Formulation Examples with Self-Tanning Compositions for Modulated Skin Toning 7th revision dd. July 2007 SELF TANNING FORMULATIONS EMULSIONS, GEL, SPRAY, WIPES SE-46-06 Name O/W Cream Comments basic cream formulation ST-08-02 O/W Cream basic cream formulation 4 SK-06-05 O/W Cream with empty liposomes for a very even tan 5 SL-01-01 Clear W/O Lotion transparent; for light skin 6 ST-16-14 W/O Lotion for light skin 7 SF-40-01 Aqueous Gel transparent 8 SF-41-01 Aqueous-alcoholic Spray for pump applications 9 SU-16-04 Gel transparent W/Si 10 SK-06-12 O/W Cream 3 % Eusolex® 2292 & 0.5 % Eusolex® 4360 11 Solution for Sprays or Wipes opaque solution 12 O/W Cream with DHA Plus 13 Colored W/O Lotion Shimmering with pearlescent pigments 14 NEW! 18SA014 NEW! SK-06-104 ST-16-28 Type page 3 DAY CARE Name Type page NEW! ST-08-76 Cream with a twinkling ‘touch of sun’ with Ronastar® Silver 15 NEW! SK-06-102 Cream providing a holiday tan (O/W) with DHA Plus 16 SK-06-106 Cream providing a summer like complexion (O/W) in vivo SPF 7 17 SK-06-75 Skin care cream providing a light summer tan (O/W) 18 ST-16-31 Velvety body lotion for a natural glow (W/O) 19 SK-06-110 ‘Rapid Summer glow’ Day Care Cream with DHA Rapid 20 Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 2 SE-46-06 Self tanning cream (O/W) Ingredients A Marlipal 1618/11 Lanette O Luvitol EHO Tegosoft TN Miglyol 812 N Propyl-4-hydroxybenzoate Art. No. INCI CETEARETH-11 1.07427 (1) (2) (3) (4) (1) (5) B 1,2-Propanediol Methyl-4-hydroxybenzoate Water, demineralized 1.07478 1.06757 (5) (5) PROPYLENE GLYCOL C Dihydroxyacetone Water, demineralized 1.10150 CETEARYL ALCOHOL CETEARYL OCTANOATE C12-15 ALKYL BENZOATE CAPRYLIC/CAPRIC TRIGLYCERIDE PROPYLPARABEN METHYLPARABEN AQUA (WATER) (5) DIHYDROXYACETONE AQUA (WATER) [%] 3.00 7.00 5.00 2.50 2.50 0.05 4.00 0.15 60.80 5.00 10.00 Procedure: Heat phase A to 75 °C, phase B to 80 °C. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C at 40 °C. Notes: pH26°C = 4.6 Viscosity 60,300 mPas (Brookfield RVT, Sp. C, 10 rpm) at 26 °C Samples contain as preservatives 0.05 % Propyl-4-hydroxybenzoate (Merck-Art.-No. 107427) 0.15 % Methyl-4-hydroxybenzoate (Merck-Art.-No.106757) Suppliers: (1) Sasol Germany GmbH (2) Cognis GmbH (3) BASF AG (4) Degussa-Goldschmidt AG (5) Merck KGaA/Rona® Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 3 ST-08-02 Self tanning cream (O/W) Ingredients A B C D Art. No. [%] INCI Tego Care 150 (1) GLYCERYL STEARATE, STEARETH-25, CETETH-20, STEARYL ALCOHOL Miglyol 812 N Isopropyl myristate Paraffin liquid Paraffin Propyl-4-hydroxybenzoate CAPRYLIC/CAPRIC TRIGLYCERIDE 1.07162 1.07158 1.07427 (2) (3) (4) (4) (4) 1,2-Propanediol Sorbitol F liquid Methyl-4-hydroxybenzoate Water, demineralized 1.07478 1.02993 1.06757 (4) (4) (4) PROPYLENE GLYCOL Dihydroxyacetone Water, demineralized 1.10150 ISOPROPYL MYRISTATE PARAFFINUM LIQUIDUM (MINERAL OIL) PARAFFIN PROPYLPARABEN SORBITOL METHYLPARABEN AQUA (WATER) (4) DIHYDROXYACETONE AQUA (WATER) Fragrance (q.s.) 8.00 3.00 2.00 12.00 2.00 0.15 4.00 2.00 0.05 49.50 5.00 11.80 0.50 PARFUM Procedure: Heat phase A and B separately to 75° C. Add phase A slowly to phase B while gently stirring. Homogenize at 65 °C for one minute. Cool down to 40° C while stirring and add phase C. Cool down to 35° C and add phase D while stirring, cool down. Notes: pH23°C = 4.6 Viscosity 42,500 mPas (Brookfield RVT, Sp. C, 10 rpm) at 23 °C Suppliers: (1) Degussa-Goldschmidt AG (4) Merck KGaA/Rona® (2) Sasol Germany GmbH (3) Cognis GmbH Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 4 SK-06-05 Self Tanning Cream O/W cream providing a very even tan Ingredients INCI Art. No. A Tego Care 150 (1) [%] GLYCERYL STEARATE, STEARETH-25, CETETH-20, STEARYL ALCOHOL 8.00 1.50 5.00 5.00 3.00 1.60 0.50 0.05 Lanette O Luvitol EHO Miglyol 812 N Paraffin liquid Abil-Wax 2434 Dow Corning 200 Fluid (350 cs) Propyl-4-hydroxybenzoate (2) (3) (4) 1.07162 (5) (1) (6) 1.07427 (5) CETEARYL ALCOHOL B 1,2-Propanediol Methyl-4-hydroxybenzoate Water, demineralized 1.07478 (5) 1.06757 (5) PROPYLENE GLYCOL CETEARYL OCTANOATE CAPRYLIC/CAPRIC TRIGLYCERIDE PARAFFINUM LIQUIDUM (MINERAL OIL) STEAROXY DIMETHICONE DIMETHICONE PROPYLPARABEN 3.00 0.15 52.20 METHYLPARABEN AQUA (WATER) C Dihydroxyacetone 1.10150 (5) Probiol L 05018 (Empty liposomes) (7) DIHYDROXYACETONE Water, demineralized AQUA (WATER) AQUA, ALCOHOL DENAT., LECITHIN, GLYCERIN, DISODIUM PHOSPHATE 5.00 5.00 10.00 Procedure: Heat phase A and phase B to 80°C. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C at 40°C Notes: Viscosity 68,000 mPas (Brookfield RVT, sp. C, 10 rpm) at 26°C Suppliers: (1) Degussa-Goldschmidt AG (5) Merck KGaA/Rona® (2) Cognis GmbH (6) Dow Corning (3) BASF AG (7) Kuhs GmbH & Co. KG (4) Sasol Germany GmbH Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 5 SL-01-01 Smooth Self-Tanning Lotion Transparent W/O Ingredients A Dow Corning 3225 C Propyl-4-hydroxybenzoate B Dihydroxyacetone Methyl-4-hydroxybenzoate 1,2-Propanediol Water, demineralized Art. No. INCI (1) 1.07427 (2) CYCLOMETHICONE, DIMETHICONE COPOLYOL 1.10150 (2) 1.06757 (2) 1.07478 (2) DIHYDROXYACETONE PROPYLPARABEN METHYLPARABEN PROPYLENE GLYCOL AQUA (WATER) [%] 23.60 0.05 5.00 0.15 35.90 35.30 Procedure: Dissolve phase B and add it to phase A. Notes: Transparent lotion, oil-free. Adjust transparency by means of variation of ratio water/Propanediol-1,2. Viscosity 12,000 mPas (Brookfield RVT, sp. 4, 10 rpm) at 24 °C. Suppliers: (1) Dow Corning (2) Merck KGaA/Rona® Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 6 ST-16-14 Self Tanning Lotion (W/O) Ingredients A B Art. No. INCI [%] Abil EM 97 Abil EM 90 Ceraphyl 368 Tegosoft DEC Dow Corning 345 Dow Corning 9041 Silicone Elastomer Blend Fragrance Babylon (1) (1) (2) (1) (3) (3) (4) BIS-PEG/PPG-14/14 DIMETHICONE, CYCLOPENTASILOXANE Dihydroxyacetone 1,2-Propanediol Glycerol, anhydrous Magnesium sulfate heptahydrate Phenonip 1.10150 1.07478 1.04093 1.05882 (5) (5) (5) (5) (6) DIHYDROXYACETONE Ethanol 96% Water, demineralized 1.00971 (5) ALCOHOL CETYL PEG/PPG-10/1 DIMETHICONE ETHYLHEXYL PALMITATE DIETHYLHEXYL CARBONATE CYCLOMETHICONE DIMETHICONE CROSSPOLYMER, DIMETHICONE PARFUM PROPYLENE GLYCOL GLYCERIN MAGNESIUM SULFATE PHENOXYETHANOL, BUTYLPARABEN, ETHYLPARABEN, PROPYLPARABEN, METHYLPARABEN AQUA (WATER) 1.50 1.30 2.00 5.00 13.00 3.00 0.30 5.00 20.00 3.00 2.00 1.00 8.00 34.90 Procedure: First dissolve the Magnesium sulfate heptahydrate in the water of phase B. Add the remaining ingredients of phase B. Add phase B slowly to phase A while stirring. Continue stirring stir for 2 minutes with high agitation and homogenize. Notes: Viscosity: 18,300 cps (Brookfield model RVT DV-II, Helipath Spindle C, 10 rpm) at 23°C Suppliers: (1) Degussa-Goldschmidt AG (2) ISP Global Technologies (3) Dow Corning (4) Drom (5) Merck KGaA/Rona® (6) Nipa Laboratorien GmbH Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 7 SF-40-01 Self Tanning Gel (aqueous) Ingredients Art. No. A Diyhdroxyacetone 1,2-Propanediol Sorbitol F liquid Methyl-4-hydroxybenzoate Water, demineralized 1.10150 1.07478 1.02993 1.06757 INCI (1) (1) (1) (1) DIHYDROXYACETONE PROPYLENE GLYCOL SORBITOL METHYLPARABEN AQUA (WATER) B Natrosol 250 HHR Water, demineralized (2) HYDROXYETHYLCELLULOSE AQUA (WATER) [%] 5.00 2.50 2.50 0.20 28.30 1.50 60.00 Procedure: Add Natrosol to the vortex of the vigorously agitated water of phase B. The rate of addition must be slow enough to permit the particles to separate and their surfaces to become individually wetted, but it should be fast enough to minimize viscosity build up of the aqueous phase while the polymer is being added. Dissolve Dihydroxyacetone in the water of phase A and add remaining ingredients while stirring. Combine phase A and B and homogenize. Notes: Transparent gel. Storage at room temperature is recommended to avoid a decrease of viscosity at about 40° C. Suppliers: (1) Merck KGaA/Rona® (2) Aqualon GmbH Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 8 SF-41-01 Self Tanning Lotion for Pump-Spray Aqueous-alcoholic Ingredients Art. No. Dihydroxyacetone Ethanol 96% Tagat L 2 1,2-Propanediol Water, demineralized 1.10150 1.00971 1.07478 INCI (1) (1) (2) (1) DIHYDROXYACETONE ALCOHOL PEG-20 GLYCERYL LAURATE PROPYLENE GLYCOL AQUA (WATER) [%] 5.00 40.00 7.00 5.00 43.00 Procedure: Dissolve dihydroxyacetone in water, add remaining ingredients while stirring. Notes: pH22°C= 5.4 (immediately after production) Suppliers: (1) Merck KGaA/Rona® (2) Degussa-Goldschmidt AG Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 9 SU-16-04 Self Tanning Gel (W/Si) Ingredients A B C D Dow Corning 5225 C DM-Fluid-A-6cs Soybean Oil RonaCare® Tocopherol Acetate Art. No. 1.30180 RonaCare® Ectoin 1,2-Propanediol Dipropylenglycol Sodium chloride Ethanol 96% 1% Caramel in water 1 % FD&C Yelllow No. 6 in water Water, demineralized 1.30200 1.07478 Dihydroxyacetone Water, demineralized 1.10150 Fragrance Melopeach 1.06400 1.00971 INCI (1) (2) (3) (4) CYCLOPENTASILOXANE, PEG/PPG-18/18 DIMETHICONE (4) (4) (5) (4) (4) (6) (5) ECTOIN DIMETHICONE GLYCINE SOJA (SOYBEAN OIL) TOCOPHERYL ACETATE PROPYLENE GLYCOL DIPROPYLENE GLYCOL SODIUM CHLORIDE ALCOHOL CARAMEL AQUA (WATER), CI 15985 (FD&C YELLOW NO. 6) AQUA (WATER) (4) DIHYDROXYACETONE AQUA (WATER) (7) PARFUM [%] 20.00 4.00 2.00 0.50 0.30 30.00 10.00 1.00 5.00 2.50 0.25 9.25 5.00 10.00 0.20 Procedure: Dissolve phase B and incorporate it into phase A. Add phases C and D successively while stirring. Homogenize. Notes: Viscosity: 9,400 cps (Brookfield model RVT DV-II, Helipath Spindle C, 10 rpm) at 23°C Suppliers: (1) Dow Corning (2) S. Black GmbH (3) Gustav Heess GmbH (4) Merck KGaA/Rona® (5) BASF AG (6) D.D.Williamson (7) Drom Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 10 SK-06-12 Self Tanning Cream (O/W) with UVA/B-protection Ingredients A Eusolex® 2292 Eusolex® 4360 Tego Care 150 Art. No. INCI 1.05382 (1) 1.05376 (1) (2) ETHYLHEXYL METHOXYCINNAMATE, BHT Lanette O Luvitol EHO Miglyol 812 N Paraffin liquid Abil-Wax 2434 Dow Corning 200 Fluid (350 cs) Propyl-4-hydroxybenzoate (3) (4) (5) 1.07162 (1) (2) (6) 1.07427 (1) CETEARYL ALCOHOL B 1,2-Propanediol 1.07478 (1) Methyl-4-hydroxybenzoate sodium salt 1.06756 (1) Water, demineralized C Dihydroxyacetone Water, demineralized 1.10150 (1) [%] BENZOPHENONE-3 GLYCERYL STEARATE, STEARETH-25, CETETH-20, STEARYL ALCOHOL CETEARYL OCTANOATE CAPRYLIC/CAPRIC TRIGLYCERIDE PARAFFINUM LIQUIDUM (MINERAL OIL) STEAROXY DIMETHICONE DIMETHICONE PROPYLPARABEN PROPYLENE GLYCOL SODIUM METHYLPARABEN AQUA (WATER) DIHYDROXYACETONE AQUA (WATER) 3.00 0.50 8.00 1.50 5.00 5.00 3.00 1.60 0.50 0.05 3.00 0.17 53.18 5.00 10.00 Procedure: Combine phases A and B separately and to 80°C. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C at 40°C Notes: Suppliers: (1) Merck KGaA/Rona® (4) BASF AG (2) Degussa-Goldschmidt AG (5) Sasol Germany GmbH (3) Cognis GmbH (6) Dow Corning Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 11 18SA014 Self Tanning Solution for Sprays or Wipes Ingredients Art. No. A Arlamol E Prisorine 2021 Prisorine 2034 Arlasolve 200 Arlacel 987 Atlas G-2330 B Dihydroxyacetone Water, demineralized Arlasolve DMI C Preservative 1,2-Propanediol INCI (1) (2) (2) (2) (1) (1) 1.10150 (3) [%] ISOPROPYL ISOSTEARATE PROPYLENE GLYCOL ISOSTEARATE ISOCETETH-20 SORBITAN ISOSTEARATE SORBETH-30 DIHYDROXYACETONE AQUA (WATER) (1) 1.07478 (3) D Fragrance Pearl FC10599 (4) 3.50 8.00 1.00 3.78 1.12 1.50 PPG-15 STEARYL ETHER, BHT DIMETHYL ISOSORBIDE 5.00 ad 100 3.00 PROPYLENE GLYCOL q.s. 0.56 PARFUM 0.08 Procedure: Mix phase A to obtain a homogeneous solution. Mix phase B to a transparent solution. Stir phase A into phase B. Homogenize for 5 minutes. Adjust pH value to 4.0 if necessary. Add phase C and the fragrance while stirring. Notes: pH value: 4.0 Appearance: opaque Samples contain as preservatives Propyl-4-hydroxybenzoate Methyl-4-hydroxybenzoate Germall 115 1.07427 (1) 1.06757 (1) (5) PROPYLPARABEN METHYLPARABEN IMIDAZOLIDINYL UREA 0.03 0.11 0.30 Suppliers: (1) Uniqema (2) Uniqema Chemie GmbH (3) Merck KGaA/Rona® (4) Parfex (5) ISP Global Technologies Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 12 SK-06-104 Self Tanning Cream with DHA Plus (o/w) Ingredients A B C Art. No. Tego Care 150 INCI (1) GLYCERYL STEARATE, STEARETH-25, CETETH-20, STEARYL ALCOHOL 8.00 1.50 6.50 6.50 1.20 0.50 0.50 0.05 Lanette O Tegosoft liquid Miglyol 812 N Abil Wax 2434 Dow Corning 200 (100cs) RonaCare® Tocopherol Acetate Propyl-4-hydroxybenzoate (2) (1) (3) (1) (4) 1.30180 (5) 1.07427 (5) CETEARYL ALCOHOL RonaCare® Ectoin 1,2-Propanediol Methyl-4-hydroxybenzoate Water, demineralized 1.30200 (5) 1.07478 (5) 1.06757 (5) ECTOIN DHA Plus 1.10152 (5) CETEARYL ETHYLHEXANOATE CAPRYLIC/CAPRIC TRIGLYCERIDE STEAROXY DIMETHICONE DIMETHICONE TOCOPHERYL ACETATE PROPYLPARABEN 0.30 3.00 0.15 56.10 PROPYLENE GLYCOL METHYLPARABEN AQUA (WATER) Water, demineralized D [%] AQUA (WATER) Fragrance "Sunshine for cream D" (6) 5.60 DIHYDROXYACETONE, SODIUM METABISULFITE, MAGNESIUM STEARATE 10.00 0.10 PARFUM Procedure: Heat phase A and phase B to 80°C. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C at 40°C Notes: pH (23°C) = 3.8 Viscosity 62,000 mPas (Brookfield model RVT DV-II, Helipath spindle C, 10 rpm) at 23°C Formulation is restricted to face applications. The presence of sodium disulfite determines the maximum concentrations of DHA Plus. Recommended concentrations in formulations for the body Æ maximum 5.4 % DHA Plus Recommended concentrations in formulations for the face Æ maximum 6.0 % DHA Plus Suppliers: (1) Degussa-Goldschmidt AG (5) Merck KGaA/Rona® (2) Cognis GmbH (6) Bell Flavors & Fragrances (3) Sasol Germany GmbH (4) Dow Corning Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 13 ST-16-28 Shimmering Self Tanning Lotion (W/O) Clear lotion of walnut brownish color Ingredients A B Art. No. INCI [%] Abil EM 97 (1) BIS-PEG/PPG-14/14 DIMETHICONE, CYCLOPENTASILOXANE Abil EM 90 Mirasil CM 5 Ceraphyl 368 Dow Corning 9041 Silicone Elastomer Blend Tegosoft DEC Fragrance Babylon (1) (2) (3) (4) (1) (5) CETYL PEG/PPG-10/1 DIMETHICONE Dihydroxyacetone RonaCare® Ectoin Caramel 250 Timiron® Starluster MP-115 FD&C Yellow No6 W082 1,2-Propanediol Glycerol, anhydrous Magnesium sulfate heptahydrate Ethanol 96% Phenonip 1.10150 (6) 1.30200 (6) (7) 1.17200 (6) (8) 1.07478 (6) 1.04093 (6) 1.05882 (6) 1.00971 (6) (9) Water, demineralized CYCLOMETHICONE ETHYLHEXYL PALMITATE DIMETHICONE CROSSPOLYMER, DIMETHICONE DIETHYLHEXYL CARBONATE PARFUM DIHYDROXYACETONE ECTOIN CARAMEL MICA, CI 77891 (TITANIUM DIOXIDE) CI 15985 PROPYLENE GLYCOL GLYCERIN MAGNESIUM SULFATE ALCOHOL PHENOXYETHANOL, BUTYLPARABEN, ETHYLPARABEN, PROPYLPARABEN, METHYLPARABEN 1.20 1.00 12.00 2.00 1.60 5.00 0.30 5.00 0.50 0.60 1.00 0.01 20.00 3.00 2.00 8.00 1.00 35.79 AQUA (WATER) Procedure: Dissolve Magnesium sulfate heptahydrate in the water of phase B. Add the remaining ingredients. Add phase B slowly to phase A while stirring. Continue stirring for 2 minutes with high agitation and homogenize. Notes: Viscosity: 16,800 cps (Brookfield RVT DV-II, Helipath Spindle C, 10 rpm) at 23°C Suppliers: (1) Degussa-Goldschmidt AG (5) Drom (9) Nipa Laboratorien GmbH (2) Rhodia GmbH (6) Merck KGaA/Rona® (3) ISP Global Technologies (7) D.D.Williamson (4) Dow Corning (8) Les Colorants Wackherr SA Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 14 ST-08-76 Day Care Cream ‘Twinkling Touch of Sun’ 2 % DHA & 1 % Ronastar® Silver Ingredients A B C D Art. No. Tego Care 150 INCI (1) [%] GLYCERYL STEARATE, STEARETH-25, CETETH-20, STEARYL ALCOHOL 8.00 1.50 5.00 5.00 1.00 0.50 0.05 Lanette O Tegosoft liquid Miglyol 812 N Abil Wax 2434 Dow Corning 200 (100cs) Propyl-4-hydroxybenzoate (2) (1) (3) (1) (4) 1.07427 (5) CETEARYL ALCOHOL Ronastar® Silver 1.17713 (5) CALCIUM ALUMINUM BOROSILICATE, SILICA, CI 77891 (TITANIUM DIOXIDE), TIN OXIDE 1,2-Propanediol Methyl-4-hydroxybenzoate Water, demineralized 1.07478 (5) 1.06757 (5) PROPYLENE GLYCOL Dihydroxyacetone Water, demineralized 1.10150 (5) CETEARYL ETHYLHEXANOATE CAPRYLIC/CAPRIC TRIGLYCERIDE STEAROXY DIMETHICONE DIMETHICONE PROPYLPARABEN METHYLPARABEN AQUA (WATER) DIHYDROXYACETONE AQUA (WATER) Fragrance "Sultan Fantasy" (6) PARFUM 1.00 3.00 0.15 62.70 2.00 10.00 0.10 Procedure: Heat phase A and phase B to 80°C. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C at 40°C Notes: pH (23°C) = 4.5 Viscosity 77,800 mPas (Brookfield model RVT DV-II, Helipath spindle D, 10 rpm) at 23°C Suppliers: (1) Degussa-Goldschmidt AG (4) Dow Corning (2) Cognis GmbH (5) Merck KGaA/Rona® (3) Sasol Germany GmbH (6) Drom Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 15 SK-06-102 Cream providing a Holiday Tan with DHA Plus Ingredients A B C Art. No. INCI Tego Care 150 (1) GLYCERYL STEARATE, STEARETH-25, CETETH-20, STEARYL ALCOHOL 8.00 Lanette O Tegosoft liquid Miglyol 812 N Abil Wax 2434 Dow Corning 200 (100cs) RonaCare® Tocopherol Acetate Propyl-4-hydroxybenzoate CETEARYL ALCOHOL 1.30180 1.07427 (2) (1) (3) (1) (4) (5) (5) 1.50 6.50 6.50 1.20 0.50 0.50 0.05 RonaCare® Ectoin 1,2-Propanediol Methyl-4-hydroxybenzoate Water, demineralized 1.30200 1.07478 1.06757 (5) (5) (5) ECTOIN DHA Plus 1.10152 CETEARYL ETHYLHEXANOATE CAPRYLIC/CAPRIC TRIGLYCERIDE STEAROXY DIMETHICONE DIMETHICONE TOCOPHERYL ACETATE PROPYLPARABEN PROPYLENE GLYCOL METHYLPARABEN AQUA (WATER) (5) Water, demineralized D [%] DIHYDROXYACETONE, SODIUM METABISULFITE, MAGNESIUM STEARATE AQUA (WATER) Fragrance "Sunshine for cream D" (6) 0.30 3.00 0.15 59.50 2.20 10.00 0.10 PARFUM Procedure: Heat phase A and phase B to 80°C. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C at 40°C Notes: pH (23°C) = 4.0 Viscosity 66,000 mPas (Brookfield model RVT DV-II, Helipath spindle C, 10 rpm) at 23°C Suppliers: (1) Degussa-Goldschmidt AG (4) Dow Corning (2) Cognis GmbH (5) Merck KGaA/Rona® (3) Sasol Germany GmbH (6) Bell Flavors & Fragrances Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 16 SK-06-106 Skin care cream providing a summer like complexion in vivo SPF 7 (International method with 10 volunteers) Ingredients A B C D Art. No. INCI Eusolex OCR Eusolex® 9020 Tego Care 150 1.05377 (1) 1.05844 (1) (2) OCTOCRYLENE Lanette O Tegosoft liquid Miglyol 812 N Abil-Wax 2434 Dow Corning 200 (100cs) Propyl-4-hydroxybenzoate (3) (2) (4) (2) (5) 1.07427 (1) CETEARYL ALCOHOL 1,2-Propanediol RonaCare® Ectoin Methyl-4-hydroxybenzoate Water, demineralized 1.07478 (1) 1.30200 (1) 1.06757 (1) PROPYLENE GLYCOL Dihydroxyacetone Water, demineralized 1.10150 (1) ® 5.00 1.00 8.00 BUTYL METHOXYDIBENZOYLMETHANE GLYCERYL STEARATE, STEARETH-25, CETETH-20, STEARYL ALCOHOL 1.50 3.50 3.50 1.20 0.50 0.05 CETEARYL ETHYLHEXANOATE CAPRYLIC/CAPRIC TRIGLYCERIDE STEAROXY DIMETHICONE DIMETHICONE PROPYLPARABEN ECTOIN METHYLPARABEN AQUA (WATER) DIHYDROXYACETONE AQUA (WATER) Fragrance "Sunshine for cream D" [%] (6) 3.00 0.30 0.15 60.20 2.00 10.00 0.10 PARFUM Procedure: Heat phases A and B to 80°C separately. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C and D at 40°C. Notes: pH (23°C) = 4.4 Viscosity 73,600 mPas (Brookfield model RVT DV-II, spindle D, 10 rpm) at 23°C SPF to be labelled = 6 (Colipa recommendation) Recommended product category designation (PCD) = low SPF Suppliers: (1) Merck KGaA/Rona® (5) Dow Corning (2) Degussa-Goldschmidt AG (6) Bell Flavors & Fragrances (3) Cognis GmbH (4) Sasol Germany GmbH Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 17 SK-06-75 Skin care cream providing a light summer tan Ingredients A B C D Art. No. INCI [%] Tego Care 150 (1) GLYCERYL STEARATE, STEARETH-25, CETETH-20, STEARYL ALCOHOL 8.00 Lanette O Tegosoft liquid Miglyol 812 N Abil-Wax 2434 Dow Corning 200 (100cs) Propyl-4-hydroxybenzoate CETEARYL ALCOHOL 1.07427 (2) (1) (3) (1) (4) (5) 1.50 6.50 6.50 1.20 0.50 0.05 1,2-Propanediol Ectoin Methyl-4-hydroxybenzoate Water, demineralized 1.07478 1.30200 1.06757 (5) (5) (5) PROPYLENE GLYCOL Dihydroxyacetone Water, demineralized 1.10150 CETEARYL ETHYLHEXANOATE CAPRYLIC/CAPRIC TRIGLYCERIDE STEAROXY DIMETHICONE DIMETHICONE PROPYLPARABEN ECTOIN METHYLPARABEN AQUA (WATER) (5) DIHYDROXYACETONE AQUA (WATER) Fragrance "Sunshine for cream D" (6) 3.00 0.30 0.15 61.45 0.75 10.00 0.10 PARFUM Procedure: Heat phases A and B to 80°C separately. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C and D at 40°C. Notes: pH (23°C) = 4.4 Viscosity 73,600 mPas (Brookfield model RVT DV-II, spindle D, 10 rpm) at 23°C Daily use ensures a light summer tan all year long. Suppliers: (1) Degussa-Goldschmidt AG (4) Dow Corning (2) Cognis GmbH (5) Merck KGaA/Rona® (3) Sasol Germany GmbH (6) Bell Flavors & Fragrances Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 18 ST-16-31 Velvety body lotion for a natural glow (W/O) Ingredients A B Art. No. INCI [%] Abil EM 97 Abil EM 90 Ceraphyl 368 Tegosoft DEC Dow Corning 345 Dow Corning 9041 Silicone Elastomer Blend Fragrance Babylon (1) (1) (2) (1) (3) (3) (4) BIS-PEG/PPG-14/14 DIMETHICONE, CYCLOPENTASILOXANE Dihydroxyacetone RonaCare® Ectoin 1,2-Propanediol Glycerol, anhydrous Magnesium sulphate heptahydrate Ethanol 96% Phenonip (5) (5) (5) (5) (5) (5) (6) DIHYDROXYACETONE 1.10150 1.30200 1.07478 1.04093 1.05882 1.00971 Water, demineralized CETYL PEG/PPG-10/1 DIMETHICONE ETHYLHEXYL PALMITATE DIETHYLHEXYL CARBONATE CYCLOMETHICONE DIMETHICONE CROSSPOLYMER, DIMETHICONE PARFUM ECTOIN PROPYLENE GLYCOL GLYCERIN MAGNESIUM SULFATE ALCOHOL PHENOXYETHANOL, BUTYLPARABEN, ETHYLPARABEN, PROPYLPARABEN, METHYLPARABEN AQUA (WATER) 1.50 1.30 2.00 5.00 13.00 3.00 0.30 2.00 0.50 20.00 3.00 2.00 8.00 1.00 37.40 Procedure: Dissolve the magnesium sulphate heptahydrate in the water of phase B. Add the remaining ingredients of phase B. Add phase B slowly to phase A while stirring an homogenize. Notes: Suppliers: (1) Degussa-Goldschmidt AG (4) Drom (2) ISP Global Technologies (5) Merck KGaA/Rona® (3) Dow Corning (6) Nipa Laboratorien GmbH Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 19 SK-06-110 ‘Rapid Summer Glow' Day Care Cream with DHA-Rapid Ingredients A B C D Art. No. Tego Care 150 INCI (1) GLYCERYL STEARATE, STEARETH-25, CETETH-20, STEARYL ALCOHOL 8.00 1.50 6.50 6.50 1.20 0.50 0.50 0.05 Lanette O Tegosoft liquid Miglyol 812 N Abil-Wax 2434 Dow Corning 200 (100cs) RonaCare® Tocopherol Acetate Propyl-4-hydroxybenzoate (2) (1) (3) (1) (4) 1.30180 (5) 1.07427 (5) CETEARYL ALCOHOL 1,2-Propanediol Methyl-4-hydroxybenzoate Water, demineralized 1.07478 (5) 1.06757 (5) PROPYLENE GLYCOL DHA-Rapid Water, demineralized 1.00155 (5) CETEARYL ETHYLHEXANOATE CAPRYLIC/CAPRIC TRIGLYCERIDE STEAROXY DIMETHICONE DIMETHICONE TOCOPHERYL ACETATE PROPYLPARABEN METHYLPARABEN AQUA (WATER) DIHYDROXYACETONE, TROXERUTIN AQUA (WATER) Fragrance "Sunshine for cream D" (6) [%] PARFUM 3.00 0.15 59.00 3.00 10.00 0.10 Procedure: Heat phases A and B to 80°C separately. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C at 40°C. Incorporate phase D. Notes: Yellowish cream. Suppliers: (1) Degussa-Goldschmidt AG (2) Cognis GmbH (3) Sasol Germany GmbH (4) Dow Corning (5) Merck KGaA/Rona® (6) Bell Flavors & Fragrances Merck provides information on application technologies and relevant regulations based upon our current knowledge and opinion at the time of printing. Merck / EMD makes no representation or warranty of any kind, express or implied, including merchantability or fitness for a particular use, with respect to such information or its application. Purchasers must independently determine the suitability of our ingredients for the purchaser’s intended product, use or process. Purchaser is responsible for observing all laws and regulations relevant to such products, uses or processes. The foregoing information and suggestions are also provided without warranty of non-infringement as to the intellectual property rights of third parties, and shall not be construed as any inducement to infringe the rights of third parties. 20
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