional Lists of Hazardous Wastes §66261.50 Mercury-Containing Products That Are Hazardous Wastes When Discarded. The following mercury-containing products are listed hazardous wastes when discarded: California Hazardous Waste Number Hazardous Waste M001 Mercury-containing motor vehicle light switches, as defined in section 66273.9, and any motor vehicle or portion of a motor vehicle that contains such switches, when any person decides to crush, bale, shred, or shear the vehicle. Motor vehicles and portions of motor vehicles from which all mercury-containing light switches have been removed are not included in this category. A light switch that cannot be removed from a vehicle due to accidental damage to the vehicle is not included. M002 Non-automotive mercury switches and any product that contains such switches. Includes any mercury switch that does not meet the listing description for M001, including but not limited to, mercury switches from household appliances and household appliances from which mercury switches have not been removed; relays; silent wall switches; and float switches. Also includes mercury-containing flame sensors and household appliances from which all mercury flame sensors have not been removed. Appliances and other products from which all mercury switches and flame sensors have been removed are not included in this category. Hazardous Waste © 2014 Lion Technology Inc., Lafayette, NJ 07848 Page 12
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