The architecture of the European-Mediterranean lithosphere: A synthesis of the Re-Os evidence Jose M. Gonzalez-Jimenez, Carlos Villaseca, William L. Griffin, Elena Belousova, Zoltan Konc , Eumenio Ancochea, Y. O'Reillv , Norman J. Pearson, Carlos J. Garrido, and Fernando Gervilla Suzanne accessory metasomatic minerals (amphibole, ABSTRACT (TRD) of sulfides in peridotite xenoliths from the subcon apatite, calcite). Interstitial glass commonly sur tinental mantle beneath central Spain (the Calatrava volcanic field) reveal that episodes of rounds these metasomatic minerals and contains Rhenium-depletion model ages mantle magmatism and/or metasomatism in the Iberia microplate were linked to crustal relics of them as well as incompletely reacted growth events, mainly during supercontinent assembly and/or breakup at ca. 1.8, 1.1, 0.9, primary silicates and newly fonned clinopyrox 0.6, and 0.3 Ga. A synthesis of available in situ and whole-rock Os-isotope data on mantle ene, olivine, and spinel (Villaseca et al., 2010). derived peridotites shows that this type of mantle (maximum TRD of ca. 1.8 Ga) is widespread in the subcontinental mantle of Europe and Africa outboard from the Betics-Maghrebides Appenines front. In contrast, the mantle enclosed within the Alpine domain records TRD as old Sulfides (1-500 J.Ull) were identified in pol ished thin sections; they are enclosed in olivine and pyroxenes, rarely at the triple junctions as 2.6 Ga, revealing a previously unrecognized Archean domain or domains in the central and between the main silicates, and more commonly western Mediterranean. Our observations indicate that ancient fragments of subcontinental in the interstitial glass. Major-element analysis lithospheric mantle have played an important role in the development of the present architec by electron microprobe shows that all the sul fides are Fe-rich monosulfide solid solution, ture of the Mediterranean lithosphere. with Fe >38.9 wt% and Ni contents >9.93 wt%. western Europe and Africa allows us to examine There is no difference in comIX'sition between Until now, the timing of formation and the the evolution and architecture of the European included and interstitial sulfides. evolution of the Iberian microplate has been Mediterranean mantle, revealing a heteroge constrained mainly from U-Pb ages of mag neous mantle structure across the region and matic zircons, Hf model ages of inherited zir indicating the presence of a previously unrecog cons, and whole-rock Nd model ages of crustal nized Archean domain. INTRODUCTION igneous and metamorphic rocks. However, there RESULTS AND INTERPRETATION In Situ Re-Os Model Ages on Mantle Sulfides has been little robust information on the age of GEOLOGICAL SETTING AND SAMPLE the lithospheric mantle beneath this continental BACKGROUND The Os-isotope comIX'sitions of over 800 individual sulfides �SO J.Illl were rreasured in crust; it is the missing key for a full understand The Calatrava volcanic field is an intracon ing of the geological framework of the Iberian tinental zone within the Central Iberian Zone of Excellence for Core to Crust Fluid Systems! microplate. This gap has now been filled by of central Spain, where upper crust only from GEMOC (Macquarie University, Australia) fol determining the Re-Os systematics of sulfides Neoproterozoic time has been preserved. The lowing the procedures described by Pearson in peridotite xenoliths that represent samples of volcanic field comprises -200 small monoge et al. (2002). In our data set, only grains with this mantle. Because Re and Os preferentially netic volcanic centers. An initial minor ultra 187Rej1880s < 1.2 were selected, thus ensuring situ using LA-MC-ICPMS at the ARC Centre concentrate in mantle sulfides, unlike those IX'tassic event at ca. 8.7-6.4 Ma was followed an accurate correction of the isobaric overlap of lithophile elements commonly used in other by the eruption of alkali basalts, basanites, and 187Re on 1880s. In our analysis we disregarded isotopic systems in the earth sciences, their iso olivine nephelinites and melilitites from 3.7 to grains with superchondritic 1870s/1880S (>0.1281; topes are uniquely useful in tracking events of ca. 0.7 Ma that entrained abundant deep-seated Walker et al., 2(02) unsupported by their low mantle melt depletion and refertilization. xenoliths, dominantly spinel lherzolites of the Re/Os, which yielded geologically unreason In this work we use in situ laser ablation Cr-diopside suite (after Wilshire and Shervais, able future Re-Os model ages. Additionally, to plasma 1975), and wehrlites and pblogopite-rich clino ensure mass spectrometry (LA-MC-ICPMS) to study pyroxenites of the Al-augite series (Ancochea, we used grains only with propagated 2 S.E. ana the Re-Os isotopic comIX'sition of sulfides 2(04). These xenoliths record different types lytical uncertainties on 1870sJ1880s of <.0.2 Ga in xenoliths from the Calatrava volcanic field of metasomatisrn including carbonatitic, silica (fable DRI in the GSA Data Repository'). multicollector-inductively coupled in central Spain. The Calatrava volcanic field undersaturated alkaline, and subduction-related contains a suite of peridotite xenoliths from styles (Villaseca et al., 2010; Bianchini et al., the lithospheric mantle underlying the crust of 2010; 0' Reilly and Griffin, 2012). the Iberian microplate. Our results suggest that The xenoliths studied here come from the El the mantle and crust constituting the Iberian Aprisco (38°S0'OS"N, 3°S0'OO''W) olivine meli microplate have coexisted since at least Paleo lite maar (Villaseca et al., 2010). They are nine zoic-Proterozoic time. The comparison of our coarse-grained lherzolites and two wehrlites that data with Os-isotopic data from mantle-derived equilibrated in the spinel facies (1.S-0.7 GPa) materials from other localities in central and at temperatures of 1120--940 °C and contain high-precision model-age constraints, The 68 sulfides from El Aprisco that meet these criteria have subchondritic 1870sJ1880s (0.1147-0.1265) with 187Re/1880s varying from subchondritic «0.358) to suprachondritic (0.432-0.572) (Fig. DR l in the Data Repository; Table DRl). Only those sulfides with 187Rej1880s < 0.07-0.08 may preserve undisturbed isotopic signatures representative of mantle melting andlor refertilization events (Griffin et al., 2004). Only 12 of our sulfides display 187ReJ1880s < 0.08 (italic font in Table DRl). A screening of the other 56 sulfides with 187Re/1880s > 0.08 in Re-Os isotope plots reveals that many of the sul fide grains show the effects of recent Re addi tion, probably associated with the magmatic activity that brought the xenoliths to the surface at ca. 2 Ma. As little or no 1870S ingrowth has occurred since this recent Re enrichment, the TRD of these sulfides (calculated assuming Re = o ppm) still provides useful minimum estimates of the timing of mantle events. For grains with 187ReJ1880s > 0.08 but uncorrelated Re-Os, we have constructed two cumulative plots of Re depletion model ages: one uses T RD ages of sul fides with "undisturbed" 1870sj1880s (grains with 187ReJ1880s < 0.08 as well as with 187ReJ1880s > Figure 1. Cumulative probability plot of Re-de pletion model ages (T ) RD for El Aprisco (Spain) mantle sulfides of the Calatrava volcanic field (black solid line) com pared with age intervals corresponding to events recorded in crust of cen tral Iberia (see references in the text) and major events of supercontinent growth (P-Pangea, G Gondwana, R-Rodinia, C-Columbia; see refer ences in the Data Repos itory [see footnote 1D. Events of amalgamation or breakup of supercon tinents recorded in the Iberian lithosphere are �D Model age (Ga) shown as gray or white dotted columns, respectively. A cumulative-probability curve of T model ages for mantle RD derived materials from both sides of the Mediterranean realm in central and western Europe and North Africa (gray dashed line) has also been included for comparison (see details in text and in the Data Repository for localities and references). Note that only positive T are RD plotted, and in the case of whole-rock (or mineral-concentrate) results, only data compared against AI203 or other melt depletion indicators (e.g., Rudnick and Walker, 2009) were con sidered. To ensure comparison among all localities, T were calculated with reference to RD Enstatite Chondrite Reservoir (Walker et al., 2002) and an uncertainty of 0.1 Ga was assumed for all single data points. 0.08 lying on horizontal trends in Re-Os plots); the other uses only those grains with 187Rej1880s > 0.08 and uncorrelated Re-Os (Table DR1). Zone (Villaseca et al., 1998) and Hf model ages 1.0--1.2 Ga inherited zircon in Hercynian gran The two plots produce identical distributions of (1.6--1.8 Ga) of inherited zircons from Hercyn ulites (Villaseca et al., 2011a), Hf model ages age peaks. Therefore the TRD obtained from all ian granulites (which have lower Paleozoic to of 0.9-1.2 Ga in magmatic zircons, and the Nd the 68 sulfide grains selected here can be used to Neoproterozoic meta-igneous and metasedi whole-rock model ages of 1.0--1.3 Ga in the unravel the evolution of the lithospheric mantle mentary protoliths) sampled in rnigrnatite ter Hercynian gabbros (297-306 Ma) that intruded beneath Iberia. ranes and lower crustal xenoliths from the Cen the Central Iberian Zone (Fig. 1; Orejana et al., tral Iberian Zone (Villaseca et al., 2011a). The 2009; Villasecaet al., 2011b). Origin and Evolution of the Iberian corresJX)ndence of mantle and crustal ages sup The alkaline (silicate to caroonatite) meta Lithosphere: A 1.8 b.y. History of Mantle JXlfts the suggestion that primary mantle differ somatisrn observed in some xenoliths of the Crust Interactions and Supercontinent entiation and crustal growth in the Iberian litho Calatrava volcanic field in the Tertiary may be Assemblies sphere took place ca. 1.6-2.0 Ga. Reworking of resJX)nsible for the negative model ages of sul Figure 1 shows a strong coincidence between this ancient lithosphere in the Neoproterozoic fides with highly radiogenic 1870s/1880S unsup the five peaks (at 1.8, 1.1, 0.9, 0.6, and 0.3 Ga) and Paleozoic may explain the four younger JXlfted by low Re/Os ratios; these were excluded in the distribution of TRn model ages of the El peaks in the sulfide T RD model ages. Thus, the from this analysis. Aprisco sulfides and the timing of well-con mantle event at ca. 0.6 Ga correlates with the Figure 1 shows that the formation of the strained magmatic events recorded in the over 0.48-0.58 Ga mafic-to-silicic magmatism in the Iberian lithosphere at ca. 1.6--2.0 Ga coincides lying crust of Iberia. Most of the ages are older Central Iberian Zone associated with the Cado with the first-order event of mantle-crust differ than the eXJX)sed crust in the irrnnediate area, mian orogeny (Pereira et al., 2010; Bandres et entiation that occurred during the assembly of implying the JX)ssible existence of older crust al., 2004). The involvement of the mantle is the supercontinent Columbia at 1.8-1.5 Ga. The at depth. Interestingly, the three main peaks in evidenced by juvenile Hf isotopic signatures 1.3-0.9 Ga timing of magmatic events recorded the El Aprisco sulfides at 1.8, 0.6 and 0.3 are (EBft up for ooth crustal and mantle materials in Iberia consistent with TRn ages obtained for mantle derived materials of comparable mantle suites to +9.7) of inherited zircons (U-Pb age 0.5-0.7 Ga) in the Hercynian granulites. Exten coincide with the amalgamation of Roclinia at sional decompression associated with delamina ca. 1.25 Ga and its breakup at ca. 0.75 Ga. The on both sides of the Mediterranean reahn (cen tion of lower-crustal rocks may have promoted peak in T tral and western Europe and North Africa). The upwelling and melting of the mantle following ning of continental collisions to form Gond RD at 0.6 Ga correlates with the begin TRD smoother curve for the synthesized European the Hercynian collision (Orejana et al., 2009). wana (ca. 0.65 Ga), whereas the Mrican mantle data largely reflects the num This would explain the correlation between the at 0.3 Ga may be correlated with JX)st-tectonic ber of intermediate model ages produced by magmatic event at 0.3 Ga recorded in mantle stages and the initiation of the breakup of Pan the mixing of sulfide JX)pulations in individual sulfides and the silicic and mafic magrnatism of gea recorded in the Central Iberian Zone at whole-rock samples (Fig. 1). ooth crustal and mantle origin recognized in the ca. 0.26 Ga (Orejana et al., 2008). The oldest Paleoproterowic event (1.8 Ga) seen in the TRn age peak Central Iberian Zone at 0.28-0.32 Ga (Feman model ages of the El Aprisco dez-Suarez et al., 2(00). Melt production in the Implications for the Architecture of the sulfides (Fig. 1) correlates with whole-rock Nd mantle beneath Iberia at 0.9-1.3 Ga is reflected European-Mediterranean Lithosphere model ages (1.7-2.0 Ga) of Neoproterozoic in sediments (ca. 560 Ma) of the Central Iberian fides, positive TRD model ages of 0.9-1.1 Ga in mantle sul tHft signatures (up to +12.8) of Figure 2 shows that mantle-derived rocks on ooth sides of the Mediterranean realm (central n::11 ... Cenozoic volcanic field , Peridotite massif .., East-dipping Subduction _A... West-dipping Subducton � Original Archean SCLM ? _ these continental riboons and the subcontinental Archean-Paleoproterozoic mantle widespread through the Betics-Magbrebides-Appenines front may be the fragmented reIIlllants of an Archean microcontinent within the inner Medi terranean area. The repetition of model age peaks at ca. 0.9-1.2, ca. 0.4-0.7, and ca. 0.3 Ga in the mantle both within and outside the cen tral-western Mediterranean reahn (Fig. 2) sug gests that this microplate was strongly modified and fragmented (but survived) during supercon tinent assembly-disruption cycles since Paleo proterozoic times. In the context of convergence of Africa and Europe during the Tertiary, dismembered blocks of this ancient microplate could have spread, colliding with passive margins (Iberia, Magrhebide, Adria), thus contributing to the development of subduction-related volcanic arcs within the inner Mediterranean (Faccenna et al., 2004; Booth-Rea et al., 2007; Garrido et al., 2011; Canninati et al., 2012). We suggest that these major tectonic events have stripped Figure 2. Cumulative-probability plots for Re-Os model ages of sulfides, platinum-group minerals, mineral concentrates, and whole-rock samples of xenoliths from Cenozoic vol canic fields and massifs in the central-western Mediterranean region (age peaks are in Ga; whole-rock ages are minimum ages). Gray fields refer to inferred original Archean subconti nental lithospheric mantle (details in text). SCLM-subcontinental lithospheric mantle. Note that in all cases, only positive Re-depletion model ages (TRO) are shown, except for Beni Boussera (Morocco), for which the Re-Os model age presented is TMA• Whole-rock and min eral-separate Os data were screened following the same criteria as in Figure 1. References for each locality are given in the Data Repository (see footnote 1). off most of the old continental crust, leav ing behind residues of ancient subcontinental mantle. This mantle, buoyant relative to the asthenosphere, would have continued to ride over the small-scale convective cells detected by seismic tomography at depths >200 km (O'Reilly et al., 2009; Faccenna and Becker, 2010), then become part of the oceanic basin and serve as the basement for the accumulation of oceanic basalts and sediments. An analo gous process has been described in detail from and western Europe and North Mrica) yield oldest whole-rock model age (TMA) of 2.3 Ga the Internal Ugurides, where a typical Meso TRn � 1.8 Ga, whereas those from the obtained by Pearson and Nowell (2004) for zoic inner Mediterranean region show ooth younger pyroxenites of the Beni Boussera Massif in overlies the Archean mantle peridotites (Ram JXlne et al., 2(05). It is important to note that maximum oceanic volcanic-sedimentary section and older (up to 2.6 Ga) ages. Many sulfides northern Morocco and the 2.4 Ga peak in pri in xenoliths from the mantle beneath western mary magmatic sulfides from peridotites of the some JXlrtions of the Archean subcontinental Europe (Calatrava, Languedoc, and Massif Cen internal Ligurides (Italy) (Alard et al., 2005). lithospheric mantle within the inner Mediterra tral) show a common oldest peak at 1.8 Ga. This A slightly older peak at 2.6 Ga has recently nean were refertilized (Mg# = 89-90 of olivine peak is also recognized in whole-rock samples been relhlfted by Konc et al. (2012) in sulfides in peridotite) by the passage of subduction from the Pyrenees (France) and Azrou (North from mantle xenoliths from the Tallante volca related fluids in the Cenozoic. However, these Mrica) but is slightly older than the oldest peaks nic field in southern Spain. These ages clearly fluids were not able to erase the old Archean at <1.4-1.3 Ga found in whole-rock samples identify an older lithospheric mantle fonned Re-Os signatures preserved in some sulfides from central Europe (Bohemian and Rhenish near the Archean-Paleoproterozoic ooundary at (Marchesi et al., 2010). Massifs). Nevertheless, although these whole ca. 2.2-2.6 Ga, sitting within the more recent rock ages were screened against indices of melt Betics-Magbrebides-Appenines front (Fig. 2) depletion in the rock (e.g., Al103; Rudnick and generated during the Alpine-Betic orogeny. ACKNOWLEDGMENTS We acknowledge William Collins, two anonymous reviewers, and Lukas: Ackennan for comments that Walker, 2009), they must been seen as a guide Seismic, gravity, and heat-flow data suggest and can only be regarded as minimum values that the structure to 70 km beneath the Medi as they may integrate multiple generations of terranean Sea consists of ribbons of continen Centre of Excellence for Core to Crust Fluid Systems, sulfides (e.g., Alard et al., 2002; Griffin et al., tal lithosphere (Valencia throu gh the Balearic Villaseca Gonzalez' grant from Fundaci6n Caja Ma 2004). All these data are consistent with the promontory, the Sardinia-Corsica block, and existence of a common Paleoproterozoic man the Hyblean Plateau beneath Sicily) separated tle on ooth sides of the Mediterranean realm, by areas of thinned subcontinental lithosphere formed ca. 1.8 Ga as recorded in the other parts or new oceanic crust (the Alboran, Uguro significantly improved the first version of this manu script. Financial support was provided by tre ARC drid convocatoria 2010, the Spanish "Ministerio de Ciencia e Innovaci6n" grant CGL201O-14848, tre Junta de Andalucia research grants RNM-131 and 2009RNM4495, and the International Lithosphere Program (CC4-:MEDYNA). The analytical data were Provenr;al, Vavilov, and Marsili Tyrrenian sea obtained In contrast, Os-bearing minerals from xeno basins) (e.g., Gueguen et al., 1997; Booth-Rea Systemic Infrastructure Grants, ARC LIEF, NCRIS, liths and peridotite massifs from the inner Med et al., 2007). In the riboon beneath Sicily, xeno iterranean region (Sicilian Hyblean Plateau, lith data suggest that thinned Archean continen Kraubath ultramafic massif) show a common tal crust overlies subcontinental mantle of the .au) and contribution 860 from the GEMOC National same age (Sapienza et al., 2007). Thus all of Key Centre (www.gemoc.mq.edu.au). of the European basement. oldest T RD peak at ca. 2.3 Ga, identical to the using instrumentation funded by DEST industry partners, and Macquarie University. 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