有机化学
研究论文
DOI: 10.6023/cjoc201608010 Chinese Journal of Organic Chemistry ARTICLE 辅助材料(Supporting Information)
表乳糖的合成研究
王家尧
姜
锐
梁晓梅
(中国农业大学理学院
金淑惠*
王道全
张建军*
北京 100193)
提供了表乳糖合成相关化合物的氢谱图、碳谱图或高分辨图. Spectrum section
1
2
3
4
5
6
7
8
9
10
11
12
10
11
http://sioc-journal.cn/ 1
H NMR spectrum of compound 5b
13
1
S3
C NMR spectrum of compound 5b
S3
H NMR spectrum of compound 5c
S4
13
1
Page No.
C NMR spectrum of compound 5c
S4
H NMR spectrum of compound 8b
S5
13
1
C NMR spectrum of compound 8b
S5
H NMR spectrum of compound 8c
S6
13
1
1
1
1
1
C NMR spectrum of compound 8c
S6
H NMR spectrum of compound 10
S7
H NMR spectrum of compound 11
S7
H NMR spectrum of compound 12
S8
H NMR spectrum of compound 13
S8
H NMR spectrum of compound 14
S9
13
C NMR spectrum of compound 14
© 2017 Chinese Chemical Society & SIOC, CAS S9
S1
Chinese Journal of Organic Chemistry
ARTICLE
12
13
14
15
1
13
1
18
19
20
21
22
23
1
S10
H NMR spectrum of compound 16
S11
C NMR spectrum of compound 16
S11
HRMS spectrum of compound 16
S12
H NMR spectrum of compound 17
S13
13
1
S10
C NMR spectrum of compound 15
13
16
17
H NMR spectrum of compound 15
C NMR spectrum of compound 17
S13
H NMR spectrum of compound 18
S14
13
C NMR spectrum of compound 18
1
H NMR spectrum of compound 1
13
S14
S15
C NMR spectrum of compound 1
S15
HRMS spectrum of compound 1
S16
http://sioc-journal.cn/ © 2017 Chinese Chemical Society & SIOC, CAS S2
Chinese Journal of Organic Chemistry
ARTICLE
1
H NMR spectrum of compound 5b
13
C NMR spectrum of compound 5b
http://sioc-journal.cn/
© 2017 Chinese Chemical Society & SIOC, CAS S3
Chinese Journal of Organic Chemistry
ARTICLE
1
H NMR spectrum of compound 5c
13
C NMR spectrum of compound 5c
http://sioc-journal.cn/
© 2017 Chinese Chemical Society & SIOC, CAS S4
Chinese Journal of Organic Chemistry
ARTICLE
1
H NMR spectrum of compound 8b
13
C NMR spectrum of compound 8b
http://sioc-journal.cn/
© 2017 Chinese Chemical Society & SIOC, CAS S5
Chinese Journal of Organic Chemistry
ARTICLE
1
H NMR spectrum of compound 8c
13
C NMR spectrum of compound 8c
http://sioc-journal.cn/
© 2017 Chinese Chemical Society & SIOC, CAS S6
Chinese Journal of Organic Chemistry
ARTICLE
1
1
H NMR spectrum of compound 10
H NMR spectrum of compound 11
http://sioc-journal.cn/
© 2017 Chinese Chemical Society & SIOC, CAS S7
Chinese Journal of Organic Chemistry
ARTICLE
1
1
H NMR spectrum of compound 12
H NMR spectrum of compound 13
http://sioc-journal.cn/
© 2017 Chinese Chemical Society & SIOC, CAS S8
Chinese Journal of Organic Chemistry
ARTICLE
1
H NMR spectrum of compound 14
13
C NMR spectrum of compound 14
http://sioc-journal.cn/
© 2017 Chinese Chemical Society & SIOC, CAS S9
Chinese Journal of Organic Chemistry
ARTICLE
1
H NMR spectrum of compound 15
13
C NMR spectrum of compound 15
http://sioc-journal.cn/
© 2017 Chinese Chemical Society & SIOC, CAS S10
Chinese Journal of Organic Chemistry
ARTICLE
1
H NMR spectrum of compound 16
13
C NMR spectrum of compound 16
http://sioc-journal.cn/
© 2017 Chinese Chemical Society & SIOC, CAS S11
Chinese Journal of Organic Chemistry
ARTICLE
HRMS spectrum of compound 16
HIGH RESLUTION MASS SPECTROMETRY REPORT Sample No. Formula (M) Ion Formula Measured Calc m/z Diff (ppm)
m/z WJY201512
02P C52 H50 O16
http://sioc-journal.cn/
C52 H50 Na O16
953.2995
953.2991
© 2017 Chinese Chemical Society & SIOC, CAS ‐0.37
S12
Chinese Journal of Organic Chemistry
ARTICLE
1
H NMR spectrum of compound 17
13
C NMR spectrum of compound 17
http://sioc-journal.cn/ © 2017 Chinese Chemical Society & SIOC, CAS S13
Chinese Journal of Organic Chemistry
ARTICLE
1
H NMR spectrum of compound 18
13
C NMR spectrum of compound 18
http://sioc-journal.cn/ © 2017 Chinese Chemical Society & SIOC, CAS S14
Chinese Journal of Organic Chemistry
ARTICLE
1
H NMR spectrum of compound 1
13
C NMR spectrum of compound 1
http://sioc-journal.cn/ © 2017 Chinese Chemical Society & SIOC, CAS S15
Chinese Journal of Organic Chemistry
ARTICLE
HRMS spectrum of compound 1
HIGH RESLUTION MASS SPECTROMETRY REPORT Sample No. Formula (M) Ion Formula Measured Calc m/z Diff (ppm) m/z 1 C12 H22 O11
C12 H22 Na O11
365.1058
365.1054
‐1.06
http://sioc-journal.cn/ © 2017 Chinese Chemical Society & SIOC, CAS S16