Southern African Humanities Vol. 21 Pages 239–261 Pietermaritzburg December, 2009 A cache of ~5000 glass beads from the Sibudu Cave Iron Age occupation Marilee Wood, 2Laure Dussubieux and 1,3Lyn Wadley 1 School of Geography, Archaeology & Environmental Studies, University of the Witwatersrand, Wits, 2050 South Africa; [email protected] 2 Field Museum, Department of Anthropology, 1400 S. Lake Shore Drive, Chicago, IL 60605; [email protected] 3 Institute for Human Evolution, University of the Witwatersrand; [email protected] 1 ABSTRACT A cache of ~5000 glass beads was recovered from a small pit in an Iron Age layer at Sibudu Cave. The bead strings incorporated brownish-red, blue-green, blue and other colours of glass beads, some copper beads and also two perforated Conus ebraeus shells. A necklace of shell disc-beads interspersed with blue glass beads was also present. Sixteen of the glass beads were analysed chemically using LA-ICP-MS at the Field Museum, Chicago. The results indicate the beads originated in India. The Iron Age layers have calibrated radiocarbon dates between AD 1020 and 1160 and they incorporate Blackburn facies ceramics. These Blackburn associations seem too early for the types of beads represented and the cache of beads may have been hidden in the shelter in the 1500s or 1600s after the Blackburn occupation. KEY WORDS: Sibudu Cave, Iron Age, glass beads, chemical analysis, Indian beads. Sibudu is a large rock shelter located approximately 40 km north of Durban, South Africa, about 15 km inland from the Indian Ocean, on a steep cliff overlooking the Tongati River. The shelter is 55 m long and about 18 m in breadth. Entering the shelter necessitates crossing the river (which is sometimes shoulder-deep) and scaling a 3 m rock face. There are sufficient hand-holds and natural steps to make entry and exit relatively easy for a sound-bodied person with a good head for heights, but it would not be possible to get cattle into the shelter. The point about access is made only to call attention to the atypical nature of the shelter for Iron Age settlement. The excavation grid is in the northern part of the shelter approximately 100 m above mean sea-level. A small trial trench roughly 1 m deep was excavated in 1983 by Aron Mazel and his stratigraphic names for the Iron Age layers, recorded in notes housed in the Natal Museum, have been retained here. The present excavations, which are ongoing, began in 1998 and Middle Stone Age (MSA) deposit over 21 m2 and Iron Age deposit over 26 m2 have been excavated by the Wadley team (Wadley & Jacobs 2004, 2006). Each metre square is divided into quadrants a (north-east), b (south-east), c (north-west) and d (south-west) and all artefacts are excavated and bagged separately from each quadrant. The uppermost occupation is from the Iron Age and directly below this is the MSA with a long and detailed cultural sequence. No Later Stone Age (LSA) remains are present in Sibudu and it seems that a long hiatus occurred between the final MSA occupations and the first Iron Age occupations. This hiatus is not detectable as a sterile unit in the stratigraphy. Today the surface of the cave floor is scoured by wind in late winter/early summer and similar circumstances in the past may have prevented the accumulation of sterile deposits. http://www.sahumanities.org.za 239 240 Southern AFRICAN humanities, vol. 21, 2009 The stratigraphy relevant to the Iron Age of the site comprises three layers. Below the surface sweep of modern dust and leaf litter is brown silt with vegetal material (BSV). The underlying brown sand with stones (BSS), which is deep in parts of the site, has been arbitrarily divided and the lower part of the layer is named BSS2. Three radiocarbon ages have been obtained from charcoal (Table 1). The calibrated dates suggest that essentially the same age is represented throughout the Iron Age occupation; this issue is discussed again later. Layers BSV, BSS and BSS2 contain ceramics, upper and lower grindstones, rare pieces of metal, bones, seeds, gourd fragments, wood, wooden stakes, a wooden digging stick and even some fragments of basketry. The ceramics are largely undecorated, with the exception of a few sherds with simple, incised parallel lines. The sparse decoration, together with the shapes of some rim fragments, suggests that the ceramics belong to the Blackburn facies of the local Late Iron Age sequence (Whitelaw pers. comm.; Huffman 2004, 2007). Blackburn sites have calibrated radiocarbon dates between about AD 1100 and 1300, but the facies may extend to about AD 1500 (Huffman 2004, 2007: 444). The name site, Blackburn (Davies 1971), has a calibrated age (all calibrations in this paper use the curve from Vogel et al. 1993) of AD 1170–1235 (Huffman 2004), while Mpambanyoni (Robey 1980) has calibrated ages between AD 1025 and 1250 (Huffman 2004). At Sibudu, the remains of a clay hut floor were found in the southern part of the excavation grid. The full extent of the floor has not been excavated, but on present evidence, the floor is likely to be about the size (~5 m across) of the ones uncovered at Blackburn, where they would have been used as foundations for Nguni-style beehive huts (Davies 1971). A beehive hut is also likely to have been placed above the clay floor at Sibudu. The Sibudu floor is unburnt and no more than about two centimetres thick, so it is more like a temporary smear than a permanent hut floor. Trampled grass that may have served as matting was near the clay floor. Several Iron Age pits (some of which were greater than a metre in diameter) were dug into the MSA deposits, creating a mixture of MSA and Iron Age material culture, food waste, ashy deposit and charcoal. The pits became refuse dumps, though they may originally have had another purpose. One pit had wooden pegs surrounding it, suggesting that a leather cover might have been staked over it. However, none of the pits was lined with dung or had any other indication of use, such as food storage. Similar pits were found at Blackburn (Davies 1971) and at even earlier sites, such as the Early Iron Age site of Msuluzi Confluence (Maggs 1980a). The Sibudu pits contained a great many well-preserved, uncarbonized seeds from a variety of edible fruits, including Sclerocarya birrea (marula) and Harpephyllum caffrum (sour plum) (Sievers Scott 2005). Some of the seeds were gnawed by rodents, which probably feasted on the refuse in the pits. TABLE 1 Sibudu Iron Age radiocarbon ages (from charcoal). Calibrated ranges rounded off to the nearest 10. Lab. No. Sample designation δ13C (‰PDB) Radiocarbon years b.p. Calibrated 1 sigma range Pta-8015 Pta-9202 Pta-9196 Square E3d, BSS pit Square F5a, hut floor Square B5c, BSS2 -22.3 -27.3 960 ± 25 970 ± 50 1030 ± 40 1040–1170 1030–1180 1010–1040 WOOD ET AL.: a GLASS BEAD CACHE FROM sIBUDU CAVE 241 Fig. 1. Intact Sibudu bead cache: front. A cache of over 5000 glass beads comprising many coiled strands (Figs 1 & 2) was found in a small hole that was deliberately dug into B4b (the south-east quadrant of square B4) from layer BSV into BSS. The bead coils fitted the shape of the hole perfectly and they may have been stored in a bag, though no trace of one preserved. The thongs or twine that originally held the beads had decayed so the neat lines of beads were no longer securely connected where they lay amongst some loose beads in the hole. Most beads were brownish-red, though blue-green and blue beads formed a design amongst the brownish-red ones. A few crimped copper beads (four whole and four fragments) Fig. 2. Intact Sibudu bead cache: back. 242 Southern AFRICAN humanities, vol. 21, 2009 Fig. 3. Conus ebraeus shells with embedded bead. were found amongst the loose beads, but more are incorporated into the strung beads along with two perforated Conus ebraeus shells (Fig. 3). These marine shells occur commonly in warm waters all along the east coast of Africa with the southern limit around Port St Johns (Richards 1981). During the excavation of the bead cache, a 10 % solution of Paraloid and acetone was painted on the coils in an attempt to hold the beads in place. A syringe was used to apply Paraloid to the coils in the centre of the cache. As far as possible, the strings of beads were removed in toto, but because the coils formed a substantial chunk more than 10 cm thick, many loose beads were embedded in the ashy silt and could not be resin-coated. An entire necklace of putative ostrich eggshell disc-beads that included some blue glass beads was recovered as part of the cache. The shell disc-bead necklace will be described elsewhere after analysis by Lucinda Backwell. The disc-beads need careful examination of the kind undertaken by Ward and Maggs (1988) on examples from KwaZulu-Natal. They note that disc-beads made from ostrich eggshell and Achatinidae are fairly common at KwaZulu-Natal Early Iron Age sites, such as Ntshekane, Ndondondwane and Magogo (Ward & Maggs 1988) and Msuluzi Confluence (Maggs 1980a). Late Iron Age sites in KwaZulu-Natal, such as Moor Park and Mpambanyoni, seldom contain disc-beads. Glass beads are far less common in KwaZulu-Natal and are reported in abundance only from Iron Age sites post-dating 1800 (e.g. Van der Merwe et al. 1989). Early Iron Age sites contain a few glass beads: one was found at Ntshekane (Maggs & Michael 1976), another at KwaGandaganda (Whitelaw 1994) and a third from a Ntshekane-phase pit on the bank of the Zinkwazi River (site 2931AB 17). No glass beads were found in the Late Iron Age sites of Blackburn and Mpambanyoni (Davies 1971; Robey 1980). In the Thukela Basin, several LSA sites have glass beads of European, but not Indian origin. Mgede Shelter yielded a pale yellow glass bead as well as green, white, and bi-coloured red and white glass beads (Mazel 1986a: 377). Mbabane Shelter produced six red glass beads with black centres and eSinhlonhlweni Shelter one blue glass bead with a white centre (Mazel 1986b: 410). Twenty glass beads found in KwaThwaleyakhe Shelter and seven in Maqonqo Shelter are thought to have been of Italian origin (Mazel 1993: 20, 1996: 25). This sparse glass bead distribution at Iron Age and LSA settlements in KwaZulu-Natal emphasizes the rarity and importance of the Sibudu bead cache. WOOD ET AL.: a GLASS BEAD CACHE FROM sIBUDU CAVE 243 PREPARATION AND CLASSIFICATION OF THE BEAD ASSEMBLAGE The glass bead cache was cleaned in the laboratory and deposit not secured with resin was sieved through 1 mm mesh to recover loose beads. The Paraloid coating has been kept on the solid lump of coiled beads, but this coating can be removed with acetone if this is considered necessary in the future. All measurements and numbers in the tables refer to the 2480 loose beads only, because the beads in the consolidated coils cannot be counted or measured. The number of consolidated beads has, however, been estimated at around 2700. This number was arrived at by weighing the 1607 small sized brownishred beads then comparing that weight to the consolidated mass (it was estimated that 10 % of the mass was matrix so 10 % of the mass was subtracted before calculating the number of beads). Classifying glass beads Several characteristics, including method of manufacture, end treatment, structure, shape, size, colour and translucency are used to classify beads. This classification draws on Kidd and Kidd (1970), Karklins (1985: 85–117) and Wood (2005: 23–38). All Sibudu glass beads are simple in structure, meaning they are made of a single undecorated layer of glass. All are drawn, that is, they were cut into lengths from glass tubes that were drawn or pulled out from a gather (globule) of molten glass that had been perforated through the centre. The perforation remains intact in the drawing process and becomes the hole in the centre of each bead. Once cut into lengths the bead ends are often heat treated (rounded) by packing them into a large pan with ash or another medium to keep them separated. They are then reheated until the glass begins to melt, smoothing or rounding the cut ends. The longer the reheating process, the rounder the beads become, but care must be taken to avoid over-melting or they will collapse and be ruined. The ends of most tubular Sibudu beads show little evidence of rounding, but they are smooth (that is, not sharp) indicating they were reheated only briefly. The Sibudu beads can be divided into three shapes: tube, cylinder and oblate. Most cataloguing systems do not distinguish between tubes and cylinders, but Wood has found it useful in classifying pre-European bead assemblages. The bodies of tubular beads have straight, parallel sides. Their ends may be slightly smoothed through reheating, but the profile remains straight. The ends of cylindrical beads are visibly rounded, but a small portion of the body can remain straight. Most irregularly shaped beads fall into this category. Oblate beads have been reheated to the point that the entire body is smoothly rounded. Their length must be less than their diameter (if they were equal the bead would be a sphere). The oblate designation is reserved for uniform, well-formed beads. Bead sizes are made up of two measurements: first the diameter, perpendicular to the perforation, is measured (Table 2) and then the length, parallel to the perforation. The TABLE 2 Size range parameters for Sibudu beads. Size range Diameter in mm minute small medium large < 2.5 2.5–3.5 3.5–4.5 > 4.5 244 Southern AFRICAN humanities, vol. 21, 2009 TABLE 3 Length ratio parameters for Sibudu beads. Length ratio designations disc Formula short length = > 1/ 5 and < 4/ 5 diameter standard long very long length = < 1/ 5 diameter length = > 4/ 5 and < 1 1/ 5 diameter length = > 1 1/ 5 and < 2 diameter length = > 2 diameter size ranges (diameter measurements) have been developed for use with southern African glass bead assemblages (Wood 2005: 33) because bead diameters there are smaller than those found in most other regions, such as the East African coast (Chittick 1974: 464; Morrison 1984: 182). Bead lengths are recorded as length-ratio (Table 3), which is the relationship between the length and diameter of the bead. These categories are adapted from Chittick (1974: 463). Bead colours are determined using the Munsell Book of Colours (Munsell 1976) under natural daylight. Bead researchers normally restrict glass translucency (or diaphaneity) descriptions to three categories: transparent, translucent and opaque. Wood has found that gradations between these categories can be useful when working with assemblages of small, monochrome drawn beads. Therefore the categories of transparent-translucent, translucent-transparent, translucent-opaque and opaque-translucent have been added to the normal three (Wood 2005: 35). Fig. 4. Brownish-red loose Sibudu beads in three size groups. 245 WOOD ET AL.: a GLASS BEAD CACHE FROM sIBUDU CAVE Fig. 5. Green, yellow, blue and blue-green loose Sibudu beads. Classifying the Sibudu glass beads As mentioned earlier, these data (Appendix 1) include only the 2480 loose beads (Figs 4 & 5), not those in the consolidated strings. Table 4 records their shapes and end treatment. Table 5 demonstrates that most Sibudu beads are small and short and that very few fall outside the boundaries of small to minute and short to standard categories. Table 6 lists colour groups and translucency for the beads. As is evident, brownish-red beads (Fig. 4) form the bulk of the assemblage. Blue-green and blue (Fig. 5) are the only other colours represented by more than a few beads. Any blue with even a touch of green is placed into the blue-green category. The designation ‘blue’ is reserved for cobalt blue beads. Chemical analysis shows that cobalt colours the blue beads and copper (sometimes with the addition of iron) colours the blue-green ones. CHEMICAL ANALYSIS OF THE BEAD ASSEMBLAGE1 Method The analyses carried out at the Field Museum, Chicago, involved a Varian inductively coupled plasma-mass spectrometer (ICP-MS) and a New Wave UP213 laser, for direct TABLE 4 Shape and end treatment of Sibudu loose glass beads. Shape tube cylinder oblate total Number 2425 54 1 2480 Heat rounded 77 54 1 132 Lightly reheated 2348 2348 246 Southern AFRICAN humanities, vol. 21, 2009 TABLE 5 Size ranges and length ratios of Sibudu loose glass beads. Size range Length ratio Standard 114 434 16 - Short 332 1370 196 2 minute small medium large Long 2 14 - Total 448 1818 212 2 introduction of solid samples. The parameters for ICP-MS were optimized to ensure a stable signal with a maximum intensity over the full range of masses of the elements and to minimize oxides and double ionized species formation (CeO+/Ce+ and Ba++/Ba+ < 1–2 %). For that purpose the argon flows, the radio-frequency power, the torch position, the lenses, the mirror and the detector voltages were adjusted using an autooptimization procedure. For better sensitivity, helium is used as a gas carrier in the laser. A single point analysis mode using a laser beam diameter of 55 µm, operating at 70 % of the laser energy (0.2 mJ) and at a pulse frequency of 15 Hz was used in order to determine elements with concentrations in the range of ppm and below, while leaving an almost invisible mark on each bead’s surface. A pre-ablation time of 20 seconds was set up to eliminate the transient part of the signal and to ensure that possible surface contamination or corrosion did not affect the results. For each glass sample, an average of four measurements corrected from the blank was used for calculating concentrations. Isotope 29Si was used for internal standardization. In order to isolate the main components of the glasses, reduced compositions were calculated by normalizing the seven major and minor oxides to 100 %. This process removes most of the compositional effects of additives, such as colourants, and permits examination of the basic glass recipe (Gratuze 1999). Two series of standard reference materials were used to determine the concentrations of major, minor and trace elements. The first series of external standards were NIST SRM 610 and 612. Both of these standards are soda-lime-silica glass doped with trace elements in the range of 500 ppm (SRM 610) and 50 ppm (SRM 612). Certified values are available for a very limited number of elements. Concentrations from Pearce et al. (1997) were used for the other elements. The second series of standards were manufactured by Corning. Glasses B and D best match the compositions of ancient glass (Brill 1999: 544). TABLE 6 Colour groups and translucency of Sibudu loose beads. Tsp = transparent; Tsp/tsl = transparenttranslucent; Tsl/tsp = translucent-transparent; Tsl = translucent; Tsl/op = translucent-opaque; Op/tsl = opaque-translucent; Op = opaque; Ind = indeterminate. Colour group indeterminate black blue blue-green green yellow brownish-red Tsp 2 - Tsp/tsl - Tsl/tsp 1 - Tsl 3 3 - Tsl/op 4 80 128 4 8 - Op/tsl 6 - Op 2 2238 Ind 1 - Total 11 2 80 134 7 8 2238 WOOD ET AL.: a GLASS BEAD CACHE FROM sIBUDU CAVE 247 Glass Corning C is generally not one of the standards used for quantitative analysis, but is measured regularly to check the reliability of our results. The detection limits range from less than 1 ppb to 2 ppm for copper and are generally under 1 ppm for most of the elements. Accuracy is generally better than 10 %. Reproducibility is better than 10 % for most elements. For more details about the performance of LA-ICP-MS for glass analysis at the Field Museum, see Dussubieux et al. (2009). Results (see Appendix 2) Ancient glass was generally made by melting sand, which is mostly silica (SiO2), with a flux (an alkali or alkali earth-based ingredient) added to lower the melting point of the mix. Sodium-based fluxes were generally obtained either from mineral deposits or from soda plant ash, the former being purer than the latter. The magnesia (MgO) and in some cases the potash (K2O) contents of the glass act as indicators of the purity of the soda flux. For example, glass made with sodium carbonate taken from mineral deposits (also called natron) contains low levels of magnesia and potash while glass made with soda plant ash will have concentrations of magnesia and potash higher than 1.5 %. Soda-rich plants are known as halophytic plants and grow in salt-rich soils. Different proportions of magnesia, soda and potash may result from the use of different types of halophytic plants. Saltpetre (potassium nitrate), a mineral efflorescence, provides a rather pure potash flux while forest plant ash that contains both potash and lime (CaO) results in a glass with a more mixed composition. Lead can also be used as flux. Alumina (Al2O3) and lime are necessary to obtain durable glass. They are generally present in the sand along with silica, although as has been mentioned lime may be added with certain fluxes. If the concentrations of lime present in the sand and/or flux are too low, additional amounts may be added separately. Differing proportions of these elements in a glass, as well as concentrations of iron (Fe), titanium (Ti) and trace elements, can help point to the sand or rock sources used by the glassmaker. Granite sand generally produces glass in which proportions of alumina are much higher than lime, while a lime sand, which may come from a coastal deposit, will result in a glass in which proportions of lime are higher than alumina. Crushed quartz pebbles, a rather pure source of silica, produce a glass low in both lime and alumina. In the glass used to make the Sibudu beads, the main constituent after silica is soda (~19 %); the low levels of magnesia (~0.8 %) indicate that the soda has a mineral origin. This type of glass is characterized by relatively high alumina concentrations (higher than 4 %) due to the addition of granite sand that contains relatively high levels of impurities and is often called mineral soda alumina (m-Na-Al) glass. Based on trace element concentrations, two subtypes have been identified for this glass. The first subtype comprises glass samples mostly from South India, Sri Lanka and Southeast Asia, which date from the fifth century BC to the tenth century AD. This glass, rare in Africa, has average uranium concentrations around 20 ppm and relatively high barium concentrations, up to ~3500 ppm. It is known as low uranium-high barium (lU-hBa) glass. The second subtype dates from the eighth to the nineteenth centuries and is more common at sites in sub-Saharan Africa and has been found on the west coast of India (Dussubieux et al. 2008). Uranium concentrations in this m-Na-Al glass are higher than in the previous subtype and average approximately 100 ppm, while barium concentrations 248 Southern AFRICAN humanities, vol. 21, 2009 are significantly lower; this subtype is labelled high uranium-low barium (hU-lBa) glass. This type of glass has been identified in Madagascar (Robertshaw, Rasoarifetra et al. 2006) as well as at numerous Iron Age sites in southern Africa (Robertshaw et al. 2003; Robertshaw, Wood et al. 2006). The m-Na-Al glass in this study has an average uranium concentration of 180 ± 80 ppm and an average barium concentration of 320 ± 90 ppm and is therefore part of the hU-lBa sub-group. Ingredients used to colour the glass samples vary. The two yellow beads (Fig. 6) contain more lead and tin than other beads, indicating they were coloured with lead stannate (PbSnO3), a yellow crystalline compound. The cobalt blue glass beads contain cobalt associated with arsenic and nickel (see Dussubieux et al. 2008 for a discussion on this colourant). The blue-green beads contain significant quantities of copper oxide (more than 0.5 %) and vary in hue depending on other additives. When more cobalt is present they are bluer, and with higher levels of lead stannate they are greener. The green beads are copper rich and contain elevated levels of lead stannate. They also contain relatively high quantities of iron (6.1 and 4.3 %), which may have played a role in the colouring of these artefacts (the one with higher iron content is more olive-green than the other). The brownish-red glass is coloured with copper; the colour was quite likely facilitated by the presence of relatively high concentrations of iron (see Dussubieux et al. 2008 for more details). Fig. 6. Sibudu test beads L–R: top SBDU 01–04, middle SBDU 05–10, bottom SBDU 11–16. DISCUSSION The cache of ~5000 beads, indeed the entire Iron Age occupation at Sibudu, is extraordinary in several ways. Such wealth in beads might be expected in association with an elite dwelling, yet the shelter is an unlikely place for this. Iron Age occupation in shelters is, in any event, atypical other than in defensive situations, for example during the Mfecane. There presently is no reason to suspect that Sibudu was used for such purposes. Another possibility is that the shelter was home to a diviner or herbalist who practiced in this unusual and relatively inaccessible place (Whitelaw pers. comm.). Clients may have brought gifts or payment for advice and healing. Only WOOD ET AL.: a GLASS BEAD CACHE FROM sIBUDU CAVE 249 the Conus ebraeus beads are local if the disc beads prove to be of ostrich eggshell. Maggs (1980a) considers that eggshell beads came from hunter-gatherers who lived in country above 1200 m a.s.l. because ostriches apparently are not endemic to coastal and bushveld environments. The rare copper beads were probably also imported (Miller & Whitelaw 1994). Caches of beads, such as the one recovered from Sibudu Cave, are rare; only one other from pre-European contexts in southern Africa is known to the authors. In it 2600 glass beads were found in a pot on a hut floor at Kgaswe homestead in eastern Botswana (Denbow 1986: 19). Three calibrated radiocarbon dates placed the site between AD 1000 and 1260. The beads indicate that a date toward the end of this span is most likely (Wood 2005: 44). The Sibudu cache is also remarkable because the care taken in excavating it allows us to see that the beads were strung for wearing. Beads strung for trade distribution would not be artfully interspersed with different colours (for example, the two blue-green beads that flank the uncommonly long brownish-red one in Fig. 1), let alone with marine shells and copper beads. The general uniformity in size and shape of the beads is also noteworthy. Origins of the beads The high alumina sand and mineral soda glass used to make the Sibudu beads suggests they were probably produced in India. Early historical sources list both Cambay on India’s west coast and Negapatam (the current spelling is Nagapattinum) on the southeast coast as ports where Portuguese and subsequent European traders procured beads for the southern and East African trade. Cambay is mentioned in several early records as a source of beads for this trade. According to Gaspar Correa’s 1512 account of Cabral’s visit to Sofala in 1501, two classes of beads were exported from Cambay: red beads (contas vermellias) and small transparent coloured glass beads (continhas de vidro cristalinas). In addition it is recorded that small transparent glass beads were taken along as gifts for “the king” (Theal 1898, II: 26–7). In 1505 Duarte Barbosa stated that Moors from Kilwa, Mombasa and Malindi brought Cambay cloths and “many small beads, grey, red and yellow” to Sofala and Angoche in small vessels called zambucos (Dames 1918: 12, 15). He also described Cambay beads as “one of the important articles of trade brought from India to the Red Sea and the East Coast of Africa by Mohammedan sea-faring traders” (Arkell 1936: 299). Tomé Pires (ca. 1511) recorded that “glass beads and other beads from Cambay” were used in the Indian Ocean trade (Freeman-Grenville 1962: 125). Axelson (1973: 46) notes that in 1506 the Portuguese at Sofala were fortunate in that a caravel arrived with “loot from Kilwa” that included beads from Cambay, because the local inhabitants did not view European ones with favour. Some scholars (Arkell 1936: 300; Francis 2002: 171) contend that beads exported from Cambay, especially the red ones (the colour of many carnelian beads), were of stone only. Careful reading of early records indicates that some glass beads were probably exported as well. In addition to the statements by Cabral and Pires already mentioned, another account by Pires noted that at Malacca traders from Borneo “take a great deal of coloured glass beads from Cambay” (Cortesão 1967: 133). If both stone and glass beads were being exported from Cambay, were they being made there? Stone beads, especially of carnelian and agate, have been made near or at Cambay for possibly two millennia (Arkell 1936: 304; Francis 2002: 108–9). Barbosa recorded that Cambay had 250 Southern AFRICAN humanities, vol. 21, 2009 many skilful turners who make … beads of sundry kinds, black, yellow, blue and red and many other colours … Here too are many workers in stones … A great amount of work is also done here in coral, alaquequas (carnelians) and other stones (Arkell 1936: 301). Although the bead colours mentioned by Barbosa could be represented by stone beads (as Arkell believed), Barbosa’s reference to both turners of coloured beads and “workers in stones” suggests he might have been saying that both glass and stone beads were being made in Cambay. However, to date we have found no records of archaeological or other evidence to suggest that glass or glass beads were actually made there. In sum, it seem likely that both stone and glass beads were exported from Cambay, but only stone beads were made there or in the near vicinity. Negapatam was also mentioned in early Portuguese records as a source of beads. Several references state that Portuguese traders were obliged to purchase beads at Negapatum because European beads were not acceptable to local inhabitants (Schofield 1958: 183; Van der Sleen 1956: 28, 1958: 212). Van der Sleen furthermore reports that when this knowledge reached the Portuguese king, he wrote to “his Governor in Negapatam, to ensure that his ships could be provided there with the beads [recorded as green, yellow and blue] wanted by the natives on the African coast” (Van der Sleen 1956: 28). In Lavanha’s account of the survivors of the wrecked Portuguese ship, Santo Alberto, who walked from just west of the Umtata River inland to Delagoa Bay in 1593, it was reported that one group of natives wore red beads in their ears. Nuno Velho Pereira, the chief captain, said he saw from their [the beads’] appearance that they came from the land of Inhaca, who is king of the people living by the river of Lourenço Marques. These beads are made of clay of all colours, of the size of coriander seed. They are made in India at Negapatam, whence they are brought to Mozambique and thence they reach these negroes through the Portuguese who exchange them for ivory (Theal 1898, II: 303). The reference to these beads, especially red ones, as clay (barros miudas) is a common misidentification because they look like terracotta or earthenware. Although Schofield maintained (based on the early records) that the beads must have been clay, he had to admit that “it is a curious fact that none of the clay beads from Negapatam have as yet been found on an archaeological site” (1938: 369). Even though many tens of thousands of beads dating to this period have been recovered in eastern and southern Africa since Schofield made this statement, not a single Indian ‘clay’ bead has been found. Bead specialists, including Van der Sleen (1958: 212, 1973: 82) and Francis (2002: 226 ff. 34) recognized that these “beads are nothing but opaque glass” (Van der Sleen 1958: 212). Indeed, they are the beads that Van der Sleen dubbed ‘Trade-wind’ and Francis called ‘Indo-Pacific’. The Lavanah account is filled with references to glass beads being used during the survivors’ journey as gifts or to pay for goods and services. It is also recorded that when they reached the latitude 27°27′, which Schofield (1958: 184) identified as in the Newcastle-Utrecht district of KwaZulu-Natal, they headed east “in which direction lay the village where their red beads were sold, which are those which come from the river of Lourenço Marques” (Theal 1898, II: 333). Again the question arises: were the beads exported from Negapatam made there? Van der Sleen (1956: 28) opined that it is unlikely beads were being made there. After a careful survey of the area in 1988, Francis found no evidence for beadmaking, glass making or glass working at the site (Francis 2002: 40). So once again we have a port WOOD ET AL.: a GLASS BEAD CACHE FROM sIBUDU CAVE 251 through which glass beads were exported, but they were evidently made elsewhere. An additional informative note about Negapatam is recorded by both Schofield and Van der Sleen: the port, which had been a Portuguese factory, was taken over by the Dutch in 1660. After the takeover, the export of beads from Negapatam “either ceased altogether or could only be carried on as contraband” (Schofield 1938: 366). Further, Van der Sleen thought that the “importation of Trade-wind beads must have stopped shortly after that time” (1958: 212). The assumption that could be drawn from this is that European beads found a greater place in the African trade after this date. Placing the Sibudu glass beads in time One method of placing a glass bead assemblage in time is to compare it to other assemblages whose dates are known. The calibrated radiocarbon dates place the Iron Age layers at Sibudu between AD 1020 and 1160. These dates coincide with the K2 period in the Shashe-Limpopo basin where many thousands of glass beads have been recovered from archaeological deposits (Fouché 1937; Gardner 1963; Saitowitz 1996; Wood 2005). Some similarities do exist between the Sibudu and K2-period assemblages: a few tubular blue-green Sibudu beads (such as SBDU05) are similar to the characteristic K2 ones, some brownish-red tubular beads are found in K2 assemblages and the yellow and green beads from both sites are macroscopically similar. The distribution of colours, however, is very different in that K2 assemblages are made up mainly of blue-green beads, while brownish-red beads occur in only small numbers (although quantities do increase in the early thirteenth century) (Wood 2005). In addition, the size and shape of the Sibudu beads, especially the brownish-red ones, are more uniform than their K2 counterparts. The beads that solidly demonstrate a lack of connection between the assemblages, however, are the cobalt blue beads. No cobalt blue beads are found in K2-period assemblages. They do appear in the bead series that succeed K2 (the Mapungubwe Oblate series and the Zimbabwe series), but those beads are made of a dark cobalt blue transparent glass that cannot be mistaken for the glass used to make the translucent-opaque lighter coloured Sibudu beads. In addition, the glass used to make all Mapungubwe and Zimbabwe series beads is a plant ash glass (Robertshaw, Wood et al. 2006) so is chemically different from that used for the Sibudu beads. Cobalt blue beads that are similar visually and chemically to the Sibudu ones do not appear elsewhere in southern African until about the fifteenth century as part of the Khami bead series (Wood 2005). Of other bead assemblages that may be related to the Sibudu beads, such as from Thulamela (AD 1435–1455 to 1505–1645, Huffman 2007: 253) and Machemma (AD 1410–1440 to 1475–1640, Huffman 2007: 258), only the southern Zambian site of Ingombe Ilede has beads that are visually similar. They come from burials that date to the fifteenth century (Huffman pers. comm.). Given the distance between the two sites, we do not suggest that they were in direct trading contact, but the similarities in the bead assemblages may indicate they date to around the same time. The chemistry of Sibudu beads tells us they were made in India, and thus it is likely they arrived in southern Africa before the end of the seventeenth century when European beads largely supplanted Indian ones. A mixture of chemistry and comparisons to other Iron Age bead assemblages in southern Africa make it unlikely they would pre-date the mid-fifteenth century. Given these parameters, the beads probably date to somewhere between AD 1450 and 1660 and could have been imported by either non-European or 252 Southern AFRICAN humanities, vol. 21, 2009 European traders since, as was noted earlier, African consumers preferred Indian-made beads to the ‘new’ varieties. Where do the Sibudu beads fit in what is now known about bead series in southern Africa? They do not match the K2 series morphologically or the Mapungubwe Oblate and Zimbabwe series chemically. They are close to the Khami series chemically but not morphologically. So it appears that they either post-date the Khami series, and are thus a new and as yet undefined series, or they are an undefined series that is more or less contemporaneous with the Khami series. This is a possibility since Portuguese records tell us that beads were being imported from both northwest (Cambay) and southeast (Negapatam) India from the beginning of the sixteenth century through to the later part of the seventeenth century. The Sibudu bead cache in the context of the Iron Age occupation To return to the archaeological evidence, it seems worth mentioning that KwaZuluNatal’s Blackburn and Moor Park sequence is not yet well understood and the issue of whether the Blackburn facies terminates in the Sibudu area at AD 1300 or 1500 depends on whether or not Moor Park is a regional development from it in southern/ interior KwaZulu-Natal (Huffman 2007 and pers. comm. to Wadley). Blackburn might have continued after AD 1300 only in the north of KwaZulu-Natal (for example, in the Richards Bay area), until it developed into Nqabeni around AD 1700. If this was the case, then the Sibudu area would have Moor Park and not Blackburn cultural items from about AD 1300. Separating the two facies will be difficult based on ceramics alone because there is overlap in the key features of the ceramics (Huffman 2007). However, if the termination date for Blackburn is about AD 1500 in the Sibudu area, then there is not necessarily a contradiction between a fifteenth/sixteenth century glass bead cache found at Sibudu and the Blackburn cultural remains at the site. The Sibudu ceramics have not yet been analysed, so it is presently not possible to provide numbers of Blackburn sherds occurring above and below the hut floor. As a result, it is not yet clear whether the three radiocarbon dates that calibrate to between AD 1020 and 1160 span the full Iron Age occupation of the site or whether they date only an early phase of occupation. Until the glass bead analysis suggested that the beads might post-date the radiocarbon dates by several centuries, it was assumed that only one Iron Age occupation was represented at the site. Now it seems possible that the charcoal found within the clay floor might predate the floor itself and that the floor could be more recent than AD 1160. If this is the case, then the floor and the bead cache are potentially contemporaneous. If, however, all the ceramics and the clay floor do represent one Iron Age occupation, the bead cache must have been buried in the shelter for some unknown purpose after the hut represented by the clay floor was abandoned. We are consequently uncertain about the relationship between the bead cache, the Blackburn material culture and the radiocarbon dates. Resolution of this issue is a project for future research that will involve getting radiocarbon dates for layer BSV. If the BSV dates prove younger than the date that we have for the hut floor, this will support the idea that the charcoal embedded in the clay predates the floor itself and that two Iron Age occupations are represented. Rarity of glass beads in Iron Age KwaZulu-Natal As we pointed out earlier, glass beads are rare in Iron Age contexts in the KwaZuluNatal region. Why should this be the case when sites further north have produced WOOD ET AL.: a GLASS BEAD CACHE FROM sIBUDU CAVE 253 many thousands of them from as early as the ninth century? From early Arabic sources, such as al-Masudi, Buzurg ibn Shahriyar, al Biruni and al-Idrisi (Wood 2005: 168–79) it appears that trading ports on the coast did not extend much south of the Bazaruto area of Mozambique, if at all. Sailing south through the Mozambique Channel is easy enough since the current flows south year-round, but the return journey north against the current is difficult so only highly lucrative trade would have encouraged traders to make the extra effort to journey farther south. Although KwaZulu-Natal could have provided ivory, a much sought after commodity in early trade, there was a plentiful supply further north. Ivory trade from the region began only after Lourenço Marques explored Delagoa Bay in 1545 (Newitt 1995: 152–3). Gold, the one commodity that could have encouraged traders to undertake the cost and risk to travel further south, was absent in the KwaZulu-Natal region. Limited exchange was carried on overland amongst local communities, however. Evidence for this is sparse, but can be gleaned from reports by early European visitors to the region, mainly survivors of shipwrecks. As we have noted, the survivors of the Santo Alberto wreck recorded the use of glass beads by some people they encountered. In another account by Perestrello, a Portuguese navigator who survived the 1554 wreck of the São Bento, it was recorded that the party encountered a man wearing a few coriander-seed sized (3–5 mm) red beads, which we rejoiced to see, it seeming to us that these beads being in his possession proved that we were near some river frequented by trading vessels, for they are only made in the kingdom of Cambaya, and are brought by the hands of our people to this coast (Theal 1898, I: 225). Once again small red beads from Cambay are mentioned. These would have been brownish-red glass beads—the same sort referred to in the Santo Alberto account and related to those from the Sibudu cache. However, the paucity of such observations as well as the absence of glass beads in archaeological sites indicates that they were very rare indeed in this part of the country. They did not become commonplace until European trade through Delagoa Bay (Maputo) and eventually Port Natal (Durban) was well established. Finally, it is always possible that, rather than being a direct product of trade, the Sibudu cache of glass beads was recovered from a shipwreck on the coast. If that were the case, however, the beads would have been recovered shortly after the wreck since they show no sign of water or beach abrasion. ACKNOWLEDGEMENTS We thank S. Woodborne of the CSIR for the radiocarbon dates. T.N. Huffman kindly discussed some of the Iron Age issues relevant to this paper. G. Whitelaw provided valuable information on archaeological sites and early records. Sibudu research is financially assisted by the NRF. We thank the School of Geography, Archaeology and Environmental Studies, University of the Witwatersrand, for ongoing support. NOTE An export permit (80/08/06/021/52) was obtained from SAHRA for the non-destructive analysis of 16 glass beads at the Field Museum of Natural History, Chicago, USA. The beads have been returned to South Africa and are in temporary storage at the University of the Witwatersrand, but they will be housed in the Natal Museum from 2009. 1 254 Southern AFRICAN humanities, vol. 21, 2009 REFERENCES Arkell, A.J. 1936. Cambay and the bead trade. Antiquity 10 (39): 292–305. Axelson, E. 1973. The Portuguese in South-East Africa 1488-1600. Johannesburg: Struik. Brill, R.H., 1999. Chemical analyses of early glasses. 2 vols. The Corning Museum of Glass, New York. Chittick, N. 1974. Kilwa: an Islamic trading city on the East African coast. The finds, 2. Nairobi: British Institute in Eastern Africa. Cortesão, A. 1944. The Suma Oriental of Tome Pires and the book of Francisco Rodrigues. 2 vols. Ser. Ii, No. 89. London: Hakluyt society. Dames, M.L., ed. 1918. The book of Duarte Barbosa, vol. I. 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MA dissertation, University of the Witwatersrand. drawn drawn drawn drawn drawn drawn 1 3 5 34 7 2 SBDU 13 drawn 1 SBDU 11 drawn 27 drawn drawn 1 1 drawn 1 drawn 2 drawn drawn 4 1 drawn 1 2 drawn 1 how made drawn quantity fragments 1 quantity SBDU 12 bead ID tube tube tube tube tube tube tube cylinder tube tube tube tube tube tube tube tube tube shape small minute lightly reheated small minute medium small small small small minute heat treated heat treated heat treated heat treated lightly reheated lightly reheated heat treated heat treated heat treated small minute small small minute medium lightly reheated lightly reheated lightly reheated lightly reheated lightly reheated lightly reheated small size range lightly reheated end treatment short standard short short short standard short short short standard short short standard short short short standard length ratio APPENDIX 1 Description of loose Sibudu glass beads. translucent translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque opaque opaque opaque/translucent opaque/translucent translucent/ opaque opaque/translucent ? diaphaneity 2.5BG 6/6 5PB 3/6 to 7.5PB 3/8 5PB 3/6 to 7.5PB 3/8 5PB 3/6 to 7.5PB 3/8 5PB 3/6 to 7.5PB 3/8 shiny to dull shiny to dull shiny to dull shiny to dull dull 5PB 2/8 5PB 3/6 blue-green blue blue blue blue blue blue blue blue 7.5PB 3/8 to 5PB 3/6 5PB 2/8 blue black black devitrified, colour gone devitrified, colour gone devitrified, colour gone devitrified, colour gone colour group devitrified, colour gone 7.5PB 3/8 N 0.5/0.6% R N 0.5/0.6% R ? ? ? ? ? Munsell code shiny shiny shiny shiny shiny dull dull heavy patina heavy patina heavy patina heavy patina crackled surface 256 Southern AFRICAN humanities, vol. 21, 2009 drawn drawn drawn drawn drawn drawn drawn drawn drawn 1 1 1 1 1 1 3 1 3 2 44 4 43 SBDU 08 SBDU 10 SBDU 06 SBDU 05 drawn drawn 1 drawn drawn drawn drawn 14 1 drawn 1 SBDU 09 drawn 1 how made SBDU 07 quantity fragments quantity bead ID lightly reheated lightly reheated lightly reheated lightly reheated heat treated lightly reheated lightly reheated lightly reheated heat treated lightly reheated lightly reheated lightly reheated lightly reheated heat treated heat treated lightly reheated lightly reheated end treatment small small small small small minute minute medium medium large minute minute small small medium large small size range long standard short long short short standard short short short standard standard long short short short short length ratio translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque transparent transparent translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent diaphaneity shiny shiny shiny to dull 2.5BG 6/2 5B 5/4 to 10B 4/4 5B 5/4 to 10B 4/4 5B 5/4 to 10B 4/4 5B 5/4 to 10B 4/4 shiny to dull shiny 2.5BG 6/6 blue-green blue-green blue-green blue-green blue-green blue-green blue-green 5B 5/4 to 10B 4/4 shiny shiny blue-green blue-green blue-green blue-green blue-green blue-green blue-green blue-green blue-green blue-green colour group 2.5BG 6/2 5B 5/4 shiny to dull dull 5B 5/4 shiny 10BG 5/6 2.5B 4/6 very shiny shiny 5BG 5/4 10B 4/4 5B 5/4 10BG 5/6 7.5B 6/4 Munsell code shiny shiny shiny shiny shiny surface WOOD ET AL.: a GLASS BEAD CACHE FROM sIBUDU CAVE tube tube tube tube cylinder tube tube tube cylinder tube tube tube tube cylinder tube tube tube shape APPENDIX 1 (continued) Description of loose Sibudu glass beads. 257 drawn drawn drawn drawn drawn drawn drawn drawn 183 16 2 320 108 1 8 1198 SBDU 14 drawn 1 drawn 1 SBDU 16 drawn 1 drawn drawn 1 1 drawn 1 how made drawn quantity fragments 4 quantity SBDU 15 bead ID tube tube tube tube tube tube tube tube tube tube tube tube tube tube tube shape minute minute minute small small small lightly reheated lightly reheated heat treated/ flattened lightly reheated lightly reheated medium medium medium medium small small small small small size range lightly reheated lightly reheated lightly reheated lightly reheated lightly reheated lightly reheated heat treated/ flattened heat treated/ flattened lightly reheated lightly reheated end treatment short long standard standard short long standard short short short short standard standard short short length ratio APPENDIX 1 (continued) Description of loose Sibudu glass beads. opaque opaque opaque opaque opaque opaque opaque opaque opaque opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ transparent diaphaneity good good shiny good good good good good shiny shiny shiny shiny shiny dull shiny surface 10R 4/4 to 10R 3/6 to 10R 2/4 10R 4/4 to 10R 3/6 to 10R 2/4 10R 4/4 10R 4/4 to 10R 3/6 to 10R 2/4 10R 4/4 to 10R 3/6 to 10R 2/4 10R 4/4 to 10R 3/6 to 10R 2/4 10R 4/4 10R 4/4 10R 4/4 10R 4/4 2.5BG 6/2 2.5BG 6/6 2.5BG 6/6 2.5BG 6/2 2.5BG 6/2 Munsell code brownish-red brownish-red brownish-red brownish-red brownish-red brownish-red brownish-red brownish-red brownish-red brownish-red blue-green blue-green blue-green blue-green blue-green colour group 258 Southern AFRICAN humanities, vol. 21, 2009 drawn drawn drawn drawn 1 1 4 1 SBDU 01 drawn drawn 1 1 drawn 1 SBDU 02 drawn 1 SBDU 04 drawn drawn 3 1 drawn 401 how made drawn quantity fragments 1198 quantity SBDU 03 bead ID oblate cylinder tube cylinder tube tube tube tube tube tube tube tube shape small lightly reheated heat treated small small medium lightly reheated heat treated small heat treated medium short short short short short short short minute small standard short standard standard short length ratio small small small small lightly reheated lightly reheated lightly reheated lightly reheated lightly reheated lightly reheated lightly reheated size range end treatment APPENDIX 1 (continued) Description of loose Sibudu glass beads. translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent/ opaque translucent opaque opaque diaphaneity dull shiny dull shiny shiny dull shiny shiny shiny shiny good good surface 7.5Y 8.5/10 5Y 8/6 5Y 8/6 7.5Y 7/8 5Y 7/8 10GY 5/4 2.5G 5/6 10GY 5/4 10GY 5/4 10GY 5/4 10R 4/4 to 10R 3/6 to 10R 2/4 10R 4/4 to 10R 3/6 to 10R 2/4 Munsell code yellow yellow yellow yellow yellow green green green green green brownish-red brownish-red colour group WOOD ET AL.: a GLASS BEAD CACHE FROM sIBUDU CAVE 259 yellow 96 21.2% 1.0% 9.1% 54.2% 0.1% 1.8% 3.5% 6926 297 33 0.07% 2.7% 30 44 0.02% 1961 6 Colour yellow LiO2 Na2O MgO Al2O3 SiO2 P2O5 K2O CaO TiO2 V2O5 Cr2O3 MnO Fe2O3 CoO NiO CuO ZnO As2O3 60 14.9% 0.9% 7.2% 64.0% 0.1% 3.2% 2.7% 4708 348 34 0.05% 2.1% 21 39 0.05% 406 3 SBDU 02 SBDU 01 Bead ID 63 19.6% 0.8% 7.6% 59.8% 0.2% 3.1% 3.6% 6004 504 30 0.11% 4.3% 188 44 0.5% 101 170 green SBDU 03 69 22.2% 0.9% 8.1% 55.3% 0.1% 2.5% 3.5% 7945 582 29 0.06% 6.1% 133 65 0.7% 62 80 green SBDU 04 SBDU 05 bluegrn 62 19.9% 0.5% 9.3% 60.8% 0.08% 3.6% 2.6% 4785 243 38 0.06% 1.8% 14 28 1.3% 39 7 SBDU 06 bluegrn 72 18.9% 0.9% 8.8% 62.9% 0.1% 2.2% 2.7% 6562 278 47 0.06% 2.4% 25 53 0.8% 586 15 SBDU 07 bluegrn 51 16.5% 0.4% 10.3% 64.9% 0.09% 4.6% 1.6% 3944 326 11 0.06% 1.0% 7.8 20 0.4% 56 17 SBDU 08 bluegrn 53 17.7% 0.7% 4.8% 69.5% 0.08% 1.3% 3.8% 4348 315 41 0.03% 1.5% 160 78 0.5% 37 258 SBDU 09 bluegrn 65 19.1% 0.7% 6.3% 67.3% 0.1% 2.0% 1.8% 4203 311 33 0.05% 1.8% 25 49 0.6% 1157 11 SBDU 10 bluegrn 39 16.0% 0.6% 5.0% 71.0% 0.1% 2.3% 2.5% 3738 374 47 0.08% 1.7% 591 221 0.7% 55 1222 61 19.5% 0.8% 5.7% 66.6% 0.1% 1.8% 3.4% 3515 312 52 0.09% 1.8% 1366 570 0.0% 67 2420 blue SBDU 11 84 18.4% 1.1% 6.0% 66.0% 0.09% 1.6% 4.6% 4986 287 28 0.04% 2.2% 1624 510 0.0% 44 2388 blue SBDU 12 68 19.2% 0.9% 7.0% 64.6% 0.2% 2.0% 3.2% 5517 360 71 0.07% 2.5% 2713 1175 0.0% 85 5489 blue SBDU 13 85 20.2% 1.0% 6.8% 61.5% 0.07% 1.4% 3.4% 5183 265 42 0.09% 3.2% 18 38 0.8% 66 7 br-red SBDU 14 55 18.4% 0.8% 4.4% 66.4% 0.2% 1.9% 3.0% 3914 358 52 0.04% 2.9% 29 32 0.7% 44 59 br-red SBDU 15 88 21.4% 0.7% 6.9% 60.7% 0.2% 2.1% 2.1% 4965 363 53 0.07% 3.5% 27 43 0.9% 60 27 br-red SBDU 16 APPENDIX 2 Results of chemical analysis of Sibudu beads. Concentrations are in weight percent or ppm of oxide (0.1% = 1000 ppm); nm = not measured. 260 Southern AFRICAN humanities, vol. 21, 2009 yellow 62 263 30 360 20 nm 0.5 1.2% 27 0.7 505 51 128 11.4 38 7.1 1.3 Colour yellow Rb2O SrO Y2O3 ZrO2 NbO2 MoO2 InO SnO2 Sb2O5 Cs2O BaO La2O3 Ce2O3 Pr2O3 Nd2O3 Sm2O3 Eu2O3 72 235 21 209 16 nm 0.4 0.6% 7 0.8 345 38 103 9.1 32 5.8 0.9 SBDU 02 SBDU 01 Bead ID 78 327 19 225 14 nm 0.08 0.09% 16 1.0 434 34 82 7.5 25 4.6 0.9 green SBDU 03 72 334 20 298 17 nm 0.2 0.09% 23 1.0 428 35 71 7.5 25 4.8 1.0 green SBDU 04 SBDU 05 bluegrn 142 322 22 783 13 nm 1.1 0.004% 45 1.0 659 25 62 5.9 21 5.4 0.9 SBDU 06 bluegrn 94 238 24 306 18 nm 0.06 0.1% 15 1.8 451 44 96 10.0 34 6.3 1.1 SBDU 07 bluegrn 153 208 25 292 7.6 nm 0.04 0.01% 17 1.1 563 35 78 8.1 27 5.6 0.6 SBDU 08 bluegrn 48 194 17 244 11 nm 0.04 0.001% 13 0.6 290 26 62 5.7 19 3.7 0.7 SBDU 09 bluegrn 51 186 18 200 10 nm 0.1 0.1% 16 0.7 286 28 65 6.4 21 4.0 0.7 SBDU 10 bluegrn 55 176 17 191 10 nm 0.03 0.005% 21 0.6 356 36 72 7.1 24 4.0 0.7 48 241 17 190 11 nm 0.04 0.01% 2.5 0.6 355 32 67 6.5 22 3.9 0.7 blue SBDU 11 47 200 21 234 13 nm 0.03 0.0005% 1.4 0.9 277 36 78 7.7 26 4.8 0.9 blue SBDU 12 68 255 25 246 16 nm 0.03 0.02% 3.2 0.9 554 49 105 10.1 34 6.3 1.2 blue SBDU 13 42 267 23 345 17 1.5 0.04 0.007% 21 0.4 353 44 89 9.6 31 6.0 0.8 br-red SBDU 14 46 201 19 444 12 6.0 0.06 0.005% 24 0.6 255 30 68 6.4 21 3.8 0.6 br-red SBDU 15 80 169 25 258 16 6.6 0.05 0.005% 30 0.8 354 40 102 8.8 29 5.4 0.9 br-red SBDU 16 APPENDIX 2 (continued) Results of chemical analysis of Sibudu beads. Concentrations are in weight percent or ppm of oxide (0.1% = 1000 ppm); nm = not measured. WOOD ET AL.: a GLASS BEAD CACHE FROM sIBUDU CAVE 261
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