Non-metallic Resources: Washington's most important minerals Crushed stone Sand and gravel (per person per year) Aggregate: 7905 crushed stone 6658 lbs sand and gravel 659 lbs cement 375 lbs clay 383 lbs salt 365 lbs phosphate Clay Rock types: Igneous Rock types: Igneous • Form from the solidification and crystallization of -magma (molten rock below ground) -lava (molten rock above ground) Mafic minerals Felsic minerals Contain iron and magnesium No iron or magnesium • Most common examples -Basalt -Granite (1000 °C) Bowen’s reaction series: arranged by temperature of formation (600° C) http://csmres.jmu.edu/geollab/fichter/IgnRx/Introigrx.html http://csmres.jmu.edu/geollab/fichter/IgnRx/Introigrx.html Rock types: Sedimentary Rock types: Sedimentary • Loose, unconsolidated accumulation of minerals or rocks • Clastic rocks: compounds weather, do not dissolve in water • Sedimentary processes -weathering -transportation/sorting -deposition -compaction and cementation into solid rock Clay minerals Iron oxides Na, Ca ions Sand http://geology.csupomona.edu/drjessey/class/Gsc101/Weathering.html http://csmres.jmu.edu/geollab/fichter/IgnRx/Introigrx.html 1 Rock types: Sedimentary Rock types: Sedimentary • Clastic rocks: compounds weather, do not dissolve in water • Classified by 1. Grain size 2. Composition - Quartz, feldspar, lithic fragments, fine-grained matrix • Clastic rocks: compounds weather, do not dissolve in water • Classified by 1. Grain size 2. Composition - Quartz, feldspar, lithic fragments, fine-grained matrix Sandstone (quartz sand) (angular particles) Breccia Shale (clay) (rounded particles) Conglomerate http://csmres.jmu.edu/geollab/fichter/IgnRx/Introigrx.html http://csmres.jmu.edu/geollab/fichter/IgnRx/Introigrx.html Rock types: Sedimentary Rock types: Sedimentary • Compounds that weather and dissolve in water form: • Compounds that weather and dissolve in water form: Chemical rocks Precipitate directly from seawater Chemical rocks Precipitate directly from seawater Biochemical rocks Plant or animal derived Biochemical rocks Plant or animal derived Clay minerals Iron oxides Na, Ca ions Sand http://csmres.jmu.edu/geollab/fichter/IgnRx/Introigrx.html http://csmres.jmu.edu/geollab/fichter/IgnRx/Introigrx.html Rock types: Sedimentary Rock types: Sedimentary • Compounds that weather and dissolve in water form: • Compounds that weather and dissolve in water form: • Carbonates (CaCO3 ) Chemical rocks Precipitate directly from seawater Chemical rocks Precipitate directly from seawater Biochemical rocks Plant or animal derived Oolitic limestone (CaCO3) http://csmres.jmu.edu/geollab/fichter/IgnRx/Introigrx.html Dolomite crystals: CaMg(CO3)2 http://csmres.jmu.edu/geollab/fichter/IgnRx/Introigrx.html 2 Rock types: Sedimentary Rock types: Sedimentary • Compounds that weather and dissolve in seawater will eventually form: Silicate • Compounds that weather and dissolve in seawater will eventually form: Salts Chemical rocks Precipitate directly from seawater Chert (SiO2) Chemical rocks Precipitate directly from seawater Halite (NaCl) http://csmres.jmu.edu/geollab/fichter/IgnRx/Introigrx.html Gypsum (CaSO4 H 2O) http://csmres.jmu.edu/geollab/fichter/IgnRx/Introigrx.html Rock types: Sedimentary Rock types: Sedimentary • Compounds that weather and dissolve in seawater will eventually form: Carbonates (CaCO3) • Compounds that weather and dissolve in seawater will eventually form: Accumulation of plant material Peat Biochemical rocks Plant or animal derived Fossiliferous rock (coquina) Chalk Coal http://csmres.jmu.edu/geollab/fichter/IgnRx/Introigrx.html Sedimentary environments Biochemical rocks Plant or animal derived http://csmres.jmu.edu/geollab/fichter/IgnRx/Introigrx.html Sedimentary environments Alluvial fans http://pages.uoregon.edu/millerm/fan.html http://explanet.info/Chapter02.htm 3 Sedimentary environments Sedimentary environments Eolian Beach Wind sorted sand and dust Typically well-sorted sand at beaches along calm coasts http://members.cox.net/theuniverse/landscape/so_cal_sand_dunes.html http://www.aloha.com/~lifeguards/bech_dir.html Sedimentary environments Sedimentary environments Tidal flats Glacial Typically fine silt and mud Poorly sorted angular boulders, gravel, sand, silt http://www.ask.com/wiki/Coastline_of_the_North_Sea Sedimentary environments http://pubs.usgs.gov/of/2004/1216/tz/tz.html Sedimentary environments Fluvial (rivers) Delta Great deal of deposition Sand along river beds Clay within swamps http://www.azgfd.gov/w_c/mudturtlemanagement.shtml Accumulation of sediment at the mouth of a river Typically a thick accumulation of silt, mud and sand http://www.solarviews.com/cap/earth/sediment.htm 4 Sedimentary environments Sedimentary environments Reef Solid structure of shells/coral Highly fossilierous limestone Shallow marine Well-sorted sand, clay and limestone Often in layers based on sea level changes Deep marine Fine grained sediments eroded from land http://www.wallpaperpimper.com Sedimentary rock samples Non-metallic Resources: (per person per year) Aggregate: 7905 crushed stone 6658 lbs sand and gravel tons per home } ~300 25,000 tons per mile of road 659 lbs cement 375 lbs clay 383 lbs salt 365 lbs phosphate Sedimentary rocks: sand Sedimentary rocks: cement • Weather resistant minerals -Quartz (SiO2 ) -Garnet (X3Y2Si3O12) -Pyrope (Mg3 Al2 Si3O12) -Almandine (Fe3Al2Si3O 12) -Spessartine (Mn3 Al2 Si3 O12) -Andradite (Ca3Fe2Si3O12) -Grossular (Ca3Al2Si3O12) -Uvarovite (Ca3Cr2Si3O12) -Rutile (TiO2) -Ruby (Al2O3 with chromium) -Sapphire (Al2O3) -Zircon (ZrSiO4 ) • Cement raw materials -85% limestone (CaCO3) -15% clay • Heated • Ground into a powder http://www.lanemt.com/golf.htm, http://www.urlesque.com/2009/08/20/animal-shaped-sand-sculptures-are-just-beachy/ • Concrete -70% aggregates (sand, gravel) -15% cement -15% water, sand and gravel to make concrete Paul Schroeder 5 Sedimentary rocks: sand and gravel uses Sedimentary rocks: sand and gravel uses • Construction • Concrete • Road construction • Railroad ballast • Mixing with asphalt • Construction fill • Bricks • Pipes • Roof shingles • Glass & refractory materials • Foundry sand (metal casting) • Abrasive -Sandblasting -Traction on icy roads and railways • Erosion control and water filtration • Computer chips • Day-to-day sand and gravel uses? http://www.foundry101.com/, http://en.wikipedia.org/wiki/Asphalt, http://www.cement.org/basics/concretebasics_concretebasics.asp Sedimentary rocks: clay uses Sedimentary rocks: clay • Day-to-day clay uses? • Ball clay -Pottery -Floor and wall tiles • Bentonite -Pet litter •Common clay -Bricks, cement Kaolinite (Al2Si2O5(OH)4) •Fire clay - Refractory products (heat resistant) •Fuller’s earth -Absorbent material -Pesticides •Kaolin -Paper coating -Porcelain http://www.purapet.com/premium-clumping-cat-litter.htm Sand mining Sand mining • Where do you find sand & gravel? • Where do you find sand & gravel? -River channels -River flood plains -Glacial deposits http://minerals.usgs.gov/minerals/pubs/mapdata/ http://www.geo.msu.edu/geogmich/sand.html 6 Sand mining Mining: sand, cement, clay and crushed stone • Where do you find sand & gravel? -River channels -River flood plains -Glacial deposits • Sand - Mined in all 50 states - 1 billion tons annually - US is the world’s leading exporter of sand - 52% : CA, TX, MI, OH, AZ, CO, WA, UT - 600 active facilities in WA state • Cement (limestone and clay) - Mined in 2/3 of US states - US produces 90 million tons/year - 50% : CA, TX, PN, MI, MO, AL - 20% imported http://quarriesandbeyond.org/articles_and_books/orewashstruct/orewashstruct.html Mining: sand, cement, clay and crushed stone Surface mine Washing Mining: sand, cement, clay and crushed stone Surface mine: GA kaolin mines Mine dewatering http://www.georgiaencyclopedia.org/nge/Article.jsp?id=h-1178 Mining: sand, cement, clay and crushed stone Crushed stone quarry, granitic material Raleigh, NC Lane Mountain Company 3119 Highway 231, valley, WA (50 miles north of Spokane) Mining: sand, cement, clay and crushed stone drill is preparing holes to hold explosives conveyer assembly carries rock to the sizing plant water truck sprays water on rock that was recently broken by the explosives. The water spray helps reduce dust. 40 foot mining bench diesel-powered 50-toncapacity haul trucks http://www.geology.enr.state.nc.us Crushing Feed opening of the 48 inch by 60 inch jaw crusher Primary crusher -- rocks up to 5 feet by 4 feet by 4 feet are crushed to 8 inches in diameter or less. Water spray reduces dust. http://www.geology.enr.state.nc.us 7 Mining: sand, cement, clay and crushed stone King Creek Pit Environmental impacts? Kapowsin Quarry Sorting http://www.wa-rock.com/ Environmental impacts Source: http://www.ecy.wa.gov/programs/wq/sand/sghearing2010.pdf Environmental impacts • High pH in concrete wash water - discharge limits between 6.5-8.5 • Turbidity • limited to 50 NTU • Erosion and sedimentation (total suspended solids) • limit for sand mines 25 mg/l • limit for crushed stone 40 mg/l Source: http://www.ecy.wa.gov/programs/wq/sand/sghearing2010.pdf Environmental impacts Source: http://www.ecy.wa.gov/programs/wq/sand/sghearing2010.pdf Environmental impacts • Temperature • over 300 WA rivers have increased temperatures • often not from sand and gravel mines… • local waters monitored for temperature changes Source: http://www.ecy.wa.gov/programs/wq/sand/sghearing2010.pdf • Oil and grease from equipment in water runoff • limited to “no visible sheen” Source: http://www.ecy.wa.gov/programs/wq/sand/sghearing2010.pdf 8 Environmental impacts Environmental impacts: Maury Island • Federal regulation • Clean Water Act (1972) • National Pollutant Discharge Elimination System • WA State Dept. of Ecology regulation • Sand and Gravel general permit • State Waste Discharge Permit • Gravel mine 1968-1978 • Four gravel mines on the southeast shore of Maury Island • Barges loaded to supply regional construction projects •1.5 – 2 million tons sand & gravel extracted per year • Process animation: http://mauryislandmine.com/Process.aspx Source: http://www.ecy.wa.gov/programs/wq/sand/sghearing2010.pdf Environmental impacts http://mauryislandmine.com/Process.aspx Salt • US and China are largest salt producers • Production at 50 million metric tons/yr • Worth $1 billion in sales revenue • Potential issues •Disruptions of land •Arsenic on site and in eelgrass beds from Tacoma smelter •Dock would shade eelgrass •Disruption of juvenile chinook salmon in eelgrass • Protection of site funded by ASARCO settlement •$111 million to WA to clean up Tacoma smelter Salt formation Salt: production methods • Bedded deposits -dry lakes, marine • Salt domes 1. Solar evaporation “sea salt” -shallow ponds -1-5 years Cargill solar evaporation, San Francisco Bay Artificial ponds cover some 43,000 acres on the shores of the Great Salt Lake Sea salt harvesting in Thailand http://web.ead.anl.gov/saltcaverns/usdeposit/index.htm http://www.virtualweberbullet.com/salt.html, http://wapedia.mobi/en/Salt, http://www.bbc.co.uk/news/10118848 9 Salt: production methods 2. Solution mining “vacuum pan salt” or “refined salt” -500-5000’ below ground -Solution mining -Freshwater forced down shafts, dissolving salt -Brine is pumped to surface -Water evaporated at high pressure http://www.saltinstitute.org/Production-industry/Production-technologies/Evaporated-salt-refined-salt/Vacuum-pan-refining Salt: production methods 3. Shaft mining “rock salt” -Miles underground -Explosives create fractures in mine face -Salt is crushed and brought to surface https://www.americanrocksalt.com/about.asp Salt: mines 10
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