Nylon Under the Hood: A History of Innovation By Eric Carlson, DuPont Automotive and Ken Nelson, DuPont Automotive If the automotive industry had its own periodic table, nylon 66 would be a key element. Thanks to its versatility, moldability and resistance to high temperatures and harsh chemicals, PA 66 nylon is the most used engineering thermoplastic in the automotive industry today. In the engine compartment, PA 66 nylon’s performance properties make it a rising star. Since its discovery in 1939, nylon use in North America has grown steadily as an automotive material. In 1960, the average car used a total of 0.4 lb of nylon, most of which avoided the harsh underhood environment. By 1995, the average car used 8.8 lb of nylon in underhood applications alone. With annual vehicle production at nearly 12 million cars, that’s more than 100 million pounds of nylon under the hood of 1995 model-year cars. This rapid growth can be attributed to government regulations requiring increases in fuel economy, the need to reduce component costs and minimize overall vehicle weight. These changes challenged creative engineers and designers to toss convention aside and expand the envelope of nylon properties to new limits. For them it’s been an exciting journey. In the Beginning Wallace Hume Carothers, director of the DuPont Experimental Station in Wilmington, Delaware, discovered nylon, a polymer comprised of synthetic fiber-forming polymeric amides with a protein-like chemical structure derivable from coal, air and water. It is characterized by extreme toughness, strength and the unique ability to be formed into fibers and various shapes. Nylon debuted at the World’s Fair in 1939, and was manufactured in a molding resin for industrial use shortly thereafter. Experiments using nylon in selflubricating bearings for the automotive industry began immediately. Though development efforts were interrupted during World War II, several quick and successful adoptions immediately following the war deepened faith in the material’s abilities to perform in tough automotive applications. The Transition Most automotive applications of nylon from the late 1940s to the early 1960s focused on less critical components such as valve stems, wiring clips, gears, bearings, bushings, switch housings and windshield wiper systems. Because automotive engineers were not very familiar with plastics, they used metals wherever possible. When nylon was used, it was sporadic, in a model here and a model there. It was seldom used across all models, car lines and OEMs. The design freedom inherent in PA 66 nylon—already accepted for retaining strength at high temperatures and compatibility with engine fluids—allowed the changes to be made while reducing overall costs. By the 1980s, automotive engineers were beginning to trust nylon in key applications. Nylon dominated fuel efficiency and emission control technology. Use of nylon not only reduced weight and cost, it also enhanced the performance of emission control devices. Emission control Under the hood, high temperatures and valve seats and stems pressures, along with the need for could be integrated with chemical resistance, made adoption of the mold, eliminating nylon in these areas move much more secondary finish operaslowly. The introduction of high tions. Designers also performance mineral and glassfound benefits in being Award-winning manifold used by Dodge and reinforced versions of the PA 66 Plymouth Neon small cars uses Zytel® nylon. able to incorporate fittings nylon, changed everything. Experiand tubings for simplified mental and early test programs in “snap-fit” assembly. With that high level of trust applications for radiators and fuel systems in the 1960s established, engineers began to use nylon more consisdemonstrated nylon’s capability for resisting heat and tently across all models, car lines and OEMs. chemicals, paving the way for serious consideration in underhood applications. DuPont introduced glass as a reinforcement to PA 66 nylon in 1968 to improve its already impressive list of properties. This performance enhancement led to underhood innovations such as engine-cooling flex fans; transmission thrust washers and spring guides; and air cleaner support brackets. Even valve stem oil deflectors, which were required to resist oil and temperatures as high as 320°F, were converted to nylon. Engineers further tapped PA 66 nylon for mechanical, pneumatic and electrical control systems, many of which had to withstand temperatures reaching 300°F. Key applications included throttle control cable end fittings, lever retainers and “umbrellas;” downshift cables and hood release cable jackets. In the 1970s, government regulations required automakers to install pollution-control devices, quickly driving up demand for nylon 66. Engineers and designers turned to these proven materials for critical air and fuel system pollution control components, many of which would have been extremely costly and too complex to manufacture in metal. Key applications included charcoal canister housings and tubings; air injector reactor seats, guides, valves and tubes; and vacuum control, diverter, thermal delay and positive crankshaft ventilation (PCV) valves. The government also mandated increases in fuel efficiency, which further challenged automotive engineers to reduce the size and weight of vehicles, their engine compartments and individual components. 2 Key developments also were pioneered in Europe, where smaller cars, higher petroleum costs and emission control mandates drove innovation. Commercial applications of plastics in air intake manifolds, brake fluid and power steering fluid reservoirs, and radiator end tanks and gas tank caps, date back to the early 1970s for major European automakers like BMW and Peugeot. Manifolds Take Shape Noted for their ability to reduce weight and cost, while boosting engine performance, thermoplastic use in manifolds gained footholds in Europe as early as the 1970s and spread quickly in the late 1980s. In the 1990s, General Motors, AC Rochester and DuPont Automotive brought the first high volume commercial air intake manifold to the U.S. market. An exhaust gas recirculation (EGR) interface adapter, gaskets, PCV valve and vacuum source are all incorporated in the design, and the entire piece was molded with DuPont™ Zytel® PA 66 resin. The innovative EGR valve interface joint, which reduced EGR temperatures to levels manageable by nylon air intake manifolds, became something of a landmark introduction for DuPont. It featured an inverted bell system that isolated the EGR valve, protecting the manifold from direct contact with the hot exhaust gas until it mixes with cooler combustion air. Without this innovation, plastic air intake manifolds may not have been possible in many North American applications. The Dodge Neon’s 2 L single overhead cam engine manifold of Zytel® nylon 66, weighing just 2.9 lb, highlights the benefits the U.S. market has gained with the adoption of nylon manifolds. In comparison, a manifold in aluminum for Neon’s dual overhead cam engine weighs 12 lb. The thermoplastic manifold also is credited for a 2 percent horsepower boost. Further, thermoplastic manifolds are credited with reducing emissions and providing additional environmental benefits. An independent study by the Institute for Plastics Testing at Stuttgart University in Germany in 1992 confirmed that nylon air intake manifolds significantly reduce carbon dioxide and nitrogen oxide emissions believed to contribute to global warming and acid rain. Nylon air intake manifolds also lower fuel consumption, and the EGR system improves engine performance and hot-start performance. Finally, the lower thermal conductivity of a plastic manifold provides denser air for better engine performance. More Than Cost and Weight Savings Weight and cost savings quickly became a given in switching from metals to plastics. Along the way, many engineers found additional, surprising benefits in nylon’s aesthetics, design adaptability, manufacturability and virtually unlimited options for creative parts integration. These benefits coincided with design challenges to reduce vehicle size to improve fuel economy without sacrificing performance. Supercharging and turbocharging in the late 1980s and 1990s, which improved performance in small engine compartments, created logistical challenges. Like a 3-dimensional puzzle, the pieces of the engine had to be scrambled and reordered. Here, the flexibility of nylon proved a problem solver. From air resonators and fuel tanks with Salvadore Dali-like shapes, to sensitive electrical and electronic applications that had to be tucked or hung in hot or exposed areas, plastics led breakthroughs. Some credit the non-conductive, corrosion and chemical resistance of nylons with enabling engineers to make such advances in vehicle design. Thermoplastic materials are also finding a home in engine rocker arm covers. After years of trial, the 1990s brought several successes, and some surprising benefits. In addition to weight and cost savings, Rover in 1992 touted sound damping capabilities using Zytel® nylon 66 resin. The Denouement The undisputed benefits of using nylon 66 in underhood applications led many industry experts to predict that at least 80 percent of air intake manifold production would be nylon by the end of the century. New molding facilities confirm that the industry has moved in that direction. Development programs incorporating fuel rails and other intake components are underway. For many, it’s simply a matter of time before nylon weaves it way into more underhood applications. One imminent program involves greater use of hightemperature resistant thermoplastics to protect sensitive electrical/electronic equipment from hotter running engines and corrosive fluids. In 1994, DuPont introduced Zytel® HTN high temperature nylon for this burgeoning market. Still in its infancy, target applications include water pump outlets, seal retainers, transmission valves and covers, rocker arm covers, as well as sensors, relays, switches, gears and bobbins. Keeping its eye on the future, in 1995 DuPont captured the industry’s attention with a heat exchanger made of Zytel® PA 66, showing the material’s versatility in another traditionally metal application. But most industry analysts credit nylon’s projected high growth to increases in the air intake manifold commercialization. Noted industry analyst Jim Best predicted the average car will use 11.06 lb of nylon in underhood applications in 2000 and 14.4 lb in underhood applications by 2005. Nylon’s growth in the engine compartment has come a long way since the days when skeptics doubted its performance under the hood—and based on industry projections, nylon has a long period of growth ahead. DuPont™ Minlon® mineral-reinforced nylon boosted performance while cutting costs of this new rocker cover for Ford developed by Bruss Sealing Systems, Germany. Minlon® proved to be the perfect material choice with its high level of creep resistance and the ability to withstand typical oil temperatures in the underhood environment. Bruss Sealing Systems also chose Minlon® instead of thermosets because of its superior resistance to microcracks. 3 Nylon Development Timeline 1939 ■ Wallace Hume Carothers, director of the DuPont Experimental Station in Wilmington, Delaware, discovers a method of creating fibers whose structures resemble natural polymers. His discovery results in the production of the first synthetic fiber— nylon. 1941 ■ Nylon resin is offered; experiments using nylon in selflubricating bearings begin. 1947 ■ Molded nylon speedometer gears are introduced; nylon fabrics are used to upholster 1948 model automobiles. 1948 ■ First large commercial plant to manufacture nylon resin gets underway at Parkersburg, WV. Two years later it will be expanded to meet demand. 1954 ■ Trademark Zytel® is adopted for DuPont nylon resin. 1955 ■ Heavy-duty truck and bus pneumatic windshield-wiper motors debut featuring nylon in rack and pinion, sliding valve parts and moving shafts. 1956 ■ First automotive radiator fan made of plastic is introduced by Citroen. This application also marks the first use of plastics for thread-forming screws. DuPont Engineering Polymers collaborated closely with DENSO Corp. to demonstrate the viability of closed-loop, composite recycling for nylon. The proof is this prototype radiator end tank made of 100 percent recycled nylon from a post consumer end tank. 4 ■ A new center-link socket with a bushing of nylon helps create a greased-for-life steering linkage. 1957 ■ Nylon resin is selected for air brake and air suspension system valve seats, inlet and exhaust valves, exhaust stem in the compressor governor and main cam for the positioning valve. A leveling valve contains wear and positioning rings of nylon and sintered nylon. 1958 1959 ■ Ball bearing retainers made of nylon replace metal retainers, effectively reducing the high premature failure rates associated with metal retainers. ■ The resistance of nylon to hydrolysis, chemicals and heat opens a new realm of opportunities in thermostat housings, valve components, inlet assemblies, radiator end caps and overflow tubing. ■ Initial vehicle testing using plumbing of nylon shows promising results: 21,000 miles of normal driving on a 1958 vehicle returned completely satisfactory results. The upper air intake manifold for the Ford Windstar’s 3.8-liter V-6 engine is injection molded from Zytel® nylon 66 resin. ■ An air-suspension vehicle featuring nylon hits the test circuit. 1960 ■ The average car uses 0.4 lb of nylon, less than one percent of total plastics use. ■ Patented “Pushlock” self-fastening system of nylon, designed by Whitso Inc. of Schiller Park, IL, replaces metal fastening system of threads, nuts and locking washers while providing exceptional holding power for automotive tubes and hoses. Pushlock, a forerunner of “snap-fit,” greatly simplifies assembly, especially in hard-to-reach spots and blind spots. 1963 ■ Nylon turns 25 years old with 45 resin formulations in the marketplace. Automotive applications include wiring clips, lamp sockets, gears, bearings, bushings, lamp lenses, switch housings, tubing, timing sprockets, cams and linkages, fasteners, coil forms and windshield wiper motors. 1964 ■ A major truckmaker selects a one-piece fuel filler neck assembly made of nylon, substantially reducing cost compared to steel, while absorbing vibration between the body-mounted fuel tank and fuel neck projecting through the body panel. ■ Nylon finds new applications in a “speedguard” passenger car cruise control system, with both cruise control and a speed warning system. Operating on the engine intake manifold vacuum, the new device tapped nylon for 13 different components, greatly reducing weight and cost through parts integration. 1968 ■ DuPont introduces glass-reinforced Zytel® 66 nylon—adding a whole new dimension of performance capabilities to the nylon family. 1970 ■ The average car uses 2.0 lb of nylon. 5 Air intake manifolds made from DuPont™ Zytel® nylon resin make a major contribution to high performance and smooth, quiet operation of the sporty Porsche Boxster. Twin manifolds are used to supply air to a 2.5 L, six-cylinder engine with two horizontally opposed banks of cylinder heads. ■ A DuPont engineer designs and constructs a vibration welding device to produce a structurally sound weld in PA 66 nylon. The vibration welding technique is used experimentally to assemble a nylon canister that could not be ultrasonically welded. An emissions canister, the first component to undergo this technique, goes commercial in 1973. 1971 ■ The first automotive fan with flexible blades for engine cooling debuts with glass-reinforced nylon, improving performance and worker safety. Replacing steel, the component weighed 60 percent less and applied 50 percent less vertical stress on the water pump bearing at 5,200 rpm. The material maintains excellent flexural strength and creep resistance under humid conditions, while providing outstanding resistance to gasoline, oil, battery acid and road salts. 1972 ■ This was the beginning of the end of the annual ritual of flushing out the radiator. Metal end tanks tended to corrode, thereby requiring frequent flushing to eliminate corrosion build-up. Because nylon does not rust, this annual service is now unnecessary and saves the environment. It is now typical for coolant to last the life of the car, eliminating frequent waste handling issues. In addition, nylon radiator end tanks can be recycled at the end of vehicle life; thereby saving the environment twice. ■ Porsche adopts a reinforced PA 66 nylon air intake manifold in its fuel injection system. 1973 ■ PA 66 nylon improves flexibility and toughness of wire harnesses as underhood electronics takes off. 1974 ■ Recent government imposed safety and pollution regulations spark plastics growth, and heat-stabilized glass-reinforced nylon 66 resin debuts in underhood delay-valve applications. ■ Automakers begin using molded-in-color nylon in components to eliminate confusion and possible misalignment during installation. 1976 6 ■ Heat-stabilized PA 66 resin is used by Ford in fuel vapor emission control canisters, sealing lids and integral mounting tabs and hooks. The nylon material reduces weight and offers improved resistance to chemicals and salt-spray corrosion compared to steel. The air intake manifold for Rover K-series fuelinjected auto engines consists of four injection molded parts joined together by vibration welding. The parts are molded from DuPont™ Zytel® PA 66 nylon resin. The complexity and curvature of these parts put this manifold assembly at the leading edge of vibration welding technology. 1977 ■ An air management valve demonstrates the ability of engineering plastics to withstand underhood environmental conditions. The emission control unit relied on at least seven separate joining methods, including the first commercial use of an induction welding process that employs a permanent aluminum screen interface. 1978 ■ Ford uses glass-reinforced PA 66 instead of metal in power steering reservoirs, reducing weight and cost, while eliminating rejects related to leaking. Units molded in nylon have integral baffles, filler necks, air bleed slots and consistent dimensional reproducibility. Chemical and corrosion resistance assures the long life of the reservoir. ■ Chevrolet Vega features the energy-saving flex fan of nylon 66, in which centrifugal force causes nylon blades to twist and reduce resistance. 1979 ■ PA 66 nylon replaces stamped sheet steel in transmission oil screens. One application is an integral intake tube; another increases oil handling capacity, to reduce weight, cut cost and improve seals essential for hotter running engines. ■ Ford uses glass-reinforced nylon radiator fans on the new Fairmont and Zephyr. Although these benefits in themselves merited a switch from steel to nylon, the true driver was safety. Nylon fans were safer than steel due to steel’s tendency to rust over time. Constant fatigue could cause rusted steel fans to break apart, which occasionally happened when an engine was in service, injuring the mechanic. Because nylon did not rust, a new benefit to nylon use under hood was born—safety. ■ Stant Manufacturing Co. uses Zytel® ST (Super Tough) PA 66 nylon resin for a snap-together gas cap and retaining ring. The product enhances durability and automated assembly. The material resists gasoline, moisture, road salt and condensation deposits. 7 1979 ■ Chrysler Corp. is the first automaker to adopt glass-reinforced nylon in brake cylinder reservoirs. The material’s chemical resistance at high underhood temperatures makes it a natural to replace cast iron, thereby reducing weight and cost, improving fit and optimizing assembly time. ■ A European fluid-level detector of nylon 66 is designed into brake fluid reservoirs. The component is molded in white and thinned at the “fill” point (from 5.1 mm to 0.76 mm) so a translucent window is achieved. ■ The fuel-injected Peugeot 505 bows with an air intake manifold intake plenum vibration welded of PA 66. 1980 ■ This time period signals the change in Europe from carburetor-equipped vehicles to electronic fuel injection, opening up design opportunities, especially in air cleaners. Horizontal fuel injection inlets allow the air cleaner to be mounted anywhere, as long as hoses lead to the inlet. The shapes required to fit into these “anywhere” spaces would be prohibitively expensive in metal. Using glass-reinforced nylon 66 reduces weight, eliminates welding and assembly and reduces tooling costs. ■ The average car uses 3.25 lb of nylon. 1982 ■ A new shift control cable, shielded by nylon 66 and capped with end fittings of glass-reinforced nylon, helps reduce noise and vibration in new front-wheel drive vehicles with lightweight bodies. Nylon allows the component to be redesigned with an encapsulated rubber damper to stop noise and vibration, and reduces weight 50 percent. This application paves the way for uses in transmission shift cables, brake cables, hood-release and door-release cables. ■ Jaguar designs a one-piece 11-blade cooling fan for its V-12 engine with Zytel® Super Tough nylon. 1983 ■ Ford replaces steel and cast iron in a hydraulic clutch actuator with Zytel® nylon 66. The master cylinder, cap for integral reservoir and slave cylinder are produced in nylon. These lightweight, easily handed plastic components are shipped prefilled and tested, improving reliability and reducing cost through more efficient assembly. By 1992, the all-plastics hydraulic clutch actuating system replaces metal assemblies. General Motors adopts glass-reinforced nylon radiator end caps for all models. 8 Working together as partners, Ford, Siemens and DuPont developed the first thermoplastic air intake manifold in Europe that incorporates an exhaust gas recirculation (EGR) system using lost-core molding. The EGR reduces hydrocarbon emissions by allowing a percentage of the exhaust gas to be returned to the manifold. The manifold of DuPont™ Zytel® nylon 66 is featured on select Ford engines, including the 1.6 L Zeta engine. 1989 ■ Substituting nylon for steel in powersteering reservoirs reduces assembly time and improves reliability by eliminating leaks associated with machining and welding. The three-part reservoir is molded in one piece with a one-piece dipstick of nylon 66 twist locked into the cover. 1984 ■ The U.S. market follows Europe in its move from carburetors to fuel injection, broadening nylon applications in this region. 1985 ■ Nissan commercializes a valve cover in DuPont™ Minlon® mineral-reinforced nylon. ■ Ford adopts glass-reinforced nylon radiator end caps on all new platforms, starting with the Escort, Tempo/Topaz and Taurus/Sable. 1986 ■ A low-pressure surge tank for a diesel truck engine radiator coolant system portends the domination of plastic over steel in this application. The support brackets and tank are molded using PA 66 nylon. ■ Rover introduces its K-series engine (Rover 200 and 400 models) with the first high-volume thermoplastic throttle body using Zytel® PA 66. The new design reduces throttle-body components, eliminates matching, finishing and assembly operations, reduces weight 40 percent and slashes product cost to approximately 65 percent of the current aluminum design. ■ Supercharging and turbocharging engines to maximize horsepower are identified as sources of engine “singing.” An air resonator blow molded of nylon 66 quiets noises in the Taurus and puts to rest any notion that crystalline thermoplastics can’t be blow molded. DuPont predicts the zip tube, air resonator and air cleaner will be the next modular component for automotive assembly. ■ Upgrading Chrysler truck transmissions from three to four speeds is made more economical by using a single housing instead of two, using PA 66 in the bearing separators and housing. ■ Nylon fans and shrouds are now used on virtually all vehicles. 1990 ■ Power steering inlet adapters of Zytel® nylon 66 molded by the lost-core process, wins the Society of Plastics Engineers (SPE) Most Innovative Use of Plastics award. ■ The average car uses 6.9 lb of nylon in underhood applications, more than twice the amount a decade before. 9 1991 ■ General Motors reduces noise, vibration and harshness by using Minlon mineral-reinforced nylon in engine timing belt covers. ■ DuPont announces a program to reclaim radiator end caps made of PA 66 nylon. ■ Rover selects PA 66 for engine rocker arm covers on the Metro and 200 Series vehicles. Replacing die-cast metal reduces weight and expands design freedom, allowing the component to be made smaller and fit into the more complex underhood layouts. 1992 ■ Volkswagen uses nylon 66 for the Transporter radiator fan shrouds. The material’s ability to withstand vibration, mechanical stress and exposure to fuel and engine fluids made it an excellent selection. ■ An all-plastic clutch actuation system for the 1990 Saturn and 1991 GM trucks wins the Society of Plastics Engineers top award in the powertrain category. Produced from glass-reinforced nylon 66, the design carries numerous patents and meets stringent Federal Motor Vehicle Safety Standards (FMVSS) molding requirements. ■ Ford of England abandons aluminum and thermosets in favor of thermoplastics for intake manifolds. ■ The first commercial high-volume thermoplastic air intake manifold in the U.S. debuts on the GM 3800 tuned port injection V-6 engine. The application garners accolades and the Society of Plastics Engineers “Most Innovative Use of Plastics” award in the powertrain category. The design integrates the exhaust gas recirculation (EGR) interface adapter, gaskets, and positive crankcase ventilation valve into the manifold vacuum source. ■ Europe’s first nylon air intake manifold with an EGR valve molded by a fusible core process debuts on Ford’s 1.6 L Zeta engine for the Escort and Mondeo. Later, this technology travels to the U.S. for the Mercury Mystique and Ford Contour. ■ DuPont breaks ground on a nylon 66 plant in Singapore to meet worldwide demand. The Electronic Throttle Control (ETC) mechanism on the 2000 Ford Transit Van enhances overall engine performance by reducing vehicle emissions, improving fuel economy and integrating cruise control. The ETC, also known as drive-bywire, was developed and produced by Teleflex Automotive Group, Inc. using DuPont™ Zytel® 33 percent glass reinforced nylon 66 resin. 10 ■ North America’s first lost core air intake manifold to incorporate an EGR valve debuts on the Dodge and Plymouth Neon, garnering the Society of Plastics Engineers “Most Innovative Use of Plastics” award in the powertrain category. 1993 1993 ■ An independent study by the Institute for Plastics Testing at Stuttgart University, Germany, shows glass-reinforced Zytel® nylon 66 offers lower energy consumption, manufacturing emissions and weight than aluminum for Ford of Europe’s Escort and Mondeo 1.6 L engine manifolds. The study analyzed energy and raw material consumption throughout the part’s lifecycle. ■ DuPont™ Minlon® mineral-reinforced nylon is used for a oneounce filter carrier plate between the shift manifold and shifter valve body, to protect shift solenoids and maintain a seal. This critical Chrysler LH transmission component requires the nylon to perform the unusual task of taking bolt load. ■ Nearly 90 percent of all U.S. made passenger vehicles use glass-reinforced PA 66 nylon for radiator end caps. 1994 ■ The Porsche 911 Carerra features four valve covers of nylon 66—Porsche’s first thermoplastic valve cover. ■ European automakers using Zytel® nylon resin in air intake manifolds now include Peugeot, Citroen, BMW, Mercedes and Ford of Europe. ■ The all-new Ford Mustang’s conical-shaped air cleaner uses both glass-reinforced nylon 66 and mineral-reinforced nylon to reduce induction noise 30 percent, add 10 horsepower and reduce space needed for the component. ■ Space restrictions on a Ford transmission spur the development of nylon use in an oil pickup tube to be incorporated into the filter case bottom. ■ DuPont introduces Zytel® HTN high temperature nylon for high temperature, high pressure underhood and electrical/ electronic applications. 1995 ■ The average car uses 8.8 lb of nylon in underhood applications. ■ Fuel-injector pods, designed using the DuPont Snap-Fit Design System and molded of Zytel® heat-stabilized nylon, help GM improve fuel injection system performance, decrease part count and reduce cost on the Oldsmobile Aurora 4.0 L engine. The blend of materials and Snap-Fit design creates the industry’s most intricate pods, allowing precise fuel spray on each cylinder’s intake valve. 11 ■ GM’s Quad 4 engine features a water-outlet housing of glassreinforced PA 66 nylon that reduces weight 66 percent and cost 75 percent compared with aluminum. ■ The Nissan Sentra debuts with the only current thermoplastic valve cover for the U.S. market, using mineralreinforced nylon. The new valve cover weighs half its aluminum counterpart and is assembled in less time. ■ GM’s new 3800 Series II V-6 engine features the first thermoplastic oil pan gasket with an integrated windage tray molded of nylon 66. The one-piece windage tray, with a molded-in gasket, improves sealing and durability, reduces assembly time and withstands ever-increasing engine demands. ■ DuPont announces it will double Zytel® nylon 66 capacity in North American capacity by 1998 to meet increasing demand, particularly in underhood components. ■ DuPont stretches the imagination with a prototype heat exchanger made of Zytel® nylon resin. The component debuts at the SAE International Congress & Exposition, and wins “Best of Show” from Automotive News. 1996 ■ The first single-core, eight runner V-8 air intake manifold of Zytel® nylon 66 debuts on the Mustang 4.6 L engine. The manifold program is so successful, car lines are quickly extended to the Ford Thunderbird and Mercury Cougar, Ford Crown Victoria and Mercury Marquis and Lincoln Town Car, making it the world’s largest production volume air intake manifold of PA 66 nylon. ■ Worldwide automotive industry demand for nylon is expected to double over the next five years from 2 billion pounds to 4 billion annually. North American nylon consumption is about 212 million pounds annually, making nylon the highest volume automotive engineering plastic. North American automotive consumption of PA 66 is expected to grow by as much as 100 million pounds by the year 2000. 2000 ■ The average car uses 11.06 lb of nylon in underhood applications alone, nearly 30 times the amount used in the entire car in 1960. Copyright © 2003 E.I. du Pont de Nemours and Company. All rights reserved. The DuPont oval logo, DuPont™, The miracles of science®, Minlon® and Zytel® are trademarks or registered trademarks of DuPont. 1995
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