SL Topic 9 : Redox processes Foreachquestionchoosetheansweryouconsidertobethebest. 1.Whichiscorrectstatementaboutreduction? A.Itinvolvesthelossofhydrogen. B.Itinvolvestheadditionofoxygen. C.Itinvolvestheadditionofelectrons. D.Itinvolvesanincreaseinoxidationnumber. 2.Inwhichspeciesdoesmanganesehaveanoxidationstateof+3? A.MnSO4 B.KMnO4 C.Mn2O3 D.MnO2 3.WhatisthecorrectnameforFeSO4? A.iron(II)sulfite B.iron(III)sulfite C.iron(II)sulfate D.iron(II)sulfide Dr Geoffrey Neuss, InThinking © http://www.thinkib.net/chemistry 1 4.WhatchangeoccurstovanadiumduringtheconversionofVO3–(aq)toVO2+? A.Itundergoesreductionanditsoxidationstatechangesfrom+5to+4. B.Itundergoesreductionanditsoxidationstatechangesfrom+3to+2 C.Itundergoesoxidationanditsoxidationstatechangesfrom–1to+2 D.Itundergoesoxidationanditsoxidationstatechangesfrom+6to+2 5.Whataretheoxidationstatesoftheelementsinsulfuricacid,H2SO4? hydrogen sulfur oxygen A. +2 +6 -8 B. +1 +6 -2 C. +1 -2 -2 D. +1 -2 0 6.Whicharecorrectstatements? I.TheoxidationstateofoxygeninH2O2is–1 II.TheoxidationstateofnitrogeninN2H4is–2 III.TheoxidationstateofhydrogeninMgH2is–1 A.IandIIonly B.IandIIIonly C.IIandIIIonly D.I,IIandIII Dr Geoffrey Neuss, InThinking © http://www.thinkib.net/chemistry 2 7.Whichchangeinvolvesnitrogenbeingoxidized? A.N2H4→NH2– B.NO2→N2O4 C.NO3–→N2O5 D.N2O→NO 8.Whichiscorrectaboutthefollowingreaction? 2I–(aq)+Cl2(aq)→I2(aq)+2Cl–(aq) A.I–(aq)gainselectronsandisreduced. B.Cl2(aq)loseselectronsandisreduced. C.I–(aq)loseselectronsandisoxidized. D.Cl2(aq)gainselectronsandisoxidized. 9.Whichchangesareexamplesofreduction? I.Cu2+→Cu+ II.NH3→N2 III.MnO4–→MnO2 A.IandIIonly B.IandIIIonly C.IIandIIIonly D.I,IIandIII Dr Geoffrey Neuss, InThinking © http://www.thinkib.net/chemistry 3 10.Whichisthecorrectorderofthedecreasingoxidisingabilityofthegroup17elements (strongestoxidizingagentfirst)? A.F2>Cl2>Br2>I2 B.Cl2>Br2>I2>F2 C.I2>Br2>Cl2>F2 D.F2>I2>Br2>Cl2 11.Whichreactionisnotaredoxreaction? A.H2S(g)+Cl2(aq) 2HCl(aq)+S(s) B.Zn(s)+2HCl(aq) ZnCl2(aq)+H2(g) C.Ag+(aq)+Cl–(aq) AgCl(s) D.3H2(g)+N2(g) 2NH3(g) 12.Inwhichreactionsarecarbonatomsoxidized? I.C2H5OH→CH3CHO+2H++2e– II.C2H4+Br2→C2H4Br2 III.C2H5Br+OH–→C2H5OH+Br– A.IandIIonly B.IandIIIonly C.IIandIIIonly D.I,IIandIII Dr Geoffrey Neuss, InThinking © http://www.thinkib.net/chemistry 4 13.WhatisthecoefficientforH+(aq)whentheredoxequationbelowisbalanced? MnO4–(aq)+Fe2+(aq)+H+(aq)→Mn2+(aq)+Fe3+(aq)+H2O(l) A.2 B.4 C.5 D.8 14.Whichisthecorrectcombinationofstatementsforthefollowingreaction? Cr2O72–(aq)+3H2O2(l)+8H+(aq)→2Cr3+(aq)+3O2+7H2O(l) species undergoes actsas Cr2O72-(aq) oxidation oxidizingagent B. H2O2(l) oxidation reducingagent C. H2O2(l) reduction oxidizingagent D. Cr2O72-(aq) reduction reducingagent A. 15.Avoltaiccellisconstructedfromahalf-cellconsistingofapieceofironinasolutionof iron(II)ionsconnectedtoahalf-cellconsistingofapieceofcopperinasolutionof copper(II)ions.Ironismorereactivethancopper.Whichstatementiscorrect? A.Ironatomsloseelectrons. B.Electronsflowfromthecopperhalf-celltotheironhalf-cell. C.Themassofthenegativeelectrodeincreases. D.TheconcentrationofCu2+(aq)ionsincreases. Dr Geoffrey Neuss, InThinking © http://www.thinkib.net/chemistry 5 16.Considerthefollowingreactionswhichalloccurinsolutionatroomtemperature. Fe(s)+Cu2+(aq)→Fe2++Cu(s) Mg(s)+Zn2+(aq)→Mg2++Zn(s) Zn(s)+Fe2+(aq)→Zn2++Fe(s) Whichisthecorrectcombinationofthestrongestoxidizingagentandthestrongest reducingagent? strongestoxidizingagent strongestreducingagent Zn(s) Fe2+(aq) B. Cu2+(aq) Mg(s) C. Mg(s) Cu2+(aq) D. Cu(s) Mg2+(aq) A. 17.Whatprocessoccursatthepositiveelectrodeinavoltaiccellandinanelectrolyticcell? voltaiccell electrolyticcell A. oxidation reduction B. oxidation oxidation C. reduction oxidation D. reduction reduction Dr Geoffrey Neuss, InThinking © http://www.thinkib.net/chemistry 6 18.Whichoccurduringtheelectrolysisofmoltensodiumchloride? I.Chlorinegasformsatthepositiveelectrode II.Electronsflowthroughthemoltenliquid III.Reductionoccursatthenegativeelectrode A.IandIIonly B.IandIIIonly C.IIandIIIonly D.I,IIandIII 19.Whicharecorrectstatementsaboutcells? I.Electrolyticcellscontainasaltbridge II.Inavoltaiccellelectronsareproducedatthenegativeelectrode III.Inanelectrolyticcellcationsacceptelectronsatthenegativeelectrode A.IandIIonly B.IandIIIonly C.IIandIIIonly D.I,IIandIII Dr Geoffrey Neuss, InThinking © http://www.thinkib.net/chemistry 7 20.Whichstatementiscorrectabouthowcurrentisconductedinanelectrolyticcell? A.Electronsmovethroughtheelectrolyteandtheexternalcircuit. B.Ionsmovethroughtheelectrolyteandthroughtheexternalcircuit. C.Ionsmovethroughthesaltbridgeandelectronsmovethroughtheexternalcircuit. D.Ionsmovethroughtheelectrolyteandelectronsmovethroughtheexternalcircuit. Dr Geoffrey Neuss, InThinking © http://www.thinkib.net/chemistry 8
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