PII: S0003-4878(00)00027-2 Ann. occup. Hyg., Vol. 45, No. 2, pp. 115–121, 2001 2001 British Occupational Hygiene Society Published by Elsevier Science Ltd. All rights reserved Printed in Great Britain. 0003–4878/01/$20.00 Changes in the Performances of Filter Media During Clogging and Cleaning Cycles S. CALLɆ*, D. BÉMER‡, D. THOMAS†, P. CONTAL† and D. LECLERC† †Laboratoire des Sciences du Génie Chimique–CNRS, 1 rue Grandville, 54000 Nancy, France; ‡Institut National de Recherche et Sécurité, Avenue de Bourgogne, 54501 Vandoeuvre les Nancy, France The performance of two filter media used in industrial air cleaning were studied both in the initial state (new filter) and after a number of collection and pulse pressure cleaning cycles. The main difference between them is that one has anti-clogging properties and the other does not. The test aerosol is composed of alumina particles with a median volumetric diameter of 2.6 mm (MMAD=4.8 mm) generated at a concentration of 700 mg mⴚ3. Filtration took place at a velocity of 2 cm sⴚ1. Two parameters, namely pressure drop and efficiency, were monitored according to the collection and cleaning cycles. The comparison of the filtration efficiency of the two media and that of the corresponding industrial dust separator at the end of the cycles showed a close agreement. The separation efficiency calculated with a new medium (corresponding to initial switch-on of the installation) was low and increased very quickly during the cycles. Finally, a phenomenological model was developed to represent the increase in pressure drop of a filter medium after cleaning and was found to be in close agreement with the experimental values. 2001 British Occupational Hygiene Society. Published by Elsevier Science Ltd. All rights reserved. Keywords: filtration; clogging; pulse-jet INTRODUCTION Recycling the air of workplaces is a ventilation technique in widespread use mainly to save energy. The quality of the recirculated air, which is monitored very closely, is directly linked to the filtration efficiency for the pollutants present in the air flow. The quality of the air can be checked by measuring the pollutant concentration in the recirculated air regularly and by measuring the separation efficiency of the filter. European standards currently classify the filter media used in general ventilation systems by means of this efficiency parameter. In the field of industrial air cleaning, the test methods are based solely on testing new media. The performance measured in this way is far removed from that of materials in use on account of the loading and regeneration cycles undergone by the media. The point of this study is to show Received 8 December 1999; in final form 17 April 2000. *Author to whom correspondence should be addressed. Tel.: +33-8340-2000; fax: +33-8350-2097; e-mail: [email protected] how the performance of a filter medium varies with the clogging and cleaning cycles, in other words in real operating conditions (filtration and regeneration). Two types of medium with different clogging properties are therefore examined. The paper then goes on to compare their performance with that of a dust separator used in wood industry. CHARACTERISATION OF FILTER MEDIA Two filter media were selected for this study of filtration performance in collection and cleaning cycles. These two media, designated C and D in what follows, are employed in industrial filters in the form of a bag and cartridge respectively. The fundamental difference between these two media is the clogging related treatment received during manufacture. Medium C is a polyester needlefelt with no specific treatment whereas medium D, made up of cellulose fibres, has a thin layer of very fine fibres on its surface constituting an anti-clogging coating. The different physical parameters determined were the mass per unit area, filter thickness, packing den- 115 116 S. Callé et al. Nomenclature af ag Cp dae ⌬P E g m Q S U W Z rf kck Ap rp filter medium packing density particle cake packing density particle concentration (kg.m⫺3) aerodynamic diameter (m) pressure drop (Pa) filtration efficiency fraction of cleaned surface air viscosity (Pa s) volumic flow rate (m3 s⫺1) filtration surface (m2) filtration velocity (m s⫺1) mass of particle per unit area (kg m⫺2) filter medium thickness (m) fibre radius (m) Kozeny and Carman constant particle specific area (m⫺1) particle density (kg m⫺3) sity and fibre size distribution. The mass per unit area was calculated from the weight and area of a sample. The thickness of each medium was determined by observation with an optical microscope. The packing density was calculated from these two parameters and the density of the fibres. Finally, image analysis carried out with a scanning electron microscope gave access to the fibre size distribution. One observation of each of the filters C and D with the electron microscope is given in Fig. 1. The arithmetic mean diameter of the fibres as well as the spread of the distribution were calculated. In the case of filter D, the distribution of the two types of fibres were considered separately. The results obtained are given in Table 1. The characterisation of the new filters was followed by measurement of the initial fractional filtration efficiency according to the standard Pr EN 779 (1998). A polydisperse test aerosol was generated upstream of the filter and samples taken alternately upstream and downstream of the filter medium using an optical counter. The separation efficiency for a given diameter (corresponding to one channel of the counter) was calculated from the number of particles of this diameter counted upstream and downstream of the filter. The efficiency value uncertainty is determined from the Student law. The aerosol selected was composed of KCl particles generated by means of nebulisation from a 1% in volume solution using a De Vilbis 40 nebuliser. This choice stemmed from the fact that the information given by the counter is only valid for particles whose refractive index is close to that of the latex particles used to calibrate the apparatus. The error on the number of particles sampled when using a KCl aerosol according to the calculations is about 5% (Bémer, 1990). As shown in what follows, this initial efficiency information is particularly important in highlighting Fig. 1. Microscopic observations of new medium C and medium D. Clogging and cleaning cycles of filter media 117 Table 1. Physical parameters of the two filter media tested Filter media C D Mass per unit area Thickness Z (µm) Packing density af (g m⫺2) 475 135 1400 400 the difference in the performance of a filter medium between initial state and after a certain number of clogging and cleaning cycles. METHODS The test rig employed for the various experiments is shown in Fig. 2. Its central section comprised a filter holder which presents a filtration surface of 130 mm diameter. At one end of the rig, a rotary brush generator (Palas RBG 1000) supplied with filtered and dried air generated alumina particles (Abralis OPTI 3S). The generation mass flow rate was about 10 mg min⫺1. The particle size distribution of the aerosol at the outlet was determined by sampling on an isopore membrane and analysis using a Coulter counter (Multisizer). The characteristics obtained were the following: volume median diameter 2.6 µm (MMAD=4.8 µm) and geometric standard deviation 1.5. The total air flow rate in the installation was held 0.246 0.225 Arithmetic mean diameter (µm) Standard deviation of the fibre size distribution 14.9 13.9/0.25 0.4 10/0.2 constant by means of a control and by-pass system to obtain a filtration velocity of 2 cm s⫺1 (66.3 Nm3 h⫺1 m⫺2). Two sampling lines upstream and downstream of the filter medium comprised a profiled probe coupled to an elbow (⭋ 16 mm), a valve and a duct linked to an optical counter (PMS Lasair 1001 or 310). The technique to determine the efficiency as a function of the particle diameter was therefore the same as that used to characterise the initial state of the filtration media. Both sections of the filter were fitted with pressure transducers that allowed continuous monitoring of the pressure drop of the filter. The cleaning technique employed was a reverse flow pulse pressure. To achieve this a cross-flow compressed air inlet was installed downstream of the filter. A time delay circuit was employed to set the valve opening time at the fixed value of 0.4 s. The overpressure recorded on the filter was 3080 Pa. Cleaning was triggered at a maximum pressure drop, designated ⌬Pmax. Different tests were conducted: test Fig. 2. Representation of the test rig to study the clogging and cleaning cycles. 118 S. Callé et al. on filter C with cleaning at ⌬Pmax=600 Pa then 350 Pa, and test on filter D with cleaning at ⌬Pmax=350 Pa. The particle detachment produced by the reverse flow pulse pressure led to a fall in pressure drop to a value termed residual. The maximum pressure drop for each medium was chosen partially on account of their respective resistances. For each of the two media tested, the protocol was the following. The pressure drop was monitored during the cycles until stabilisation of the residual pressure drop occurred. The efficiency was determined during the cycles after the first and the fourtieth cleaning and compared to the previously measured initial fractional efficiency. RESULTS Observation of each medium during the cycles revealed layered detachment of the cake particles formed on the surface of the filter. Koch et al. (1996) also referred to this type of observation following pressure-pulse cleaning. It is called patchy cleaning. The higher the quantity of particles collected, the larger the cleaned surface area. In contrast, as the cycles progressed it appeared that the average surface area of the cleaned zones diminished. Change in pressure drop with the cycles Figures 3 and 4 show the changes in pressure drop of media C and D respectively with the cycles during cleaning at a maximum pressure drop of 350 Pa (40 cycles). The first collection cycle of each of the new filters followed three stages. The particles were firstly collected inside the filter, which led to a small increase in pressure drop. A transition zone was then observed during which the particles began to accumulate on the surface of the filter medium until the formation of a layer that then increased linearly in the same way as the pressure drop. These collection cycle mechanisms have been studied in details by Lee and Liu (1982), Fig. 3. Change in the pressure drop of medium C as the cycles progressed. Fig. 4. Change in the pressure drop of medium D as the cycles progressed. Brown (1993), Walsh et al. (1996), Japuntich et al. (1997) and Thomas et al. (1999). The change in pressure drop had a specific pattern during the collection periods following one cleaning cycle. In contrast to the first collection stage of the new filter, the pressure drop firstly increased rapidily then rose more or less linearly. This phenomena, observed by Humphries (1981) on woven cloths and needlefelted fabrics clogged by an aluminium oxide powder, is a characteristic of patchy cleaning. Observations of the filter medium after cleaning represented in Fig. 5 tends to confirm this hypothesis. The flow of particles through the cleaned gaps has a much higher velocity than around the remaining layers. The pressure drop therefore increases very quickly. From this hypothesis, a model of the change in pressure drop with time after one cleaning cycle was constructed. The aim is to give a way of characterising each experimental cleaning cycle in term of pressure drop according to the hypothesis of patchy cleaning. The key parameter of the calculation is the cleaned fraction, g, defined as the ratio of the cleaned surface area to the total filtration surface area. For a given value of g and by dividing the cleaned filter into two systems, one formed by the cleaned parts of Fig. 5. Patchy cleaning illustration. Clogging and cleaning cycles of filter media 119 the filter the second by the non cleaned zones, the pressure drop and filtration flow rate were determined. The pressure drop calculation models are respectively that of Darcy (1) for the new filter and that of Kozeny–Carman (2) for the dust cake. 3 ⌬Pf = m·U·Z· 16af 2·(1 + 56·a3f) ⌬Pg = m·kck·U·A2p r2f ag W · (1⫺ag)3 rp (1) (2) From the data relative to filter medium C, curves of the change in pressure drop after cleaning for different values of the cleaned fraction could be deduced. They are shown in Fig. 6. The considerable influence of the cleaned fraction was observed. For both types of medium, the residual pressure drop after each cleaning cycle increases as the cycles progress until reaching a more or less constant value. Different hypotheses can be put forward to account for this pattern. This increase in residual pressure drop could be explained by two coexisting phenomena. The quantity of particles inside the filter medium increases as the cycles progress while remaining a non regenerable fraction. The pressure drop after each cycle therefore increases up to a threshold corresponding to maximum filling of the filter. In addition, the deposit on the surface of the filter medium is more and more cohesive and thefore better resists the cleaning pulse pressure. Figure 7 shows the changes in the residual pressure drop of media C and D as a function of generated mass per unit area, cleaned at a maximum pressure drop of 350 Pa, as well as the trend curves fitted to the experimental points. It would clearly appear that the anti-clogging treatment of medium D facilitates detachment of the particles. This therefore has a residual pressure drop that increases much more slowly than that of filter C. After cleaning, medium D recovers, in terms of pressure drop, to properties closer to its initial state than medium C. Fig. 6. Change of pressure drop after cleaning as a function of the fraction cleaned. The different curves represent different values of g : 0.1 (top), 0.3, 0.5, 0.7, 0.9 (bottom). Fig. 7. Comparison of the change in residual pressure drop for medium C (䊐) and medium D (왖). Comparative tests on medium C cleaned for two maximum pressure drops (350 and 600 Pa) gave the results shown in Fig. 8. The residual pressure drop following cleaning at 600 Pa was always higher than that following cleaning at 350 Pa. The explanations put forward earlier also apply in this case. The later the cleaning is carried out, the greater the quantity of particles collected on the surface and inside the medium and the greater the tendency towards particle cohesion. The particle cake remaining on the surface after cleaning may also have been more compressed. These arguments support the hypothesis that the quantity of dust particles that can potentially be cleaned varies inversely with the maximum pressure drop. Changes in filtration efficiency with the cycles The filtration efficiency as a function of the particle diameter was monitored at different stages of the first collection cycle and just after the first cleaning cycle of filter medium C. The pressure drop of the filter at each of these points was respectively 18 (new state), 150, 300, 600 (maximum pressure drop) and 39 Pa Fig. 8. Comparison of the changes in the residual pressure drop of filter C cleaned at two different maximum pressure drops: ⌬Pmax=350 Pa (䊏) and ⌬Pmax=600 Pa (䊊). 120 S. Callé et al. Fig. 9. Change in the filtration efficiency of medium C in new state at different steps of the first clogging for 0.25 µm particles (t=0; 20; 33; 55 min) and just after the first cleaning (t=55 min). (cleaned state). The results are shown in Fig. 9 for a diameter of 0.25 µm, close to the minimum filtration efficiency. The filtration efficiency increases very quickly at the start of the collection cycle, reaching values close to 100% when the pressure drop of the filter reaches its maximum value. Then, just after cleaning, the efficiency falls to a value slightly above its initial value. The efficiency therefore tends to increase to a limit value during the cycles and with the increase in the quantity of particles remaining. The fractional filtration efficiency at the end of 40 cycles (when the residual pressure drop had reached a more or less constant value) was compared to the initial efficiency for each of the two media. The curves are shown in Fig. 10 for filter medium D cleaned at 350 Pa. The first conclusion is that the separation efficiency of the filter medium increases until reaching, for particles with an average diameter between 0.15 and 10 µm, values greater than 90%. At the end of 40 cycles, the fractional efficiency showed much less variation. The efficiency was more than 90% at all sizes, but it must be remembered that the penetration (100% minus efficiency) would still vary several-fold with particle size. Fig. 10. Filtration efficiency of medium D as a function of particle size in initial state (䊊) and in cleaned state after 40 cycles (왖), ⌬Pmax=350 Pa. Comparison with the separation efficiency of an industrial dust separator A comparison between the efficiency as a function of the particle diameter of a medium tested on the test rig shown in Fig. 2 at the end of the cleaning cycles and that of an industrial collector for wood dust operating at a filtration flow rate of 12 000 m3 h⫺1 was carried out. The medium C studied forms part of the industrial filter whose efficiency was measured on site. The technique used to determine the separation efficiency of the industrial filter was based on employing a fluorescent tracer aerosol generated upstream of the filter (Bémer et al., 1998). The concentrations upstream and downstream of the separator were measured in particle size ranges using an Andersen 1 CFM cascade impactor and allowed determination of its filtration efficiency. The separation efficiency of filter C, cleaned at 350 Pa, after 40 cycles and that of the industrial filter are shown in Fig. 11. Both curves are very close. These results, although obtained in non identical conditions (flow rate, concentration, nature of the particles, etc.), show the extent to which the collection and cleaning cycles must be taken into account to determine correctly the real separation efficiency of the filter medium used in industrial separators. Finally, they show that the tests carried out on new filter medium employed in industrial filtration units, in other words without taking collection and cleaning cycles into account, are meaningless. CONCLUSION This work forms part of a more general occupational risk prevention study encompassing the monitoring of the performance of industrial filtration units. Monitoring the pressure drop as the cycles progress has shown that from a certain number of cycles onwards, the pressure drop of the medium changes in a more or less constant manner. The separation efficiency as a function of the particle diameter Fig. 11. Filtration efficiency of medium C cleaned at 350 Pa after 40 cycles (왖) (measured on the test rig) and of an industrial filter (䊐) (measured on site) as a function of particle size. Clogging and cleaning cycles of filter media measurements taken at different stages of the cycles (new state, clogged then cleaned state) have demonstrated the high filtration performance of the medium. This work has finally highlighted the hypothesis of patchy cleaning for high dust concentration conditions on both filter media tested. Later other filter media with variable clogging properties will be tested. The study will be followed by a parametric experimental study primarily focussed on particle size, filtration velocity and cleaning characteristics (intensity, direction of the nozzle). Modelling of the pattern of pressure drop with the cycles is also currently in progress to further examine the hypothesis of patchy cleaning. Finally the last aim is to carry on with the in situ measurements to improve the test method developped for filter media. REFERENCES Bémer D. Exploitation des propriétés physiques d’un aérosol pour la mesure de la taille des particules et de leur concentration—applications. Thesis, Université de Paris XII, 1990. Bémer D, Regnier R, Calle S. Measurement of the fractional 121 efficiency of an industrial dust separator using a fluorescent aerosol. Journal of Aerosol Science 1998;29(S1):S1077–8. Brown RC. Air filtration—an integrated approach to the theory and applications of fibrous filters. 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