Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
64211
Copper-II-Sulfate-5-Hydrate
Page
Revised edition: 15.02.2014
Version: 101
1.
Identification of the Substance/Mixture and of the Company/Undertaking
1. 1.
Product Identifier
1. 2.
Product Name:
Copper-II-Sulfate-5-Hydrate
Article No.:
64211
1
Printed: 20.04.2016
Relevant identified Uses of the Substance or Mixture and Uses advised against
Identified uses:
Industrial application.
Animal feed additive
Water treatment.
Algaecide
Uses advised against:
1. 3.
1. 4.
Details of the Supplier of the Safety Data Sheet (Producer/Importer)
Company:
Kremer Pigmente GmbH & Co. KG
Address:
Hauptstr. 41-47, 88317 Aichstetten, Germany
Tel./Fax.:
Tel +49 7565 914480, Fax +49 7565 1606
Internet:
www.kremer-pigmente.de
EMail:
[email protected]
Importer:
--
Emergency No.
Emergency No.:
+49 7565 914480 (Mon-Fri 8:00 - 17:00)
2.
Hazards Identification
2. 1.
Classification of the Substance or Mixture
Classification according to EC
Regulation 1272/2008
H302
Cat.: 4
H315
Cat.: 2
H319
Cat.: 2
H410
Cat.: 1
Classification according to EC
Regulation No. 67/548 or No. 1999/45
Harmful (Xn)
R22
Irritating (Xi)
R36
Irritating (Xi)
R38
Hazardous to the
R50
Acute aquatic toxicity, category 1
Hazardous to the aquatic environment, hazard category 1
Acute toxicity (oral), hazard category 4
Skin irritation, category 2
Eye irritation, category 2
Harmful if swallowed.
Causes skin irritation.
Causes serious eye irritation.
Very toxic to aquatic life with long lasting effects.
Harmful if swallowed.
Irritating to eyes.
Irritating to skin.
Very toxic to aquatic organisms.
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
64211
Copper-II-Sulfate-5-Hydrate
Page
Revised edition: 15.02.2014
Version: 101
2
Printed: 20.04.2016
environment (N)
R53
May cause long-term adverse effects in the aquatic environment.
Safety Phrases:
Possible Environmental Effects:
2. 2.
Label Elements
Classification according to EC
Regulation 1272/2008
Hazard designation:
GHS07-1
GHS09
Signal word:
Warning
Hazard designation:
H302
H315
H319
H410
Harmful if swallowed.
Causes skin irritation.
Causes serious eye irritation.
Very toxic to aquatic life with long lasting effects.
P273
P280
P301+P312
P302+P352
P305+P351+P338
Avoid release to the environment.
Wear protective gloves/ clothing/ eye/ face protection.
If swallowed: Call a poison center or physician if you feel unwell.
If on skin: Wash with soap and water.
If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses and continue rinsing.
If eye irritation persists: Get medical advice/ attention.
Take off contaminated clothing and wash before reuse.
Safety designation:
P337+P313
P362
Hazardous components for labelling:
2. 3.
Other Hazards
3.
Composition/Information on Ingredients
3. 1.
Substance
3. 2.
Mixture
Chemical Characterization:
Copper(II)-sulfate-pentahydrate
Hazardous Ingredients:
Copper(II)-sulfate-Pentahydrate (Xn; R22-36/3850/53; H302-315-319-400-410)
CAS-Nr: 7758-99-8
EINECS-Nr: 231-847-6
EC-Nr: 029-004-00-0
Additional information:
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
64211
Copper-II-Sulfate-5-Hydrate
Page
Revised edition: 15.02.2014
4.
First Aid Measures
4. 1.
Description of the First Aid Measures
Version: 101
3
Printed: 20.04.2016
General information:
Intoxication symptoms may occur after several hours, therefore a
48 hour medical observation is necessary.
After inhalation:
Supply fresh air. If required give artificial respiration. In case of
complaints or unconsiousness consult a physician. In case of
unconsciousness place patient stable in side position for
transportation.
After skin contact:
Remove contaminated clothing immediately. Wash off immediately
with plenty of water and soap.
If irritation continues consult a physician.
After eye contact:
Rinse open eyes with plenty of water. In case of discomfort seek
medical help.
After ingestion:
Rinse mouth with plenty of water.
Induce vomiting as long as affected person is conscious.
Immediately get medical help.
4. 2.
Most important Symptoms and Effects, both Acute and Delayed
Symptoms:
No further information available.
Effects:
4. 3.
Indication of any Immediate Medical Attention and special Treatment needed
Treatment:
No further information available.
5.
Fire-Fighting Measures
5. 1.
Extinguishing Media
Suitable extinguishing media:
Product itself does not burn.
Use extinguishing media for surrounding fire.
Unsuitable extinguishing media:
Water
5. 2.
Special Hazards arising from the Substance or Mixture
Special hazards:
In case of fire: formation of sulfur dioxide and trioxide.
5. 3.
Advice for Firefighters
Protective equipment:
Wear self-contained respiratory protective device and full
protective gear.
Further information:
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
64211
Copper-II-Sulfate-5-Hydrate
Page
Revised edition: 15.02.2014
Version: 101
4
Printed: 20.04.2016
Contaminated extinguishing water and debris should be disposed
of according to local regulations.
6.
Accidential Release Measures
6. 1.
Personal Precautions, Protective Equipment and Emergency Procedures
Personal precautions:
Avoid formation of dust, wear protective clothing. Keep spectators
away.
Ensure adequate ventilation.
6. 2.
Environmental Precautions
Environmental precautions:
Prevent contamination of soils, drains and surface water.
Contact local authorities if product pollutes soil or vegetation.
6. 3.
Methods and Material for Containment and Cleaning Up
Methods and material:
Remove remains with water.
Take up mechanically and collect in suitable containers for
disposal.
6. 4.
Reference to other Sections
For information for safe handling see Section 7.
Protective clothing, see Section 8.
See Section 13 for information on disposal.
7.
Handling and Storage
7. 1.
Precautions for Safe Handling
Instructions on safe handling:
Provide adequate ventilation.
When dissolving: always pour the product into the water. Never
pour water into the product.
Hygienic measures:
Avoid contact with skin, eyes and clothing. Do not inhale dust.
7. 2.
Conditions for Safe Storage, including any Incompatibilities
Storage conditions:
Store containers in a well ventilated location.
Store in tightly sealed containers in a dry and cool room.
Requirements for storage areas and
containers:
Observe official regulations on storage and handling of water
hazardous substances.
Information on fire and explosion
protection:
Precautionary measures in reference to the general rules
concerning fire prevention.
Storage class (VCI):
13; Non combustible solids
Further Information:
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5
Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
64211
Copper-II-Sulfate-5-Hydrate
Page
Revised edition: 15.02.2014
7. 3.
Version: 101
5
Printed: 20.04.2016
Specific End Use(s)
Further information:
No further information available.
8.
Exposure Controls/Personal Protection
8. 1.
Parameters to be Controlled
Parameters to be controlled (DE):
none known
Parameters to be controlled:
Derived No-Effect Level (DNEL):
Predicted No-Effect Concentration
(PNEC):
Additional Information:
8. 2.
Exposure Controls
Technical protective measures:
Provide adequate ventilation in case of dust formation.
Personal Protection
General protective measures:
Keep away from foodstuffs and drinks. Do not eat, drink or smoke
during work. Wash hands before breaks and at the end of work.
Avoid contact with skin, eyes and clothing.
Do not inhale dust.
Respiratory protection:
In case of formation of dust.
Dust mask recommended when very dusty: with particle filter P2.
Hand protection:
Chemical protective gloves (EN 374 (Europe), F739 (US)).
Protective glove material:
Suitability and durability of a glove is dependent on usage, e.g.
frequency and duration of contact, chemical resistance of glove
material and dexterity. Always seek advice from glove suppliers.
Eye protection:
Tightly fitting safety goggles (EN 166).
Body protection:
Protective clothing, chemical resistant safety shoes.
Environmental precautions:
Avoid contamination of sewage system, open water ways and
ground water.
9.
Physical and Chemical Properties
9. 1.
Information on Basic Physical and Chemical Properties
Form:
crystalline
Color:
blue
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
64211
Copper-II-Sulfate-5-Hydrate
Page
Revised edition: 15.02.2014
Odor:
Version: 101
6
Printed: 20.04.2016
odorless
Odor threshold:
No information available.
pH-Value:
4 (50 g/l; 20°C)
Melting temperature:
Boiling temperature:
not determined
Flash point:
not applicable
Evaporation rate:
not applicable
Flammability (solid, gas):
not flammable
Upper explosion limit:
not determined
Lower explosion limit:
not determined
Vapor pressure:
10 hPa (20°C)
Vapor density:
No information available.
Density:
2.28 g/cm3 (20°C)
Solubility in water:
288 g/l
Coefficient of variation (nOctanol/Water):
not determined
Auto-ignition temperature:
not determined
Decomposition temperature:
Splitting of the water of crystallization of the pentahydrate:
30°C (splitting of 2 waters)
110°C (splitting of further 2 waters of crystalliza tion)
250°C, splitting of the water of crystallization of the monohydrate
Viscosity, dynamic:
not applicable
Explosive properties:
Product does not present an explosion hazard.
Oxidizing properties:
Bulk density:
9. 2.
Further Information
Solubility in solvents:
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
64211
Copper-II-Sulfate-5-Hydrate
Page
Revised edition: 15.02.2014
Version: 101
7
Printed: 20.04.2016
Viscosity, kinematic
Burning class:
Solvent content:
Solid content:
Particle size:
Other information:
10.
Stability and Reactivity
10.1.
Reactivity
Stable if used according to specifications.
Loss of water of crystallization when heated.
10.2.
Chemical Stability
Stable if used according to specifications.
10.3.
Possibility of Hazardous Reactions
10.4.
Conditions to Avoid
Conditions to avoid:
Thermal decomposition:
Thermal decomposition beween 110-250°C: successive loss of
crystal water up to the water-free (anhydrous) product (colorless).
Thermal decomposition above 500°C: release of sulfu r dioxide.
10.5.
Imcompatible Materials
None known.
10.6.
Hazardous Decomposition Products
None known.
Contact of aqueous solutions with various metals (iron, zinc,
aluminium, ect.): heavy corrosion, formation of sulphur oxide
gases.
10.7.
Further Information
11.
Toxicological Information
11. 1.
Information on Toxicological Effects
Acute Toxicity
LD50, oral:
300 mg/kg (rat)
LD50, dermal:
No information available.
LC50, inhalation:
No information available.
Primary effects
Irritant effect on skin:
Slight irritant effect.
Irritant effect on eyes:
Slight irritant effect
Inhalation:
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
64211
Copper-II-Sulfate-5-Hydrate
Page
Revised edition: 15.02.2014
Version: 101
8
Printed: 20.04.2016
No information available.
Ingestion:
Harmful if swallowed.
Sensitization:
No sensitizing effects known.
Mutagenicity:
No data available.
Reproductive toxicity:
No data available.
Cancerogenity:
No data available.
Teratogenicity:
No information available.
Specific target organ toxicity (STOT):
No data available.
Additional toxicological information:
12.
Ecological Information
12. 1.
Aquatic Toxicity
Fish toxicity:
LC50: < 1 mg/l (96h, fish)
Daphnia toxicity:
Bacteria toxicity:
Algae toxicity:
12. 2.
Persistency and Degradability
Method is not applicable for inorganic substances.
12. 3.
Bioaccumulation
No information available.
12. 4.
Mobility
No data available.
12. 5.
Results of PBT- und vPvP Assessment
The contents of the preparation do not comply with the criteria for
the classification as PBT or vPvB.
12. 6.
Other Adverse Effects
Water hazard class:
Harmful for fish and bacteria.
Behaviour in sewage systems:
Further ecological effects:
Very toxic for water organisms.
AOX Value:
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
64211
Copper-II-Sulfate-5-Hydrate
Page
Revised edition: 15.02.2014
13.
Disposal Considerations
13. 1.
Waste Treatment Methods
Version: 101
9
Printed: 20.04.2016
Product:
Dispose of according to official national and local regulations.
European Waste Code (EWC):
Uncleaned packaging:
Dispose of according to official local regulations.
Waste Code No.:
14.
Transport Information
14. 1.
UN Number
ADR, IMDG, IATA
14. 2.
14. 3.
14. 4.
14. 5.
3077
UN Proper Shipping Name
ADR/RID:
UMWELTGEFÄHRDENDER STOFF, FEST, N.A.G. (Kupfer(II)-sulfat)
IMDG/IATA:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Copper-sulphate)
Transport Hazard Classes
ADR Class:
9
Hazard no.:
9
Classification code:
M7
Tunnel no.:
E
IMDG Class (sea):
9
Hazard no.:
9
EmS No.:
F-A,S-F
IATA Class:
9
Hazard no.:
9
Packaging Group
ADR/RID:
III
IMDG:
III
IATA:
III
Environmental Hazards
Labelling according 5.2.1.8 ADR/RID: fish and tree
Labelling according 5.2.1.6.3 IMDG: fish and tree
Labelled with "P" according 2.10 IMDG: yes
14. 6.
Special Precautions for User
14. 7.
Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code
14. 8.
Further Information
15.
Regulatory Information
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
64211
Copper-II-Sulfate-5-Hydrate
Page
Revised edition: 15.02.2014
15. 1.
Version: 101
10
Printed: 20.04.2016
Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture
Water hazard class:
2, hazardous for water
Local regulations on chemical accidents:
Employment restrictions:
The employment restrictions for young workers in accordance with
the Youth Employment Protection Law (94/33/EC) are to be
observed.
Restriction and prohibition of application:
Technical instructions on air quality:
15. 2.
Chemical Safety Assessment
A Chemical Safety Assessment has not been carried out for this
product.
15. 3.
Further Information
16.
Other Information
This product should be stored, handled and used in accordance
with good hygiene practices and in conformity with any legal
regulations. This information contained herein is based on the
present state of knowledge and is intended to describe our product
from the point of view of safety requirements. It should be
therefore not be construed as guaranteeing specific properties.