PS Geochemical Exploration in Northern South America: Recent Successes from Venezuela, Colombia, and Peru* Dietmar Schumacher1 Search and Discovery Article #30287 (2013)** Posted October 29, 2013 *Adapted from a poster presentation given at AAPG International Conference and Exhibition, Cartagena, Colombia, September 8-11, 2013 **AAPG©2013 Serial rights given by author. For all other rights contact author directly. 1 E&P Field Services, USA, France, and Malaysia ([email protected]) Abstract Detailed geochemical and research studies document that hydrocarbon microseepage from petroleum accumulations is common, is predominantly vertical (with obvious exceptions in some geologic settings), and is dynamic (responds quickly to changes in reservoir conditions). Since microseepage is nearly vertical, the extent of an anomaly at the surface can approximate the productive limits of the reservoir at depth. Furthermore, the detailed pattern of seepage can reflect reservoir heterogeneity, discriminate between charged and uncharged compartments, and identify areas of bypassed pay. Results of recent microbial and soil gas surveys in Venezuela, Colombia, and Peru establish the value of hydrocarbon microseepage data for high-grading prospects and aiding field development projects. These surveys were conducted in the Eastern Venezuela basin, the MaracaiboCatatumba basin in western Venezuela, the Guajira and Cesar Rancheria basins in northern Colombia, the Middle Magdalena Valley basin in central Colombia, and the Lancones basin in Peru. Results from the underexplored Lancones basin identified structures that warrant additional study due to strong hydrocarbon indications. The Guajira survey documented previously unrecognized oil potential in a basin known only for its biogenic dry gas. Results from eastern Venezuela and Cesar Rancheria successfully discriminated prospects on basis of probably hydrocarbon charge. Surveys over two old oil fields in western Venezuela and in the Middle Magdalena Valley identified bypassed pay and several new drilling opportunities. High-resolution microseepage surveys offer a flexible, low-risk and low-cost environmentally friendly technology that not only complements traditional geologic and seismic data, but add value to such data. Properly integrated with other exploration data, their use has led to discovery of new reserves and drilling fewer dry or marginal wells. Geochemical Exploration in Northern South America: Recent Successes From Venezuela, Colombia, and Peru Dietmar (Deet) Schumacher, E&P Field Services -- USA, France, and Malaysia ABSTRACT Detailed geochemical and research studies document that hydrocarbon microseepage from petroleum accumulations is common, is predominantly vertical with obvious exceptions in some geologic settings), and is dynamic (responds quickly to changes in reservoir conditions). Since microseepage is nearly vertical, the extent of an anomaly at the surface can approximate the productive limits of the reservoir at depth. Furthermore, the detailed pattern of seepage can reflect reservoir heterogeneity, discriminate between charged and uncharged compartments, and identify areas of bypassed pay. Results of recent microbial and soil gas surveys in Venezuela, Colombia, and Peru establish the value of hydrocarbon microseepage data for high-grading prospects and aiding field development projects. These surveys were conducted in the Eastern Venezuela basin, the MaracaiboCatatumba basin in western Venezuela, and Guajira and Cesar Rancheria basins in northern Colombia, the Middle Magdalena Valley basin in central Colombia, and the Lancones basin in Peru. Results from the under explored Lancones basin identified structures that warrant additional study due to strong hydrocarbon indications. The Guajira survey documented previously unrecognized oil potential in a basin known only for its biogenic dry gas. Results from eastern Venezuela and Cesar Rancheria successfully discriminated prospects on basis of probably hydrocarbon charge. Surveys over two old oil fields in western Venezuela and in the Middle Magdalena Valley identified bypassed pay and several new drilling opportunities. High-resolution microseepage surveys offer a flexible, low-risk and low-cost environmentally friendly technology that not only complements traditional geologic and seismic data, but add value to such data. Properly integrated with other exploration data, their use has led to discovery of new reserves and drilling fewer dry or marginal wells. BASICS OF HYDROCARBON MICROSEEPAGE Most oil and gas accumulations have a surface geochemical expression, unless they are greatly underpressured or contain heavy oil (API Gravity < 15) Petroleum accumulations are dynamic and their seals imperfect Hydrocarbons can move vertically through thousands of meters of strata without observable faults or fractures in relatively short time (weeks to months) Microseepage is dominated by hydrocarbon gases (C1 - C5) and aromatic hydrocarbons Microseepage is predominantly vertical except in structurally complex areas with many faults or fracture leak points Prospects with an associated microseepage anomaly are 4 to 6 times more likely to result in a commercial discovery than prospects lacking such an anomaly. MICROSEEPAGE DETECTION METHODS Due to the varied surface expressions of hydrocarbon microseepage, a number of different methods are available for detecting and mapping hydrocarbon microseepage. Some of these methods are surface geochemical methods, some are microbiological, and some are non-seismic geophysical methods. MICROSEEPAGE MODEL Halo Apical Halo Anomaly GEOCHEMICAL Anomalous Surface Concentrations Carbonate Precipitation Oxidizing Zones Pyrite Precipitation High Polarization Anomaly also sulphur, pyrrhotite greigite, uranium, etc. Bacterial Degradation of Hydrocarbons Light Hydrocarbons Seep Upward from Trap Creating a Reducing Zone GEOPHYSICAL High Resistivity Anomaly Reducing Zones Magnetic Anomaly Low Resistivity Anomaly Seismic Velocity Anomaly Gas Oil Water Remote sensing, satellite imagery analysis. Detects hydrocarbon-induced alteration of soils and sediments Aeromagnetics, micromagnetics. Detects seep-induced magnetic anomalies in shallow subsurface Soil gas, acid extracted soil gas, fluorescence. Measures concentration and composition of hydrocarbon gases and aromatic hydrocarbons in soils Microbiological. Measures concentration and distribution of hydrocarbon-utilizing bacteria Biogeochemical, geobotanical. Measures trace elements and vegetation stress due to hydrocarbon leakage Survey Design Considerations Sampling Strategy - Survey Design Survey Objectives Target Size, Shape Geologic Setting Topography, Vegetation Logistical Considerations Ability to Sample Along, Between Seismic Lines Geologic Analogs for Calibration Permitting; Environmental Issues Prior Experience Data Integration PANEL 1 MOST & SSG Anomalies N 1790000m H -30C1 A -29C1 -28C1 C1 -11 -27WB C1 -7A -5A -32 WB26 WB -25C1C1 C1 -23 -24 -33 C1 C1 C1 -22 C1 -34 C1 -21 1 C1-3) G-Ballena-1 (C2 -35 -20 C1 C1 G-2 -19 -36 G-3 C1 C1 G-4 -18 -37 C1 G-11 C1 G-5 -17 G-6 C1 G-10 -38 C1 G-7 -16 C1 -39 G-8 C1 -15 C1 -14 G-9 -40 C1 C1 N 1785000m N 1780000m C1 -12 C1 C1 N 1775000m -13 C1 C1 -45 C1 -46 C1 -47 C1 Rancheria-2 C1 -5 C1 C1 N 1765000m C1 -3 -2 -1 C1 1K-4 -1 -5 2K1K -7 1K-6 1K 1K-8 -2 2K -3 2K B-1 L-1 -4 2K B-2 -9 1K 1K-10 -5 2K -6 2K -7 2K L-2 L-3 B-4 L-4 B-6 -11 1K 1K-12 -13 1K -14 1K B-5 X X X 2K 1K 3K E N 1750000m -15 1K 1K-161K-17 -18 1K 1K-19 0A K-3 -209A A 1KK-2 1-1 -21 A 8A -227A AL1KK-2 1-2 1K AK-2 -236A ALA 1-6 1KK-2 -245A ALA 1KK-2 1-3 AL1-4 AL A -25 4A 1K K-2 3A -26 AL1-5 1K K-2 2A -27 Almirante 1K K-2 L-5 Aruchara-2 N 1740000m 0A S-2 9A S-1 8A 3A S-1 L-2 7A 4A S-1 L-2 6A S-1 5A 5A L-2 S-1 6A 4A L-2 S-13A 7A S-1 L-2 2A 8A S-1 L-2 9A A L-2 0A S -11 A L-3 SA-10 1A L-3 2A S-9 3A L-3 L-3 4A 5A A 6A L-3 L-3 S-8 9A 0A 1A 2A L-3 L-37A 8A -3A-2AA-1A 4A 5A L-3 L-3 L-4 L-4 L-4 L-43A SESES-7 L-4 L-4 L-46A 7A SE A8A A A L-4A-1 9A L-4A-2 S-6 L-4A-3A0A A 1A A L-5A-4 L-5 A2A S-5 A-5 L-5A-6A3A A L-5A-7A4A S-4 L-5 A5A A A-8 L-5 A6A S-3 A-9 L-5 0A 7A A A-1 8A2A L-5A-11A S-2 9A 0A 1A 5A 3A4A 4A 8A 5A 9A 7A L-5A-1 2A 6A A 6A 0A 7A 1A 8A 2A 3A 9A 3A 4A 5A 6A L-5 L-6 L-6A-1 A-1A-1 L-6A-1 L-6A-1 L-6A-1 7A 8A 9A0A L-6A-2 L-6A-2 L-6A-2 S-1 L-6A-1 L-6A-2 A-2 A-2A-2 A-2 A-2 A-2A-3 A -6A SN -5A SN -4A SN -3A SN -2A SN -1A SN B N 1735000m C N 1730000m I K 4A L-1 5A L-1 6A L-1 7A L-1 8A L-1 9A L-1 0A L-2 1A L-2 2A L-2 N 1745000m 1A U-3 0A U-3 9A U-2 8A U-2 7A U-2 A U-265A U-2 4A U-2 3A U-2 A U-22 1A U-2 0A AF-2 A A U-2 9A AF-3 F-5F-4 U-1 A 8A A F-7 U-17A F-8 A U-1 0A 1AF-9 7A6A 5A 3A2AF-1 3A2A1A0A 9A F-1 F-2 AB 6A F-2 F-2 F-2F-1 F-1 F-1 F-1F-1F-1 AB5A U-2 U-1 5A U-1U-1 A F-2 U-14 3A U-1 2A 6L-1A U-1 1A 6L-2A U-1 21AB -1A 0A M-3A AB WM -2A U-1 A-3A 6L 20 AB -51 M199A WMWM 1K U-9 6L-4A -52 MF-3 A AB 1K 181A -53 -5A U-8Maicao-1 MF-4AB A 1K 6L 17 -54 U-7 M-AB 1K 3A -55 A 6L-6A 16 1K 1K-56 F-4 U-6 A M15AB 4 6A A -57 M1K 1K-58 -59 AB F-4M6L-7A 5A58 U-5 F-4 F-4A 1K A M-14 -60 57 6L-8A 1K 1K-61 -62 U-4A AB M-A 1K -63 56 M-13 U-3 A 6L-9A 1K -64 AB M- A A 1K -65 U-2A M-12 M-55 1K -66 6L-10 A 1K 1K-67 -68 U-1 1K -69 6L-11 A 1K 1K-70 7A 6A 6L-12 Z-1Z-1Z-15A4A 3A 2A A Z-1Z-1Z-1 1A 0A A A 6L-13 Z-1Z-1Z-9 A A A Z-8Z-7Z-6 A A M-A54 53 M-A Z-5Z-4 A Z-3Z-2A A M-A52 Z-1 9AB A51 M50 MM-A AB M-A49 M-10 M-A48 11AB MM-47 46A M-A M-A45 M-A44 43 M-A 42 M- A M-41 40A M39A M38A M- A M-A37 A M-36 M-35 34A M- A M-33 32A M- A 31 MA saure-1 M-30 29A MA 28 M27A M-A 26 M-A M-A25 1AB 24 M-A M23 M-A 2AB M-A22 MB 21 Guaitapa-1 M20A M-3A B M-A 4A MB M-19 18A M-5A MA B A 17 MM-6A A 16 A MA 14 B M-15 M-A13MA 12 M-7AB A MM-11 M-8A M-10 9A A 3A -14 2A 1A 1-1 0A PF 1-1 1-1 PF PF1-1PFPF 5A 1-8AA 1-1 PF1-9 PF PF A 1-7 Epehin-1 PF A 1-6 PF A 1A -28 0A 9A 1K K-2 -29 1-5 -30 1K PF A K-2 1K 8A 7A K-1 -31 1-4 1K -32 -33 K-1 K-1 6A PF A 1K 1K 5A K-1 -34 1-3 K-1 1K K-14A -35 3A PF A 1K K-1-36 1K K-12A -37 1-2 -38 1K K-11A PF A 1K K-10A A-40 1-1A 1K-39 K-9 PF 1K K-8 -41 A 1K K-7 -42 A 1K K-61K-43 A -44 A -45 A -46 A K-5 A 1K K-41K K-31K K-21K-47 K-11K-481K-49 -50 1K -8 2K -9 2K -10A 2K A -11 2K -12A A -28 2K -13 A 2K 2K -14 -29 2K A Tinka-12K-15 A 2K -30 3 2K -16 -24 2K -17A-18 -19 -31 -212K-222K-2 2K -25 -26 -27 2K2K-20 2K 2K 2K 2K 2K 2K 2K -32 2K -33 2K -34 2K Aruchara-1 L-6 A B-7 A L-7 A B-8 A L-8 A B-9 A L-9 0A B-1 0A L-1 1A B-1 1A L-1 2A B-1 2A L-1 3A B-1 3A L-1 4A B-1 N 1755000m -50 F B-3 N 1760000m -48 -49 C1 -4 C1 C1 -2 1K -3 1K -41 -43 -44 C1 G -1 1K GUAJIRA BASIN-BAJA GUAJIRA AREA NORTHERN COLOMBIA METHANE CARBON ISOTOPES sample S-1A -57.1 sample A-26A -50.9 sample A-27A -45 sample A-29A -26.8 sample A-30A -28.1 -50.6 sample M-5AB -42 C1 -11 -10 C1 -9 C1 -5A WA -4A WA C1-8 -3A -2A WA -7 WA C1 -1A WA -6 Riohacha-1 C1 N 1770000m -31 J D AAA -12 -11 -10 -9A -8A -7A -6A -5A -3A -4A -2A -1A -6A-5A-4A SO SO SO SO SO SO SO SO SO SO SO SESESE SO MM-8A M-7A M-6A 4A 5A M- MM-3A M-2A M-1A Sorpresa-1 Manantiales-1 2A 1A4A A-3 A-3 A-3 3A A-3 6A A-3 8A A A-3 E-1 N 1725000m Sistema de fallas de OCA N 1720000m E 1120000m E 1125000m E 1130000m E 1135000m E 1140000m E 1145000m E 1150000m E 1155000m E 1160000m E 1165000m 0 Km E 1170000m 2 Km 4 Km E 1175000m 6 Km E 1180000m E 1185000m E 1190000m E 1195000m E 1200000m E 1205000m E 1210000m E 1215000m E 1220000m 8 Km Geologic Setting The Guajira basin occupies the southern part of the Guajira Peninsula in northern Colombia. Exploration targets are primarily of Early Miocene age, but the area may also have potential in older reservoirs (Eocene, Oligocene, Cretaceous). Existing production in the Guajira basin is biogenic dry gas. No oil or thermogenic gas has been discovered in the basin to date. Survey Objectives The objectives of this reconnaissance survey are: To determine if a petroleum system for oil and thermogenic gas exists in the basin. To evaluate the magnitude and extent of the microseepage anomalies. To establish the composition of the migrating hydrocarbons (oil, condensate, gas). Guajira Basin, Northern Colombia Ethane (C2) vs. Propane (C3) / Sorbed Soil Gas Composition Geochemical Lead / Hydrocarbon Microseepage Survey / Guajira Basin, Northern Colombia Line B / Sum (C2-C4) 50.00 140.00 40 FREQUENCY Oil 120.00 C2 30 Tinka-1 40.00 / C3 =2 Condensates 20 Propane (C3), ppm Sum (C2-C4), ppm 100.00 30.00 Aruchara-1 20.00 10 Gas 80.00 0 0 2 4 6 OIL 8 ETHANE / PROPANE 60.00 OIL & GAS 40.00 10.00 Sample Locations 2K-27 2K-26 2K-25 2K-24 2K-23 2K-22 2K -31A 2K -20A 2K -19A 2K -17A 2K -18A 2K-21A 2K -15A 2K -16A 2K -8 2K -9 2K -13A 2K-14A 2K -7 2K-12A 2K -5 2K -6 2K-11A West 2K-10A 2K -3 2K -4 2K -2 1K -4 2K -1 1K -2 1K -1 0.00 1K -3 20.00 0.00 East 0.00 50.00 500.00 100.00 150.00 Geochemical Lead / Hydrocarbon Microseepage Survey / Guajira Basin, Northern Colombia Line C / Sum (C2-C4) BIOGENIC GAS C1/(C2+C3) Sopresa-1 200.00 CONDENSATE 10.00 L E OIL I Guajira Basin, Colombia Geochemical Lead Near Previously Drilled Hole Isotopic Composition of Sorbed Soil Dry Gas SO-1A SO-4A SO-7A SO-10A SE-5A SO-4M SO-7M SO-10M S-1A L-68A L-65A L-64A A-33A A-32A A-28A A-23A A-20A L-62A A-14A L-59A A-11A A-8A L-56A A-5A L-53A A-2A L-50A L-32 L-47A L-44A L-41A L-38A L-29A L-35A L-26A L-23A L-20A L-17A L-14A H Sample Locations 350.00 Santa Ana-1 East A C D E F G H I J K SINGLE DRY GAS MIXED DEEP GAS 100.00 West 300.00 Guajira Basin, Northern Colombia 100.00 300.00 0.00 250.00 Hydrocarbon Composition, Sorbed Soil Gas C1/(C2+C3) vs. C2/(C3+C4) 1000.00 400.00 Sum (C2-C4), ppm 200.00 Ethane (C2), ppm Ethane - Propane Correlation for Sorbed Soil Gas Geochemical Lead Near Previously Drilled Dry Holes C A J K G LEGEND Anomaly A Southwest of Sorpresa-1 Sorpresa-1 Tinka-1 Aruchara Northeast of Riohacha-1 West of Ballena-1 Between Epehin-1 & Maicao-1 Near Manantiales-1 Z1A, Z2jA ALTERED F D SOURCE ROCK 1.00 0.00 1.00 2.00 C2/(C3+C4) 3.00 4.00 5.00 Hydrocarbon Composition of Selected Microseepage Anomalies SURVEY LOGISTICS The surface geochemical reconnaissance survey was conducted along roads and trails across an area of 5400 square kilometers. Samples were collected at 250-1000 meter intervals. Four 2-man crews collected samples from 598 locations in 12 days. Microbial samples were collected at 20 cm depth; sorbed soil gas samples were collected at a depth of one meter. Guajira Basin, Colombia: Isotopic Composition of Sorbed Soil Gas Guajira Samples 1. 2. 3. 4. 5. 6. S-1A A-26A A-27A A-29A A-30A M-5AB Genetic characterization of natural gases by compositional and isotopic variations (Schoell, 1983). Figure shows relative concentrations of C2+ hydrocarbons in relation to carbon isotopic composition of methane. Arrows Ms and Md indicate expected compositional changes due to shallow and deep migration, respectively. B represents biogenic gas, M is mixed thermal and biogenic gas. To represents oil-associated gas, Tc is gas associated with condensate, and TT represents thermal dry gas derived from oil-prone (m) or humic (h) source rocks. Numbers 1-6 identify Guajira basin sorbed soil gas samples. Four of the samples represent oil-assiciated methane, however, samples 4 and 5 may represent coal-derived gases. 6 Legend 5 X B X 4 Biodegrated North Sea Oils I X R1 3 3 Ring/2-Ring Carbonate Source Oil North Sea Clastic Marine Shale C X 2 Nonmarine Lacustrine / Deltaic / Paralic Sources A X X X 1 0 0 10 20 30 40 50 60 API Gravity A crossplot of API Gravity against fluorescence parameter R1, approximate equal to the 3-Ring/wRing intensity ratio, for oils derived from a variety of source types (Barwise and Hay, 1996). The red dashed line is the North Sea API Gravity versus R1 correlation for non-degraded oils. Letters refer to specific microseepage anomalies in the Guajira basin. The data suggest that anomalies A and C (Oca fault zone) and anomaly F (Aruchara) may be associated with higher gravity oils than anomalies B (Oca fault zone) and I (central area). CONCLUSIONS The results of this reconnaissance surface geochemical survey of the Guajira basin support the following conclusions: One, possibly two, petroleum systems exist in addition to the previously known biogenic gas hydrocarbon system. Oil and oil-associated gas generation and migration have occurred in the basin. The presence of oil and associated thermogenic gas is documented by sorbed soil gas data, carbon isotopic composition of methane and ethane, fluorescence analysis of soil extracts, and gas chromatography of selected solvent extracts. The principal microbial and soil gas anomalies occur in the southwestern and south-central parts of the basin. Seepage is especially strong near the Oca fault zone. The survey identified a number of geochemical leads that warrant additional geological, geophysical, and geochemical evaluation. PANEL 2 QLC BLOCK, EASTERN VENEZUELA BASIN - PROSPECT EVALUATION 25 N 1083000 m 70 167 3DL-23 5 3DL-25 N 1081000 m NL-113 156 3DL-22 133 74 NL-121 121 3DL-21 NL-114 122 3DL-20 103 3DL-24 102 125 208 NL-101 NL-102 209 126 NL-131 151 197 93 NL-122 NL-115 N 1080000 m 191 NL-116 222 NL-134 NL-142 93 142 NL-143 NL-135 N 1079000 m NL-124 50 NL-118 146 149 102 NL-136 NL-126 65 NL-145 NL-137 CPZ-8S 65 31 NL-107 130 NL-127 NL-120 109 124 199 NL-146 NL-138 NL-128 V6-37 115 143 113 109 NL-148 NL-130 V3-10 STR-9 88 21 109 V3-9 V4-18 149 10 NL-149 N 1076000 m 76 NL-150 V3-8 96 NL-151 V4-17 141 V5-28 STR-10131 148 NL-60 145 NL-61 NL-75 NL-76 145 113 V9-34 LVF-2 STR-11 68 V5-27 LVF-19 152 LVF-18 V7-32 55 LVF-17 LVF-16 180 NL-34 NL-63 75 211 NL-35 135 280 120 VZ-29S NL-95 59 NL-36 66 NL-78 V5-26 V6-30 71 151 145 73 V3-7 V4-16 V5-25 V6-29 V7-29 V7-30 NL-85 83 64 16 61 NL-100 NL-97 460 m62 CLIFF-N1 V9-N-CLIFF CLIFF-N2 39 V9-29 95 NL-6 34 NL-18 192 36 NL-19 94 67 V12-30 V11-30 NL-7 NL-29 125 NL-38 67 CLIFF-N4 177 NL-30 90 97 VZ-103S V3-6 NL-152 N 1074000 m 25 104 NL-153 V3-5 VZ-102S N 1073000 m 104 111 V4-15 V5-24 73 V6-28 34 VZ-30S 72 120 V4-14 V5-23 102 GOS-1A GOS-1 78 V3-4 44 133 V3-3 V4-12 V5-21 64 131 V3-2 V4-11 V6-27 112 75 V5-22E V4-13 82 16 41 V7-28 V8-28 NL-20 29 24 25 V13-NCL 35 36 6 V11-29 V12-29 V13-29 V14-29 V15-29 167 38 V8-27 V6-25 V7-26 51 49 35 V9-27B V9-27A 63 117 V8-26 V9-26 UTM Northing (meters) V12-28 V9-25 V8-25 VG-2S 64 V11-27 38 V13-28 60 25 V12-27 V13-27 24 41 V14-28 V15-28 37 V14-27 13 NL-9 48 V16-29 28 V16-28 70 V17-28 48 23 48 V16-27 V17-27 L1-31 65 V15-27 61 51 44 54 33 54 58 39 17 V11-26 V12-26 V13-26 V14-26 V15-26 V16-26 V17-26 L1-30 79 49 19 56 V11-25 V12-25 V13-25 33 V14-25 38 60 14 33 V15-25 V16-25 L1-29 V17-25 V10-25 171 49 56 101 21 V5-20 V6-24 V7-24 V8-24 V9-24 72 105 62 47 140 41 65 V3-1 V4-10 V5-19 V6-23 V7-23 V8-23 V9-23 3 L2-31 V10-27 V10-26 34 400 m V10-24 N 1072000 m 87 V11-28 50 VG-1S 93 40 V7-25 46 33 V10-28 83 V7-27 124 V6-26 NL-8 92 NL-39 V10-29 67 70 V9-28A V9-28 32 25 V12NCLCLIFF-N3 37 V10-30 30 NL-5 99 NL-21 63 NL-65 VZ-27S 40 30 NL-17 NL-37 55 53 54 NL-4 150 NL-22 34 NL-16 67 NL-28 44 44 75 NL-96 NL-15 NL-27 147 NL-84 94 65 NL-99 NL-23 85 NL-51 LA VIEJA DEEP 110 128 78 NL-26 NL-50 70 14 NL-3 76 NL-14 NL-49 NL-64 37 V7-31 V6-31 174 NL-48 130 NL-112 139 NL-13 93 NL-25 56 V7-33 109 28 NL-2 NL-24 120 LVF-1 82 VZ-26 NL-111 67 NL-33 115 VZ-25 NL-62 209 105 VZ-21 VZ-22 65 VZ-18 80 LVF-3 VZ-3 VZ-13 VZ-6VZ-28 132 VZ-23 LVF-4 VZ-11 LVF-5 LVF-14 LVF-22 VZ-24 VZ-10 152 166 52 VZ-20 145 VZ-5 VZ-4VZ-17 103 73 LVF-6 VZ-1 71 VZ-19 VZ-14 LVF-13 42 V9-33 LVF-21 171 V8-33 VZ-7 VZ-12 LVF-8 LVF-7 133 112 127 VZ-15 LVF-9 VZ-9 152 LVF-10 LVF-12 LVF-20VZ-2 NL-77 VZ-8 LVF-11 VZ-16 74 88 LVF-23 135 123 NL-47 79 120 120 NL-1 98 NL-12 91 85 142 67 132 V8-34 LVF-15 126 120 NL-11 211 NL-32 129 NL-74 V9-35 NL-98 NL-31 74 NL-46 81 V9-36 NL-94 114 141 NL-45 NL-59 98 320 m 120 NL-110 110 59 V9-37 92 91 VZ-104S67 N 1075000 m 125 NL-72 NL-73 NL-93 96 NL-10 NL-44 68 NL-58 146 3DL-1 83 STR-7 STR-6 132 V10-39 92 101 81 V5-29 129 V12-40 124 V9-38 114 138 81 NL-129 NL-139 NL-147 STR-5 127 NL-57 NL-92 3DL-2 161 NL-109 157 105 185 NL-91 118 3DL-3 165 V5-30 N 1077000 m V6-38 V12-41 138 NL-43 NL-71 113 3DL-4 113 159 NL-56 V9-39 V5-31 80 V12-42 158 NL-83 104 V5-32 219 58 NL-42 119 NL-70 V9-40 107 NL-90 171 89 143 81 V5-33 65 157 NL-119 3DL-12 3DL-13 72 NL-108 V12-43 152 NL-69 198 3DL-5 146 3DL-14 139 186 NL-41 49 NL-55 NL-82 117 3DL-15NL-106 247 NL-125 NL-144 116 118 NL-40 70 45 87 3DL-16 NL-105 NL-117 NL-81 131 NL-89 138 3DL-6 217 90 49 69 186 N 1078000 m 102 NL-123 104 NL-54 NL-68 128 NL-88 158 3DL-7 173 V11-44 V10-44 42 90 NL-80 3DL-11 259 NL-104 91 43 NL-53 84 118 NL-87 150 NL-103 131 3DL-17 118 146 3DL-18 3DL-19 66 NL-132 CPM-1X NL-133 135 3DL-9 3DL-8 164 132 31 84 NL-67 NL-86 144 3DL-10 143 NL-140 NL-141 NL-52 NL-66 45 NL-79 99 N 1082000 m 15 45 91 V12-24 V11-24 43 29 V14-24 V13-24 68 77 44 78 V11-23 V12-23 V13-23 V14-23 96 31 54 L1-28 73 V17-A24 V17-B24 46 V15-24 V16-24 57 V15-23 30 L2-30 48 39 L2-29 L3-29 104 80 L2-28 L3-28 37 49 25 132 29 V16-23 V17-23 L1-27 L2-27 L3-27 L5-28 N 1071000 m 37 37 63 96 56 V5-18 V6-22 V7-22 V8-22 V9-22 59 25 69 V4-8 V5-17 V6-21 52 31 V4-7 V5-16 87 N 1070000 m V4-6 N 1069000 m 230 220 210 200 190 180 170 160 150 460140 m 130 120 110 CM-1052 100 90 80 70 60 50 40 30 SCE-1 20 10 N 1066000 m N 1065000 m N 1064000 m N 1063000 m N 1062000 m 36 90 71 73 67 75 50 30 V10-21 V11-21 V12-21 V13-21 V14-21 V15-21 V16-21 V17-21 L1-25 L2-25 L5-25 20 79 46 54 V9-20 V10-20 V11-20 V12-20 34 V8-19 V7-19 V9-19 64 60 49 47 V5-14 V6-18 V7-18 V8-18 18 99 30 V10-19 V11-19 V12-19 70 59 55 22 V9-18 V10-18 V11-18 V12-18 68 V13-20 360 m 44 V13-19 39 V13-18 71 33 36 49 42 26 75 61 89 49 V5-13 V6-17 V7-17 V8-17 V9-17 V10-17 V11-17 V12-17 V13-17 43 115 48 43 V5-12 V6-16 V7-16 60 63 V4-2 V5-11 24 71 V4-1 V5-10 V8-16 52 77 V6-15 V7-15 50 46 V6-14 45 69 V5-9 V6-13 45 V6-12 38 V10-16 20 100 V8-15 V10-15 V11-15 33 V8-14 V9-14 45 13 52 V8-13 V9-13 47 16 V7-12 36 V10-14 V12-B16 44 19 V12CLIFF V12-15 VAC-1 29 V11-14 38 42 V10-13 V11-13 99 26 134 V11-16 122 V9-15 41 V7-14 28 V9-16 75 V7-13 52 92 V5-8 V10-12 65 V14-19 39 41 93 V15-17 V14-N16 101 54 V14-16 V15-16 57 V14-15 63 21 60 V16-19 L1-23 V17-19 120 V15-18 31 23 V17-20 L1-24 30 V16-20 V15-19 92 3 24 76 V15-20 V14-18 V14-17 18 59 742 42 L1-22 V17-18 V17-A18 V16-18 37 43 20 V16-16 V17-16 L1-20 52 29 40 L3-24 L4-24 L5-24 99 L2-23 50 55 L5-22 25 12 L4-21 12 66 L2-20 L3-20 L5-23 45 L4-22 80 L3-21 L2-21 77 L4-23 L3-22 99 280 m 62 82 L3-23 42 L2-22 60 36 V17-17 L1-21 11 V16-17 L5-26 45 L2-24 L5-21 49 28 L5-20 L4-20 62 48 25 31 4 52 30 V16-15 V17-15 L1-19 L2-19 L3-19 L4-19 L5-19 V15-S15 57 33 V13-14 50 64 V12-12 V11-12 28 V14-20 V13-15 V12-14 V12-13 73 30 V13-16 78 124 V14-14 V15-14 43 51 32 V13-13 V14-13 V15-13 22 25 38 49 V16-14 V17-14 L1-18 L2-18 33 36 71 L3-18 L4-18 L5-18 81 31 22 15 40 45 31 V16-13 V17-13 L1-17 L2-17 L3-17 L4-17 L5-17 22 93 23 42 29 70 20 32 37 29 58 V13-12 V14-12 V15-12 V16-12 V17-12 L1-16 L2-16 L3-16 L4-16 L5-16 VACA CAPAYA V9-12 V8-12 L5-27 117 V15-22 43 13 64 24 L2-26 22 V14-22 63 V8-20 44 65 V6-19 V9-21 26 24 V17-22 L1-26 92 V13-22 84 80 V11-22 V4-4 52 N 1067000 m 94 V7-20 V4-5 V4-3 N 1068000 m 57 V8-21 53 V16-22 51 V12-22 35 53 V10-22 VACA MERECURE 62 V6-20 72 V5-15 101 V7-21 34 78 42 L4-27 V10-23 49 V4-9 V13A-12 97 21 60 19 V5-7 V6-11 V7-11 V8-11 37 34 83 42 V5-6 V6-10 V7-10 V8-10 44 36 34 39 41 42 28 34 66 88 46 51 40 76 V9-11 V10-11 V11-11 V12-11 V13-11 V14-11 V15-11 V16-11 L1-15 V17-11 L2-15 L3-15 L4-15 L5-15 39 55 33 59 36 98 16 61 39 45 29 33 24 22 V9-10 V10-10 V11-10 V12-10 V13-10 V14-10 V15-10 V16-10 V17-10 L1-14 L2-14 L3-14 L4-14 L5-14 51 42 36 71 54 33 51 92 23 V5-5 V6-9 V7-9 V8-9 V9-9 V10-9 V11-9 V12-9 V13-9 48 8 43 73 V5-4 V6-8 V7-8 V8-8 35 65 V5-3 V6-7 50 39 V5-2 V6-6 79 21 V5-1 V6-5 21 23 V5-S1 V6-4 42 48 26 50 36 30 32 38 V15-9 V16-9 V17-9 L1-13 L2-13 L3-13 L4-13 L5-13 46 96 26 76 33 27 51 56 24 37 26 50 72 52 V9-8 V10-8 V11-8 V12-8 V13-8 V14-8 V15-8 V16-8 L1-12 V17-8 L2-12 L3-12 L4-12 L5-12 23 40 42 40 36 58 54 54 37 43 70 20 24 23 26 V8-7 V9-7 V10-7 V11-7 V12-7 V13-7 V14-7 V15-7 V16-7 L1-11 V17-7 L2-11 L3-11 L4-11 L5-11 73 42 24 29 177 148 64 82 48 53 2930 32 34 115 27 V7-6 V8-6 V9-6 V10-6 V11-6 V12-6 V13-6 V14-6 V15-6 V16-6 V17-6 L1-10 L2-10 L3-10 L4-10 L5-10 114 V7-7 440 m 73 V14-9 VZ-201S SVA-1 36 16 38 18 53 48 84 52 32 33 79 85 50 30 26 39 V7-5 V8-5 V9-5 V10-5 V11-5 V12-5 V13-5 V14-5 V15-5 V16-5 L1-9 V17-5 L2-9 L3-9 L4-9 L5-9 50 31 31 126 54 65 40 57 59 35 25 17 15 19 18 V8-4 V9-4 V10-4 V11-4 V12-4 V13-4 V14-4 V15-4 V16-4 V17-4 L1-8 L2-8 L3-8 L4-8 L5-8 21 V8-3 78 20 V9-3 V10-3 25 N 1061000 m 12 30 V8-2 V9-2 39 82V11-E3 V11-N2 35 52 61 V12-3 25 V13-3 V14-3 58 46 V16-3 V17-3 L1-7 61 69 11 V14-2 V15-2 V16-2 2 95 V17-2 L1-6 74 V14-1 5 47 91 36 V13-2 V15-3 V12-2 36 V9-1 V8-S1 64 V15-1 50 48 2 L3-7 L4-7 L5-7 36 L2-7 ISLA 62 50 53 49 L2-6 L3-6 L4-6 L5-6 61 40 16 34 V16-1 L1-5 L2-5 L3-5 93 5 V9-S1 L2-4 15 L3-4 106 51 N 1060000 m V10-2 15 V8-1 V9-S2 V8-S2 N 1059000 m N 1058000 m E 366000 m E 367000 m E 368000 m E 369000 m E 370000 m E 371000 m E 372000 m E 373000 m E 374000 m E 375000 m E 376000 m E 377000 m E 378000 m E 379000 m E 380000 m E 381000 m E 382000 m E 383000 m E 384000 m E 385000 m UTM Easting (meters) Scale 1:50000 0 km 1 km 2 km 3 km 4 km 5 km Geologic Setting The Quiamare La Ceiba (QLC) block in the Eastern Venezuela basin lies within a structurally complex zone just beyond the western edge of the prolific petroleum province known as the El Furial trend. The QLC concession is located in the Santa Rosa structural block and includes the Quiamare, La Vieja, La Ceiba, and Tacata oil fields. Production is primarily from the Milocene Oficina and Eocene Merecure formations. Heavy oil is present in the shallow reservoirs of the old La Vieja field; light oil and condensate characterize deeper reservoirs. Tacata Area: Example of Integration Between Geology and Microbial Data South Edge Tacata Field 250 North Edge Tacata Field 4 km 250 30 00 20 TAR 1 200 TAG 12 Microbial Values L17-39 L17-38 L17-37 L17-36 L17-35 L17-34 L17-33 L17-32 L17-31 L17-30 L17-29 L17-28 L17-27 L17-26 L17-25 L17-24 L17-23 L17-22 L17-21 L18-9 L17-20 L17-19 L17-18 L18-8 L18-7 L17-17 L17-16 L17-15 L17-14 L18-10 L18-8B L18-8A L18-8C L18-6 L18-5 L18-4 L18-3 L18-2 L18-1 24 00 00 0 South M icrobial Values 00 00 24 00 13 14 3000 16 Ma event TWTT (ms) Datum =+500m TAR 1 00 Sample Locations 30 00 30 North 40 00 50 30 100 50 30 0 24 00 24 Smoothed Microbial Values 12 150 100 0 00 30 30 00 200 500M West 150 Sm oothed M icrobial Values North to South microbial profile across Tacata field illustrating the strong microseepage anomaly associated with the field. The accompanying seismic section and structure map illustrate the structural complexity of the Tacata area. Survey Objectives The objectives of the QLC geochemical survey are: Determine the magnitude and lateral extent of hydrocarbon microseepage anomalies associated with the various exploration prospects, and with the La Vieja and Tacata fields. High-grade the major prospects based on their probable hydrocarbon charge. Determine the composition of the migrating and/or reservoired hydrocarbons. Identify geochemical leads that warrant further geologic and seismic study. Survey Logistics A geochemical survey was conducted over a 575 square kilometer area in the eastern half of the QLC block. Surface conditions ranged from open grassland in the eastern part of the ara to dense, almost impenetrable jungle in the west. Samples were collected at 500-1000 meter intervals in a grid pattern. Sample sites were located with hand held 12 channel Garmin GPS units. Two to three 3-man crews collected 1587 microbial samples and 200 sorbed soil gas samples in 60 days. Microbial samples were collected at 20 cm depth; sorbed soil gas samples were collected from a depth of one meter. CONCLUSIONS The results of microbial and sorbed soil gas analyses support the following conclusions: The most intense microseepage is associated with the surface expressions of the Urica fault near Urica and extending west to just north of La Vieja field. Significant microseepage anomalies are associated with the La Vieja Deep prospect and the central part of the Vaca Merecure prospect. There is no geochemical anomaly associated with the Vaca Capaya prospect. A cluster of microseepage anomalies extends E-W along the acial portion of Tacata field. The absence of a single large anomaly -- one coincident with the mapped closure -- suggests that the trap is either not fully charged, or more compartmentalized than seismic data suggest. PANEL 3 APPLICATIONS FOR FIELD DEVELOPMENT AND PRODUCTION Because hydrocarbon microseepage is predominantly vertical, the extent of the anomaly at the surface can approximate the productive limit of the reservoir at depth. The detailed pattern of microseepage over a producing field can also reflect reservoir heterogeneity and distinguish hydrocarbon-charged compartments from drained or uncharged compartments. Additionally, since hydrocarbon migration is dynamic, seepage patterns change rapidly in response to production-induced changes. Evidence for such changes are identified with detailed soil gas, microbial, and/or fluorescence surveys. When such surveys are repeated over the life of a producing field or waterflood project, the changes in seepage patterns can reflect hydrocarbon drainage. Los Manuelas Field, Western Venezuela The Los Manuelas Field is located in the southwestern Maracaibo-Catatumbo basin, and occurs on the crest of a tightly folded anticline bounded on the east side by a westdipping reverse fault. The principal reservoirs occur in the Eocene Mirador, but other reservoirs occur in the Oligocene, Paleocene, and Cretaceous. The field was discovered in 1930 and is now largely depleted. The principal objective of the microseepage survey was to determine (1) if the field has a surface geochemical expression, and (2) to document the geochemical evidence for the likely presence of bypassed pay in the old field, and (3) and the possible field extension to the north beyond the present productive limits. For comparison with the old oil field, we also acquired samples across a recently discovered and as yet undeveloped field (La Palma) nearby. Old Oil Field - Microseepage Pattern 100 75 55 Microseepage values are generally low over the old (1930) oil field, however, the presence of several well-defined microbial anomalies may indicate location of by-passed pay. Note that most of the anomalies terminate against the trapping fault at east edge of the field. The results of the microbial and sorbed soil gas analyses form document very strong hydrocarbon microseepage over the new field, and lower but still significant microseepage over portions of the Los Manuelas field. The relatively low microseepage values over the old field are believed to reflect its long production history and lower reservoir pressures. High seepage values from over the northeast portion of Los Manuelas may reflect its shorter production history and greater remaining potential. New productive wells have been drilled within several of these microseepage anomalies, one of which is illustrated on the seismic section to the right. Santa Lucia Field, Middle Magdalena Valley Basin, Colombia The Santa Lucia field is a small 3-well field situated on a faulted anticline in the Middle Magdalena Valley basin, central Colombia. The field produces 19-21 API Gravity oil and some associated gas from Lower Tertiary fluvial sands in the Esmeraldes-La Paz formations. At the time of the microseepage survey, 3 wells were producing 150-300 BOPD from depths of 2500-2600 meters. The survey area encompassed approximately 16km2, and consisted of low-lying farm and pasture land. Soil samples were collected at 250 meter intervals in a grid pattern. The objectives of the Santa Lucia microseepage survey were: Determine magnitude and areal extent of hydrocarbon microseepage anomalies associated with the oil field. Identify areas that may represent by-passed pay or leakage from an undrained reservoir compartment. Determine the composition of the migrating and/or reservoired hydrocarbons. Determine if the fault between wells SL-1 and SL-2 is a sealing fault. Correlate hydrocarbons from surface microseepage anomaly with the reservoired hydrocarbons. The results of the microbial and adsorbed soil gas analysis documented the presence of strong microseepage at a number of locations north and east of the producing wells. The most prospective microseepage anomaly occurs as a 500-800m wide zone along the eastern edge of the field, between wells SL-1 and SL-2. The data suggest that this represents by-passed oil, or possibly oil from an untested reservoir compartment. Gas chromatographic and fluorescence analysis of crude oil from the producing well were correlated with results of similar analyses performed on solvent extracts of soil from the microseepage anomaly. Chromatographic data support the conclusion that SL-1 oil is not in communication with oil from the SL-2 reservoir, and that the intervening fault is a sealing fault. Fluorescence characteristics of the crude oils independently support this conclusion and show a high degree of correlation with the soil extract data. N 1,359,000m -9.50 Map 3 Microbial Values Image Map 0 -9.50 0 INDEX MAP - SANTA LUCIA FIELD 1800000 160 -9.000 S8-17 S9-16 SANTA LUCIA-2 2040 S7-14 540 S8-16 S8-15 400 S6-15 340 360 2080 S10-11 S8-14 S9-13 S7-12 S6-14 520 300 S7-11 380 S11-11 S6-13 S7-10320 S8-12 240 PC-81-10 S6-12 2060 S6-11 500 2000 S8-11 S8-10 S6-10 S2-10 2080 300 S2-9 2020 -9.0 00 S1-7 2040 -8.5 00 S2-6 S6-8 S3-5 480 S1-4 PT-96-004 2060 S10-7 S11-7 S7-1 S1-2 S2-1 2080 S3-4A S9-3 340 360 2200 L85-130 -8.5 2680 S11-5 2100 2120 S15-7 380 S15-6 2040 S16-1 S6-2 S15-3 S16-5 S16-6 S8-1 S3-15A S3-14A S16-9 S16-10 2080 2620 260 2160 275 325 375 425 475 L85-152 S15-1 S16-7 S16-8 S6-1 2100 EG-778 2120 2600 2180 340 225 2060 S3-10A 2100S3-12A 2100 375 425 475 275 325 375 425 Wavelength (nm) S9-16 Dilution 1:1 475 25 23 20 18 15 13 10 8 5 3 0 225 475 25 23 20 18 15 13 10 8 5 3 0 225 S9-15 Dilution 1:1 0 S15-2 S3-11A 420 SL-3 60 325 275 325 375 425 Wavelength (nm) 475 45 Wavelength (nm) S16-3 S15-4 400 280S16-4 S3-13A S3-1A -8.0 00 2640 MUZANDA-1 S16-2 S15-5 S9-1 S4-1 S3-9A S3-2A 320 SL-2 75 15 2160 S15-9 S15-8 275 Wavelength (nm) 2140 300 2020 360 S15-10 2140 S3-8A S3-3A 2120 300 2660 S11-3 S11-1 S9-2 S8-2 S6-3 225 SL2 Dilution 1:200000 30 320 S11-4 2180 S10-2 S11-2 S10-1 440 S3-7A 280 N 1,349,500m N 1,349,000m 2160 00 2080 S11-6 S10-5 S10-4 S10-3 340 S4-2 S3-5A S1-1 S9-4 S8-3 S6-4 2140 S3-6A S9-5 S8-5 2160 S8-4 2120 -8.500 S2-2 N 1,350,000m S9-8S10-6 S9-7 S9-6 S8-6 S7-3 S7-2 S2-3 S1-3 260 S7-4 SL-1 460 S2-4 2060 N 1,350,500m S8-8 2000 S6-6 S3-2 S3-1 0 125 113 100 88 75 63 50 38 25 13 0 225 SL-1 90 1020 340 S11-8 S10-8 S9-9 S8-9 S7-7 S7-6 S6-7 2100 S3-3 S2-5 S1-5 PC-81-6 320 S7-5 S8-7 SANTA LUCIA-1 S3-4 S2-7 S1-6 N 1,351,000m S6-9 S3-6 S2-8 N 1,351,500m 105 400 2140 S9-10 280 -9.0 00 N 1,352,000m 360 2120 S11-9 S10-9 S9-11 2040 S7-9 S7-8 A "C" FALL 260 N 1,352,500m 120 S11-10 S8-13 S9-12 S10-10 2220 2020 SL-1, SL-2, & SL-3 NORMALIZED 380 2060 S11-12 2100 PC-81-4 2040 Tr8X8 Tr7X4 2020 320 S11-13 280 220 N 1,353,000m Tr6X8 PT-96-005 2000300 2260 S10-12 S9-14 260 -9.000 L85-152 1020 M7815 S11-16 S11-15 S11-14 S10-13 S9-15 2240 S7-13 30 2280 280 S10-17 S11-17 S10-16 S10-15 SL-2 S10-14 S6-17 S27S28 S6-16 Intensity S7-15 S9-18 0 S9-17 -8.00 S7-16 S26 15 420 260 S9-20 S9-19 S8-19 560 S7-17 S6-20 S25 240 60 Intensity S11-19 S11-18 S10-18 360 S12-1 SL-3 S7-19 S8-22 S8-21 S8-20 S7-18A S7-18 00 S6-21 -8.0 S6-19 S6-18 S24 220 2020 S9-16 S10-11 240 Fingerprinting of Santa Lucia oils suggests SL1 oil not in fluid communication with SL2 and SL3 oils. Upper figure represents a C7 Oil Transformation Star Diagram; lower figure shows Fluorescence Data 25 23 20 18 15 13 10 8 5 3 0 225 S10-11 Dilution 1:1 Intensity FALL A "A" S10-19 580S9-21 S8-23 S6-23 S6-22 2020 S23 L85-130 SL-2, S9-15, S9-16, S10-11 NORMALIZED S9-15 90 75 45 Tr1X2 Tr5 340 SL-2 120 105 Intensity S1 S7-20 S6-24 -8.500 S9 S19 S22 PC-81-8 -9.0 00 S2 S8 S18 S20 S21 PC-81-2 N 1,354,500m -9.00 0 S7 S17 N 1,355,000m 440 2300 S12-2 SANTA LUCIA-3 S30 S7-21 S10-20 S9-22240 S8-24 S29 S11-20 S6-25 S3 S16 N 1,355,500m GM000002 320 S12-3 S11-21 S10-21 S9-23 150 GM000001 Tr2 GM000003 S10-22 S8-25 S7-22 S31 S4 S6 600 S11-22 S9-24 S32 220 S5 S10 S14 N 1,353,500m 2320 S13-1 S33 S7-23 L85-128 S11 S13 S12 1800000 S15 N 1,354,000m 460 -9.500 0 1600000 Tr3X2 Tr4X2 280 S12-4 S11-23 135 2340 PT-96-006 M-11-78 1980 "B" 300 S9-25 -8.50 800000 400000 200000 1400000 LA S13-3 S13-2 S7-24 S34 10 1200000 FAL S13-4 S35 0 1000000 260 S13-5 S12-6 S12-5 S11-24 S7-25 1020 0 S12-7 S11-25 620 S9-27A S9-27 S9-26 S36 20 Intensity S37 S9-28 S9-28A S40 S39 S38 50 40 30 2000 M-78-07 2090 480 S13-6 S12-8 -8.50 80 70 800000 S14-5 240 60 N 1,356,000m Reservoir Oil Fingerprinting 640 Intensity 220 Map 3 Microbial Values Image Map.srf 1400000 BOGOTA 600000 Soil-to-Oil Correlation -9.000 120 110 100 90 00 -8.5 N 1,356,500m 00 -10.0 L-84/85-126 130 600000 N 1,357,000m 660 140 VALLEDUPAR DPTO CESAR 1000000 N 1,357,500m 1200000 N 1,358,000m 150 VALLEDUPAR 1600000 N 1,358,500m 275 325 375 425 Wavelength (nm) 275 325 375 425 Wavelength (nm) 475 Comparison of fluorescence fingerprint of SL2 oil with soil extracts from nearby seepage anomaly shows strong correlation with SL2 oil. 2120 360 280 400 2080 N 1,348,500m 380 2580 2200 300 220 2140 400 320 N 1,348,000m E 1,041,000m E 1,041,500m E 1,042,000m E 1,042,500m E 1,043,000m E 1,043,500m E 1,044,000m E 1,044,500m E 1,045,000m E 1,045,500m E 1,046,000m E 1,046,500m E 1,047,000m E 1,047,500m E 1,048,000m E 1,048,500m E 1,049,000m E 1,049,500m E 1,050,000m E 1,050,500m E 1,051,000m E 1,051,500m E 1,052,000m E 1,052,500m Scale 1:25,000 0m 500 m 1,000 m 1,500 m 2,000 m 2,500 m PANEL 4 LANCONES BASIN, PERU - RECONNAISSANCE SURVEY Geologic Setting The Cretaceous Lancones basin is one of a number of rift-related marginal basins in western South America. It is located in northwestern Peru and is bordered by the Amotape-Tahuin Massif (La Brea Mountains) on the west and volcanic arc strata on the east. Sediments in the basin are primarily of Upper Cretaceous and Cenozoic age, however Paleozoic rocks are present in the Paito area. Surface anticlines in the northern part of the basin represent potential exploration leads and prospects. Survey Objectives The objectives of this reconnaissance survey are: to determine the presence of a petroleum system for oil and/or thermogenic gas. to high-grade the major anticlines and other exploration leads on the basis of likely hydrocarbon charge. to document the composition of the migrating hydrocarbons (oil, condensate, or dry gas). to identify geochemical leads that warrant geologic and seismic evaluation. Survey Results The results of this reconnaissance geochemical survey: BPZ Lancones Project / Northern Peru Legend C1/(C2+C3) vs. C2/(C3+C4) / Sorbed Soil Gas Analysis 1000.00 Totoras Anticline Jabomillos Anticline Galinazos document the presence of at least one, possibly two, petroleum systems in the basin. Anticline 2 Anticline 3 The Gap Abejas Well Olympic Gas Field BIOGENIC GAS 100.00 C1/(C2+C3) identified several anticlines or portions of anticlines with strong hydrocarbon microseepage anomalies. SINGLE DRY GAS MIXED DEEP GAS CONDENSATE 10.00 the composition of the migrating hydrocarbons ranges from thermogenic dry gas to gas associated with light oil and/or condensate. OIL ALTERED SOURCE ROCK 1.00 0.00 1.00 2.00 C2/(C3+C4) 3.00 4.00 5.00 SUMMARY AND CONCLUSIONS The results of recent microbial and soil gas surveys in Venezuela, Colombia, and Peru document the value of hydrocarbon microseepage data for high-grading prospects and aiding firld development projects. These surveys were conducted in the Eastern Venezuela basin, the Maracaibo-Catatumba basin in western Venezuela, the Guajira and Cesar Rancheria basins in northern Colombia, the Middle Magdalena Valley basin in central Colombia, and the Lancones basin in Peru. Results from the underexplored Lancones basin identified structures that warrant additional study due to strong hydrocarbon indications. The Guajira survey documented previously unrecognized oil potential in a basin known only for its biogenic dry gas. Results from eastern Venezuela and Cesar Rancheria successfully discriminated prospects on basis of probably hydrocarbon charge. Surveys over two old oil fields in western Venezuela and in the Middle Magdalena Valley identified bypassed pay and several new drilling opportunities. High-resolution microseepage surveys offer a flexible, low-risk and low-cost environmentally friendly technology that not only complements traditional geologic and seismic data, but adds value to such data. Properly integrated with other exploration data, their use has led to discovery of new reserves and drilling fewer dry or marginal wells. SELECTED REFERENCES Klusman, R.W., 2002, The interpretation and display of surface geochemical data, in D. Schumacher and L.A. LeSchack, eds., Surface Exploration Case Histories: AAPG Studies in Geology No. 48, and SEG, Geophysical Reference Series No. 11, p. 1-24. Lopez, J.P., D.C. Hitzman, and J. Tucker, 1994, Combined microbial, seismic surveys predict oil and gas occurrence in Bolivia: Oil and Gas Journal, 24 October 1994, p. 67-69. Rice, G.K., J.Q. Belt Jr., and G.E. Berg, 2002, Soil-gas hydrocarbon pattern changes during a West Texas waterflood, in D. Schumacher and L.A. LeSchack, eds., Surface Exploration Case Histories: AAPG studies in Geology No. 48 and SG Geophysical Reference Series No. 11, p. 157-174. Schumacher, D., 1996, Hydrocarbon-induced alteration of soils and sediments, in D. Schumacher and M.A. Abrams, eds., Hydrocarbon Migration and its Near-Surface Expression: AAPG, Memoir 66, p. 71-89. Schumacher, D., 1999, Surface geochemical exploration for petroleum, in T. Beaumont and N. Foster, eds., Exploring for Oil and Gas Traps: AAPG, Treatise of Petroleum Geology Handbook, p. 18-1 to 18-27. Schumacher, D., 2010, Integrating hydrocarbon microseepage data with seismic data doubles exploration success: Proc. Indonesian Petroleum Association, 34th Annual Conference, IPA-10-G104, 11pp. Schumacher D., and M.A. Abrams, edgs., 1996, Hydrocarbon Migration and its Near-Surface Expression: AAPG, Memoir 66, 445 pp. Schumacher, D., and L.A. LeSchack, eds., 2002, Surface Exploration Case Histories: Applications of geochemistry, magnetic, and remote sensing: AAPG Studies in Geology No. 48 and SG Geophysical Reference Series No. 11, 486 pp. Tucker, J., and D.C. Hitzman, 1994, Detailed microbial surveys help improve reservoir characterization: Oil and Gas Journal, V. 92, no. 23, p. 6568. ACKNOWLEDGMENTS I would like to thank the members of Geo-Microbial Technologies (GMT) and GMT International who participated in these surveys, and the exploration companies who have allowed us to show these survey results. Special thanks are due Mc. Lesta Morrison for preparing these poster panels. PANEL 5
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