431 Sustain. Environ. Res., 24(6), 431-441 (2014) The incorporation of the “final sink” concept into a metric for sustainable resource management Ulrich Kral* and Paul H. Brunner Institute for Water Quality, Resource and Waste Management Vienna University of Technology Vienna 1040, Austria Key Words: Sink, substance flow analysis, resource management, copper, PFOS ABSTRACT Several metrics exist to evaluate the environmental performance of products, processes and systems. A deficiency of the present evaluation schemes is that they do not follow materials to “the very end” in the anthroposphere such as mineralization in incinerators for organic substances, and to . final storage in underground structures for inorganic substances. The goal of the article is to propose a new metric for evaluating material use in view of longterm sustainability based on the sink concept. The core idea is to determine the fraction of a substance that is directed towards an appropriate final sink, and to put this fraction into relation to the fraction of the substance that is totally lost in sinks. The authors advocate applying such a metric to entire urban systems and nations. Finally, all non-recyclable wastes and emission have to find final . sinks no matter if they are placed in the anthroposphere or environment. First, the term sink and (appropriate) final sink is defined taking into account that the definition must be substance specific, must include long time frames, and must distinguish (i) between transformation and storage processes as well as (ii) between anthropogenic and geogenic sinks. Hence, an approach for the identification of sinks within substance flow systems is presented as well as an approach to calculate the indicator “Final Sink Ratio”. Next, two urban metabolism case studies are presented to illustrate the concept: The first substance is well managed and nearly completely directed into appropriate final sinks. The second substance is an example of high risk for sink overloading in the near future. In both cases the paths of the selected substances through anthropo. sphere and loads on environment have been modeled by substance flow analysis. The case studies demonstrate: a) how the new metric can be used to support sustainability assessments on multilevel scale, b) that waste management plays a key role for directing hazardous substances into final sinks, and c) that substance flows lacking of appropriate final sinks are difficult . to manage and pose a certain risk for men and environment. INTRODUCTION Human activities such as nourishing, cleaning, residing and working, and transport and communicating require the utilization of matter. Building materials, food, energy carriers and water are exploited and processed in order to satisfy human needs. The use of goods and substances goes hand in hand with waste and emissions. Even though many of them are recycled, there is a certain fraction of non-recyclables that have to be disposed of. Non-recyclables matter addresses a) waste fractions that lack of utilization as second life product such as air-pollution-control (APC) residues *Corresponding author Email: [email protected] from incineration, and b) emission flows such as carbon, heavy metals and persistent organic pollutants (POPs). This poses the fair question: “Where should the non-recyclables finally end up?” In general, they have to enter appropriate final sinks no matter if they . are placed in the anthroposphere or environment. The importance and relevance of final sinks have been highlighted by the German Expert Committee for Environmental Concerns who formulated proposal for an European resource strategy [1]. Therefore, the future need of final sinks will be of increasing concern due to the fact that waste and emission increase with ongoing increase of resource consumption. The experts 432 Kral and Brunner, Sustain. Environ. Res., 24(6), 431-441 (2014) pinpointed the consequences of missing final sinks: the restriction of material use. Presently, carbon is a prominent example that enters the atmosphere as intermediate sink with global consequences of climate change. Even though final sinks are identified, they are not fully utilized due to technological, economic and regulative constraints. Apart from carbon, several other substances are utilized nowadays without the identification and utilization of final sinks. Up to know, a systematic metric for sustainable resource use . with respect to final sinks is missing. The aim of the article is to present a final sink oriented metric for sustainable resource use. The objective and motivation includes: (1) defining and categorizing the terms sink/final sink and make them ready for waste management policy and practice, supporting this with an indicator, and (2) demonstrating the application of the indicator through case studies. . MATERIALS AND METHODS 1. Sinks as Constituent of Substance Flow Systems . to environmental chemistry terminology into “advection”, “diffusion” and “source/sink” [e.g., 6]. The law of mass conservation is applied to each process based on the thermodynamic principles [e.g., 7]: . (1) where s is a specific substance of interest, is the . sum of flows into the process in mass per time, is the sum of flows leaving the process in mass per time, and is the alteration of mass within the stock. Figure 1 presents a generic process which is . defined in space and time, including the flows. Individual processes can be compiled in order to represent entire substance flow systems. An example is given in Fig. 2. As stated by Brunner and Rechberger [3], substance flow systems can be created on multilevel scale (e.g., nations, regions, plants). In common, they include the definition of spatial and temporal system boundaries, the identification of . single processes and their linkages called flows. 1.2. Identification of “sinks” and “final sinks” within substance flow systems The term “sink” and “final sink” is used by several disciplines and definitions are more or less linked with operationalized concepts. For example, environmental scientists use sink terms to model the fate of substances in environmental media [e.g., 8]. Waste policies and representatives in the waste sector highlight specific end-of-pipe technologies such as landfills as sink for hazardous materials [e.g., 9,10] and incinerators as final sinks for specific pollutants [e.g., 11,12]. Recently, Baccini and Brunner [2] defined the term “sink” within the framework of anthropogenic metabolism as the “antonym for the term source, which stands for the origin of an import of a substance into the anthroposphere”. Hence, the authors located sinks (i) within the anthroposphere, (ii) on the border between anthroposphere and environment, and (iii) in the environment. . For this article, the term “substance” is defined according to Brunner and Rechberger [3] as “any (chemical) element or compound composed of uniform units”. We propose a distinction between sinks, final . In this section, we (i) explain a generic, single process for modelling the fate of substances, and the compilation of single processes that represent an entire substance flow system, and (ii) the identification and definition of “sources”, “sinks” and “final sinks” as . specific processes within substance flow systems. 1.1. The metabolism of matter represented on both the process and system level At root, the utilization of matter and the impact of human activities on environment are chemical and physical phenomena. The presence of substances and their characteristics are prerequisite for anthropogenic and natural cycling of elements. Several tools have been developed and put forward to evaluate resource use as wells as emission flows. For example, tools like Life Cycle Assessment and Risk Assessment are used. Assessing the significance and importance of substance flows follows the analytical representation of fluxes in the anthroposphere and the environment. For the anthroposphere, substance flow analysis (SFA) has been proven to be a practical tool for analyzing the material sources, pathways and stocks [e.g., 2-4]. For the environmental spheres, multi media fate modelling and single medium modelling [5] are used to yield predicted environmental concentrations. Those methods track selected substances through predefined systems and improve an understanding regarding the fate of substances. . In common, the basic modelling unit is a metabolic process (Fig. 1). It is bounded by a spatial and temporal scale. Process functions can be categorized according to SFA terminology into “transport”, “transformation”, and “storage” [3], or according . Fig. 1. Plot of a generic SFA process, defined in space and time including as the substance flow in mass per time entering the process, as the substance flow in mass per time leaving the process and as the resulting alteration of mass within the process. The generic metabolic process includes substance flows and stocks. . 433 Kral and Brunner, Sustain. Environ. Res., 24(6), 431-441 (2014) Fig. 2. The generic substance flow system includes processes within the anthroposphere and the environment. Flows are given in [mass time-1] and stocks in [mass]. sinks and appropriate final sinks: A sink is either a process accumulating materials, or it is a transformation of “destroying” substances, e.g., by mineralization. A final sink is a special kind of sink that either holds a substance no longer able to leave the sink by transport, or transforms (e.g., by mineralization or degradation) a substance so that it does not exist in their original form anymore. An appropriate final sink for a substance is a final sink where the concentration, speciation and mobility of a substance pose accepted environmental and human health risks. The categorization of process as “source” or “sink” is derived from the defined substance flow system. The toolbox for flow and stock calculation includes SFA to assess anthropogenic processes, multimedia and single medium fate models to assess environmental processes. The categorization of process as “appropriate final sink” is derived from assessment tools such as risk assessment or even by legal thresholds derived from suitable evaluation schemes. . To classify a process as “source” or “sink” within a substance flow system, we use the difference of input and output flows, namely the net flow Ä in mass per time. A positive net flow characterizes a sink process; a negative net change characterizes a source process. . (2) To identify a “sink” process as “final sink” within a substance flow system, we separate “final sinks” that (a) hold substances. In this case the condition of Ä = must be fulfilled. And (b) transform substances so that they do not exist in their original form any- more. In this case, the efficiency ( ) of the final sink is assessed by . (3) To give some practical examples for sink process, we classify them into intermediate/final and anthropogenic/geogenic sinks (Fig. 3): Intermediate/final sinks. It is a question of time which refers to the retention time of a substance within a process. It depends on the substance characteristics interacting with the process functions (e.g., chemical transformation). Anthropogenic/geogenic sinks. Final sink functions are determined by site-specific physical, chemical and biological processes on the one hand, and substance characteristics on the other hand. Those functions can be found in environmental spheres as well as in anthropogenic endof-pipe technologies. It is a question of physical allocation of individual processes. End-of-pipe technologies such as incinerators, waste water treatment plants are uniquely coined “anthropogenic”. The allocation of environmental media into “anthropogenic” or “geogenic” depends on local circumstances and subjective classification schemes. For example, it can be argued that agricultural or urban soil relates to the anthroposphere because it is intensively used by humans. 2. Final Sinks as Metric for Sustainable Resource Management . To assess long-term strategies for the use of sub- 434 Kral and Brunner, Sustain. Environ. Res., 24(6), 431-441 (2014) stances, Döberl and Brunner [13] stated that the “finalsink-problem should be considered when monitoring sustainability”. In addition, they proposed a simple indicator to assess substance flows on multilevel scale by relating the “amount of substances a region/process directs in final sinks” to the “total amount of substances emitted by a region/process”. We take up this idea and propose a refined version of the indicator. The new indicator (ë) quantifies a mass share of a substance in non-recyclable material flows. It puts the amount of substance flows into appropriate final sinks in relation to the total amount of flows into waste management and environmental sinks. The indicator strives for the regional assessment of non-recyclable material flows. Therefore, it deliberately focuses on a specific region without taking the whole life cycle of a substance into account. Exports from one region into another region are not assessed. These flows cross the spatial system boundary of the selected region and are allocated to the export region. If they need to be taken into account in the assessment, the systems boundaries . must be expanded to include the export region. Where ë is the Final Sink Ratio in [%], is the sum of all non-recyclables flows i on a substance specific level s, namely waste and emissions in mass per time. The term “sink” refers to the definition given in Sec. 1.2 and addresses a positive net flow of a substance in a process. The sinks provided by waste management refer to end-of-pipe technologies. Those in the environment refer to soil, water, and air. The term (appropriate) final sink refers to the definition . given in Sec. 1.2. From a policy point of view, the level of the ë provides long-term strategies that dispose of nonrecyclable wastes and emissions with valuable . guidance (Table 1). . 3. Case Studies In this section, we exemplify the metric for sustainable resource use, supporting this with two case studies. They demonstrate that non-recyclables (wastes, emissions) have to find appropriate final sinks. They highlight the need for vital sinks provided by the waste management sector and pinpoint environmental media as uncontrolled intermediate sinks for . substances. The first substance - copper (Cu) - mainly enters appropriate final sinks which have to be managed to a (4) Anthropogenic (End-of-pipe technologies) - Storage: Storage facilities of waste - Transport: Sewer channels for nutrients - Storage: Sanitary Landfills for persistent substances - Transformation: Thermal Treatment for organic substances Intermediate Final - Storage: Urban Soil for persistent substances - Transportation: Two environmental compartments that exchange heavy metals - Storage: Deep Sea Sediments for persistent substances - Transformation: Ambient air for formaldehyde in smoke from cigarettes Geogenic (Environmental media) Fig. 3. Framework for categorization of sinks and examples. Kral and Brunner, Sustain. Environ. Res., 24(6), 431-441 (2014) 435 Table 1. Interpretation of the indicator results and conceivable options for long-term strategies Indicator (Final Sink Ratio) score ë=1 0<ë<1 Interpretation and options for action All non-recyclable wastes and emission are directed to appropriate final sinks. Strategies and measures have to be developed that increase ë by shifting certain substance flows into appropriate final sinks, and/or transforming non-recyclables flows into recyclable flows that become second life products, and/or increasing the capacity of appropriate final sinks. If these three options are not sufficient to bring ë to a score of “l”, the substance has to be managed in intermediate sinks or final sinks. ë=0 If non-recyclables exist but appropriate final sinks cannot be identified and/or utilized, the substance use has to be restricted and existing stocks have to be managed. certain extent. The second substance - perfluorinated surfactants perfluorooctanesulfonate (PFOS) - is an example of high risk for potential sink overloading. In both cases the paths of the selected substances through anthroposphere and the loads on environment have been modeled by SFA. We structure each case study as follows: (1) Background, (2) Determination of the substance flow system, and (3) Calculation of the . indicator ë. 3.1. Cu in Vienna . (1) Background Cu is a subject of interest because of its relevance from both a resource and an environmental point of view. In this case study we focus on the urban scale exclusively, because Cu is used in infrastructures and . electronics, and Cu is a tracer of urban emissions. Two anthropogenic sinks are of special interest: The surface landfill taking up Cu in bottom-ash and APC residues, and underground storage facilities (e.g., salt mines) taking up selected APC residues from solid and hazardous waste incineration (landfill as sink). . Two environmental sinks are of special interest: (1) Hydrosphere: Cu has to be removed from waste water streams in order to meet quality standards in both effluents from waste water treatment and receiving waters. To do so, waterborne Cu is outward transferred with the sewage sludge that could be applied on land (soil as Cu sink) or thermal treated and disposed of in landfills (landfill as sink). This raises the question regarding the efficiency to route Cu into appropriate final sinks. (2) Urban soil: Cu emissions from goods in use enter urban soil. On the one hand Cu is used as construction material such as roof sheds, cullies and water spouts. Those surfaces are exposed to weathering and corrosion resulting in Cu emissions. On the other hand, brake pad wear covers Cu that enters urban soil and sewer systems via surface runoff. So, urban soil act as Cu sink as long as non-point sources emit Cu and as long as site specific soil characteristics render . the Cu immobile. . (2) Determination of the substance flow system Figures 4 and 5 represent the Cu metabolism of the . City of Vienna on an annual base. The spatial system . boundary is set with the city limits. . (3) Calculation of the indicator ë Figure 6 shows each SFA process from Figs. 4 and 5 categorized as “source” or “sink” process according to Eq. 2. Cu import into the city and releases from industry and commerce act as main Cu sources. In the production and use phase, private households, technical infrastructure and vehicles act as consumer sinks. Waste management provides the “anthropogenic sinks” of landfill and underground storage as well as recycling facilities for out of town sources. Environment provides the “geogenic sinks” of hydrosphere, soil and . atmosphere. We assume that all non-recyclable wastes are routed into appropriate final sinks. In other words, Cu fractions in landfills and underground storage facilities pose an acceptable ecological risk. Environmental media are not classified as “appropriate final sink” because there are no stringent monitoring data and legal thresholds available (for urban soil and river sediments). So, the classification follows a strong . interpretation of the precautionary principle. 3.2. PFOS in Switzerland . (1) Background Perfluorooctane sulphuric acid and its derivatives are collectively named PFOS which are persistent, bioaccumulative and toxic. They become regulated under the POPs Regulation 850/2004 [14] and Regulation 2006/122/EG [15]. According to the British Environment Agency [16] it regulates banning of production, placing on the market and use of some chemicals controls on stockpiles of POP chemicals requirements to reduce, minimise and eliminate releases of the POP content of waste. In 2010, PFOS has been added to the convention with some exemptions for specific applications [17]. Therewith, PFOS “shall be disposed of or recovered, without undue delay in such a way as to ensure that the POP content is destroyed or irreversibly transformed so that the remaining waste and releases do not exhibit the characteristics of POP” [14]. In other words, PFOS flows have to enter appropriate . 436 Kral and Brunner, Sustain. Environ. Res., 24(6), 431-441 (2014) Fig. 4. Substance flow system for copper, representing Vienna on an annual base for the year 2008 [data taken from 21]. Values for copper flows and changes in stocks are given in t yr -1, for copper stocks in tons. The flows are represented as Sankey arrows proportional to the flow rate; figures for stocks are given within the process boxes. . Fig. 5. Substance flow system for copper, representing the waste management system of Vienna on an annual base for the year 2008. Values for Cu flows and changes in stocks are given in t yr-1, for copper stocks in tons. The flows are represented as Sankey arrows proportional to the flow rate; figures for stocks are given within the process boxes. . 437 Source Sink Ä = Inputflow - Output flow [t yr-1] Kral and Brunner, Sustain. Environ. Res., 24(6), 431-441 (2014) Production and Use Waste Management Environment Fig. 6. Sources and sinks of copper, representing Vienna on an annual base for the year 2008. Copper sinks accommodate 21,303 t yr-1 in total of which 65% are exported to external regions, 30% accumulate in the households, technical infrastructure, and vehicles. 5% in landfills and 0.08% accumulate in the environment. . Fig. 7. Substance flow system for PFOS, representing Switzerland on an annual base for the year 2007 [data taken from 18]. Values for PFOS flows and changes in stocks are given in kg yr-1, for PFOS stocks in kg. The flows are represented as Sankey arrows proportional to the flow rate; figures for stocks are given within the process boxes. 438 Kral and Brunner, Sustain. Environ. Res., 24(6), 431-441 (2014) Ä = Inputflow - Output flow [kg yr-1] In the sections that follow, the results are presented and discussed on a case study base. . Non-recyclable copper flows account for 1,130 t yr-1, of which 1,114 t yr-1 enter appropriate final sinks such as landfills and underground storage facilities, About 16 t yr-1 enter environmental compartments. Based on this information, the ë is calculated to be . 99% (1114/1130). The high score of ë indicates that (a) much Cu is part of non-recyclables (waste) entering appropriate final sinks (landfill, underground storage), and (b) less Cu enters intermediate sinks such as environmental . media. For Vienna, we classify Cu in bottom-ash from solid waste incineration as “non-recyclable” because recovering technologies to gain metals are not in place. The mixture of bottom-ash fractions, APC residues, cement and water is sent to landfill. This appropriate final sink has to be managed by a special containment system combined with an operational concept. It requires the pumping of groundwater in order to send it to the waste water treatment plant. Consequently, the status of the landfill as “appropriate final sink” is only valid as long as the containment system is intact and the operation concept takes place. If one of the two fails, the landfill becomes an intermediate sink. In this case, the indicator ë decreases to a level of 1.5%. It can be increased if metal recovery from bottom-ash fractions takes place. Different technologies are under development in order to bring them on the market . [e.g., 19]. Sink RESULTS AND DISCUSSION . 1. Cu in Vienna Source final sinks such as physio-chemical treatment, incineration on land, and use principally as a fuel or other means to generate energy, excluding waste containing PCBs. Consequently, European Union urges member states to implement strategies in view of PFOS management. The representation of the individual state regarding PFOS in stockpiles and waste flows serves (a) as valuable base for the elaboration of risk reduction measures, and (b) as baseline for the assessment . of the efficiency of future measures. . (2) Determination of the substance flow system In Switzerland, the Federal Office for the Environment conducted a national study regarding the determination of stockpiles and waste fractions containing PFOS in 2007 [18]. Figure 7 visualizes the results, namely the annual PFOS balance from a system . perspective. . (3) Calculation of the indicator ë Figure 8 shows each SFA process categorized as “source” or “sink” process according to Eq. 2. The production and use phase as well as the waste water treatment plant acts as main PFOS sources. The landfill releases PFOS too, which is due to disposal of hazardous materials. Waste management provides the “anthropogenic sink” of incineration. Environment provides the “geogenic sinks” of hydrosphere, soil and . atmosphere. Fig. 8. Sources and sinks of PFOS, representing Switzerland on an annual base for the year 2007. PFOS sinks accommodate 2,284 kg yr-1 of which 76% enter incineration, 22% the environment and 1% is exported abroad. . Kral and Brunner, Sustain. Environ. Res., 24(6), 431-441 (2014) Cu in non-recyclable waste fractions is mainly routed to appropriate final sinks such as underground storage facilities or surface landfills. Those types of landfills are “appropriate final sinks” for specific substances depending on site-specific circumstances such as barrier functions and operational concepts. From an ecological risk point of view, both landfill . types have to be actively managed. Underground storage provides long-term encapsulation of hazardous material from biosphere due to natural barriers. The probability of exposure cannot be fully excluded, because the heavy metals are still present. But, the efforts to control the fate of substances are minimized in contrast to landfills on the surface. In the case of underground landfills, the longterm accessibility is a key element of sustainable landfill management. This ensures two folds: (i) Substances can be recovered and utilized or rendered harmless if proper technologies become technical and economical feasible. (ii) Subsurface processes can be investigated and monitored in the case of accidents. . The long-term environmental risks from surface landfills can be assessed in detail through a combination of site-specific risk assessments and monitoring . data in order to design management options [20]. In this case study, all Cu loads into environment reduce the ë, because environmental media are simply classified as intermediate sink. To increase the ë by shifting certain Cu emissions to “appropriate final sinks”, long-term risk assessment studies that yield predicted environmental concentrations and corre. sponding risks are needed. 2. PFOS in Switzerland . Non-recyclable PFOS flows account for 2,254 kg yr-1, of which 1,744 kg yr-1 enter appropriate final sinks such as incineration. About 507 kg yr-1 enter environmental compartments. Based on this information, the ë . is calculated to be 78% (1744/2254). The incinerators are appropriate final sinks for PFOS, because they are mineralized. The efficiency of degradation is äincineration = 99.5% (Eq. 3). The rest of 0.5% (9 kg yr-1) is covered by incineration residues . that enter landfills. European Regulations urges member states to phase-out PFOS and to treat the wastes through, e.g., incineration. This technology is an appropriate final sink for PFOS, because it transforms these hazardous substances into less toxic ones. To assess the efficiency of present and future measures, the Swiss Authorities conducted a national PFOS balance. It visualizes annual PFOS fluxes and stocks. We use those data and calculate the proposed indicator ë from a national system perspective. Results show the ratio ë with 78%. 439 In other words, about three quarters of PFOS fluxes enter final sinks with respect to European Legislation. The rest of 22% enters intermediate sinks such hydrosphere and soil. This poses ecological and health risks because the intermediate sinks are uncontrolled. The final whereabouts of PFOS and the impacts on protec. tive goods are hardly ponderable. The benefit of combining SFA with the ë is two folds: (1) SFA determines the sources, pathways and sink of PFOS in a rigid and transparent way. This enables the identification of risk reduction measures. (2) The proposed indicator ë assesses the actual efficiency of measures that route PFOS containing waste into final sinks. Hence, it serves as monitoring indicator that yields the temporal evaluation of efficiency driven by measures taken in the future. . CONCLUSIONS Human activities in general and waste management in special produce two types of material flows: recyclables and non-recyclables. Recyclables end up in second life products. Non-recyclables such as specific waste fractions and emissions have to be disposed of in appropriate final sinks. This article presents a new metric for sustainable resource use, namely the "Final Sink Ratio" ë. The methodology of calculation is based on SFA. It is a practical tool for analyzing the substance sources, pathways and stocks on multilevel scale from nations, to regions and single plants. The applicability of the indicator has been tested in two case studies, namely for Cu in the city of Vienna and . for PFOS in Switzerland. First, the indicator shows the efficiency of measures to get rid of non-recyclable waste and emissions in a sound way. It reveals the importance of sinks, provided by the waste management sector and those . in the environment. Second, the combination of the indicator with SFA is two-fold beneficial: (i) Results can be used to identify risk reduction measures. (ii) The indicator serves as monitoring score to assess measures taken in . the future. Third, appropriate final sinks in the anthroposphere have to be managed to a certain extent in order to achieve accepted environmental risks. For example, landfills are needed to store inorganic substances. They require technical barriers and operational concepts. The combination of site-specific risk assessment and monitoring is essential for sound and economic management. Incinerators are needed to mineralize organic substances. They require effective and sophisticated waste collection schemes in order to route . organic substances to the plant. Fourth, we propose a resource strategy that incorporates the ë as indicator. It can be used to benchmark nations and individual regions. In the case of carbon, the United Nations Framework Convention on Climate Change aims to manage the carbon content in the 440 Kral and Brunner, Sustain. Environ. Res., 24(6), 431-441 (2014) atmosphere. So, nations periodically update and publish national inventories of anthropogenic carbon emissions and removals by sinks. Even though, there are conventions for other substances like POPs and heavy metals, we propose a systematic and consistent sustainable resource strategy on European and national level that incorporates the final sink viewpoint. Such an accounting scheme considers (i) selected substances such as heavy metals, POPs, nitrogen and compounds, and so on, (ii) all non-recyclable flows which means the incorporation of wastes and emissions, (iii) all available sinks, final sinks and appropriate final sinks, (iv) an indicator to assess the ratio of substance flows that enter “appropriate final sinks” whether they are located in the anthroposphere (end-of-pipe technologies) or in the environment, and (v) regulative measures (e.g., risk reduction, substitution) if a specific substance cannot be routed to an “appropriate final sinks” completely. This article should serve as starting point for a critical discussion on the way to sustainable resource use. . ACKNOWLEDGEMENT 9. 10. 11. 12. 13. This study was supported by the Austrian Science Fund (FWF): I 549-N21. REFERENCES 1. 2. 3. 4. 5. 6. 7. 8. SRU, On the Way to an European Resource Strategy: Orientation Based on a Substance Oriented Environmental Policy. German Advisory Council on the Environment, Berlin, Germany . (2005) (in German). Baccini, P. and P.H. Brunner, Metabolism of the Anthroposphere: Analysis, Evaluation, Design. . 2nd Ed., MIT Press, Cambridge, MA (2012). Brunner, P.H. and H. Rechberger, Practical Handbook of Material Flow Analysis. CRC Press, . Boca Raton, FL (2004). Månsson, N., B. Bergbäck, D. Hjortenkrans, A. Jamtrot and L. Sörme, Utility of substance stock and flow studies. J. Ind. Ecol., 13(5), 674-686 . (2009). Hertwich, E., O. Jolliet, D. Pennington, M.Z. Hauschild, C. Schulze, W. Krewitt and M.A.J. Huijbregts, Fate and exposure assessment in the life-cycle impact assessment of toxic chemicals. In: H.A. Udo de Haes, S. Kotaji, A. Schuurmans and S. Edwards (Eds.). Life-Cycle Impact Assessment: Striving Towards Best Practice. . SETAC Press, Pensacola, FL (2002). Maniak, U., Hydrology and Water Resource Management - Introduction for Engineers. Springer, Berlin, Germany (2010) (in German). . Lucas, K., Thermodynamics. 7th Ed., Springer, . Berlin, Germany (2008) (in German). USEPA, Total Risk Integrated Methodology. 14. 15. 16. 17. 18. 19. TRIM.FaTE Technical Support Document. Volume I: Description of Module. US Environmental Protection Agency, Washington, DC . (2002). Scharff, H., Landfills as sinks for (hazardous) substances. Waste Manage. Res., 30(12), 1234. 1242 (2012). UBA, Waste Management - Treatment Processes. Federal Environment Agency, Dessau, Germany. www.umweltbundesamt.de/themen/abfallressourcen/entsorgung/deponierung-lagerung . (2011) (in German). Morf, L.S. and P.H. Brunner, Municipal Solid Waste Incineration as Sink for Substances Substance Flow Analysis for Hg in an Incinerator at Würzburg. Vienna University of Technology, Vienna, Austria. http://www.zvaws.de/infos/hg_ . bilanz2005.pdf (2005) (in German). UBA, Role of Waste Incineration in Germany. Federal Environment Agency, Dessau, Germany. http://www.umweltdaten.de/publikationen/fpdf-l/ . 3649.pdf (2008) (in German). Döberl, G. and P.H. Brunner, Substances and their (final) sinks - A new indicator for monitoring sustainability. Indicators for Evaluating Sustainable Development - The Ecological Dimension. Berlin, Germany, Nov. 1-2 (2004). . EU, Regulation (EC) No 850/2004 of the European Parliament and of the Council of 29 April 2004 on Persistent Organic Pollutants and Amending Directive 79/117/EEC. European . Union, Brussels, Belgium (2004). EU, Directive 2006/122/EC of the European Parliament and of the Council of 12 December 2006 Amending for the 30th Time Council Directive 76/769/EEC on the Approximation of the Laws, Regulations and Administrative Provisions of the Member States Relating to Restrictions on the Marketing and Use of Certain Dangerous Substances and Preparations (Perfluorooctane Sulfonates). European Union, . Brussels, Belgium (2006). BEA, EU POPs Regulation Guidance: Guidance on Regulation (EC) 850/2004 on Persistent Organic Pollutants (as amended). British Environment . Agency, Bristol, UK (2012). EC, COMMISSION REGULATION (EU) No 756/2010 of 24 August 2010 Amending Regulation (EC) No 850/2004 of the European Parliament and of the Council on Persistent Organic Pollutants as Regards Annexes IV and V. European Union, . Brussels, Belgium (2010). Buser, A. and L.S. Morf, Substance Flow Analysis for Switzerland. Federal Office for the . Environment, Bern, Switzerland (2009). Morf, L.S., R. Gloor, O. Haag, M. Haupt, S. Skutan, F. Di Lorenzo and D. Böni, Precious metals and rare earth elements in municipal solid waste - Sources and fate in a Swiss incineration Kral and Brunner, Sustain. Environ. Res., 24(6), 431-441 (2014) . plant. Waste Manage., 33(3), 634-644 (2013). 20. Laner, D., Understanding and Evaluating Longterm Environmental Risks from Landfills. Ph.D. Dissertation, Institute for Water Quality, Resource and Waste Management, Vienna University of . Technology, Vienna, Austria (2011). 21. Kral, U., C.Y. Lin, K. Kellner, H.W. Ma and P.H. Brunner, The copper balance of cities: Exploratory insights into a European and an Asian city. J. Ind. 441 Ecol., 18(3), 432-444 (2014). Discussions of this paper may appear in the discussion section of a future issue. All discussions should be submitted to the Editor-in-Chief within six months of publication. . Manuscript Received: November 8, 2013 Revision Received: March 6, 2014 and Accepted: March 13, 2014
© Copyright 2026 Paperzz