The Danger of Chlorofluorocarbons Troy Walker [email protected] Science and Global Change Scholars Program Bioengineering Question: To what extent are chlorofluorocarbons (CFCs) the greatest danger to global warming and climate change in comparison to carbon dioxide? CFC History CFCs first became marketed in the 1930’s as a “safe” component of coolants, refrigerants, and propellants. After much growth, the harm they produce on the environment was revealed in the late 1970’s through numerous scientific reports. Response to this newfound information came in the form of the Montreal Protocol of 1987 which banned all production and usage of CFCs. Atmospheric Composition Nitrous Oxide 7% Methane 13% 79% Carbon Dioxide CFCs vs CO2 • Effects of CFCs When CFCs enter the atmosphere, UV rays cause them to break apart, exposing the chlorine that is a part of their chemical structure. A single chlorine molecule can then go and bind and break apart thousands of ozone molecules. This process depletes the ozone layer. • • • Future Threat CFCs have an atmospheric lifetime of 20-100 years. Since CFC emissions were at their highest right before the Montreal Protocol of 1987, many particles still pose a threat for another 50 or more years. Additionally, recent loopholes in the Protocol have allowed for new CFCs to be produced. Other 1% • • CO2 makes up 65% of all greenhouse gases (not counting water vapor) while CFCs make up a small fraction of 2% CO2 traps heat in the troposphere while CFCs deplete the ozone layer and trap heat to a much lesser extent CFC production has been halted while CO2 production is continuing to increase CO2 is both a naturally occurring and artificial compound while CFCs are completely artificial CO2 molecules have lifetimes around 30-75 years while CFCs have lifetimes around 20-100 years (this is why they are able to destroy so much ozone) All countries have laws in place against CFCs since the Montreal Protocol was a global treaty What is Being Done CFCs have been completely banned from production through the Montreal Protocol. The ozone layer was going to be allowed to heal naturally over time, but with the recent discovery of loopholes in the Protocol, the expected time of complete healing has been pushed back as lawmakers look to address the loopholes. Potential Danger Conclusion Contrary to what I expected, the collected data and opinions of experts I asked has convinced me that CFCs are less of a threat than most other greenhouse gases. For starters, they are significantly less responsible for global warming because they are as good at trapping heat as other GHGs but are significantly less plentiful. Additionally, through the efforts of international treaties and cooperation, their severe impact on the ozone layer is lessening as more molecule’s lifetimes end. My thanks to Drs. Holtz, Merck, and Eubanks for their assistance throughout my two years in the Scholars Program
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