Code: FDS-01 SAFETY DATA SHEET According Regulation (EC) 1907/2006 Page 1 / 9 Revision Nº: 14 Date: 2016/05/04 ZINC OXIDE Supersedes Rev. Nº:13 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name: Zinc oxide Description: Not available Synonyms: Zinc white, flowers of zinc, philosopher’s wool Index- No: 030-013-00-7 CAS-No: 1314-13-2 EC-No: 215-222-5 REACH Registration- No: 01-2119463881-32-0028 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Colouring agents, pigments Food/feedstuff additives Fuels and fuel additives Intermediates Laboratory chemicals Lubricants and lubricant additives Plating agents and metal surface treating agents Process regulators, other than polymerisation or vulcanisation processes component in batteries Corrosion inhibitors and anti-scaling agents Fertilisers Pharmaceutical substance Photosensitive agents and other photo-chemicals Process regulators, used in vulcanisation or polymerisation processes Processing aid, not otherwise listed Semiconductors See section 16 for a complete list of uses for which a Generic Exposure Scenario (GES) is provided as annex 1.2.2. Uses advised against No uses advised against has been identified 1.3. Details of the supplier of the safety data sheet Asturiana de Zinc, S.A.U. 33417-San Juan de Nieva, Castrillón ASTURIAS-ESPAÑA +34 985 128 100 [email protected] 1.4. Emergency telephone number Phone (24h): +34 985 128 100 Single emergency telephone number inside the EU: 112 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Category Acute aquatic toxicity, category 1 Chronic aquatic toxicity, category 1 Hazards statements H400: Very toxic to aquatic life H410: Very toxic to aquatic life with long lasting effects. 2.2. Label elements Hazard pictograms Signal word: Warning Hazard statements: H410: Very toxic to aquatic life with long lasting effects. Precautionary statements: P273: Avoid release to the environment P391: Collect spillage. P501: Dispose of contents/container to hazardous waste. This document is the property of Asturiana de Zinc, S.A.U Reproduction in whole or in part without written consent is not permitted. The information contained in this Product Safety Data Sheet is based on our current knowledge and does not represent a warranty of the properties described herein. The receiver of our product should observe, at his own responsibility, the applying rules and regulations. Only the electronic version is a controlled document, so that a paper copy is considered outdated. F-PG-001-13 Code: FDS-01 SAFETY DATA SHEET According Regulation (EC) 1907/2006 ZINC OXIDE Page 2 / 9 Revision Nº: 14 Date: 2016/05/04 Supersedes Rev. Nº:13 2.3. Other hazards No data available SECTION 3: Composition/information on ingredients Content Name EC No. (%) Zinc oxide 99.8 % min 215-222-5 Lead oxide as Pb 0.005 % max 231-100-4 Cadmium oxide as Cd * 0.003 % max 231-152-8 Iron oxide as Fe** 0.001 % max 231-096-4 Copper oxide as Cu 0.001 % max 231-159-6 CAS No. Index No. 1314-13-2 7439-92-1 7440-43-9 7439-89-6 7440-50-8 030-013-00-7 082-001-00-6 048-002-00-0 - (*) Cadmium content for Zinc Oxide of Pharmaceutical Grade: 0.001 % max. (**) Iron content for Zinc Oxide of Pharmaceutical Grade: 0.020 % max. Contains no other components or impurities that will influence the classification of the product. SECTION 4: First aid measures 4.1. Description of first aid measures 4.1.1. General information First aider needs to protect himself. In the case of loss of conscience, do neither give water to drink nor provoke vomit 4.1.2. Following inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Zinc oxide may cause irritation to the respiratory tract. Symptoms may include coughing and shortness of breath. Inhalation can cause a flu-like illness (metal fume fever). This 24- to 48-hour illness is characterized by chills, fever, aching muscles, dryness in the mouth and throat and headache. 4.1.3. Following skin contact In case of contact, flush skin with water. Wash clothing before reuse. Call a physician if irritation occurs. 4.1.4. Following eye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. 4.1.5. Following ingestion Large oral doses may cause irritation to the gastrointestinal tract. If swallowed, call a physician. 4.2. Most important symptoms and effects, both acute and delayed Possibility of metal fume fever: delayed, transient, generally benign, flu-like condition. 4.3. Indication of any immediate medical attention and special treatment needed No data available SECTION 5: Fire-fighting measures 5.1. Extinguishing media 5.1.1. Suitable extinguishing media Non combustible. Use extinguishing media appropriate to surrounding fire conditions. 5.1.2. Unsuitable extinguishing media Not identified 5.2. Special hazards arising from the substance or mixture May liberate hazardous vapors/ fumes under fire conditions. 5.3. Advice for fire-fighters Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid inhalation of dusts 6.2. Environmental precautions Prevent contamination of soil, water and drain systems. This document is the property of Asturiana de Zinc, S.A.U Reproduction in whole or in part without written consent is not permitted. The information contained in this Product Safety Data Sheet is based on our current knowledge and does not represent a warranty of the properties described herein. The receiver of our product should observe, at his own responsibility, the applying rules and regulations. Only the electronic version is a controlled document, so that a paper copy is considered outdated. F-PG-001-13 Code: FDS-01 SAFETY DATA SHEET According Regulation (EC) 1907/2006 ZINC OXIDE Page 3 / 9 Revision Nº: 14 Date: 2016/05/04 Supersedes Rev. Nº:13 6.3. Methods and material for containment and cleaning up Clean spills in a manner that does not disperse dust into the air. Forward for disposal. 6.4. Reference to other sections Please refer to section 8 and 13 for more information SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid breathing dust. Avoid getting in eyes or on skin. Wash thoroughly after handling 7.2. Conditions for safe storage, including any incompatibilities Store at ambient temperature, in a dry place away from direct sunlight, heat and incompatible materials (see Section 10). Tightly closed container. Reseal containers immediately after use. Store away from food and beverages. 7.3. Specific end use(s) No data available SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits: Zinc Oxide [1314-13-2]: VLA-ED® mg /m3 (INSHT): 2 resp. frac. VLA-EC® mg/m3 (INSHT): 10 resp. frac. The DNEL for inhalation derived under REACH for insoluble Zn compounds (Inhalable fraction – Workers) is 5 mg Zn/m3 8.2. Exposure controls Please refer to exposure assessment annex for appropriate engineering controls. a. Respiratory protection Required when dusts are generated. Recommended filter type: P2 b. Hand protection Glove material: nitrile rubber. Penetration time for the glove material can vary with the gloves thickness, usage and exposure. Ensure that the glove is intact, without holes or tears. c. Eye protection Safety glasses. Close-fitting safety goggles may be necessary in some circumstances to prevent eye contact with dust. d. Skin protection Protective clothing e. Hygiene measures Do not inhale the substance. Change contaminated clothing. f. Environmental exposure controls Use adequate local or general ventilation to maintain the concentration of dust in the working environment well below recommended occupational exposure limits. Supply sufficient replacement air to make up for air removed by the exhaust system. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties 9.1.1. Appearance Physical state. Solid (powder) Colour: White to yellowish white powder Odour: Odourless 9.1.2. Safety relevant basic data pH (@20ºC): not applicable Melting point: ZnO is very stable. No melting occurs. No exothermic or endothermic peaks are observed. No oxidation or decomposition was observed Boiling point/boiling range: Not relevant; the sample decomposes before boiling Vapor pressure: 12 mm @ 1500 ºC Density: 5.607 g/cm3 Relative vapor density (air=1): no data available Evaporation rate: no data available Water solubility (@ 20ºC): practically insoluble This document is the property of Asturiana de Zinc, S.A.U Reproduction in whole or in part without written consent is not permitted. The information contained in this Product Safety Data Sheet is based on our current knowledge and does not represent a warranty of the properties described herein. The receiver of our product should observe, at his own responsibility, the applying rules and regulations. Only the electronic version is a controlled document, so that a paper copy is considered outdated. F-PG-001-13 Code: FDS-01 SAFETY DATA SHEET According Regulation (EC) 1907/2006 Page 4 / 9 Revision Nº: 14 Date: 2016/05/04 ZINC OXIDE Supersedes Rev. Nº:13 Partition coefficient n-octanol/water (log value): not applicable Flash point: not applicable Flammability: not flammable Autoflammability temperature: not applicable Explosive properties: not explosive Oxidizing properties: not oxidizing 9.2. Other information No data available SECTION 10: Stability and reactivity 10.1. Reactivity Intimate mixtures of chlorinated rubber and zinc oxide in the presence or absence of hydrocarbon or halocarbon solvents react violently or explosively at about 216 ºC. Zinc oxide and magnesium metal fillings or powder can react violently when heated. Please verify technical documentation to determine any incompatibilities with your own process. 10.2. Chemical stability The material is stable under normal conditions 10.3. Possibility of hazardous reactions Violent reactions possible with: hydrogen peroxide, magnesium 10.4. Conditions to avoid Excessive temperature 10.5. Incompatible materials See 10.1. This list of products is not exhaustive: please verify technical documents to determine any incompatibilities with your process. 10.6. Hazardous decomposition products No information available SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity: Product/ingredient name Result Zinc oxide LC50 Inhalation Dusts and mists Zinc oxide LD50 Oral Zinc oxide LD50 Oral Species Rat Dose >5.7 mg/L Exposure 4 hours Rat Rat 15000 mg/kg >5000 mg/kg NA NA Skin irritation (IUCLID): Species: rabbit, result: not irritation Eye irritation (IUCLID): Species: rabbit, result: highly irritating Sensitization (IUCLID): Patch-test, human, result: negative Genetic toxicity: based on the available data there is insufficient ground to classify zinc oxide as genotoxic (RAR) “in vitro” (IUCLID): Ames test, S. Typhimurium, result: negative Mouse lymphoma assay, result: positive “in vivo” (IUCLID): Cytogenetic assay, rat, chronic inhalation, 0.1-0.5 mg/m3, result: increase of chromosomal aberrations in bone narrow cells. SECTION 12: Ecological information 12.1. Toxicity 12.1.1.Acute aquatic toxicity The Acute aquatic toxicity database on zinc contains data on 11 standard species obtained under standard testing conditions at different pH and hardness. Since the transformation/dissolution of zinc metal is dependent on pH, the available acute aquatic toxicity dataset has also been considered for 2 different pH ranges separately. The full analysis of these data is given in the CSR. This document is the property of Asturiana de Zinc, S.A.U Reproduction in whole or in part without written consent is not permitted. The information contained in this Product Safety Data Sheet is based on our current knowledge and does not represent a warranty of the properties described herein. The receiver of our product should observe, at his own responsibility, the applying rules and regulations. Only the electronic version is a controlled document, so that a paper copy is considered outdated. F-PG-001-13 Code: FDS-01 SAFETY DATA SHEET According Regulation (EC) 1907/2006 ZINC OXIDE Page 5 / 9 Revision Nº: 14 Date: 2016/05/04 Supersedes Rev. Nº:13 The reference values for acute aquatic toxicity, based on the lowest observed EC50 values of the corresponding databases at different pH and expressed as Zn+2 ion concentration are: for pH <7: 0.413 mg Zn+2/L (48 hr - Ceriodaphnia dubia test according to US EPA 821-R-02-012 standard test protocol) for pH >7-8.5: 0.136 mg Zn+2/L (72 hr - Selenastrum capricornutum (=Pseudokircherniella subcapitata) test according to OECD 201 standard protocol) As demonstrated by transformation/dissolution (T/D) testing according to OECD guidelines, zinc oxide is less soluble, as compared to soluble zinc compounds. Applying the molecular weight correction and the results of the T/D testing (CSR), the specific reference values for acute aquatic toxicity of zinc oxide are: For zinc oxide (based on 62% solubilisation capacity on finest powders at most conservative loading of 1 mg/L at pH 8 (RA zinc oxide, ECB 2008), and a ZnO/Zn molecular weight ratio of 1.24): for pH <7: 0.83 mg Zn/L (based on 48 hr Ceriodaphnia dubia test cfr above) for pH >7-8.5: 0.27 mg Zn/L (based on 72 hr Selenastrum capricornutum test cfr above) 12.1.2. Chronic aquatic toxicity: freshwater The chronic aquatic toxicity database on zinc contains high quality chronic NOEC/EC10 values on 23 species (8 taxonomic groups) obtained under a variety of conditions. These data, outlined in the CSR, were compiled in a species sensitivity distribution, from which the PNEC was derived (expressed as Zn +2ion concentration). This PNEC is an added value, i.e. it is to be added to the zinc background in water, see table below. 12.1.3. Chronic aquatic toxicity: marine waters The chronic aquatic toxicity database on zinc contains high quality chronic NOEC/EC10 values on 39 species (9 taxonomic groups) obtained under a variety of conditions. These data, outlined in the CSR, were compiled in a species sensitivity distribution, from which the PNEC was derived (expressed as Zn +2ion concentration). This PNEC is an added value, to be added on the zinc background in water, see table below. 12.1.4. Sediment toxicity The chronic toxicity of zinc to sediment organisms in the freshwater was assessed based on a database containing high quality chronic NOEC/EC10 values on 7 benthic species obtained under a variety of conditions. These data, outlined in the CSR, were compiled in a species sensitivity distribution, from which the PNEC was derived (expressed as total Zn contained in the sediment). This PNEC is an added value, to be added on the zinc background in the sediment, see table below. For the marine sediments, a PNEC was derived using the equilibrium partitioning approach, see table below. 12.1.5. Soil toxicity The chronic toxicity of zinc to soil organisms was assessed based on a database containing high quality chronic NOEC/EC10 values on 18 plant species, 8 invertebrate species and 17 microbioal processes, obtained under a variety of conditions. These data, outlined in the CSR, were compiled in a species sensitivity distribution, from which the PNEC was derived (expressed as total Zn contained in the soil). This PNEC is an added value, to be added on the zinc background in the soil, see table below. 12.1.6. Toxicity to micro-organisms in STP The PNEC for STP was derived by applying an assessment factor to the lowest relevant toxicity value: 5.2mg Zn/L Environmental compartment Freshwater Saltwater PNEC value for Zn 20.6* µg/L 6.1* µg/L Freshwater sediment Saltwater sediment Soil STP 235.6 mg/kg sediment dry weight**. 113 mg/kg sediment dry weight** 106.8 mg/kg soil dry weight***. 52 µg/L *added value, « PNECadd » **A generic bioavailability factor of 0.5 is applied by default, according to the EU risk assessment (ECB 2008) *** A generic bioavailability/ageing factor of 3 is applied by default (ECB 2008). 12.2. Persistence and biodegradability Zinc is an element, and as such the criterion “persistence” is not relevant for the metal and its inorganic compounds in a way as it is applied to organic substances. An analysis on the removal of zinc from the water column has been presented as a surrogate for persistence. The rapid removal of zinc from the water column is documented in the CSR. So, zinc and zinc compounds do not meet this criterion, neither. 12.3. Bioaccumulative potential Zinc is a natural, essential element, which is needed for the optimal growth and development of all living organisms, This document is the property of Asturiana de Zinc, S.A.U Reproduction in whole or in part without written consent is not permitted. The information contained in this Product Safety Data Sheet is based on our current knowledge and does not represent a warranty of the properties described herein. The receiver of our product should observe, at his own responsibility, the applying rules and regulations. Only the electronic version is a controlled document, so that a paper copy is considered outdated. F-PG-001-13 Code: FDS-01 SAFETY DATA SHEET According Regulation (EC) 1907/2006 ZINC OXIDE Page 6 / 9 Revision Nº: 14 Date: 2016/05/04 Supersedes Rev. Nº:13 including man. All living organisms have homeostasis mechanisms that actively regulate zinc uptake and absorption/excretion from the body; due to this regulation, zinc and zinc compounds do not bioaccumulate or biomagnify. 12.4. Mobility in soils For zinc (like for other metals) the transport and distribution over the different environmental compartments e.g. the water (dissolved fraction, fraction bound to suspended matter), soil (fraction bound or complexed to the soil particles, fraction in the soil pore water,...) is described and quantified by the metal partition coefficients between these different fractions. In the CSR, a solids-water partitioning coefficient of 158.5 l/kg (log value 2.2) was applied for zinc in soils (CSR zinc 2010). 12.5. Results of PBT and vPvB assessment Considering the items 12.2. and 12.3. above, zinc and zinc compounds are not PBT or vPvB. 12.6. Other adverse effects No data available SECTION 13: Disposal considerations 13.1. Waste treatment methods 13.1.1. Product/packaging disposal Waste should be recycled. Waste codes/waste designations according to EWC/AVV: EWC code 10 05 04 wastes from zinc thermal metallurgy: other particulates and dust. Specification of the waste material number and EWC-code are for illustrative purposes only. Which waste catalogue number and code to use must be decided by the end user based on the actual use of the product. Contaminated containers and packaging of dangerous substances or preparations must be treated in the same manner as the actual products contained in them. Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste and repealing certain Directives. 2014/955/EU: Commission Decision of 18 December 2014 amending Decision 2000/532/EC on the list of waste pursuant to Directive 2008/98/EC of the European Parliament and of the Council Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 13.1.2. Waste treatment options On-site waste water treatment techniques can be applied to prevent releases to water e.g.: chemical precipitation, sedimentation and filtration SECTION 14: Transport information 14.1. UN number : 3077 14.2. UN proper shipping name: Environmentally Hazardous Substance, solid, N.O.S. (zinc oxide) 14.3. Transport hazard class(es): 9 14.4. Packing group: III 14.5. Environmental hazards: Marine Pollutant: Yes 14.6. Special precautions for user: Not applicable 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code The product is packaged so is out of the scope of Annex II of MARPOL73/78. SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture This substance is not listed in the Annex I of Regulation (EC) No 689/2008. COUNCIL DIRECTIVE 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related to chemical agents at work (fourteenth individual Directive within the meaning of Article 16(1) of Directive 89/391/EEC). Council Directive 94/33/EC of 22 June 1994 on the protection of young people at work. Disposal in accordance with local regulations. Seveso Substance: Yes Main Seveso Category: 9i Very toxic to aquatic organisms This document is the property of Asturiana de Zinc, S.A.U Reproduction in whole or in part without written consent is not permitted. The information contained in this Product Safety Data Sheet is based on our current knowledge and does not represent a warranty of the properties described herein. The receiver of our product should observe, at his own responsibility, the applying rules and regulations. Only the electronic version is a controlled document, so that a paper copy is considered outdated. F-PG-001-13 Code: FDS-01 SAFETY DATA SHEET According Regulation (EC) 1907/2006 ZINC OXIDE Page 7 / 9 Revision Nº: 14 Date: 2016/05/04 Supersedes Rev. Nº:13 15.2. Chemical safety assessment A Chemical safety assessment has been carried out SECTION 16: Other information 16.1 Indication of changes Format upgrade, section 3, 14.7 and 16.2 16.2 Key literature references and sources for data CHEMICAL SAFETY REPORT, zinc oxide IUCLID 5, Ed. 2000 Risk Assessment Report (RAR), Zinc oxide, Final report, May 2008 NIOSH Zinc Oxide RTECS#: ZH4810000, may 2009 Límites De Exposición Profesional Para Agentes Químicos En España, 2016. (INSHT). Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Commission Regulation (EC) No 790/2009 of 10 August 2009 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures 16.3 Classification for mixtures according to regulation (EC) 1207/2008 [CLP] Classification based on a worst case sample, according to Classification procedure Regulation (EC) Nr. 1207/2009. 16.4 Further information List of uses for which a Generic Exposure Scenario (GES) is provided as annex: IU number Identified Use (IU) name GES code 1 Zinc oxide production-Direct GESZnO 0 2 Zinc oxide production-Indirect GESZnO 0 3 Zinc oxide production-Wet GESZnO 0 9 Component for production of inorganic zinc compounds GESZnO 2 10 Electrogalvanizing GESZnO 2 11 Electroplating GESZnO 2 12 Zinc production by electrowinning GESZnO 2 13 Laboratory reagent GESZnO 3 14 Zinc production by pyrometallurgy GESZnO 2 15 Zinc oxide production & refining GESZnO 0 16 Component for production of organic zinc compounds GESZnO 2 17 Component for production of Inorganic pigments GESZnO 1, GESZnO 4 18 Component for production of Coatings / paints, inks, enamels, GESZnO 1, GESZnO 4 varnishes 19 Use of ZnO-containing paints & coatings GESZnO 7 20 Artists supply: Use of ZnO-containing paints & coatings Generic consumer/environment* 21 Component for Paper coating GESZnO 1, GESZnO 5 22 Use of ZnO-containing paper coatings GESZnO 6 23 Component for Textile & leather coating / treatment GESZnO 1, GESZnO 5 24 Use of ZnO-containing textile & leather coatings GESZnO 6 25 Additive / component for production of ceramics GESZnO 1, GESZnO 4 26 Additive /component for production of frits GESZnO 1, GESZnO 4 27 Use of ZnO-containing glazes and glassy thin film coatings GESZnO 6 This document is the property of Asturiana de Zinc, S.A.U Reproduction in whole or in part without written consent is not permitted. The information contained in this Product Safety Data Sheet is based on our current knowledge and does not represent a warranty of the properties described herein. The receiver of our product should observe, at his own responsibility, the applying rules and regulations. Only the electronic version is a controlled document, so that a paper copy is considered outdated. F-PG-001-13 Code: FDS-01 SAFETY DATA SHEET According Regulation (EC) 1907/2006 Page 8 / 9 Revision Nº: 14 Date: 2016/05/04 ZINC OXIDE Supersedes Rev. Nº:13 28 Additive for the production of Friction agents GESZnO 1, GESZnO 4 29 Use of ZnO-containing friction agents: Brake pads GESZnO 6 30 Additive / component for production of glass GESZnO 1, GESZnO 4 31 Surface treatment of flat glass GESZnO 1, GESZnO 4 32 Use of ZnO-containing glass & ceramics in dinnerware GESZnO 6 33 Use of ZnO-containing glass in displays GESZnO 6 34 Use of ZnO-containing glassy thin film coatings GESZnO 6 35 Additive in the manufacturing of electronic components GESZnO 1, GESZnO 4 36 Additive in the manufacturing of ferrites GESZnO 1, GESZnO 4 37 Additive in the manufacturing of varistors GESZnO 1, GESZnO 4 38 ZnO in electrotechnical contact material GESZnO 1, GESZnO 4 39 Batteries/Fuel cells GESZnO 1, GESZnO 4, GESZnO 5 40 Component for production of rubber, resins and related GESZnO 1, GESZnO 5 preparations 41 Use of ZnO-containing rubber for tyres 42 Use of ZnO-containing rubber and other resins for medical devices GESZnO 7 and applications 43 Component for preparations 44 Use of ZnO-containing polymers for floor, wall coverings and GESZnO 7 similar preparations 45 Use of ZnO-containing polymers for cable protecting & isolating GESZnO 7 coatings 46 Use of ZnO-containing polymers for tube &sheet articles GESZnO 7 47 Use of ZnO-containing polymers for molded articles GESZnO 7 48 Use of ZnO-containing plastic thin films coatings Generic consumer/environment 49 Additive for the production of Sealants / Adhesives / Mastics GESZnO 1, GESZnO 5 50 Use of ZnO-containing Sealants / Adhesives / Mastics Generic consumer/environment 51 Additive for the production of Lubricants / Grease / Metal working GESZnO 1, GESZnO 5 fluids 52 Use of ZnO-containing Lubricants / Grease / Metal working fluids Generic consumer/environment 53 Additive for the production of Polishes / wax blends GESZnO 1, GESZnO 5 54 Use of ZnO-containing Polishes/ wax blends Generic consumer/environment 55 Use of ZnO-containing catalysts GESZnO 1, GESZnO 5 56 Use of ZnO-containing adsorbents GESZnO 1, GESZnO 5 57 Additive for production of de-icing products GESZnO 1, GESZnO 5 58 Use of ZnO-containing de-icing products Generic consumer/environment 59 Additive for ther production of pyrotechnic products GESZnO 1, GESZnO 4 60 Use of ZnO-containing pyrotechnic products Generic consumer/environment 61 Additive for the formulation of nutrition additives GESZnO 1, GESZnO 4, GESZnO 5 62 Additive for the formulation of animal feedstuffs GESZnO 1, GESZnO 4, GESZnO 5 63 Additive for the formulation of biocidal products GESZnO 1, GESZnO 4, GESZnO 5 64 Use of ZnO-containing biocidal products GESZnO 6, GESZnO 7, Generic consumer/environment 65 Additive for the formulation of cleaning products GESZnO 1, GESZnO 4, GESZnO 5 66 Use of ZnO-containing cleaning products GESZnO 6, GESZnO 7, Generic consumer/environment 67 Additive for the formulation of fertilizers GESZnO 1, GESZnO 4, GESZnO 5 polymer-matrices, GESZnO 7 plastics and related GESZnO 1, GESZnO 5 This document is the property of Asturiana de Zinc, S.A.U Reproduction in whole or in part without written consent is not permitted. The information contained in this Product Safety Data Sheet is based on our current knowledge and does not represent a warranty of the properties described herein. The receiver of our product should observe, at his own responsibility, the applying rules and regulations. Only the electronic version is a controlled document, so that a paper copy is considered outdated. F-PG-001-13 Code: FDS-01 SAFETY DATA SHEET According Regulation (EC) 1907/2006 Page 9 / 9 Revision Nº: 14 Date: 2016/05/04 ZINC OXIDE Supersedes Rev. Nº:13 68 Use of ZnO-containing fertilizer's formulations Generic consumer/environment 69 Additive in the formulation of cosmetics GESZnO 1, GESZnO 4, GESZnO 5 70 Use of cosmetics GESZnO 6, GESZnO 7, Generic consumer/environment 71 Additive in dentistry products GESZnO 1, GESZnO 4, GESZnO 5 72 Additive in the formulation of pharma / veterinary products GESZnO 1, GESZnO 4, GESZnO 5 73 Use of pharma / veterinary products GESZnO 6, GESZnO 7, Generic consumer/environment End of safety data sheet This document is the property of Asturiana de Zinc, S.A.U Reproduction in whole or in part without written consent is not permitted. The information contained in this Product Safety Data Sheet is based on our current knowledge and does not represent a warranty of the properties described herein. The receiver of our product should observe, at his own responsibility, the applying rules and regulations. Only the electronic version is a controlled document, so that a paper copy is considered outdated. F-PG-001-13
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